1ST YEAR(PRAJWAL-1) 19.12.

2020

NANO SPECIAL JEE MAIN [PRAJWAL-1]

JR COLLEGE & COACHING CENTRE

IMPORTANT INSTRUCTIONS:
1) The test is of 3 hours duration.
2) The Test has 75 questions. The maximum marks are 300.
3) There are three parts in the question paper A, B, C consisting of Mathematics, Physics and Chemistry
having 25 questions in each part.
4) Marking Scheme and pattern of questions is as follows:
a)
Q.No Type Marking Scheme
1 - 20
+4 for correct response
26 - 45 MCQ
-1 for incorrect response
51 - 70
b) Question Numbers: 21 to 25, 46 to 50, 71 to 75
Numeric Type of Questions: The answer to the question is numeric TRUNCATED / ROUNDED OFF to
two decimal places (eg: 304, -40, 3010,-124.12, 6.33 etc.).
Marking Scheme: +4 for correct response. No negative marks

MATHEMATICS
( )
1. lim → =
(a) 0 (b) 1 (c) ∞ (d) does not exist
( ) ( )
2. lim → =
(a) cos 2 – 2 sin 2 (b) cos 2 + 2 sin 2 (c) sin 2 – 2 cos 2 (d) sin 2 + 2 cos 2

3. lim → =
/ / /
(a) (b) (c) (d) e
4. lim → + + ⋯+ ( )( )
=
. .
(a) 1 (b) (c) (d)

5. lim → =
(a) e (b) (c) (d)
6. lim → 1 − cos 1 − cos
(a) (b) (c) (d)
( )
7. lim → =
(a) (b) (c) (d) 56
( ) ( )
8. lim → =
( ) ( )
(a) 1 (b) (c) (d)
[ ]
9. lim → [ ]
is (where [ ] is g.i.f)
(a) 1 (b) 0 (c) does not exist (d) 2
10. lim → =

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(a) (b) (c) (d) 0

11. If 7 − ≤ ( ) ≤ 7 + for all ≠ 0 , then lim → ( )=
(a) 3 (b) 5 (c) 7 (d) 9
( )! ( )!
12. lim → ( )!
=
(a) 1 (b) (c) 0 (d) 2
( ⋯ )( ⋯ )
13. lim → ( )
=
⋯
(a) (b) (c) 1 (d) 0
14. lim → =
(a) 0 (b) (c) (d) 1
15. lim → =
(a) (b) (c) (d)
( )( )
16. lim → =
(a) (b) (c) 1 (d) 2
{ ( ….( { }))}
17. The value of , is lim → √

√
(a) (b) √2 (c) 1 (d) 2
18. Arrange the following limits in the ascending order.
(1) lim → (2) lim →

(3) lim → (4) lim →

. .
(a) 1, 2, 3, 4 (b) 3, 1, 4, 2 (c) 1, 2, 4,3 (d) 2, 1, 3, 4
[ ]
19. If [x] is the greatest integer function, then lim → − =
(a) 0 (b) (c) (d)
. .
20. If = lim → and = lim → √ then
√
(a) = (b) 2 = (c) =2 (d) =3
21. for x > 0; lim → (sin ) + =

22. If lim → 1+ − = , then ‘a’ is equal to

23. Evaluate lim → /
.

/
24. lim → is equal to . Then =

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25. If [x] denotes the greatest integer less than or equal to x then lim → {[1 ]+
[2 ] + [3 ]+⋯+ [ ]} is . Then k =

PHYSICS
26. One mole of an ideal gas at temperature expands according to the law =
(constant). The work done by the gas till temperature of gas becomes is
(a) ( − ) (b) ( − ) (c) ( − ) (d) ( − )
27. One end of a 2.35 m long and 2.0cm radius aluminum rod ( = 235 . )is
held at 20 . The other end of the rod is in contact with a block of ice at its melting
point. The rate in . at which ice melts is
[Take latent heat of fusion for ice as × 10 . ]
(a) 48 10 (b) 24 10 (c) 2.4 10 (d) 4.8 10
28. A rod of length L and uniform cross-sectional area has varying thermal conductivity
which changes linearly from 2K at end A to K at the other end B. The ends A and B of
the rod are maintained at constant temperature 100 and 0 , respectively. At steady
state, the graph of temperature : T = T(x) where x = distance from end A will be

(a) (b)

(c) (d)
29. Two sheets of thickness d and 2d and same area are touching each other on their face.
Temperature , , shown are in geometric progression with common ratio r = 2.
Then ratio of thermal conductivity of thinner and thicker sheet are

(a) 1 (b) 2 (c) 3 (d) 4

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30. A wall has two layer A and B each made of different material, both the layers have the
same thickness. The thermal conductivity of the material a is twice that of B. Under
thermal equilibrium the temperature difference across the wall B is 36 . The
temperature difference across the wall A is
(a) 6 (b) 12 (c) 18 (d) 72
31. Three rods made of the same material and having same cross sectional area but
different lengths 10cm, 20 cm and 30 cm are joined as shown. The temperature of the
joint is

(a) 20 (b) 23.7 (c) 16.4 (d) 18.2

32. Six identical conducting rods are joined as shown in figure. Points A and D are
maintained at temperature of 200 and 20 respectively. The temperature of
junction B will be

(a) 120 (b) 100 (c) 140 (d) 80

33. A metallic rod of cross-sectional area 9.0 and length 0.54 m, with the surface
insulated to prevent heat loss, has one end immersed in boiling water and the other in
ice-water mixture. The heat conducted through the rod melts the ice at the rate of 1 gm
for every 33 sec. The thermal conductivity of the rod is
(a) 330 (b) 60
(c) 600 (d) 33
34. A hollow sphere of inner radius R and outer radius 2R is made of a material of thermal
conductivity K. It is surrounded by another hollow sphere of inner radius 2R and outer
radius 3R made of same material of thermal conductivity K. The inside of smaller
sphere is maintained at 0 and the outside of bigger sphere at 100 . The system is
in steady state. The temperature of the interface will be
(a) 50 (b) 70 (c) 75 (d) 45
35. Two rods A and B of different materials but same cross section are joined as in figure.
The free end of A is maintained at 100 and the free end of B is maintained at 0 . If
=2 , = 2 and rods are thermally insulated from sides to prevent heat losses,
then the temperature of the junction of the two rods is

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(a) 80 (b) 60 (c) 40 (d) 20

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50. A cylindrical rod with one end in a steam chamber and the outer end in ice results in
melting of 0.1 gm of ice per second. If the rod is replaced by another with half the
length and double the radius of the first and if the thermal conductivity of material of
second rod is that of first, the rate at which ice melts in gm/sec will be

CHEMISTRY
51. Which of the following exhibits optical isomerism
(a) Propanol (b) Propan-2-ol (c) Butan-1-ol (d) Butan-2-ol
52. The E isomer among the following

(a) (b) (c) (d)

53. Decreasing order of -I effect
(A) -CN (B) NO2 (C) –NH2 (D) - F
(a) B > A > D > C (b) B > C > D > A (c) C > B > D > A (d) C > B > A > D
54. Which type of overlap of orbital involves in hyper conjugation.
(a) − (b) − (c) − (d) p - p
55. The pair given are

and
(a) Enantiomers (b) Homomers (c) Diastereomers (d) None
56. Polarity in Multiple bonds caused by an attacking reagent is called
(a) Electromeric effect (b) Mesomeric effect
(c) Hyper conjugation (d) All
57. Which of the following is true for Mesomeric effect.
(a) It is a permanent effect
(b) Mesomeric effect dominates inductive effect
(c) Both (d) None
58. Mesomeric effect, Inductive effect both present in
(a) CH2 = CH - Cl (b) CH2 = CH – CH2 - Cl
(c) CH2 = CH - CH2 – CH = 0 (d) All
59. Which of the following is true about Resonance
(a) It involves displacement of electron only
(b) Basic valency rules must not be violated

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(c) More structures, more stability

(d) All
60. True statement about hyperconjugation.
(a) Must have atleast one – sp2 hybrid carbon
(b) Adjacent to sp2 carbon must be sp3 carbon
(c) both (d) None
61. Isoentropic process is
(a) adiabatic and irreversible process (b) isothermal and reversible process
(c) Adiabatic and reversible process (d) Isothermal and reversible for which Q = 0
62. According to third law of thermodynamics
(a) The entropy of a substance at 0 K is zero
(b) Entropy of hydrogen ion is zero at 0 K
(c) Net change in entropy in conversion ( ) (130 )→ ( ) (200 ) is zero
(d) Entropy generally decrease in combustion reactions.
63. One mole of an ideal diatomic gas (Cv = 5cal) was transformed from initial 250C and
1L to the state when temperature is 1000C and volume 10 L. The entropy change of the
process can be expressed as (R = 2 calories/mol/K)
(a) 3 ln + 2 ln 10 (b) 5 ln + 2 ln 10

(c) 7 ln + 2 ln (d) 5 ln + 2 ln
64. By how much does the entropy of 3 mole of an ideal gas change in going from a
pressure of 2 bar to a pressure of 1 bar without any change in Temperature. If the
surrounding is at 1 bar and 300K. (Expansion is again of the constant external pressure
of surrounding).
(a) + 7.29 J-K-1 (b) +4.82 J-K-1 (c) -5.29 J-K-1 (d) -8.35 J-K-1
65. For a perfectly crystalline solid Cp.m = aT3 + bT, where a and b constant. If Cp,m is 0.40
J/K mol at 10 K and 0.92 J/K mol at 20 K, then molar entropy at 20 K is:
(a) 0.92 J/K mol (b) 8.66 J/K mol (c) 0.813 J/K mol (d) None of these
66. Look at the following diagram:

The enthalpy change for the reaction → will be

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(a) -25 kJ (b) -40 kJ (c) +25 kJ (d) -65 kJ

67. The difference between ∆ ∆ (on a molar basis) for the combustion of n-
octane(l) at 250C would be:
(a) -13.6 kJ (b) -1.14 kJ (c) -11.15 kJ (d) +11.15kJ
68. The heat of formation of HCl at 348 K from the following data, will be
0
0.5 H 2 ( g )  0.5Cl2 ( g )  HCl H 298  22060 cal
The mean heat capacities over this temperature range are
H2(g), Cp = 6.82 cal mol-1K-1 ; Cl2(g), Cp = 7.71 cal mol-1K-1; HCl(g),
Cp = 6.81 cal mol-1K-1
(a) -20095 cal (b) -32758 cal (c) -37725 cal (d) -22083 cal
69. From the following data of ∆ of the following reactions,
1
C ( s )  O2 ( g )  CO ( g ) H  110kJ
2
C ( s )  H 2O ( g )  CO ( g )  H 2 ( g ) H  132kJ
What is the mole composition of the mixture of steam and oxygen on being passed over
coke at 1273K, to maintain constant temperature:
(a) 0.5 : 1 (b) 1 : 0.6 (c) 0.8 : 1 (d) 1 : 1
70. When 12.0 g of carbon reacted with limited quantity of oxygen, 57.5kcal of heat was
produced, calculate the number of moles of CO produced (∆ ( )= -94.05kcal,
∆ ( ) = −21.41 .
(a) 0.5 mol (b) 0.46 mol (c) 0.64 mol (d) 0.74 mol
71. Number of species that act as Nucleophiles
NO2 , Cl  , Cl ,OR  , I  , NO  , BF3 , H 2O
72. Pick out (-I) effect species.

73. 1 mole of an ideal gas A (Cv,m = 3R) and 2 mole of an ideal gas B are , =
taken in a container and expanded reversible and adiabatically from 1 litre to 4 litre

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starting from initial temperature of 320 K. Find the magnitude value of ∆ /10 for the
process is:
74. 10 litres of a monoatomic ideal gas at 00C and 10 atm pressure is suddenly released to 1
atm pressure and the gas expands adiabatically against this constant pressure. The final
volume (L) of the gas.
75. If heat of reaction for the given acid-base reaction:
HA  NaOH  NaA  H 2O; H  4.7kcal
The heat of dissociation of HA is ___.

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JEE MAIN (PRAJWAL-2 ) KEY

1 C 2 A 3 A 4 B 5 C 6 C 7 A 8 C 9 B 10 A
11 C 12 C 13 B 14 D 15 B 16 D 17 B 18 B 19 C 20 C
21 1 22 1.5 23 72 24 2 25 3 26 B 27 C 28 B 29 A 30 C
31 C 32 C 33 B 34 C 35 A 36 C 37 D 38 A 39 B 40 D
41 A 42 B 43 C 44 D 45 A 46 2800 47 1440 48 2 49 2.4 50 0.2
51 D 52 C 53 A 54 B 55 A 56 A 57 C 58 A 59 D 60 C
61 C 62 B 63 B 64 B 65 C 66 A 67 C 68 D 69 B 70 A
71 4 72 5 73 96 74 64 75 9

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