CCR Platforming™ with CycleMax™ Regeneration Process Technology CCR Control A Honeywell Company © 2013 UOP LLC. All rights reserved. UOP - CONFIDENTIALCycleMax III CCR CycleMax III Reduction Zone i Disengaging Hopper Bag Collector Regenerated Cat Dust Collector Regeneration posuere Gas Blower Zone Last Reactor = Catalyst Collector System Gas H, Lock Hopper * uop A Honeywell Comp 5th Generation CCR Regenerator Regenerator Stack Split Regeneration Tower operates under pressure Tapered Regenerator Innerscreen Gas once through Chlorination Zone Addition of Reheat Gas Heater (for improved temperature control) HCBN and 02 environments separated by “N2 Bubbles” Modified Lock Hopper (same as CM Il) Catalyst lifted continuously via L- Assemblies in vertical lift lines Additional fines removal after the Regeneration Tower Modified Reduction Zone for improved catalyst drying Numerous units sold — first startups expected in 2014 12.2 UOP - CONFIDENTIAL CCR ControlCatalyst Flow (Circulation) ‘A Honeywell Company Four Loops: ° Spent Catalyst Transfer ° Intra-regenerated Catalyst Transfer * CCR Catalyst Circulation Control Regenerated Catalyst Transfer Vi: Catalyst Collector F1: Spent Catalyst Dust ‘V2: Spent Catalyst Collector Disengaging Hopper F2: Regenerated Catalyst V3: Chloride Adsorber Dust Collector ‘V4: Regeneration Tower BI: Spent Catalyst Lift Gas/ V5: Regenerated Catalyst Fines Removal Blower Disengaging Hopper B2: Regenerated Catalyst Lift V6: Lock Hopper / Fines Removal Blower Disengaging Drum H: Preheat Gas Heater V7: Lock Hopper V8: Lock Hopper Surge Drum V9: Reduction Zone 1263 UOP - CONFIDENTIAL CCR ControiCatalyst Flow (Circulation) rd Dat + Spent catalyst transfer ° Regenerated catalyst f transfer a ° Catalyst circulation i control ab 8; Sea Dun Lack 12-4 UOP - CONFIDENTIAL CCR ControlCatalyst Flow (Circulation) op Spent Catalyst Transfer Catalyst Collector removes hydrocarbon from catalyst. Ree er tee eae Lee aA) Kerra aiis Ges cee (ei alec eit) Cerca) ° Deca ce Co Be eee Ne TU acl Ce Whole catalyst is pushed: down from Spent Catalyst. isenigaging Hopper to Chloride Adsorber by differential STR tt ee eeu Catalyst flows by gravity to Regeneration Tower for rere ae UOP - CONFIDENTIAL CCR Contro!Catalyst Flow (Circulation) 126 UOP - CONFIDENTIAL A Honeywell Company Intra-regenerated Catalyst Bicuciicg Regenerated catalyst gravity flows Cola L-valve assembly engages: Peels Grnrcrnnurece Bees Catalyst is lifted via lift line to Regs : Catalyst Disengaging hopper. forte Neral tacit Milas gs: etl len eligi eMule mali Mls es ree Whole catalyst flows by gravity to Hopper Disengaging Hopper. CCR ControlCatalyst Flow (Circulation) A Honeywell Company Lock Hopper system LH System includes 3 vessels: Lock Hopper Disengaging Drum Lock Hopper Lock Hopper Surge Drum Reick easiest ome Hopper Disengaging Drum (LHDD). Lock Hopper transfers small batches of catalyst from LHDD to Lock Hopper Surge Drum. The frequency of batch catalyst transfer controls the cee eer mee Ce Rael eT Catalyst flows by gravity into Lock Hopper Surge Drum 127 UOP - CONFIDENTIAL CCR ControlCatalyst Flow (Circulation) Cree eters Beesley 128 UOP - CONFIDENTIAL CCR ControlCatalyst Flow (Circulation) ‘A Honeywell Company Spent catalyst transfer ° Intra-regenerated catalyst transfer * Regenerated Catalyst transfer ° CCR Catalyst circulation control V1: Catalyst Collector FI; Spent Catalyst Dust Collector ‘V2: Spent Catalyst Disengaging Hopper; Regencrated Catalyst Dust Collector V3: Chloride Adsorber BL: Spent Catalyst Lift Gas! ‘V4: Regeneration Tower Fines Removal Blower V5: Regenerated Catalyst Disengaging _B: Regenerated Catalyst Lift oper Fines Removal lower VS: Lock Hopper Disengaging Drum ys PreherGuc Heme ‘V7: Lock Hopper V8: Lock Hopper Surge Drum V9: Reduction Zone 129 UOP - CONFIDENTIAL CCR ControtCatalyst Flow (Circulation) * Spent catalyst transfer ° Intra-regenerated catalyst transfer * Regenerated Catalyst transfer * CCR Catalyst circulation control Vis Caayst Colesor 1 Spent Catalyst st Collstor ‘V2: Spent Catalyst Disengeging Hopper Fp: Regenerated Catalyst Dust Collector V3: Chloride Adsorber BI: Spent Catalyst Lift Gas! V4: Regeneration Tower Fines Removal Blower ‘V5: Regenerated Catalyst Disengaging 9. Regenerated Catalyst Lift / Hopper Fines Removal Blovet ‘V6: Lack Hopper Disengaging Drum H: Preheat Gas Heater V7: Lock Hopper V8: Lock Hopper Surge Drum V9: Reduction Zone 12-40 UOP - CONFIDENTIAL CCR ControtReactor / CCR Catalyst Regeneration Loop uop Pressure Profile Catalyst flow 1. Catalyst collector 2. Lift line (N2) 3. Spent Cat. Disengaging hopper Chloride Adsorber tion tower Reg Lift Line (N2) ited Cat. Disengaging per Disengaging Drum 9. Lock hopper 40. Lock Hopper Surge Drum 11. Lift line (H2) 12. Reduction zone 13. Reactors Key: Reactor Pressure 90-125 psig (3.5-9 kg/cm2g) Regenerator Pressure 35 psig (2.5 kg/cm2g) teat 80 psig (typical) Zone 77 psig RX #4 (typical) 50 psig (typical) Catalyst Collector off oe" UOP - CONFIDENTIAL 47 psig (typical) ‘A Honeywell Company CCR ControlReactor / CCR Catalyst Regeneration Loop uop Process Environments 12-12 Catalyst flow Catalyst collector Lift line (N2) Spent Cat. Disengaging hopper Chloride Adsorber Regeneration tower Intra Reg Lift Line (N2) Regenerated Cat. Disengaging Hopper 8. Lock Hopper Disengaging Drum 9. Lock hopper 10. Lock Hopper Surge Drum 41. Lift line (H2) 12, Reduction zone 13, Reactors Oe te te Sete) Environments separated by “nitrogen bubbles” (isolation systems activate on loss of bubble) Key Uf, Aydrogen | Hydrocarbon \\\\ Nitrogen nd Oxygen Spent Cat Dust Collector or RegeneratedCat Dust Collector Regenerated Cat DE UOP - CONFIDENTIAL CCR ControlCCR Catalyst Regeneration Loop Catalyst flow 1. 8. 9. 2. 3. 4. 5, 6. 7. Catalyst collector . Lift line (N2) . Spent Cat. Disengaging hopper Chloride Adsorber . Regeneration tower . Intra Reg Lift Line (N2) . Regenerated Cat. Disengaging Hopper Lock Hopper Disengaging Drum Lock hopper 10. Lock Hopper Surge Drum 11. Lift line (H2) 12. Reduction zone 13. Reactors 12-43 A Honeywell Company Spent Cat Dust Collector Reduction Zone RegeneratedCat Dust Collector factor Regenerated — Cat DH Regeneration] eet Lock Hopper — Disengaging Lock Catalyst, Hopper Collector Lock Hopper ‘Surge Drum Booster Gas UOP - CONFIDENTIAL CCR ControtCCR Catalyst Regeneration Loop uop Special elbows turn catalyst direction without erosion of line * Catalyst flow Oxidized - Catalyst collector a - Lift line is reduced. - Disengaging hopper - Regeneration tower - Nitrogen seal drum — Reswors — ~ Lock hopper - Lift line eae Spent catalyst is cooled to 300°F (150°C) with gas from reduction Catalyst zone Collector ~] ‘ Dust removed from catalyst in Elutriator. Regener System pressure 7” dropped across Catalyst is regenerated fram vant nae 0, separated from H, with N, Nitrogen > Isolation =e Valves LH transfers catalyst one batch at a time from regenerator pressure to reactor pressure Catalyst Addition Hopper Spent catalyst is lifted with N, to Regenerated catalyst is lifted the top of the CCR structure and yf * with H, to H, separated from O, with N, L-Valve Assemblies the top of the CCR structure 12-14 UOP - CONFIDENTIAL CCR ControlProcess Pressures ‘A Honeywell Company * Reactor section: higher pressure » Regeneration section: low pressure » Pressures separated by gradients across standpipes (gradients created by gas flow through catalyst bed) Key sj Reactor Pressure MM 30.5 psig (3.5-9 kg/em? g) \ Regenerator Pressure 35 psig (2.5 kg/cm? g) 12-45 Reduction Lone —» EE Disengaging k <— Hopper Regeneration Tower Reactors Ng Seal Drum Lock Catalyst Hi Collector ope Catalyst Addition Hopper Na Lif 4 Booster Gas Gas vf Lift Gas L-Valve Assemblies CCR Contro! UOP - CONFIDENTIALProcess Environments Dust Special Collector Elbows Reduction Zone Dsengeging Hopper Regeneration Tower Reactors Nitrogen Ny Seal Dum Isolation Valve Lock Catalyst Hopper Collector Catalyst Addition Hopper Booster Gas Lift Gas L-Valve Assemblies 12-46 UOP - CONFIDENTIAL * Reactor section: H,/HC environment * Regeneration section: O, environment * Environments separated by “nitrogen bubbles” (isolation systems activate on loss of bubble) Key Mii Aydrogen / Hydrocarbon \\\\ Nitrogen Oxygen CCR ControlCatalyst Collector uop A Honeywell Company Special Dust Elbows Collector Reduction . ‘Zone —~a| Disengaging Hopper Regeneration Tower Reactors. Isolation Valves Catalyst Collector catalyst, DO Addition ~, Hopper () Isolation, Valves No Lift Booster Gas Gas Ny Lift Gas L-Valve Assemblies 1247 UOP - CONFIDENTIAL CCR ControlL-valve Uuop A Honeywelt Ci Elbows Spent Cat Dust Collector on RegeneratedCat Dust Collector Regenerated CatDE Lock Hopper Disengaging Drm Lock Catalyst Hopper Collector Lock Hopper ‘Surge Drum Booster Gas 12-18 UOP - CONFIDENTIAL CCR ControlL-Valves and Lift Lines uop A Honeywell Company Special Dust Elbows Collector Disengaging Hopper Regeneration Tower Reactors Nitrogen Nj Seal Drum Isolation Valves Lock Catalyst Hopper Collector ~s| Catalyst Addition sj Hopper Booster Gas Lift Gas L-Valve Assembies 12-19 UOP - CONFIDENTIAL CCR ControlL-Valves and Lift Lines All lift systems similar Primary lift gas provides majority of lift gas * Catalyst enters into horizontal section * Secondary gas pushes a catalyst into lift line it cas. £ controlling catalyst Inlet transport rate ¢ Screen inserts prevent catalyst backflow 12-20 UOP - CONFIDENTIAL Catalyst | Dur-0-Lok | Couplings \ Skin Temperature ¥ Indicator 1) Removable Spool Piece Primary Lift Gas Inlet CCR ControlRegenerated Catalyst L-Valve ‘A Honeywell Company 12.21 UOP - CONFIDENTIAL CCR ControlL-Valve Assembly 12-22 UOP - CONFIDENTIAL CCR ControlCatalyst Lift Line neywell Company Special Ebows spent Cat \_ Baitceecte ° Straight vertical upflow Reduction - Low erosion Zone RegeneratedCat DustColleor_ ~— - Low fines make U - Special joints (Dur-o-lok) to minimize attrition Chloride ‘Adsorber 4 Reactor. rae Lock Hopper — Disengagng ‘Dram Tower Lock Hopper Lock Hopper ‘Surge Drum Booster Gas 12-23 UOP - CONFIDENTIAL CCR ControtLift Lines Dust Collector > Special Elbows Reduction Zone Disengaging Hopper Regeneration Tower Reactors Np Seal Drum Isolation Velves Lock Catalyst Hopper Collector Catalyst Addition Hopper Booster Gas NpLift Lift Gas, Gas \7 L-Valve Assemblies 12-24 UOP - CONFIDENTIAL ° Straight vertical upflow - Low erosion - Low fines make - Special joints (Dur-o-lok) to minimize attrition CCR Contro)Lift Lines A Honeywell Company » Dur-O-Lok™ Couplings Lift Pipe - Preferred method for coupling - Machined coupling minimizes gap and offset - Spent and regenerated catalyst lift lines - Designed to minimize attrition - One vertical line up from L-Valve with minimum number of joints - Seal is provided by an internal O-ring with an external split coupler Set screws, 2 Required, of Which One Shall Have a Hole Drilled through the Shaft for Field Installation of Safety Wire Red Silicone "Ring (or Equal) ‘aution: Lateral stresses lead to hydrogen leaks & fires 12-25 UOP - CONFIDENTIAL CCR ControlDur-O-Lok Coupling Tapered Retaining Ring Split Coupler Pipe Hub Moltipie Machined Grooves TN Gite Covi rie \ Spt KK Split Coupler \- ed ere Sree Figure 1. DUR 0 LOK® Coupling 12-26 UOP - CONFIDENTIALLift Lines — Impactless Elbow A Honeywell Company ° Allows for direction change aS * Downward sloping line to reduction zone or disengaging hopper * Designed to minimize catalyst attrition neon 1 20 degree Becentrie — wae Lift slope to \ <—Pipe destination \ single vertical lift from L-valve Catalyst Oatlet 12.27 UOP - CONFIDENTIAL CCR ControlDisengaging Hopper uop Special Elbows Spent Cat Dust Collector Reduction Zone RegeneratedCat Dust Collector (adsabes Regenerated Reactors agent Lock Hopper _— Disengaging Drm Lock Catalyst Hopper Collector — Lock Hopper ‘Surge Drum Booster Gas 12-28 UOP - CONFIDENTIAL CCR ControlLift Gas and Fines Removal Circuit 12-29 * Consists of: + Blower(s) provide gas for Spent catalyst L-Valve assembly Spent catalyst lift line Disengaging hopper Dust collector Lift gas blower Fines removal blower lifting and elutriation » Small amount of nitrogen makeup for losses to regeneration tower, reactors and blower seals ° Two major loops Lift gas Elutriation gas * Fines - < 0.04 Wt% of CCR rate - Elutriation gas rate set so that 20-30% whole pills are collected uoP Special Thow +] Disengaging Hopper, Catalyst to Regeneration “Tower Catalyst From Reactors pera Assembly i Lif Gas Controllers - CONFIDENTIAL A Honeywell Company Noon PDI Control Elutriation ines * Gs Remaval Blower 2 Controller Page / Pressure Gas FO Lift Gas Blower srillback Cicoier CCR ControlDust Collection = Reverselet Gas Inlet Felted Cloth Filter Elements ———~ Fines and Gas Inlet Dust Oudet 12-30 a Gas Outlet UOP - CONFIDENTIAL ° Elutriation gas and catalyst fines and chips enter side Catalyst fines and chips collected on felted filter bags Gas flows through the filter elements and exits the top Differential pressure transmitter indicates bags need cleaning Cleaned on-line with reverse jet pulse of nitrogen into bags CCR ControlDust Collection A Honeywell Company 12:31 UOP - CONFIDENTIAL CCR ControlDust Collection A Honeywell Company 12-32 UOP - CONFIDENTIAL CCR ControlChloride Adsorber UCP ‘A Honeywell Company Special Elbows Spent Cat Dust Collector Ne RegeneratedCat ‘Dust Collector i Chloride ~Adsorber Regenerated Reactors pean Lock Hopper Booster Gas 12-33 UOP - CONFIDENTIAL CCR Contro}Chloride Adsorber uop Catalyst Inlet nozzle contains orifice plate. * Annular baffle to allow catalyst and regeneration vent gas contact for chloride recovery. * Nuclear level detector to monitor level (Point Switch) * Good heat tracing and insulation is critical in prevent condensation and corrosion. * Bottom head lined with Hastelloy * Catalyst exits to regeneration tower via outlet nozzles 12-34 UOP - CONFIDENTIAL CCR ControiChloride Adsorber Thermocouples A Honeywell Company 12.35 UOP - CONFIDENTIAL CCR ControtChloride Adsorber Transfer uop 12-36 UOP - CONFIDENTIAL CCR ControlRegenerator voPp A Honeywell Company Special <7 Elbows poet Q nas Collector \ an Wo Zone ‘RegeneratedCat ‘Dust Collector aL Regenerated Reactox aor, | Regeners 1" Sower Lock Hopper Disengaging Drum Lock Catalyst Hopper Collector Lock Hopper Surge Drum Booster Gas 12.37 UOP - CONFIDENTIAL ‘CCR ControlRegeneration Tower (CM 2&3) uop A 4! ‘} Seal gas from blower Burn zone z| = Regeneration gas from heater 4 o Reheat gas from blower Reheat zone { Chlorination zone Chloride injection Air to drying zone Air from cooling zone to air heater Drying zone { Cooling zone { Air to cooling zone 12-38 UOP - CONFIDENTIAL CCR ControlRegeneration Tower — Burn Zone ‘A Honeywell Company Bun Zone Outlet Catalyst enters from Chloride Theron a \ Z Cast Adsorber y a LL | ° Seal gas preheats catalyst and 1) fade prevents fluidization Direct Seal Gas Inlet dierseics © Coke is burned off the catalyst ° Catalyst exits to reheat zone * Screens made with profile wire Tapered Sumo —'r=s=" «Outer screen is vertical and te Sa attached to shell Sie , ; qo * Inner screen is sloped inward Reheat Zone and attached to head inlet * Thermocouples along length 12-39 UOP - CONFIDENTIAL CCR ControlRegeneration Tower Inner Screen UOP - CONFIDENTIAL CCR ControlRegeneration Tower Head & Inner Screen ‘A Honeywell Company 12-44 UOP - CONFIDENTIAL CCR ControlTop Portion of Inner Screen Burn Zone UOP A Honeywell Company Perforated plate added as a secondary containment barrier 12-42 UOP - CONFIDENTIAL CCR ControlRegenerator Screen Profile Wire (back) UOP - CONFIDENTIAL A Honeywell Company CCR ControlCat Tracker Assembly A Honeywell Company 12-44 UOP - CONFIDENTIAL CCR ControtRegeneration Tower — Chlorination Zone A Honeywell Company e Guide vanes as viewed from below 12-45 UOP - CONFIDENTIAL CCR Contro!Regeneration Tower — Drying ZoneRegeneration Tower — Drying Zone ‘A Honeywell Company ¢ Catracker « 4 TI to monitor potential temperature — excursion : 12-47 UOP - CONFIDENTIAL CCR ControlRegeneration Blower Circulates hot regeneration gas Inconel impeller Shaft sealed with N, on delta P control Carbon ring seals Bearings lubricated by oil mist system * Warehouse spare plug specified 12-48 Motor uo! $ I J From Oil Mist System Coupling Mono-Block Bearings 0,000 hr. Rating Multiple Carbon-Ring Type Seal Differential Pressure Regulator - CONFIDENTIAL at Tight Anchor Expansion Joint CYM-RO1-49 CCR ControlRegeneration Gas Blower 12-49 UOP - CONFIDENTIAL CCR ControlRegeneration Cooler Air cooled shell and tube exchanger Stainless steel construction * Removes heat of combustion from burn zone effluent ¢ Regeneration gas on tube side ° Air flow from cooler blower on shell side ° Welded joints to prevent leakage 12-50 UOP - CCNFIDENTIAL To Atmosphere Tube Flange sheet \ Regeneration Gas Flow Transition Pieces Flange Air Flow from butterfly valve at blower discharge CCR ControlRegeneration Cooler A Honeywell Company 12-51 UOP - CONFIDENTIAL CCR ControlRegeneration Cooler Blower uop 12-52 UOP - CONFIDENTIAL CCR ControlElectric Heaters A Honeywell Company * Immersion-type heaters ° Heaters required: - Regeneration gas - Reheat Gas - Drying air - Reduction gas heaters (2) ° Element bundles fill shell * Gas flow required to prevent overheating of elements Gas Talet Cooling tenet ! a / ho rower f Controller High Temperature Shutoff 12-53 UOP - CONF DENTIAL CCR Contro! Gas Outlet Xt Full Baffles Heater Heating Element (Heat Shields) Shell BundleElectric Heaters — Dual Element Up Cooling Power Space Controller Unheated Length Heating Element 7 Bundle TRC T 3 Phase Gas Outlet Terminal Box. Gas Inlet Baffles (Heat Shields) Shell ¢ Multiple bundles in series required for high AT 12-54 UOP - CONFIDENTIAL CCR ControlElectric Heater A Honeywell Company 12-55 UOP - CONFIDENTIAL CCR ControtRegeneration Gas Electric Heater 12-56 UOP - CONFIDENTIAL CCR ControlElectric Heater Elements ‘A Honeywell Company 12.57 UOP - CONFIDENTIAL CCR ControtLock Hopper System 12-58 Reduction Zone Reactor Catalyst Collector AHo Special Elbows Spent Cat Dust Collector erated Cat Collector Regeneration] Lock Hopper Disengaging Booster Gas UOP - CONFIDENTIAL CCR ControlLock Hopper System A Honeywell Company * Three vessels Lock Hopper Disengaging Drum Lock Hopper Lock Hopper Surge Drum » Killed Carbon Steel > Catalyst flows by gravity when ce permitted by XV-valves = Zones operate in booster gas a] environment Eee » Regulate CCR catalyst ’ circulation rate * Transfer catalyst from — eE regenerator pressure to | reduction zone pressure | / (typically 35 psig to 70 psig) Batch catalyst transfer between vessels. 12-59 UOP - CONFIDENTIAL CCR ControlAir Dryer * Package dryer for air to drying zone * Two desiccant chambers * Timers cycle desiccant chambers in and out of service Off-line chamber reactivated by depressurization and purging with dry air slipstream * Dry air must be 5 mol-ppm H,0 or less -85°F (-65°C) dew point Prefilter After Filter L__ Plant Drying Air Air to Regenerator Sample Connection Desiccant Chambers 12-60 UOP - CONFIDENTIAL CCR ControlAir Dryer A Honeywell Company 12-64 UOP - CONFIDENTIAL CCR Controtuop ‘A Honeywell Company 12-62 UOP - CONFIDENTIAL CCR Control