Propylene Glycol

Other names: (.+/-.)-1,2-Propanediol; (RS)-1,2-Propanediol;

1,2-Dihydroxypropane; 1,2-Propandiol; 1,2-Propanediol; 1,2-Propylene
glycol; 1,2-Propylenglykol; 1,2-propanediol (propylene glycol);
2,3-Propanediol; 2-Hydroxypropanol; DL-1,2-Propanediol; DL-Propylene
glycol; Dowfrost; Ilexan P; Isopropylene glycol; Methylethyl glycol;
Methylethylene glycol; Monopropylene glycol; NSC 69860; PG 12;
Prolugen; Propane-1,2-diol; Propylene glycol USP; Propylenglycol; Sentry
Propylene Glycol; Sirlene; Solar winter ban; Solargard P; Trimethyl glycol;
Ucar 35; propanediol; propylene glycol (1,2-propanediol);
«alpha»-Propylene glycol.
InChI: InChI=1S/C3H8O2/c1-3(5)2-4/h3-5H,2H2,1H3
InChI Key: DNIAPMSPPWPWGF-UHFFFAOYSA-N
Formula: C3H8O2
SMILES: CC(O)CO
Molecular Weight: 76.09
CAS: 57-55-6

Physical Properties

Property Value Unit Source

∆cH°liquid -1822.90 ± 4.10 kJ/mol NIST Webbook

∆cH°liquid -1838.10 ± 2.30 kJ/mol NIST Webbook

∆cH°liquid -1823.50 ± 1.80 kJ/mol NIST Webbook

∆fG° -301.70 kJ/mol Joback Method

∆fH°gas -429.80 ± 4.10 kJ/mol NIST Webbook

∆fH°gas -421.00 ± 3.00 kJ/mol NIST Webbook

∆fH°gas -435.30 kJ/mol NIST Webbook

∆fH°liquid -501.00 ± 4.10 kJ/mol NIST Webbook

∆fH°liquid -486.00 ± 3.00 kJ/mol NIST Webbook

∆fH°liquid -500.30 ± 1.80 kJ/mol NIST Webbook

∆fusH° 8.18 kJ/mol Joback Method

∆vapH° 67.50 ± 0.50 kJ/mol NIST Webbook

∆vapH° 76.00 kJ/mol NIST Webbook

∆vapH° 64.50 ± 0.20 kJ/mol NIST Webbook

 Property Value Unit Source

∆vapH° 62.20 kJ/mol NIST Webbook

∆vapH° 63.60 ± 0.30 kJ/mol NIST Webbook

∆vapH° 71.20 ± 0.10 kJ/mol NIST Webbook

∆vapH° 71.20 kJ/mol NIST Webbook

∆vapH° 65.00 kJ/mol NIST Webbook

∆vapH° 64.70 kJ/mol NIST Webbook

logPoct/wat -0.64 Crippen Method

Pc 5791.74 kPa Joback Method

Tboil 460.20 K NIST Webbook

Tboil 460.45 K NIST Webbook

Tboil 460.15 ± 2.00 K NIST Webbook

Tboil 459.15 ± 1.00 K NIST Webbook

Tboil 461.15 ± 3.00 K NIST Webbook

Tboil 460.60 ± 0.50 K NIST Webbook

Tboil 461.00 ± 0.20 K NIST Webbook

Tboil 459.80 ± 0.50 K NIST Webbook

Tboil 459.15 ± 1.00 K NIST Webbook

Tboil 460.55 ± 0.50 K NIST Webbook

Tboil 462.00 ± 2.00 K NIST Webbook

Tboil 460.15 ± 2.00 K NIST Webbook

Tboil 459.15 ± 2.00 K NIST Webbook

Tboil 458.45 ± 3.00 K NIST Webbook

Tboil 461.65 ± 3.00 K NIST Webbook

Tc 614.38 K Joback Method

Tfus 230.21 K Joback Method

Vc 0.24 m3/kg-mol Joback Method

Temperature Dependent Properties

 Property Value Unit Temperature (K) Source

Cp,gas 135.47 J/mol×K 451.96 Joback Method

Cp,liquid 180.30 J/mol×K 276.7 NIST Webbook

Cp,liquid 189.90 J/mol×K 298.0 NIST Webbook

Cp,liquid 177.00 J/mol×K 303.0 NIST Webbook

η 0.00 Pa×s 451.96 Joback Method

∆vapH 64.00 ± 2.00 kJ/mol 353.0 NIST Webbook

∆vapH 58.20 kJ/mol 378.0 NIST Webbook

∆vapH 58.60 kJ/mol 389.5 NIST Webbook

∆vapH 66.50 kJ/mol 390.5 NIST Webbook

∆vapH 60.00 ± 0.30 kJ/mol 430.5 NIST Webbook

∆vapH 56.20 ± 0.20 kJ/mol 430.5 NIST Webbook

∆vapH 52.00 ± 0.30 kJ/mol 430.5 NIST Webbook

∆vapH 47.50 ± 0.60 kJ/mol 430.5 NIST Webbook

∆vapH 56.00 kJ/mol 431.5 NIST Webbook

Sources

Joback Method: https://en.wikipedia.org/wiki/Joback_method

NIST Webbook: http://webbook.nist.gov/cgi/inchi/InChI=1S/C3H8O2/c1-3(5)2-4/h3-5H,2H2,1H3
Crippen Method: http://pubs.acs.org/doi/abs/10.1021/ci990307l

Legend

∆cH°liquid: Standard liquid enthalpy of combustion (kJ/mol).

Cp,gas: Ideal gas heat capacity (J/mol×K).
Cp,liquid: Liquid phase heat capacity (J/mol×K).
η: Dynamic viscosity (Pa×s).
∆fG°: Standard Gibbs free energy of formation (kJ/mol).
∆fH°gas: Enthalpy of formation at standard conditions (kJ/mol).
∆fH°liquid: Liquid phase enthalpy of formation at standard conditions (kJ/mol).
∆fusH°: Enthalpy of fusion at standard conditions (kJ/mol).
∆vapH°: Enthalpy of vaporization at standard conditions (kJ/mol).
∆vapH: Enthalpy of vaporization at a given temperature (kJ/mol).
logPoct/wat: Octanol/Water partition coefficient .
Pc: Critical Pressure (kPa).
Tboil: Normal Boiling Point Temperature (K).
Tc: Critical Temperature (K).
Tfus: Normal melting (fusion) point (K).
Vc: Critical Volume (m3/kg-mol).

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