Sri Chaitanya Chemistry SINGLE CORRECT Question BANKkkkkkkkkkkkkkkkkkkkkkkk

Sri Chaitanya IIT Academy Chemistry
SRI CHAITANYA IIT ACADEMY, INDIA

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A Right Choice for the Real Aspirant
ICON Central Office, MADHAPUR-HYD
QUICK REVISION TEST
Single Correct Choice Type Questions
1 If each hydrogen atom is excited by giving 8.4eV of energy, then the number of spectral lines emitted
during their deexcitation is equal to :
A. 0 B. 2 C. 3 D. 4
Answer :A
s
Solution : The minimum energy required for excitation of e1 s in H-atom is 10.2eV
er
pp
2 As the electron moves from point ‘x’ to point ‘y’ in the sommerfeld’s orbit shown the following
change can be observed
to
e_
je
iit
e/
.m
A. kinetic energy decreases B. potential energy decreases

//t
s:
C. velocity decreases D. the net energy will be decreases

tp
Answer :B
ht
Solution : Conceptual
IUPAC name of
A. 1,2 – diethoxyethanal B. 1,2- diethoxy propanone
C. Ethoxy ethyl ethanoate D. Ethyl ethoxy ethanoate
Answer :D
Solution : IUPAC name is Ethyl ethoxyethanoate
4 Which of the following method (s) is/are used to determine the molecular weight of a carboxylic acid
Quick Revision Test Single Choice Questions Page 1
https://t.me/iitjee_toppers
A
Chloroplatinate method B. Silver salt method
.
C
Liebig’s method D. none of these
.
Answer :B
Solution : To determine M.W of a carboxylic acid silver salt method is used.
5 Outer electronic configuration of 2nd period element which forms strongest acidic oxide
A. 2s 2 2 p5 B. 3s3 3 p5 C. 2s 2 2 p3 D. 3s 2 3 p 4
Answer :C
6 A metal forms hydro peroxide with formula M ( HO2 )2 . The formula of that metallic sulphate
s
A. M 2 SO4 B. MSO4
er
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C. M 2 ( SO4 )3 D. M 3 (SO4 )2
Answer :B to
e_
Solution : In MCl2 valence of M = 2
je
iit
 formula of its sulphate is MSO4

e/
7 Ionisation energies i.e. I1 and I 2 of Mg are 740 & 1440 k.J mol-1. The percentages of Mg 1 of and Mg 2
.m
//t
when 1mole of Mg absorbs 285.5 K.Cal of energy, are

s:
A. % Mg   68.4%, %Mg 2  31.6% B. % Mg   75%, %Mg 2  25%

tp
ht
C. % Mg   60%, %Mg 2  40% D. % Mg   72%, %Mg 2  28%
Answer :A
740
Solution : I .E1 of Mg Per 1g   31
24
1440
I .E2 of Mg Per 1g   60 But energy available per I .E2 is 50  31  19 hents nearly 31% of Mg 
24
ions are ionised

8 Covalent radii of carbon and silicon atoms are 0.77Å and 1.11Å respectively. the
bond length is
A. B. C. D.
Answer :A
Solution : conceptual
9 Two forms of D-glucopyranose are frequently called
A. enantiomers B. Anomers
C. Diastereomers D. Stereoisomers
Answer :B
Solution : They are called anomers because they differ in position of – OH group on first chiral caron
10
s
er
pp
Hydrogenation of the above compound in the presence of poisoned palladium catalyst gives
to
e_
A. an optically active compound B. an optically inactive compound
je
iit
C. a racemic mixture D. a diastereomeric mixture

e/
.m
Answer :B
//t
s:
tp
ht
Solution :
The compound formed is optically inactive due to absence of chiral C atom

11 Which group is always taken as a substituent in the IUPAC system of nomenclature ?
A.  NO2 B. C  N D.  NH 2
C.
Answer :A
Solution : Self – explanatory.
12 Which of the following effects of –OCH3 group,stablise the following carbocation?
A. – Inductive effect B. + Mesomeric effect
C. – Mesomeric effect D. + Inductive effect
Answer :B
Solution : lone pair of electrons of oxygen are involved in resonance
13 Identify the least stable carbanion from the following,
s
NH2 F
er
NH2 F
NH2 F O2N NO2
NH2
pp
NO2 F
NO2
A B C
. . .
to D.
e_
NO2
NO2
je
NO2
iit
Answer :D
e/
Solution : Mesomeric effect does not operate at meta position

.m
14 Which among the following is most basic?

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s:
tp
A B
C. D.
ht
. .
Answer :A
Solution : In ‘A’, lone pair of electrons of nitrogen atom are readily available for
donation,as they are not involved in resonance.
15 CuI 2 is unstable even at ordinary temperature because :
A. the Cu 2 ion with a comparatively small radius has a strong polarizing power.
B. the Cu 2 ion with a 17 electron outer shell has weak polarizing power
C. the I  ion with a larger radius has a high polarisability.
D. both (A) and (C)
Answer :D
Solution : Polarisation of the I  by the Cu 2 results in the transference of an electron towards Cu 2
makes it as oxidizing agent and I  as a reducing agent, reduces Cu 2 to Cu  and itself

oxidized to I 2
16 Which of the following is not linear ?
A. CO2 B. ClO2 C. I 3 D. NO2
Answer :B
Solution :
s
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to
e_
A) O  C  O , (B)
je
sp
linear
iit
e/
.m
//t
s:
tp
sp
ht
linear
(C) (D) O  N  O

17 Which of the following statements is correct ?
A. Hybridisation of carbon in C3O2 is sp 2
B. In Cr2 O72  all Cr  O bond lengths are identical
C. Three centre two electron bonds exist in B2 H 6 and Al2Cl6
D. In AgI , the colour is attributed to charge transfer spectrum
Answer :D
Solution : (A) O  C  C  C  O
| | |
sp sp sp
(B) ;
Therefore, all Cr  O bond lengths are not equal.
s
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(C) to
e_
B2 H 6 is an example of 3-centre 2- e  bond which is also known as
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Banana bond
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But Al2Cl6 have covalent bonds only and there is no electron deficient bonding as depicted in the
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s:
given structure .
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(D) Agl is bright yellow coloured compound due to the polarization of anion, I  . The bigger anions
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are more polarized and hence electrons get excited by partial absorption of visible light
18 Identify the correct statement from the following with regard to Lassaigne’s Test,
A. violet coloration during the detection of sulphur is due to the formation of ferric ferrocyanide
B. Blue coloration during the detection of nitrogen is due to the formation of ferric thiocyanate
C. If both nitrogen and sulphur are present, the formed NaCNS give blood red colour with berric
chloride
D. Red blood coloration is due to the formation of Na4[Fe(CN)5NOS]
Answer :C
Solution : NaCNS + 3Na ------à Na2S + NaCN
19 The IUPAC name of the following compound is,
A. 2-Cyano-4-hydroxybromobenzene B. 4-Bromo-3-cyanophenol
C. 4-Bromo-3-cyanophenol D. 2-Bromo-5-hydroxybenzenecarbonitrile
Answer :D
Solution : Cyano group is the principal functional group
s
er
20 In which of the following compound manganese shows maximum radius ?
pp
C. MnO
A. MnO2 B. KMnO4
to D. K3[ Mn(CN )6 ]
e_
Answer :C
je
Solution : Mn is +2 oxidation state in MnO while in other compounds it is in

iit
higher oxidation state. As

e/
number of electrons per proton decreases the size decreases.

.m
//t
21 The difference between the wave number of first line of Balmer series and last line of
s:
paschen series for Li 2 ion is

tp
R 5R C. 4R R
ht
A. B. D.
36 36 4
Answer :D
1 1 1 1
Solution :   RH Z 2  2  2   first line of Balmer,   9 RH 4  9
 n1 n2   
1
last line of paschen =   9 RH  
9
RH
Difference is :
4
22 Copper forms two oxides. For the same amount of copper twice as much was used to
form first oxide than to form second one. What is the ratio of valences of copper in first
and second oxides
A. 2 : 1 B. 1 : 2 C. 4 : 1 D. 1 : 4
Answer :A
23 In alkaline medium, ClO2 oxidizes H 2O2 to oxygen and is reduced to Cl  . How

many moles of H 2O2 are oxidized by one mole of ClO2 ?
A. 1.5 B. 2.5 C. 3.5 D. 5
Answer :B
Solution : [2ClO2  5H 2 O2  2OH   2Cl   5O2  6 H 2O ]
2 moles of ClO2  5 moles H 2O2
s
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pp
1 mole of ClO2  2.5 moles of H 2O2 ]
24 MnO4 ions are reduced in acid medium to Mn2  whereas they are reduced in neutral
to
conditions to MnO2. The oxidation of 25 ml of a solution (X) containing Fe2+ ions
e_
required in acidic condition 20 ml of solution of (Y) containing MnO4 ion. What
je
volume of solution of (Y) would be required to oxidize 25 ml of a solution of X

iit
containing Fe2+ ions in neutral solution ?

e/
.m
A. 11.4 ml B. 33.3 ml C. 12.0 ml D. 35. ml

//t
Answer :B
s:
Solution : MnO4  Mn 2  (acidic medium) Change in OS = 5

tp
ht
Solution x solution y
( Fe2 ) ( MnO4 )
N1V1 = N2V2
N  25 = 5 M V
(for MnO4 N = 5M in acidic medium)
25 N = 514 x 20; 25 N = 100 M ------ (1)
In neutral medium
+7 +4
MnO4 à MnO2
Change in OS = 3
Solution x solution y
Fe2 ( MnO4 )
(For MnO4 ; N = 3 M)
25 N = 3 M x V ---- (2)
From eq. (1) & (2)
s
100 M = 3 M  V
er
pp
100
V  33.3ml
3
to
e_
25 Which alkene will yield a meso dihalide when reacted with Br2 / CCl4 at room temperature ?
je
iit
A B C D
e/
. . . .
.m
Answer :B
//t
Solution : Trans alkene undergoes anti addition to produce meso compound

s:
tp
ht
26 4-Methyl – 1,3-pentadiene react with HBr , The possible products obtained are
A. 4-Bromo-2-methyl-2-pentene B. 4-Bromo-4-methyl-1-pentene
C. 4-Bromo-4-methyl-2-pentene D. All the above
Answer :D
27 Which sample contains the largest number of atoms
A. 1 mg of C4 H10 B. 1 mg of N 2 C. 1 mg of Na D. 1 ml of water
Answer :D
28 Which of the following compounds represents a meso isomer
A B C D
. . . .
Answer :A
29 An energy of 24.6 eV is required to remove one electron from a helium atom. The minimum energy
required
to remove both electrons from helium atom is
A. 38 eV B. 57 eV C. 79 eV D. 92 eV
s
er
pp
Answer :C
I1  24.6 ev
Solution : He  He   He 2+
I2
to
e_
je
He+ is H-like species and Bohr theory is applicable

iit
I 2 (He)  I1 (He  )   E1 (He  )

e/
.m
z2
//t
=  [ 13.6 x ]
n2
s:
tp
22
= 13.6 x 2  54.4 ev
ht
Total energy required = I1  I2

= 24.6 + 54.4 = 79 ev
30
The formal charge of the O-atoms in the ion is
A. - 1 B. 0 C. + 1 D. - 2
Answer :B
1
Solution : Formal charge, Q f  6 -4  (4)  0
2
31 Correct order of electron affinity of the elements C, N, O and Cl is
A. Cl > N > C > B. Cl > C > O > C. Cl > O > N > C D. Cl > O > C > N
O N
Answer :D
32 0.42 g of an organic compound on combustion gave 0.924 g of CO2 and 0.243 g of H 2O .

Due to distillation of 0.208 g of the compound with NaOH, ammonia evolved required
N
30 ml of H 2 SO4 for complete neutralization. The percentage composition of oxygen
20
is
A. 32.45 B. 24.48 C. 16.28 D. 7.8
Answer :B
Solution : % composition of oxygen = 100 – [% C + % H + % N]
s
er
33 Which of the following statements is right
pp
A. Bond length (C-C) between 2 and 3 carbon atoms in 1-pentene is 1.54 A0
5 4 3 2 1 to
e_
(CH 3 CH 2 CH 2  CH  CH 2 )
je
B. Number of carbon atoms collinear in CH3  C  C  C  C  CH 3 is four

iit
e/
.m
C. IUPAC name of is 1,2-dimethoxy ethanone

//t
s:
tp
NH - COCH3
ht
D. The functional group present in is amide
Answer :D
34 Among ortho, meta and para methoxy anilines, the basic nature decreasing order is
A. o - > p - > m B. p - > m - > o C. p - > o - > m D. o - = p - = m -

- - -
Answer :C
Solution :  OCH3 group has + R and – I – effect para effect is to be considered
35 The correct decreasing order of SN reactivity of the following halides is
I) II)
III) IV)
A. 3 > 1 > 2 > 4 B. 1 > 3 > 2 > 4 C. 2 > 4 > 3 > 1 D. 4 > 2 3 > 1
Answer :A
Solution : Reactivity order : I > Br > Cl
s
er
: 20   10 –
pp
36
to
e_
je
A
iit
B C D
.
e/
. CH2 CH2 OH . . CH2CHO

.m
Answer :B
//t
s:
tp
37 Which of the following reagents is best useful to distinguish between propyne and propene ?
ht
A. Br2 / CCl4 B. dil. KMnO4 C. Con. H2SO4 D.

AgNO3in NH4OH
Answer :D
Solution : Alkenes and terminal alkynes can be distinguished by Tollen’s reagent
38 The geometry with respect to the central atom of the following molecule are :
N ( SiH3 )3 ; Me3 N ; ( SiH3 )3 P
A. Planar, planar, planar B. Pyramidal, pyramidal, pyramidal
C. Pyramidal, planar, planar D. Planar, pyramidal, pyramidal
Answer :D
39 Two moles of N2 H 4 loses 16 moles of electrons and gets converted into a new
compound ‘X’. Assuming all the ‘N’ appears in the compound, what is the oxidation
state of ‘N’ in the compound ‘X’ ?
A. + 2 B. - 2 C. + 3 D. - 1
Answer :A
Solution : Two moles of N2H4 loses 16 moles of e-s
One mole of H 4 loses, no. of electron = 8 mole
(-2)
N2 H4  8  y
s
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(-2) ( 2)
N  4 N
to
e_
40 The major product formed in the reaction is
je
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e/
.m
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s:
tp
ht
A
B.
.
C
D.
.
Answer :D
Solution :
41 What volume of O2 measured at standard conditions will be formed by the action of100 mL of 0.5N
KMnO4 on hydrogen peroxide in an acidic solution? The skeleton equation for the reaction is,
KMnO4  H 2 SO4  H 2 O2  KHSO4  MnSO4  H 2 O  O2 :
A. 0.12 litre B. 0.28 litre C. 0.56 litre D. 1.12 litre
s
er
Answer :C
pp
Solution : (c) 2KMnO4  5O2
M V to
e_
No of moles of KMnO4   0.01
1000
je
iit
2 × 0.01 moles  5  0.01 moles O2

e/
5  0.01 22.4
.m
0.01 moles KMnO4   0.56

2
//t
42 The number of Fe 2 ion oxidized by one mole of MnO4 ions is: (In acid medium)
s:
tp
1 2 C. 5 3
A. B. D.
ht
5 3 2
Answer :C
Solution : Mn 7   5e  Mn 2  ;
Fe 2   Fe 3  e
43 0.2 g of a sample of H 2O2 required 10 mL of1N KMnO4 in a titration in the presence of
H 2SO4 . Purity of H 2O2 is:
A. 25% B. 85% C. 65% D. 95%
Answer :B
Solution : Meq. of H 2O2  Meq. of KMnO4
w
 1000  10  1
34 / 2
 wH 2 O2  0.17
0.17
 Percent purity =  100  85%
0.2
44 How many moles of a metal carbide M4C3 (completely soluble and ionisable)can be
completely oxidised by one mole of KMnO4 in mild alkali medium into HCOO  ions ?

 
OH 
 MnO4  MnO2 
 
1 1 1 3
A. B. C. D.
6 2 4 10
s
er
Answer :D
pp
Solution : As stage – I, if the reaction succeeds, HCl will be produced, which is stronger
acid as compared to the other acidic functional groups in the starting compound.
Formation of strong acid is never favored. to
e_
45 The no of stereo isomers formed by the given compound.
je
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e/
.m
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s:
tp
ht
A. 2 B. 3 C. 4 D. 5
Answer :A
Solution : Trans has center of symmetry and cis exists in d and l forms
Ans : 2n – 1
46 HCl
CH 2  CH  C  CH  Major product is
A
B.
.
C CH 2  CH  CH  CH 2Cl D.
.
Answer :D
KOH
47 BrCH 2  CHBr  CH 2 Br  product is
 One eqvt  
A. Br CH 2 – CH  CH 2 Br B. Br CH2CBr  CH2
C. CH 2  C  CH 2 D. CH 2  CH – CH2 Br
Answer :B
Solution : More acidic hydrogen is on central carbon.
Cl2 / hv
48  A . The product A is
s
CH 2  CH  CH 3 
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pp
A ClCH 2  CHCl  CH 3 B. ClCH 2  CH 2  CH2Cl
.
C CH 2  CH  CH 2Cl to
e_
D.
.
je
Answer :C
iit
e/
.m
49 A flask contained N 2 and CO gases in a molar ratio , 3: 2 at 500 atmospheres of

pressure . Due to a small hole , the gases are leaked out. The molar ratio of the
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N 2 and CO gases which they effuse out initially is

s:
tp
A. 1: 3 B. 3: 2 C. 2 : 3 D. 2 : 5
ht
Answer :B
rN 2 nN M C0 PN
Solution :  2   2
rC0 nC0 M N2 PCo
PN 2 3

PC0 2
50 To an evacuated vessel with movable piston under external pressure of 1.0 atm at O0C ,
0.1 mole of Helium and 1.0 moles of an unknown compound ( vapour pressure is
0.68 atm at O0C ) are introduced .
Then which of the following properties are correct ?
A. Total pressure of the vessel is 0.68 atm B. Total volume of the gasses at O0C is 7L
C. Number moles of the compound is 0.5 D. Total number of moles of the gases is 2
Answer :B
Solution : PHe = Ptotal  0.68
 0.38 atm
COOH
CH2
COOH
COOH
CH2
CONH 2
COOH
51 Which of the following can most readily undergo CH2

CN
reaction
s
er
A C D
B.
pp
. . .
Answer :B to
e_
je
iit
52
e/
.m
//t
s:
When the substance undergoes dehydrohalogenation by E2 reaction the major

tp
product formed will be

ht
Cl CN COOH
A C D 3 
CHCOOH Cl2
CH KCN HO3  
P 2  CH 2 CH2  CHCOOH
B. 3
. . .
COOH COOH COOH
Answer :C
Solution : Trans elimination product is the major product
53
In this reaction, the major product is
A B C
D.
. . .
Answer :A
Solution :
Stable carbonium ion

54
s
er
In the reaction ,
pp
the major product is
to
e_
A B C D
je
. . . .
iit
e/
Answer :D
Solution : Nucleophilic substitution reaction is given by alkyl side chain of Benzene
.m
//t
55 The decreasing order of stability of the following carbocations

s:
tp
  
P. CH 3 C HOCH 3 Q. CH 3 C HCH 3 R. CH 3 C HCOCH 3 is
ht
A. P > R > Q B. P > Q > R C. R > Q > P D. R > P > Q
Answer :B
Solution :
 
CH 3 C HOCH 3 is Stabilised by resonance. CH 3 C HCH 3 is stabilised by hyper conjugation.
is destabilised due to presence of withdrawing group .The order is
  
CH 3 C HOCH 3 > CH 3 C HCH 3 > CH 3 C HCOCH 3
56 There are primary (x) ,secondary(y) and tertiary (z) amino groups in histamine,which is least basic ?
A. z B. x C. y D. all are equally basic
Answer :C
s
Solution : secondary amine’s (y) lone pair is part of aromatic sextet .If it is donated,
er
the molecule ceases to be aromatic. Hence it is least basic
pp
57
to
What is the equivalent weight of P4 in its disproportionation into PH3 and H 2 PO2 ? ( mol wt is M)
e_
M M C. M M
A. B. D.
je
4 3 12
iit
e/
Answer :B
.m
( 3) ( 1)
Solution : P4  P H 3  H 2 PO2
//t
s:
In disproportionation
tp
E  Eoxidised  Ereduced
ht
M M M
E  
12 4 3
58 Which of the following has a peroxy linkage
A. KMnO4 B. K2CrO4 C. K2 S2O7 D. K2TiO4
Answer :D
Solution : . K2TiO4 has peroxy bond
59 The following reactions were started with only reactants.If the equilibrium
concentrations of every species is 0.01 M, extent of reactions taking place at
equilibrium
I. Pcl5 ( g )  Pcl3 ( g )  cl2 ( g ) ;
II. 2HI ( g )  H 2 ( g )  I 2 ( g )
A. I > II B. I < II C. II =I D. data insufficient

Answer :B
0.1 0.1
Solution : Kc for I   0.1
0.1
0.1 0.1
Kc for II  1
(0.1) 2
 Extent of reaction is I < II < III
s
er
(0.1)2
pp
K c for III   100
0.1 (0.1)3
60 The vapours density of to
N2O4 at certain temperature is 30. What is the %
e_
dissociation of N2O4 at this temperature?
je
A. 53.3 % B. 106.6 % C. 26.7 % D. None

iit
Answer :A
e/
Solution : At equilibrium
.m
N 2O4  2 NO2
//t
s:
t=0 1 0
tp
ht
1  x 92
At equilibrium 1-x 2x. i 
1 60
∴ x = 0.533 & % dissociation = 53.3 %

61 A mixture of 2 moles of CH4 and 34 g of H2 S was placed in an evacuated
container, which was then heated to & maintained at 7270C. When equilibrium is
established as the gaseous reaction CH 4  2 H 2 S  CS2  4 H 2 , the total pressure
in the container was 0.92 atm and the partial pressure of hydrogen was 0.2 atm.
What was the volume of container ?
A. 25 L B. 300 L C. 200 L D. 10 L
Answer :B
Solution : CH4  2H 2 S  CS2  4H 2 Total moles = 3+2x
4x
Initial 2 10 0 given PH 2  0.2   0.92
3  2x
moler At equilibrium 2-x 1-2x x 4x ∴ x = 0.183
Total moles in flask = 3+2x = 3.366
nRT
V  299.84 L
P
O CH
62
CH3
s
A ; A is
er
pp
O O O O
C - OH C - OCH3
A B C
to
COOH
D.
. . .
e_
je
Answer :B
iit
e/
.m
//t
Solution :
s:
tp
ht

H

63
II in the above sequence of reaction is
A C D
B.
. . .
Answer :C
64
The structure of the product is
A C D
B.
. . .
Answer :C
65
s
er
pp
.
to
e_
The product is
je
iit
e/
A
B.
.
.m
//t
s:
tp
C
D.
.
ht
Answer :C
( i ) HI cold
66
I (CH 3 )3 C  O  CH 3 
Which of the following is right
A. The products in reaction I are (CH3 )3 COH and CH3 I
B. The products in reaction II are (CH3 )3 COH and C6 H 5 I
C. The products in reaction II are (CH3 )3 CI and C6 H 5OH
D. The products in reaction I are and CH3 I

Answer :C
67 Consider only the reduction half reaction in the following.
CN(aq )  MnO4 ( aq )  CNO(aq )  MnO2( s )
Which of the following is correct?
s
er
A. Two moles of OH  ions to be added to the left side of the reaction
pp
B. Two moles of OH  ions to the right side of the reaction
C. Two moles of OH  ions to both sides of the reaction
D. Four moles of OH  ions to right side of the reaction to
e_
Answer :D
je
Solution : MnO4  2 H 2O  3e   MnO2  4OH 

iit
68
e/
800 c
.m
 The major product is

HBr
//t
s:
A
B.
.
tp
ht
C
D.
.
Answer :A
Solution : at lower temperature kinetically controlled product is major (ie) 1, 2 – addition product
69 Which of the following is incorrectly matched?
Quinoline
A. 
H 2 / Pd  BaSO4
ether
B. 
NaNH 2
C.
D D
excess NaNH 2 D2 O D2 / Pt | |
D. H  C  C  H    D  C C D
| |
D D
Answer :C
Solution : Bulkier base gives Hoffman product
70 If Cu2 S is treated with acidic solution of KMnO4 it is completely oxidized to Cu 2 and SO2 is liberated.
s
er
Moles of KMnO4 required for complete oxidation of 1.25 mol of Cu2 S is
pp
A. 5 B. 3 C. 1 D. 2
Answer :D to
e_
Solution : 8MnO4   5Cu2 S  Cu 2  Mn 2  SO2
je
iit
( n  5) ( n  8)
e/
.m
8 moles  5 moles
//t
?  1.5 moles
s:
8 1.5
tp
 2
5
ht
71 What is the product of dehydrohalogenation of (R,R) – 2, 3- dibromobutane?
A B C D
Answer :B
Solution :
72 The pH at which Mg(OH)2 begins to precipitate from a solution containing 0.1M Mg 2
( K sp of Mg (OH )2  11011 )
A. 5 B. 6 C. 11 D. 9
Answer :D
Solution : When Mg(OH)2 starts precipitation, then
[ Mg 2 ][OH  ]2  Ksp of Mg(OH)2
0.1 [OH  ]2  11011
[OH  ]  105
s
P OH  5
er
pp
PH  9
73
to
A sample of hard water contains 0.005 moles of CaCl2 / Lit . The minimum concentration of Na2 SO4 that
e_
must be added for removing Ca 2 from this is_______(Ksp of CaSO4  2.4  105 )
je
iit
A. 4.8  10 5 moles / Lit B. 48  103 moles / Lit

e/
.m
C. 4.8  10 8 moles / Lit D. 4.8  10 3 moles / Lit

//t
Answer :D
s:
Solution : For CaSO4  Ca 2  SO42

tp
ht
[Ca +2 ][SO 4 -2 ]=Ksp
0.05  [ SO42 ]  2.4  10 5
2.4 10 5 2.4

[SO42 ]   102
0.005 5
24
  103  4.8  103
5
74 Freshly precipitated Al and Mg hydroxides are stirred vigorously in a buffer solution containing 0.25M
NH 4Cl and 0.05M NH 4OH . Kb for NH 4OH  1.8  105 Ksp of Al (OH )3  6  1032 , Ksp of
Mg (OH ) 2  8.9  10 12 then the [OH  ] conc of the solution is
A. 8.9  10 12 B. 3.6  106 C. 3  105 D. 10 10
Answer :B
Solution : For buffer solution
[ Salt ]
POH   log kb  log
[base]
0.25
P OH   log1.8  105  log
0.05
[OH ]  3.6 106 M

75
s
er
.
pp
The structure of the product in the above reaction is
to
e_
je
iit
A B D
e/
C.
. . .
.m
//t
Answer :C
s:
Solution : SeO2 oxidises alpha carbon to carbonyl groups in carbonyl compounds.

tp
ht
76
.
The structure of the product is
A
B.
.
C
D.
.
Answer :B
77 In the given reaction
A
B.
s
.
er
pp
to
e_
C
D.
.
je
iit
e/
Answer :A
.m
Solution : Most stable carbocation is formed with the loss of chlorine from  -position.
78
//t
s:
tp
ht
A C D
B.
. . .
Answer :B
79
.
In the mechanism of the above, the species that is not formed/not
involved.
A B C
D.
. . .
Answer :B
80 Which of the following is more reactive towards electrophilic substitution
A C
B. D.
. .
Answer :A
81 A balloon of radius of 3mts at a pressure of 1atm and 250 C at sea level density of air
is 1.22 kg/m3. If air present in balloon is replaces by Hydrogen gas. How many moles
s
of Hydrogen received to fill the balloon.
er
A. 2.3  103 B. 6.93  103 C. 4.62  103 D. 9.24  103
pp
Answer :C
4
Solution : Volume of balloon=  r 3
3 to
e_
je
PV
No. of moles of ‘He’ =  4.6  103
iit
RT
e/
82 150ml of I2 solution is divided into two unequal parts. I part react with hypo solution is
.m
acidic medium 15ml of 0.4M hypo was consumed. II part was added with 100ml of
0.3M NaOH solution. Residual base required 10ml of 0.3M H2SO4 for complete
//t
neutralization. Intial concentration of I2 is

s:
A. 0.2 M B. 0.1M C. 0.08M D. 0.04M

tp
Answer :B
Solution : (I) I 2  Na2 S2O3  2 NaI  Na2 S4O6
ht
m.moles of hypo = 15  0.4  6
m. moles of I 2  3
(II) 3I 2  6 NaOH  5NaI  NaIO3  3H 2O
30  2  3
m.mole of I2 reacted with NaOH   12
2
Total m-moles of I 2  3  12  15
15
M  0.1
150
83 The equilibrium constant KP for the reaction N2O4 ( g )  2 NO2 ( g ) is 4.5 what would
be the average molar mass in (gm/mole) of an equilibrium mixture N2O4 & NO2 of a
total pressure of 2 atm?
A. 69 B. 80.5 C. 57.5 D. 85.5
Answer :C
Solution : N 2O4 ( g )  2 NO2 ( g )
1 0
1 2
4 2
KP  P
(1   2 )
  0.6
Average molar mass = 92. X N 2O4  46. X NO2
s
er
= 57.5
pp
84 Consider the partial decomposition of ‘A’ as 2 A( g )  2 B( g )  C( g ) . At equilibrium 700ml
to
of gaseous mixture contains 100ml of gas ‘C’ at 300k. If equilibrium pressure is 10 atm,
e_
the value of KP is
40 1 28 10
je
A. B. C. D.
7 28 10 28
iit
Answer :D
e/
Solution : 2 A( g )  2 B( g ) C ( g )
.m
400 ml 200 ml 100 ml

//t
For Ideal gas volume % = mole %

s:
85 A mixture of Na2C2O4 and NaHC2O4 required equal volumes of 0.1M K2Cr2O7 for
tp
oxidation and 0.1M NaOH for neutralization in separate titrations. The molar ratio of
ht
Na2Cr2O4 and NaHC2O4 in the mixture is

A. 1:1 B. 2:1 C. 1:2 D. 3:1
Answer :B
Solution : Let Na2C2O4  x
NaHC2O4  y
With K2Cr2O7 both get oxidized
 v  0.1 6  ( x  y )  2
With NaOH only NaHC2O4 gets neutralized

 v  0.1 1  y  1  y  0.1v
0.6v  0.2v
x  0.2v
2
 x : y = 2:1
86 In order to prepare a buffer of pH = 8.26, the amount of ( NH4 ) 2 SO4 required to be

mixed with 1L of 0.1M NH3 ( pKb  4.74) is
A. 1 mole B. 10 mole C. 0.5 mole D. 5 mole
Answer :C
Solution : pOH = 14 – pH = 5.74
[ NH 4 ] [ NH 4 ]
pOH  pK b  log  4.74  log
[ NH 3 ] 0.1
s
er
[ NH 4 ]  1
pp
 [( NH 4 ) 2 SO4 ] 
1
 0.5 mole to
e_
2
je
iit
87
e/
.m
then ‘A’ is
//t
s:
A B C D
tp
. . . .
ht
Answer :B
88
‘A’ is
A B D
C.
. . .
Answer :A
89 CH3CHO react most readily with
A NH 2  NH2 B C Ph  NH  NH2 D H 2 N  OH
. . . .
Answer :A
s
90 Excess of CH 2 N 2
CH  CH  ' A ' , then ‘A’ is
er
pp
A. CH 3  C  C  CH 3 B. CH  C  CH3
to
e_
D.
je
C.
iit
Answer :C
e/
.m
//t
91 100 ml of 0.01M KMnO4 oxidizes 10 ml of H 2O2 sample in acidic medium. The

s:
volume strength of H 2O2 sample is

tp
ht
A. 11.2 vol B. 5.6 vol C. 2.8 vol D. None
Answer :C
Solution : eq KMnO4  eq H2O2
100  0.01 5  10  M  2
5 11.2
M 11.2  V .S  V .S   11.2   2.8 vol
20 4
92 K sp of M (OH ) 2 is 3.2  10 11 . The pH of its saturated solution in water is
A. 10.3 B. 10.6 C. 3.7 D. 3.4
Answer :B
Solution : M (OH )2( s )  M 2( aq )  2OH  ( aq )
K sp  4 s3  3.2 1011
s  2  10 4 M
[OH  ]  2s  4 104 M
pH  14  pOH  14  log(4 104 )  10.6

93 Compound ' X '(C4 H 8O) gives positive haloform test but does not give 2,4-DNP derivative is
A B C
D.
. . .
s
Answer :A
er
Solution : A-gives +ve haloform test but not give 2,4- DNP derivation
pp
BD-does not give +ve halo form test
to
e_
C- gives +ve halogorm test & give 2,4-DNP derivation
je
iit
e/
94
.m
//t
s:
tp
ht
‘A’ is
A B D
C.
. . .
Answer :A
95
The value of x is
A. 6 B. 4 C. 3 D. 2
Answer :A
s
Solution : Each requires two CH3 Mg Br &  OH , SH contain active ' H ' and two more
er
pp
CH3 Mg Br molecules
96 The hydrolysis of to
e_
je
iit
e/
.m
//t
s:
in aqueous acetone gives

tp
ht
Find the correct statements
A. K and L B. only K C. L and M D. Only M
Answer :A
97 Which of the following statements regarding a liquid is not correct

A. Surface tension of a liquid depends on temperature
B. Surface tension is an intensive property
C. The SI unit of surface tension is Nm 1
D. For a liquid surface tension and surface energy have different values
Answer :D
98 When 20g of C11H8O2 is dissolved in 50g of C6 H 6 ( K f  1.72 K kg mol 1 ) a
s
freezing point depression of 2K is observed The van’t noff factor is
er
pp
A. 0.5 B. 1 C. 2 D. 3
Answer :A to
e_
Solution : T f  iK f m
je
iit
20 x1000
2  ix1.72 x = ix 4 i  0.5
e/
172 x50
.m
99 A solution containing 8.6 g / L of urea is isotonic with a 5% solution of unknown

solute. Molecular weight of the solute(non electrolyte) is
//t
s:
A. 348.9 B. 174.5 C. 87.5 D. 34.89

tp
ht
Answer :A
Solution :  = C.R.T
1   2
C1  C2
8.6 5
 M= 348.9
60.1 Mx0.1
100 Which of the following can give purple color with neutral FeCl3 ?
(i) (ii) (iii) (iv)
A. ii and iv B. i & iii C. ii & iii D. iii & iv
Answer :A
Solution : The phenolic – OH groups give purple colour with neutral FeCl3
101 Major product of the following reaction is
s
er
pp
to
e_
je
A B C D
. . . .
iit
e/
Answer :A
.m
Solution : Hoffman elimination

//t
102
s:
tp
ht
The product B is
A B C
D.
. . .
Answer :B
103 At a certain temperature, the equilibrium constant KC is 4 for the reaction
A2 ( g )  B2 ( g )  C2 ( g )  D2 ( g ) . If we take 1mole each of the four gases in a 10 – L flask,

and the equilibrium is reached, what would be the equilibrium concentration of A2 ( g )?
A. 0.331M B. 0.033M C. 0.0667M D. 0.0133M
Answer :C
s
er
pp
Solution :
to
e_
(1  x )2
je
kc   4  x  0.333
(1  x) 2
iit
e/
[ A2 ]eq  0.0667 M
.m
104 Which of the following alcohols cannot be oxidized by K2Cr2O7 ?

//t
s:
A CH  CH  OH B C CH 2  CH  CH 2  OH
D.
tp
3 2
. . .
ht
Answer :B
105 H  / H 2O
In the given reaction X  R Mg Cl (excess)  30  alcohol
O O O
A. || B. R  CONH2 C. || D. ||
R  C  Cl R C  R R C  H
Answer :A
106 Solubility of AgI in 0.05M BaI 2 solution is 10 15 M . The solubility of AgI in water is
A. 25  107 B. 107 M C. 5 108 D. 108 M .
Answer :D
k sp
Solution : 10 15 
0.1
ksp  10 16
5  ksp
 10 8 M
107 A complex is represented as CoCl3 xNH3. Its 0.1 molal solution in water shows
T f  0.558 K . K f for H 2O is 1.86 K molality 1. Assuming 100% ionisation of
complex and co-ordination number of Co is six. The formula of complex:
s
A. [Co( NH3 )6 ]Cl3 B. C. D. [Co( NH 3 )3 Cl3 ]
er
[Co( NH3 )5 Cl ]Cl2 [Co( NH3 )4 Cl2 ]Cl
pp
Answer :B
to
e_
Solution : T f  K f  molality  i; 0.558  1.86  0.1 i or i  3
je
Thus complex is [CoCl.xNH3 ].Cl2 . Since co-ordination number of CO is six, thus

iit
e/
complex is [CO( NH3 )5 Cl ]Cl2 .

.m
108 E o for two reaction are given below :

//t
Cr 3  3e  Cr; E o  0.74V
s:
OCl   H 2O  2e  Cl   2OH  ; E o  0.94V

tp
What will be the E o for ?

ht
3OCl   2Cr  3H 2O  2Cr 3  3Cl   6OH 

A. -1.68V B. 1.68V C. -0.20V D. 0.20V
Answer :B
Solution : E o cell  E o catlohed  E o anode
 0.94  (0.74)
 1.68V
109 The reagent that can be used to convert butan-2-one to propanoic acid is
A. B. Fehling’s C. Tollen’s reagent D. NaOH , I 2 / H 

solution
NaOH , NaI / H 
Answer :D
Solution :
110 In the reaction

OH
+ C2H5I 
C2 H5O
 anhydrous C2 H5 OH 
 A. The product A is
s
er
pp
A. C6 H 5OC2 H 5 B. C2 H 5OC2 H 5 C. C6 H 5OC6 H 5 D. Both A & B
Answer :D
Solution : C2 H 5O   C2 H 5  I  C2 H 5OC2 H 5 to
e_
je
111 The acidic strength of methoxy phenols is

iit
A. m  Phenol  p  o B. C. D.
e/
m  Phenol  o  p p  o  Phenol  m p  o  m  Phenol

.m
Answer :B
//t
s:
112 The herbicide propranil shown below, is synthesized commercially from chlorobenzene.
tp
Which sequence of following reactions would be most effective for carrying out this
ht
synthesis
H
Cl N
O
Cl
A. Chlorination, nitration, reduction, acylation
B. Chlorination, reduction, nitration, acylation
C. Nitration, chlorination, reduction, acylation
D. Nitration, reduction, chlorination, acylation
Answer :C
Solution :
113 A volatile solute AB is dissolved in water, in which mole fraction of water is 5/6. If 50% of
molecules of AB get dissociated into A and B and remaining 50% get dimerised into
(AB)2. Then relative lowering in vapour pressure will
A. Increase by 20%
B. Increase by 25%
s
C. Remain same because mass of solute is unchanged
er
D. Remain same because no of solute particles will not change
pp
Answer :A
to
e_
P0  P in
Solution : 
P0 in  N
je
iit
1
e/
2 ABA  B  ( AB)2
2
.m
1 0 00
//t
1  10.5 0.50.25
s:
so i  1.25
tp
ht
1.25  1 / 6
RLVP   0.2
1 5
1.25  
6 6
In normal condition
1/ 6
RLVP   1/ 6
1/ 6  5 / 6
0.2  (1/ 6)
% change  100  20%
(1/ 6)
114 Given, 2 H 2O  O2  4 H   4e  ; E 0  1.23V , H 0f ( H 2O )  285.8kJ mol 1
The S 0 for the fuel cell reaction 2H 2  O2  2 H 2O at 298K is,
A. 474.8JK 1 B. 325.0JK 1 C. 474.8JK 1 D. 571.6JK 1
Answer :B
Solution : G 0   nFE 0
4  96500  1.23  (285.8 103  2)  298  (S )
S  324.89  325 JK 1
115 The enthalpy of neutralization of a weak monobasic acid in 1M solution with a strong base
is –56.1 kJ mol–1 whereas the enthalpy of ionization of the acid is 1.5 kJ mol–1 and
DH°neutralisation of strong acid against a strong base is – 57.3 kJ equiv–1. The percent
ionization of the weak acid is
s
er
A. 10 B. 20 C. 25 D. 80
pp
Answer :B
Solution : The heat that was used in the process to
e_
 56.1  ( 57.3)  1.2kJ / mole remaining 0.3 kJ / mole was not required, as it already
je
0.3
undergoes ionization. So % of ionization   100  20%
iit
1.5
e/
.m
116 What is the minimum pH required to prevent the precipitation of ZnS in a solution that is
//t
0.01M ZnCl2 and saturated with 0.1M H2S? (Given: KSp  1021 , Ka1  Ka2  10 20 )
s:
tp
A. 0 B. 1 C. 2 D. 4
ht
Answer :B
ksp of Zns 10 21
Solution : The [S 2 ]required  2
  1019
[Zn ] 0.01
H 2 S 2 H   S 2
[ H  ]2 [1019 ]
1020 
0.1
[ H  ]  0.1  PH  1
117
what is x
A. CH 3COOH B. C. (CH3CO)2 O D. CHO  COOH

BrCH 2  COOH
Answer :C
Solution : Perkin’s reaction.
s
118 The product of acid hydrolysis of M and N can be distinguished by
er
pp
to
e_
je
iit
e/
.m
A. Lucas test B. 2,4, - DNP C. Fehlings solution D. isocyanide test

//t
Answer :C
s:
Solution :
tp
ht
Aldehydes and ketones can be distinguished with Fehlings solution.
119 A weak acid HA after treatment with 12ml of 0.1M strong base has a pH of 5. At the end
point the volume of same base required is 26.6 ml. The Ka of acid is
A. 1.74 105 B. 6.2  10 4 C. 3.9  108 D. 8.2  106
s
er
Answer :D
Solution : Total no. of equivalents of acid = no. of equivalent of base used at the end of
pp
titrations
 26.6  103  0.1 to

e_
je
before the equivalents point the mixture acts as a butter so

iit
e/
no.of eq of acid
[ H  ]  Ka 
.m
no.of eq of salt
//t
5 26.6  0.1 10 3  12  0.1 10 3

s:
10  K a 
12  0.110 3
tp
ht
K a  8.219  10 6
120 A binary solution is prepared with 1 mole of liquid A( PA0  50mm ) and 1 mole of liq.
B ( PBo  100mm) . If the pressure over the mixture is reduced, then the pressure at which
last trace of liquid will disappear, will be
A. 75 mm B. 66.67 mm C. 150 mm D. 133.33 mm
Answer :A
Solution : The disappearance of last trace of liquid indicates that the solutions undergoes
complete boiling. So at that condition the vapour pressure over the mixture = the
atmospheric pressure.
121
The correct IUPAC name for
A. 4-(methyl amino)-2-methyl-1-pentene B. 2, N-dimethyl-1-penten-4-amine
D. 1,3-dimethyl-3-buten-1-amine
C.
Answer :C
Solution : Double bond is of lower priority
s
er
pp
122 The correct sequence of steps below describe the best synthesis of 5-oxohexanoic acids
starting with 1-methyl cyclo pentan-1-ol.
to
e_
A. 1. Conc. H 2 SO4 , 2. Dry Gaseous HBr, 3. Mg, ether, 4. CO2
je
B. 1. H 2 SO4 , heat 2. Conc. KMnO4

iit
e/
C. 1. Conc. KMnO4 , 2. CH3 MgBr  ether , 3. H 3O 

.m
//t
D. 1. H 2 SO4 and heat 2. Conc. KMnO4 , 3. LiAlH 4 , 4. H 3O 

s:
Answer :B
tp
ht
123 An ether solution of PhCO2 H (1), PhNH 2 (2) and PhNO2 (3) is extracted with NaOH. After
extraction, compounds present in the ether layer.
A. 1 & 2 B. 1 & 3 C. 2 & 3 D. 1 only
Answer :C
Solution : Sodium hydroxide does not react with 2 and 3.
124 A certain reaction is spontaneous at low temperature but non spontaneous at high
temperature. Which of the following is true for the reaction ?
A. H  0, S  0 B. H  0, S  0 C. H  0, S  0 D. H  0, S  0
Answer :D
Solution : G  H  T S
When H  0 and S  0 then G will be negative at low temperatures and the reaction
will be spontaneous.
125 The enthalpy of solution of sodium chloride is 4 KJ mol 1 and its enthalpy of hydration of
ions is 784 kJ mol 1 . The lattice enthalpy of NaCl (in kJ mol 1 ) is
A. +788 B. +398 C. +394 D. +780
Answer :A
Solution : H sol  H lattice  H hydration
s
er
4  (784)  Hlattice
pp
H lattice  788
to
e_

126 Cl2
CH 3COOH  KCN
 A  H 3O
 B  
 C   D What is D ?
je
P
iit
COOH COOH
e/
COOH
CH2 CH2 CH2
.m
COOH CONH2 CN D. CH3COOH

A. B. C.
//t
s:
Answer :D
tp
Solution :
ht
Cl CN COOH
Cl2 KCN 
CH 3COOH P
 CH 2   CH 2 H 3O
  CH 2 
  CH 3COOH
COOH COOH COOH
127
X is_________
A. B. C. D. both b and c
Answer :D
Solution :
s
er
pp
to
e_
je
iit
128 The iso electric points of Aspartic acid, glycine and Lysine are 2.77, 5.97 and 9.74
e/
respectively. The solution of the mixture of these three amino acids is maintained at pH
.m
5.97 . The solution is subjected to electrolysis . The amino acid migrating towards anode
//t
is________
s:
A. aspartic acid B. Glycine C. Lysine D. both a and b

tp
ht
Answer :A
Solution : pH of aspartic acid is 2.77 . The solution of it is basic as pH of solution is 5.97.
So the acid exists as anion in basic medium and migrate to anode
129 18 gm of ice is converted into water at 00 C and 1 atm. The entropies of H 2O( s ) and
H 2O( l ) are 38.2 and 60 J/mol .K respectively . Then the enthalpy change for this
conversion is
A. 5951.4 J/mol B. 595.14 J/mol C. -5951.4 J/mol D. -595.14 J/mol
Answer :A
Solution : At equilibrium G  0
H  T S
S  S H 2O ( s )  S H 2O ( l )  21.8 J / mol.k ( entropy is positive)
H  273(21.8)  5951.4 J / mol
s
130 If a reaction is carried out at 400K,0.01 % of the total number of collisions are effective . The energy of
er
pp
activation of the reaction is
A. 13.3 KJ/mol B. 23.5 KJ/mol C. 3.2 KJ/mol

to D. 30.6 kJ/mol
e_
Answer :D
je
0.01
Solution : e  Ea / RT 
iit
100
e/
.m
 Ea
 2.303 log104
RT
//t
s:
Ea  2.303 8.314  400  ( 4)  30.6 KJ

tp
ht
131 5 g of radioactive species having molar mass 200 undergoes decay with decay constant of  .
The intial specific activity can be given by
A. 3 1023  dps B. 3 1024  dps C. 3 1021  dps D. 3 1020  dps
Answer :C
Solution : Specific activity = activity shown by 1 g species = rate shown per g of species
.N A 6 1023  
Activity =  .N      3  1021
M 200
132 AlCl3 on reaction with aqueous Na 2CO3 gives
A. Al 2 (CO3 )3 B. Al2O3 C. Al(OH)3 D. Al4C3
Answer :C
133 Which of the following colloid can be prepared by electrical dispersion as well as reduction
method?
A. Sulphur B. Ferric hydroxide
C. Arsenious sulphide D. Gold
Answer :D
Solution : By Bredg’s arc method as well as reduction method when AuCl3 is reduced by SnCl2 .
s
AuCl3  3SnCl2  2 Au  3SnCl4
er
pp
134 Which of the following is a process of stabilising a sol?
A. Coagulation B. Peptisation to
C. Dialysis D. Flocculation
e_
Answer :C
je
iit
e/
.m
135 Which of the following anions will have minimum flocculation value for the ferric
hydroxide sol
//t
s:
A. SO42  B. Cl  C. Br  D. [ Fe(CN ) 6 ]3

tp
ht
Answer :D
136 Polyphosphates are used as water softening agents because they:
A. Form soluble complexes with anionic species
B. Precipitate anionic species
C. Form soluble complexes with cationic species
D. Precipitate cationic species
Answer :C
Solution : Polyphosphates are used as water softening agents because they form soluble
complexes with cationic species
137 Suppose the bond energies of H  H , O  O , and O  H bonds are x1 , x2 and x3 and latent
heat of vaporisation of H 2O( l ) into H 2O( g ) is x4 , Then the heat of formation of liquid water is
s
er
x2 x2
pp
A. x1   x4  2 x3 B. x1   x4  2  3
2 2
to
e_
x2 x1 x2
C. x1   x3  x4 D.   x3  x4
2 2 2
je
iit
Answer :A
e/
1
Solution : H 2( g )  O2( g )  H 2 O( l )
.m
2
//t
H  B.E (reac tan t )  B.E ( product )

s:
tp
1
 [ B.E ( H  H )  B.E (0  0)]  [ H v  2 B.E(OH ) ]
ht
x2
 x1   x4  2  x3
2
138
The suggested mechanism for the reaction is
The rate equation is
A. B.
C. D.
Answer :D
Solution :
s
er
pp
to
e_
Hence,
je
iit
139 Sodium peroxide which is a yellow solid, when exposed to air becomes white due to the formation
e/
of
.m
A. H 2O2 B. Na2O
//t
s:
C. Na2O and O3 D. NaOH and Na2Co3

tp
Answer :D
ht
Solution :
140 Which set of terms correctly identifies the given carbohydrate ?
(1) Pentose (2) Hexose (3) Aldose
(4) Ketone (5) Pyranose (6) Furanose
A. 1,3 and 6 B. 1,3 and 5 C. 1,4 and 6 D. 2,3 and 6
Answer :A
Solution : Compound has 5 carbon atoms. Its first carbon has  H and OH groups – so its aldose.
It is a 5 membered hetero cyclic ring like furan.
141
s
er
H 3O 
pp
CH 3 MgBr  Q  P , then P is
to
e_
je
iit
e/
.m
A. B. C. D.
//t
s:
Answer :D
tp
ht
142 For given amino acid
Iso electric point P.I is
s
8.95  2.18 2.18  10.75 8.95  10.79 D. None of these
er
A. B. C.
2 2 2
pp
Answer :C
Solution : conceptual to
e_
je
143 Arsenous sulphide sol is prepared by passing H 2 S through arsenous oxide solution. The charge
iit
e/
developed on the particles is due to adsorption of

.m
A. H  B. O 2 
//t
C. OH  D. S 2 
s:
tp
Answer :D
ht
Solution : CONCEPTUAL
144 Amylopectin in starch has
A.   D - Glucose units joined by C1  C4  – Glycosidic linkages
B.   D Glucose units joined by C1  C4  – Glycosidic linkages
C.   D Glucose units Joined by C1  C5   Glyclosidic linkages
D.   D Glucose units Joined by C1  C4  – Glycosidic linkages
Answer :A
145 The number of tetrapeptides possible from 3 different amino acids
A. 4 B. 27 C. 81 D. 12
Answer :C
Solution : The no of possible polypeptide from ‘n’ different amino acids is nm
m = total no of amino acids in peptide
so 34  81
146 A Freshly prepared Fe(OH )3 precipitate is peptised by adding FeCl3 solution. The charge
s
er
on the colloidal particle in due to preferential adsorption of
pp
A. Cl  ions B. Fe3 ions C. OH  ions D. Fe 2 ions
to
e_
Answer :B
je
iit
e/
147 Lassaigne’s test for the detection of nitrogen fails in

.m
A. urea B. semicarbazide C. Hydrazine D. phenyl hydrazine

//t
s:
Answer :C
tp
ht
148 For H 3 PO3 and H 3 PO4 the correct choice is
A. H 3 PO3 is diabasic and reducing B. H 3 PO3 is diabasic and non-reducing agent

agent
C. H 3 PO4 is tribasic and reducing D. H 3 PO3 is tribasic and non reducing agnet
agent
Answer :A
149 Ammonal is a mixture of
A. ‘Al’ powder  Fe2O3 B. NH 3  RCHO
C. ‘Al’ powder  NH 4 NO3 D. TNT  NH 4 NO3
Answer :C
150 1
The total energy emitted in watts by 15mg of a  -emitter 58 Ce141 (t  31.11 days ) , If average
2
energy of  particles emitted by 58 Ce141 is 0.442 MeV.
A. 2.5 watt B. 0.63 watt C. 3.286 watt D. 1.167 watt
s
er
Answer :D
pp
3
 0.693  15 10 
Solution : Rate  N     6  1023 
 
 31.11 24  60  60   141 to 
e_
je
 1.65  1013
iit
1.6 106
e/
Total energy  [1.6 1013  0.442 MeV ] 

107
.m
//t
= 1.167 watt
s:
151 In the graph, isotherm, for physical adsorption of gases on solids

tp
ht
Which is wrong statement
A. Both Freundlisch and Langmuir can explains the curve
x
B. At low press P
m
C. Only desorption takes place at III stage
D. In physicsl adsorption multilayers are formed with increase of pressure
Answer :C
152 In a unit cell, anions ‘A’ occupy all fcc positions and cations ‘B’ occupy half of the tetra
hedral voids, and if the crystal compound consists only A&B then the void space is how
much (nearly)
s
A. 25% B. 16% C. 37% D. 54%
er
pp
Answer :A
Solution : for fcc, rA 
a
to
e_
2 2
je
Volume (a)  a 3
iit
e/
4 1 4
(4   rA3 )   (8   rB3 )
.m
P.E.  3 2 3
a3
//t
s:
P.E.  0.75  void  0.25  25%

tp
ht
153 K4 [ Fe(CN )6 ] reacts with ozone and forms
A. Fe(OH )2 B. KOH C. K3[ Fe(CN )5 NO] D. K3[ Fe(CN )6 ]
Answer :D
154 A 1 gm sample of H 2O2 solution containing x percent H 2O2 by weight required x ml of KMn O4 for
complete oxidation in acidic medium. The normality of KMn O4 is
5 10 15 20
A. B. C. D.
17 17 17 17
Answer :B
x
Solution : Ans :B wt. of pure H 2O2  g.
100
x 1 x
No.of gm equivalents of H 2O2    .
100 17 1700
x x 10
  N N 
1700 1000 17
155 Ammonium dichromate on heating produces
A. NO2  Cr2O3  H 2O B. N2O  Cr2O3  H 2O C. N2  Cr2O3  H 2O D. NO  CrO  H 2O
Answer :C
s
Solution : (C) Fact based
er
pp
155 10 g of a sample of bleaching powder is treated with excess dilute acid. The liberated
to
Cl2 is passed through KI solution . I 2 produced in this reaction, requires 100ml of 1M
e_
hypo solution for complete reaction. Available chlorine content of that hypothetical
je
sample is
iit
A. 71% B. 35.5% C. 3.55% D. 7.1%

e/
.m
Answer :B
//t
Solution : (B) CaOCl2  H 2 SO4  CaSO4  H 2O  Cl2

s:
tp
Cl2  2 KI  I 2  2 KCl
ht
I 2  2 Na2 S2 O3  Na2 S4 O6  2 NaI
(mole of Cl2  1 mole of I 2  2 moles of Hypo)
No. of moles of hypo consumed = MV2  1  0.1  0.1
0.1
No. of moles of Cl2 liberated =  0.05
2
Man of Cl2  0.05  71  3.55g
3.55
% man of Cl2   100  35.5%
10
s
er
pp
to
e_
je
iit
e/
.m
//t
s:
tp
ht

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Single Correct Choice Type Questions

during their deexcitation is equal to :

A. kinetic energy decreases B. potential energy decreases

C. velocity decreases D. the net energy will be decreases

A. 1,2 – diethoxyethanal B. 1,2- diethoxy propanone

C. Ethoxy ethyl ethanoate D. Ethyl ethoxy ethanoate

Quick Revision Test Single Choice Questions Page 1

 formula of its sulphate is MSO4

when 1mole of Mg absorbs 285.5 K.Cal of energy, are

A. % Mg   68.4%, %Mg 2  31.6% B. % Mg   75%, %Mg 2  25%

C. % Mg   60%, %Mg 2  40% D. % Mg   72%, %Mg 2  28%

ions are ionised

Quick Revision Test Single Choice Questions Page 2

9 Two forms of D-glucopyranose are frequently called

C. a racemic mixture D. a diastereomeric mixture

The compound formed is optically inactive due to absence of chiral C atom

12 Which of the following effects of –OCH3 group,stablise the following carbocation?

Quick Revision Test Single Choice Questions Page 3

A. – Inductive effect B. + Mesomeric effect

C. – Mesomeric effect D. + Inductive effect

13 Identify the least stable carbanion from the following,

Solution : Mesomeric effect does not operate at meta position

14 Which among the following is most basic?

15 CuI 2 is unstable even at ordinary temperature because :

C. the I  ion with a larger radius has a high polarisability.

Quick Revision Test Single Choice Questions Page 4

makes it as oxidizing agent and I  as a reducing agent, reduces Cu 2 to Cu  and itself

16 Which of the following is not linear ?

A. CO2 B. ClO2 C. I 3 D. NO2

17 Which of the following statements is correct ?

A. Hybridisation of carbon in C3O2 is sp 2

B. In Cr2 O72  all Cr  O bond lengths are identical

C. Three centre two electron bonds exist in B2 H 6 and Al2Cl6

D. In AgI , the colour is attributed to charge transfer spectrum

Quick Revision Test Single Choice Questions Page 5

Therefore, all Cr  O bond lengths are not equal.

D. Red blood coloration is due to the formation of Na4[Fe(CN)5NOS]

Quick Revision Test Single Choice Questions Page 6

19 The IUPAC name of the following compound is,

Solution : Mn is +2 oxidation state in MnO while in other compounds it is in

higher oxidation state. As

number of electrons per proton decreases the size decreases.

paschen series for Li 2 ion is

Quick Revision Test Single Choice Questions Page 7

23 In alkaline medium, ClO2 oxidizes H 2O2 to oxygen and is reduced to Cl  . How

A. 1.5 B. 2.5 C. 3.5 D. 5

2 moles of ClO2  5 moles H 2O2

volume of solution of (Y) would be required to oxidize 25 ml of a solution of X

containing Fe2+ ions in neutral solution ?

A. 11.4 ml B. 33.3 ml C. 12.0 ml D. 35. ml

Solution : MnO4  Mn 2  (acidic medium) Change in OS = 5

(for MnO4 N = 5M in acidic medium)

25 N = 514 x 20; 25 N = 100 M ------ (1)

Quick Revision Test Single Choice Questions Page 8

From eq. (1) & (2)

Solution : Trans alkene undergoes anti addition to produce meso compound

C. 4-Bromo-4-methyl-2-pentene D. All the above

27 Which sample contains the largest number of atoms

Quick Revision Test Single Choice Questions Page 9

28 Which of the following compounds represents a meso isomer

to remove both electrons from helium atom is

He+ is H-like species and Bohr theory is applicable