Paaras Thakur

Thermochemistry
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Example
Example
Example
Example Using the bond enthalpy data given below, calculate the enthalpy change for the
reaction C2H4(g) + H2(g) ⟶ C2H6(g)
Example Using the bond enthalpy data given below, estimate the enthalpy of formation of
gaseous isoprene
Example
 Which of the following sets represent the normal physical states of the
Example
elements concerned at 25oC and one bar pressure, with ΔHo(formation) = 0.

a. C(diamond), S8(s), Na(s)

b. C(diamond), C(graphite), Br2(l)
c. C(graphite), Br2(g), P4(white)
d. C(graphite), Br2(l), I2(s)
Example 50 mL of water takes 5 minutes to evaporate from a vessel on a heater connected to
an electric source which delivers 400 W. The enthalpy of vaporization of water is

a. 40.3 kJ mol-1
b. 43.2 kJ mol-1
c. 16.7 kJ mol-1
d. 180.4 kJ mol-1
 The mathematical expression for the standard enthalpy of sublimation is
Example
given by

a. ΔHo (sublimation) = ΔHo (fusion) - 2ΔHo(vaporization)

b. ΔHo (sublimation) = ΔHo (fusion) - ΔHo(vaporization)
c. ΔHo (sublimation) = ΔHo (fusion) + ΔHo(vaporization)
d. ΔHo (sublimation) = ΔHo (combustion) + ΔHo(dissociation
Example Which among the following has maximum standard enthalpy of formation?

a. Glucose
b. Sucrose
c. Hexane
d. Ethanol
Example The standard enthalpies of formation of H + and OH- ions in water are zero and -
229.6 kJ mol-1 respectively. The standard enthalpy of formation of liquid water is -
285.6 kJ mol-1. Then the enthalpy of neutralization of HCl(aq) by KOH(aq) is

a. 229.6 kJ mol-1
b. -173.4 kJ mol-1
c. 56.0 kJ mol-1
d. -56.0 kJ mol-1
Example In which of the following thermochemical changes is Δ Ho always negative?

a. Enthalpy of solution
b. Enthalpy of hydrogenation
c. Enthalpy of reaction
d. Enthalpy of transition
Example The heat of atomization of PH3(g) is 228 kcal mol-1 and that of P2H4(g) is
355 kcal mol-1. The energy of the P—P bond is

a. 102 kcal mol-1

b. 51 kcal mol-1
c. 26 kcal mol-1
d. 204 kcal mol-1
Example
Example
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