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Arsenic in Water
Arsenic in Water
Arsenic in Water
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Abstract
Arsenic is a common pollutant present in water and WHO has prescribed that arsenic more than
10 μg /L present in water is dangerous for health. The report studied the causes of arsenic in
water that were both natural and industrial. He report further looked into the health impact of
arsenic in water and found that arsenic in water is an important source of different types of
cancers including skin, lungs, and bladder cancer etc. Arsenic is water was also seen to be
contributing dental problems in people. The report also examined different ways including
natural and artificial ways of removing arsenic from water. Results from many scholarly articles
are cited to report their findings. Lastly, presence of arsenic in different regions of world
including Myanmar, and US is reported. The report is concluded by summarizing the findings of
study in conclusion.
Introduction
1. Arsenic in drinking water
Arsenic is a common element that is found naturally in rocks and soils and is used for a number
of industries and agriculture. Arsenic is present in both organic and inorganic forms in soil and
inorganic arsenic is the most toxic form when present in water and food. It is also a byproduct of
the smelting of copper, mines and coal. Arsenic can be used to make pesticides for wood
protection and killing insects on cotton and other agricultural crops in conjunction with other
components. (National Research Council, 1999)
Arsenic can reach the water system from natural deposits in the soil or from industrial and
agricultural contamination. It is generally accepted that naturally occurring arsenic dissolves out
of some rock layers as ground water levels drop dramatically. Some of the factories in the United
States and in other parts of the world dump thousands of pounds of arsenic into the atmosphere
per year. When released, arsenic persists in the atmosphere for a long time. Rain, snow, and
eventual settlement eliminate arsenic from the climate. Arsenic can slowly penetrate ground
water on the ground or in surface water. Any arsenic containing fertilizers used in the past or
industrial waste may create high levels of arsenic in private wells. It can also mean in the past
that chemical fertilizers or herbicides have not been adequately engineered or overused. (Arsenic
and Drinking Water, 2015)
In water, As (V) or more prevalent arsenate is the most common valence state in aerobic surface
waters and As (III) or more commonly known as Arsenite is present in anaerobic ground-water.
The prevailing As (III) compound is responsible for the pH range of 4 to 10 when the As (V)
species are adversely charged. As (III) removal efficiencies are low in contrast with As (V),
when calculated by some technology because of negative charges. (Arsenic in drinking water,
1999)
2. Physicochemical parameters in drinking water
Water can dissolve many substances, including organic and inorganic compounds, as a universal
solvent. The inconceivability of water in its purest form can be calculated by this excellent
property of water. Water quality refers generally to the water aspect that has the maximum
degree at which plants and animals grow properly. Aquatic species must survive with a stable
atmosphere and ample nutrients to grow them; productivity may depend on the water body's
physical and chemical characteristics. Only when physical and chemical parameters are usable at
optimum level will optimal efficiency be reached. Water for human use has to be free of the use
of organisms and toxic compounds.
Owing to the human population, industrialization, and pesticide use in agriculture and human
activities the contamination of waterways is rising. The growth of living organisms in the water
body is determined by parameters such as temperature, turbidity, nutrients, hardness, alkalinity,
dissolved oxygen, etc. Therefore, the measurement of water quality includes study of physical,
biological and Microbiological criteria that represent the ecosystem's biological and abiotic
status. (Solanki, 2015)
3. Mineral forms of arsenic
There are about 200 mineral species, of which, Arsenic is the main constituent. Roughly 60% of
them are arsenates, 20% sulfides and sulfur-salts and the other 20% are made up of arsenide,
arsenite, oxides, silicates and elemental. In certain mineral deposits and in particular the sulfide
minerals, arsenic is present. In iron pyrite, galena, and chalcopyrite and in sphalerite, it is less
natural. Arsenopyrite, FeAs, is the most abundant mineral of arsenic. Arsenic is used as a gold
mineralization predictor or pathfinder in geochemical studies. In sedimentary rocks, iron and
sulfide can co-precipitate arsenic. Iron deposits, iron ores and manganese nodules are arsenic
rich. The marine environment has recognized complex organic compounds containing arsenic
like, tetramethylarsonium salts, arsenocholine, arsenobetaine, dimethyl (ribosyl) arsine oxides,
and arsenic which contains lipids. Only a relatively small portion of the total ocean arsenic exists
in water solution, as much of this is dissolved into suspended particulate content. (Thornton et al.
1997)
In January 2013 a total of 55 wells were tested in seven villages covering the As pollution
spectrum in the Ayeyarwady basin of Myanmar for laboratory research. High levels of As (50–
630 μg / L) have been measured in wells with a deep depth of 60 m and high Fe (up to 21 mg /
L) and low SO4 (< 0.05 mg / L) levels. In shallow, (< 30 m) grey sands and shallow, as well as in
deep orange sands, As concentrations < 10 μg / L were assessed. (Van et al., 2014)
20. Conclusion
In conclusion, it can be said that arsenic contamination of water is very dangerous for heath
because it enhances the chances of cancer. Arsenic present in water more than 10 μg / L is above
the WHO prescribed level and it is harmful for health because human body cannot absorb it.
There are different mineral forms of arsenic and it is present in both organic and inorganic forms.
Inorganic form of arsenic is more toxic and causes different health issues. There are different
natural and artificial methods of removal of arsenic from water and modern methods of arsenic
removal are considered more efficient as compared to conventional methods. This report
reviewed many academic researches and reported their results in the areas of health and water
treatment. It is the need of the time that arsenic contaminated water is properly treated before
drinking so that its negative impact on the health is reduced.
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