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Assessing Mineral Resources in Society:

Metal Recycling
Opportunities, Limits,
Infrastructure
Acknowledgements
Acknowledgements

Copyright © United Nations Environment Programme, 2013 von Blottnitz, University Cape Town, South Africa; Patrick
Editor: International Resource Panel, Working Group on the Waeger, EMPA, Switzerland; Philippe Wavrer, BRGM, France;
Global Metal Flows Rolf Widmer, EMPA, Switzerland; Patrick Wollants, Leuven
University, Belgium and Guomei Zhou, Ministry of Environmen-
This summary booklet was prepared by M. Buchert, C. Merz (both
tal Protection, China.
Öko-Institut e. V.) and M. Reuter.
We would like to thank Christian Hudson and Marinus Kluijver
Tomas Marques, UNEP and Philip Strothmann supervised the
for providing scientific and English editorial support for the full
preparation of this summary booklet and provided valuable
report.
input and comments.
Photos: istockphoto.de: © Harrie Marinus (cover_1, p. 3), © Jon-
Thanks go to Ernst Ulrich von Weizsäcker as co-chair of the
ceclearvision (cover_2), © Milos Peric (cover_3), © JDNY59
Resource Panel and Thomas E. Graedel as leader of the Global
(cover_4), © Marco Hegener (cover_5); © zora zhuang (p. 7_1), ©
Metal Flows Working Group, the members of the Resource
Morton Photographic (p. 7_3), © JohnnyG (p. 7_4), Sergei Devy-
Panel and the Steering Committee for fruitful discussions.
atkin (p. 9_6), © deepblue4you (p. 10), © iSci (p. 12_1), © assalve
Lead author of the report metal recycling – opportunities, (p. 12_2), © urbancow (p. 13), © ugur bariskan (p. 14), © Jörg
limits, infrastructure: Markus Reuter Reimann (p. 15), © Rob Belknap (p. 18), © Caboclin (p. 19_1), ©
Report authors: Markus Reuter, Outotec Oyj, Finland and Aalto Dejan Ristovski (p. 19_2), © studio9 (p. 19_3), © Ivan Stevanovic
University, Finland; Christian Hudson, DIW, Germany; Antoi- (p. 22_1), © Richard Clark (p. 22_2), © Pete Saloutos (p. 23), ©
nette van Schaik, MARAS, Netherlands; Kari Heiskanen, Aalto sturti (p. 24_1), © Irochka (p. 24_3, p. 28_3), © Stefanie Angele
University, Finland; Christina Meskers, Umicore, Belgium and (p. 24_4). Öko-Institut e. V. (p. 9_3, p. 9_4, p. 9_5, p. 11_2, p. 11_3,
Christian Hagelüken, Umicore, Germany. p. 11_4). photocase.de: © Norman Bates (p. 9_1). pixelio.de:
© Marcus Stark (p. 2), © Oliver Moosdorf (p. 7_2). Fotolia.com:
Contributors (Alphabetical): Helmut Antrekowitsch, Univer-
© HandmadePictures (p. 16), © Stefanie Angele (p. 24_3), © To-
sity Leoben, Austria; Diran Apelian, WPI, USA; Bo Bjorkman,
bif82 (p. 31). Shutterstock.de © Tobias Machhaus (p. 26). Umicore
Luleå University of Technology, Sweden; Bart Blanpain, Leuven
Precious Metals Refining (p. 22_3, p. 24_2, p. 28_1).
University, Belgium; Françoise Bodenan, BRGM, France; Mieke
Campforts, Umicore, Belgium; Amélia Enríquez, UNEP, Brazil; Design and creativ concept: www.3fdesign.de
Bernd Friedrich RWTH Aachen, Germany; Stefan Gössling- Disclaimer: The designations employed and the presentation
Reisemann, University of Bremen, Germany; Daniel Froelich, of the material in this publication do not imply the expression
ENSAM, Chambéry, France; Tom Jones, Leuven University, of any opinion whatsoever on the part of the United Nations
Belgium; Yasushi Kondo, Waseda University, Japan; Jinhui Li Environment Programme concerning the legal status of any
Tsinghua University, China; Hans-Rainer Lotz, Volkswagen, country, territory, city or area or of its authorities, or concerning
Germany; Stefan Luidold, University Leoben, Austria; Elisabeth delimitation of its frontiers or boundaries. Moreover, the views
Maris, ENSAM, Chambery, France, Kazuyo Matsubae, Tohoku expressed do not necessarily represent the decisionor the
University, Japan; Nourredine Menad, BRGM, France; Shinsuke stated policy of the United Nations Environment Programme,
Murakami, Tokyo University, Japan; Kenichi Nakajima, NIES, nor does citing of trade names or commercial processes con-
Japan; Tetsuya Nagasaka, Tohoku University, Japan; Shinichiro stitute endorsement.
Nakamura, Waseda University, Japan; Sheraz Neffati, ICDA,
ISBN: 978-92-807-3267-2
France; Shuji Owada, Waseda University, Japan; Jim Petrie,
University of Cape Town, South Africa; Georg Rombach, Hydro Job Number: DTI/1535/PA
Aluminium, Germany; Susanne Rotter, University of Berlin, Ger- UNEP promotes environmentally sound practices globally and
many; Mathias Schluep, EMPA, Switzerland, Guido Sonnemann, in its own activities. This publication is printed on FSC-certified
University of Bordeaux, France, Philip Strothmann, UNEP, paper with 80 % recycled fibre, using eco-friendly practices. Our
France; Pia Tanskanen, Nokia, Finland; Karel van Acker, Leuven distribution policy aims to reduce UNEP’s carbon footprint.
University, Belgium; Jacques Villeneuve, BRGM, France; Harro
2
The following is an excerpt of the Report 2b
of the Global Metal Flows Working Group

Metal Recycling
Opportunities, Limits,
Infrastructure

The full Report is available on CD-ROM (available


inside the back page of this summary booklet).

3
Preface
Preface

Increasing demand has revealed that metals any stage of recycling limits performance,
are a priority for decoupling economic growth and shows as well that basic thermodynam-
from resource use and environmental deg- ic, technological, and economic limitations
radation. Metal recycling is increasingly pro- may prevent metallurgical metal recovery for
moted as an effective decoupling approach, some combinations of metals and materials.
but there is little systemic information avail-
The complementary Material-Centric recy-
able regarding recycling performance, and
cling view point, as presented in the first re-
still less on the true recycling rates that are
port, has the capability to answer the ques-
possible and on how to improve recycling
tion of how much is recycled, but does not
systems. The former topic was the subject of
pretend to answer why and what should be
an earlier report from the International Re-
done to improve recycling of metals. This
source Panel. The present report address-
new report sheds light on how to improve the
es the second topic, discussing the benefits
recovery of all metals, but especially those
and necessity of approaching recycling from
critical technology elements that were shown
products by considering them as complex
to have low recycling rates. It presents a
“designer minerals”.
physics-based approach to Design for Recy-
This Product-Centric approach therefore cling and for Resource Efficiency, as well as
takes account of the complexities of mod- for estimating opportunities and limits of re-
ern products (often much more complex than cycling. These techniques can aid decision-
geological minerals), and the ways in which makers in arriving at improved recycling ap-
non-traditional mixtures of elements are now proaches.
common. The approach gains much useful
perspective from experience in classical min- Prof. Ernst U. von Weizsäcker
erals and metallurgical processing. Co-Chair of the
International Resource Panel
Modern technology systems require not only
efficient End-of-Life collection of products
Prof. Thomas E. Graedel
but also effective sorting after collection
and an optimum suite of physical separa- Leader of the
Global Metal Flows Working Group
tion, modern metallurgical technologies, and
integrated infrastructure for an economi-
cally viable recovery of metals from sorted Prof. Markus Reuter
recyclates. The report shows how failure at Lead Author

4
Preface
Preface

The challenge of sustainable development at products to the recycling and collection indus-
the beginning of the 21st century has become try to the consumers. As recycling is primarily
a systemic one, with environmental, social an economic industrial activity, economic driv-
and economic dimensions on an equal footing. ers must align with long-term economic goals,
UNEP and the UNEP-hosted International Re- such as conserving critical metal resources for
source Panel consider that our contributions future applications, even if their recovery may
also need to be systemic, for example through be currently uneconomic.
the promotion of resource efficiency, improved
Getting all stakeholders on board is crucial if
materials recycling and life-cycle thinking.
we want to meet the increasing metal needs
This report from the Panel provides unrivalled
of the future in a sustainable way. A wide, sys-
science to inform policy makers about how
temic approach based on the solid under-
the recycling of metals can be optimized on an
standing of the industrial and economic fac-
economic and technological basis along prod-
tors driving recycling will be needed. Such
uct life cycles in the move towards sustainable
knowledge base will require coherent regula-
metals management.
tory frameworks and powerful incentives for
The report shows that sustainable metals all stakeholders to participate as we move to-
management requires more than improving wards an inclusive, low carbon and resource
recycling rates of selected materials. We need efficient global Green Economy.
to change the whole mindset on recycling of
metals, moving away from a Material-Centric Achim Steiner
approach to a Product-Centric approach. Re- UN Under-Secretary General and
cycling has become increasingly difficult to- Executive Director UNEP

day and much value is lost due to the growing


complexity of products and complex interac-
tions within recycling systems.
This is why the focus needs to be on optimizing
the recycling of entire products at their End-
of-Life instead of focusing on the individual
materials contained in them. Such a transition
will depend on the mobilization of everyone in
the value chain, from operators in the prima-
ry production of metals and metal-containing

5
UNEP
UNEPIRP’s activities
IRP’s activities on metalson metals

International Resource Panel (IRP) Global Metal Flows Working Group


The International Resource Panel was estab- The International Resource Panel launched the
lished in 2007 by UNEP to provide independent, Global Metal Flows Working Group in order to
coherent and authoritative scientific assessment contribute to the promotion of the re-use and
on the sustainable use of natural resources and recycling of metals and the establishment of a
the environmental impacts of resource use over sound, international recycling society. There-
the full life cycle. fore it is publishing a series of scientific and
authoritative assessment reports on the global
By providing up-to-date information and the best
flows of metals. The expected results of these
science available, the International Resource
include identification of potentials for increased
Panel contributes to a better understanding of
resource efficiency at national and internation-
how to decouple human development and eco-
al levels. The present booklet summarizes the
nomic growth from environmental degradation.
findings of Report 2b: Metal Recycling – Oppor-
The information contained in the International
tunities, Limits, Infrastructure.
Resource Panel’s reports is intended to be pol-
icy-relevant and support policy framing, policy
and programme planning, and enable evaluation
and monitoring of policy effectiveness. Relevance of metals for sustainable
development
Economic development is deeply linked to the
use of metals. The growing demand for metals
puts permanent pressure
on our resources. Met-
als are high-value resources and can in principle
be easily re-used and recycled. Re-use and re-
cycling activities of metals on a global scale can
contribute to turning waste into resources, thus
closing material loops. Expected benefits are re-
duced environmental impacts of primary metal
production, securing of metal availability, as well
as reduced metal prices, and promotion of jobs
in the related economic sectors.

6
7
Objectives
Objectives ofof
the the
ReportReport

Motivation and objectives new “designed minerals”, i. e. the human-made


products. The specific challenge of recycling de-
Metal recycling has a long tradition, since peo- signed minerals derives from the fact that they
ple realized that it is more resource- and cost- may contain more than 40 elements while geo-
efficient than throwing the resources away with logical minerals can be made up of, for example,
the waste and starting all over again with mining one main metal and around 15 minor metals.
and primary metals production. Until recently, These complex mixtures require a deep under-
recycling concentrated on few specific metals, standing of thermodynamics to separate mod-
mainly base metals like steel, copper or alumi- ern products into economically viable metal, al-
num, as most products were relatively simple. loys, compounds etc. that flow back into prod-
Due to increasingly complex, multi-material ucts. It would be clear therefore that product
products metal recycling in the 21st century is designers also have a key role to play in efforts
becoming a more challenging business. aimed at increasing metal-recycling rates.
Previous UNEP reports showed that far too Giving answers on how to increase metal-recy-
much valuable metal today is lost because of im- cling rates – and thus resource efficiency – from
perfect collection of End-of-Life (EoL)products, both quantity and quality viewpoints mean a real
improper recycling practices, or structural defi- challenge. Critical questions revolve around the
ciencies within the recycling chain including the amount and composition of recycling inputs, the
lack of proper recycling technologies for some required technological infrastructure in a par-
metals embedded in certain EoLproducts. ticular region, and worldwide economic realities
of recycling.
Increase of metal-recycling rates The present summary booklet highlights the fol-
lowing main points:
Report 2b of UNEP’s International Resource
Panel summarized in this booklet accentuates ■■ Economics of recycling and legislation
the current opportunities and limits of metal re- ■■ Recycling and metallurgical infrastructure
cycling and envisions the infrastructure needed and technology
in order to maximize the recovery of valuable re-
■■ Collection as part of the recycling system
sources from waste streams. For this purpose
it promotes a Product-Centric approach which ■■ Design for Resource Efficiency (DfRE)
takes account of the multi-material composi- ■■ Material and resource efficiency targets
tion of modern products and applies the avail-
■■ Education, information, R&D and system &
able technological know-how of recovering met-
als from complex geological minerals to these process simulation

8
Geological Designed
Copper Mineral Copper “Mineral”
Chalcopyrite CuFeS2

More than More than

15 Minors e.g. 40 Elements


Au, As, Pd, Se, etc. Complexly Linked as Alloys, Compounds etc. for Product Functionality Reasons

Geological Product Design and Material Combina- Material Joined


Linkages tions Create New “Minerals” Connections Materials

Product-Centric recycling: application of


economically viable technology and methods
throughout the recovery chain to extract metals
from the complex interlinkages within designed
“minerals” i. e. products, gleaning from the
deep know-how of recovering metals from
complex geological minerals.

9
Recycling economics
Recycling economics, technology and legislation

Policy framework for environmen- The minor metals challenge


tally sound recycling
Functional product requirements lead to com-
Economics, technology and legislation are three plex material mixtures in design, making diffi-
core issues of metal recycling. They need to cult the recovery of minor metals. Weight-only
be designed in a way that promotes high re- EoLrecycling targets in legislation further ag-
cycling rates for many metals simultaneously gravate existing difficulties. Minor metals like
so as not to limit the recycling of a metal while palladium and indium are embedded in small
another one is maximized. This point is cru- concentrations in million or even billion units
cial because the lack of legislation and control of End-of-Life devices like discarded mobile
leaves room for actors in the recycling chain to phones, notebooks or cars. Often ending in in-
just extract the most valuable components from formal recycling chains, these metals are of-
the waste and carelessly discard the rest. Often ten lost. Therefore in the case of minor met-
rooted in poverty and in a lack of understanding als effective international arrangements will be
of the characteristics of recyclates this behav- required to facilitate transparent cross-border
ior causes considerable harm to man and envi- transportation to large central plants which ful-
ronment as several of the non-valuable compo- fill the requirements of Best Available Tech-
nents contain hazardous substances which re- niques (BAT). Bulk material like steel or alu-
quire adequate treatment and disposal. minium fractions dismantled from EoLproducts
could be addressed at local level. This could fos-
ter for instance the steel and aluminium recy-
cling industry in some African countries.
Very often complex EoLproducts are treat-
>> Create a global level playing field for ed in an inappropriate way which poses risks
all stakeholders to health and environment and loses relevant
>> Promote an adequate legislative quantities of material. The main challenges are
Messages

framework for BAT-based recycling the global establishment of an efficient collec-


Policy

tion and dismantling/separation infrastructure,


>> A metallurgical infrastructure is key
knowledge transfer to and appropriate collabo-
to metal recycling
ration with the informal recycling sectors in de-
veloping countries and the creation of new busi-
ness models for international co-operations.

10
Creation of a level playing field
There is a need to create a level playing field The technology required for each step (collec-
within the recycling sector through the inter- tion, pre-processing, recycling) can vary consid-
nalization of external costs. In some cases the erably: while for the pre-processing stage care-
support of promising recovery solutions is nec- ful manual dismantling offers very high recov-
essary even if they are currently not economic ery rates, for the recovery of critical metals from
so as to prevent recycling practices which can special metal fractions high-tech and large-
harm human health and the environment. scale metallurgical refining plants may be the
best solution. These plants are often operated
Common international standards have to be de-
by companies with large experience in metallur-
fined and to be agreed upon for pre-treatment
gy of primary as well as secondary material.
and refining processes/plants. This helps stake-
holders in the recycling system to operate on a Concerning the collection of waste by private or
‘best practice’ basis, along social, environmen- public operators economic incentives are need-
tal, technological and economic considerations. ed which guarantee that all components arriv-
In this regard, the design ing in the waste streams are collected and pro-
of policies and regulations cessed to the next stages in the BAT recycling
Messages

>> Policy and regulations


aimed at improving recycling chain. Measures include extended producer re-
must be supported by
Policy

results must be supported by sponsibility, deposit schemes, and the fair dis-
thermodynamics and
thermodynamics and realis- tribution of the profits obtained from the recy-
realistic economics
tic economics. cling of the valuable fractions among all actors
in the recycling chain.
Promotion of best available tech-
niques (BAT)
In the first place a much wider use of Best Avail-
able Techniques (BAT) is necessary to increase
metal recovery rates. These BAT should be de-
fined as the processes which promise the high-
est material efficiency with lower overall envi-
ronmental impacts along each step of the recy-
cling chain.

11
Adaptive infrastructure
Adaptive infrastructure and technology

Recycling infrastructure and


technology
The nature of today´s products is becoming in- and metallurgical processing infrastructure
creasingly complex: to provide the multitude of to produce high quality metals from complex
ever new functionalities many different materi- multi-material recyclates. This requires all
als are closely combined. The challenge of re- stakeholders in the recycling chain (product de-
cycling such products can be illustrated by the signers, collectors and processors) to under-
separation of a thoroughly mixed cup of coffee stand the whole system and the respective infra-
into its primary components: pure extracted cof- structure to be adaptive to the changing com-
fee, water, milk and sugar crystals. position of the EoLproducts. Therefore, expert
knowledge is needed to be able to deal with in-
The general lines of the appropriate recycling
creasing complexity. Moreover, recycling tech-
system can be developed following the Prod-
nologies need to be flexible and optimally linked
uct-Centric approach: based on the holistic view
to simultaneously maximize the recovery of vari-
of all elements contained in an EoLproduct, it
ous and often vastly chemically different, metals
maintains and innovates a sophisticated physical
and elements.

Taking the
multi-material- Product-Centric Approach
composition of Initial general question Steel (Fe)
modern products
How can we use a product as resource? Aluminium (Al)
into account,
the Product-
Centric approach Cobalt (Co) | Nickel (Ni)
answers the
Precious metals | Copper (Cu)
question of how
to best recycle Others, e.g. Indium (In)
a product in
order to achieve EoL Product Pre-treatment Metallurgical Processing
maximum
resource
efficiency. Less waste

12
Messages
>> Create the right environment to promote >> Use physics depth to understand the
a Product-Centric approach-based recy- metallurgical complexity to create metals

Policy
cling system from recyclates

Pre-treatment The Metal Wheel


Pre-treatment breaks down complex products The primary metallurgy-derived Metal Wheel of-
into components that can be directed into the fers valuable lessons on how to design recycling
appropriate recycling streams. Therefore, the systems in order to achieve maximum recovery
EoLproducts are separated and sorted mechani- of the different metals. Centered on the EoL-
cally. Already at this stage the degree of separa- product at first the main metal components, the
tion and sorting determines the possible future so-called carrier metals, are differentiated (see
qualities of the recyclate. Suitable dismantling, Figure “Metal Wheel”). Each corresponding slice
sorting and robust, adaptive and high-tech ex- in the Metal Wheel represents the complete in-
tractive metallurgical (both hydro- and pyromet- frastructure for carrier metal production and
allurgy) infrastructure are hence needed to deal refining. During refining operations the carrier
with two major developments in product design: metals are recovered while accompanying met-
miniaturization and the variability of products als (in the form of alloys, compounds and imper-
and their composition. Highly adaptive manual fectly sorted and liberated materials) undergo
dismantling and sorting is also an example of different fates: in the best case (green circles)
the requirements needed to ensure the needed they are compatible with the carrier metal and
flexibility in recycling systems. can be recovered alongside or they are recover-
able from other output streams (e. g. dust, slag)
Recycling and refining in subsequent processing. In the other cases,
In analogy to the
depicted with yellow and red circles, the accom-
geological miner-
als processed by The metal fractions leaving pre-treatment are panying metals are mainly lost or only recovered
primary met- supplied to the secondary metals industry which for low-quality products like cement. As a criti-
allurgy, EoL- recovers the different metal elements or alloys cal example, the processing of copper and pre-
products can of economic value. In order to maximize the re- cious metals like platinum group metals, gold
be considered covery care has to be taken that the metal mixes and silver in the iron processing route has to be
human-made de- entering a specific recycling route have com- avoided by proper sorting as far as possible be-
signed minerals. patible characteristics. Only then metallurgical cause there these valuable elements are lost.
Thus the recy- processing will succeed in economically sepa- On the other hand, the processing of precious
clers of complex rating them. As the characteristics of metals are metals with copper as a carrier allows their re-
modern products determined by their physicochemical properties, covery with high rates.
increasingly need knowledge of primary metallurgy is an equally
the expertise of important requirement for improved recycling
metal miners. processes.

13
Examples
Examples offor carrier
carrier routes
metal routes

Fe Au Ag W Mn Nb Mo Si
l
eta )
M
rie l (
r Fe Au Ag Pt Pd Rh Cu Si
Ca tee
r
S Steel recycling route Au Ag Pt Pd Rh FeOx FeOx
Steel, which predominantly consists of iron along with some other alloying elements, is the metal with

Cu
the largest global volumes and its recycling infrastructure has been established for centuries.
Au Ag Pt Pd Rh FeOx FeO Today
up to 90 % of the steel reaching its End-of-Life is recycled. However, various steel incompatible metals
x

through incomplete liberation, mixed recyclates, complex product designs etc., which enter the steel
recycling route are not recoverable. While in some cases they still contribute to the functionality of the
recycled steel as alloying elements (e. g. silicon, molybdenum, niobium, manganese and tungsten, if
Fe
they dissolve and do not oxidize to slag or volatilize) other elements (e. g. copper or platinum-group
metals (PGMs)) are lost and even detrimental to the quality of the recycled product.
In very specific PM and PGM recycling processes iron can serve as a solvent and then be sent to the cop-
Au Ag Pt Pd Rh Cu Si
per route in which the precious metals are recovered and the small quantity of iron used is lost to slag.

Cu Au Ag Pt Pd Rh FeOx FeOx
)
r Me
tal
r (Cu
rr pe
ie
C op
a Copper recycling route
C The physico-chemical properties of copper make it act as a collector for many precious metals (e. g.
gold, silver, platinum, palladium, rhodium) during pyro-metallurgical processing (metal smelting).
These metals, e. g. present in complex products and recyclates such as printed wiring boards and elec-
tronic components, which have high value but in commercial products generally occur in trace quan-
tities only, are concentrated in the copper phase during smelting and can subsequently be recovered
through further hudro- and pyrometallurgical technology. Also nickel can be won back this way after
dissolving in the copper and recovered through hydrometallurgical methods. Aluminium, rare earths or
lithium accumulate as oxides in the slag and are generally not recovered due to the high related effort.
Slags are generated in pyro-metallurgical processes in large volumes and today are mainly used as low-
grade products e. g. in road construction. Copper metallurgy is a key for the recycling of various metal
mixtures occurring in complex recyclates. Its infrastructure and deep know-how are therefore a prerequi-
ste for a sustainable society, as it has the robustness to take care of the recyclates shown on page 9.

14
tal
Me e)
ie l (F
r Al2O3 V2O5
MgO SiO2
rr
Ca ee
SrO SrO
CaO CaO KCl

St
WO FeO REOs
3
CaF2 x BaO
TiO2 ZrO2 MgO
In2O3
K P Cd Hg Al2O3
BaO
Ga2O3
Na F ZrO2
ThO2 Cl Na
REOs Hg Ag Bi Pb P TiO2
Ta2O5 As K
Nb2O3 Pb
Cd Au Sn Zn Ti Sb Cr
CaF2 Zn Sb SiO2
Fe Mn
Br REs
Ta
Th Si Mg
Ni Nb V
Al2O3 Co Sn Ni Cr
W Cu B
Cu Ti Au V Nb Al2O3
Pd
Mo Si Pd Cr Ag Zr
Pt Mo Cl
SiO2 Pb Rh Sn Si Zn FeOx
Al Pt Al Al
CaO Fe Remelt Ti REs
Th MgO
F Fe Steel (BOF&EAF)
Refine Pyro
Si F/Cl
Metallurgy
Zr Al
FeOx Mn Remelt
Mg
Br
CaO
Cl Ni TRIP Steel Hydro Metallurgy
Austenitic Remelt
The “Metal Zn
K/Na
P2O5
MgO Fe
Ni/Cr Li
Wheel”, based on Cr
An
Hydro&Pyro MnO
Stainless Steel metallurgy

primary metal-
lurgy but equally Co
Zn EoL RE
Hydro-Metallurgy
AIXy Cu Al2O3

Product
RLE/Fume MgO
RE(O)s Sb2O3

valid for metals Pb RE In CaXy SiO2


Cu In Pt Special Battery
Ga/As SrO
Bi Smelt Recycling
P
recycling reflects Refine
Ni SiXy CaO
Au Sn Cu/Ni Sn P
the destina- Ge Smelt/Refine Smelt/Refine Co REOs
Ga Sb Au
tion of different Cd Pt FeOx
Se Th K
elements in base- Al2O3 Ag
Rh
Pd Ag
CaO
metal minerals Pb Te Cu Li2O
REs As
SiO2
Mo
as a function of FeOx Hg Br Co As
Zn Sb Sb Bi
interlinked met- V2O5 In
Bi Cd
In2O3 F Pb ZrO2
TiO2 Sn Na REOs
allurgical process Ta2O5 SrO Ga2O3 Ge
P Zn MnO FeOx
Nb2O3
Cl K
technology. Each ZrO2
MgO
MnO
In
CaO
MgO Nb2O5
WO3
In2O3 V2O5
slice represents BaO
Al2O3
SiO2 FeOx TiO2
Ta2O5
SiO2
REOs Al2O3
the complete ) CaO Cu2O
NiO ThO2
WO3

infrastructure for per (Cu


Cop
base or carrier tal e
Carrier M
metal refining.

Essential Carrier Metals. El Mainly Recovered Element.

Metal phase: Dissolves mainly in Carrier Metal if Metallic


(Mainly to Pyrometallurgy). El Mainly element in Alloy or Compound in Oxidic Product, not
recovered separately, but not detrimental and even possible
Compounds mainly recovered from Dust, Slime, Speiss, Slag functionality.
(Mainly to Hydrometallurgy).
El Mainly Element Lost, not always compatible with Carrier
Compounds not recovered from Dust, Slime, Speiss, Slag, but Metal or Product.
mainly to Benign Low Value Products.
15
Collection
Collection as part of the recycling system

All steps are relevant tion is hence a crucial issue in order to improve
resource efficiency but the establishment of a
Recycling is a chain of activities: collection, pre- suitable collection infrastructure still poses chal-
processing (separation & sorting), and final pro- lenges, mainly from an economic point of view.
cessing (recycling & refining). The overall recov- Additionally, consumer acceptance plays an im-
ery efficiency for each material results as the portant role.
product of the efficiencies of each step. Thus, its The main metal-containing resources for post-
optimization requires the combination of the re- consumer waste are cars, electronic applianc-
spective best-performing technologies, both in es, packaging and diverse small metal products,
terms of recovery efficiency and environmental e. g. toys or bikes. The main collection options
soundness. for these goods are collective municipal or com-
mercial collection, individual producer and re-
Collection is key tailer collection, and collection by the informal
sector. Charity initiatives, small-scale pilot proj-
As collection stands at the beginning of the re- ects, or event-based collection can also contrib-
cycling chain it is a prerequisite in order to en- ute to the collection of electrical and electron-
able any subsequent activity. Moreover, especially ic equipment waste (WEEE), which in terms of
in industrialized countries, it often constitutes a metal recovery constitutes a high-value stream
Material-Centric- weak link in the overall recycling chain. Collec- (depending of precious metal content).
Recycling-Chain
All steps in the
recycling chain System Collection Pre-processing Final processing Net yield
are relevant
for the overall
recovery efficiency Formal
(Europe, formal mainly
– illustration integrated
UNU 2008, 60 % take-back 25 % mechanical 95 % smelter 15 %
based on the Chancerel system processes
example of gold et al. 2009)

recycling from
printed wiring
boards by a formal
Informal manual
system in Europe individual backyard
and the informal
(India, Keller
80 % collectors 50 % sorting and 50 % leaching 20 %
2006) dismantling
sector in India.

16
Collection
Collection as part of the recycling system

The balance between these collection routes costs and effort and can, in general, be econom-
depends on the policies and economics of the ically and environmentally feasible. The opti-
different countries. Thus, in OECD-countries mal ranges for segregation are affected by poli-
in general the formal sector prevails while cies and collection schemes as well as recycling
developing countries have a strong informal technology, economics and metallurgical infra-
sector. As an example, in Europe, the con- structure.
sumers pay for collection, whereas in devel- In any case, the identification of the suitable
oping countries usually the waste collectors waste stream for an EoLproduct requires data
pay consumers for their obsolete appliances on its compositional structure. To date, informa-
tion on product composition is still incomplete,
and metal scrap. In the latter case often im-
but it is indispensable for optimizing recycling
pressive collection rates are reached because
systems with suitable process simulation tools
poor people rely on the income generated
that map the complete recycling chain.
from the valorization of the waste. This shows
how strong economic stimulus for collection
is a key factor. Quantitative aspects of collection
The economics of recycling depend on the avail-
Qualitative aspects of collection able quantities reaching the pre-processing and
recycling facilities. The supplies, which need to
A large variation in the properties of the col-
be assured by the appropriate collection sys-
lected waste will adversely affect product qual-
tems, have to be sufficient in volume and stable
ity and recovery, thus increasing losses, during
in order to provide economic reliability.
the subsequent processing steps. The streams
In many developing countries the establishment
may even become economically unviable for
of a formal sector is hampered by the fact that
processing when incompatible materials and
collectable waste volumes are insufficient for
compounds are mixed. In general products to
economic operation because they are recovered
be recycled must be separated, liberated, sorted
by the informal sector at higher prices.
etc. into recyclates streams that can be treated
economically in appropriate BAT metallurgical
infrastructure. Thus source-segregated collec- >> Enhance availability of information on

Messages
tion offers the quality that is best suited for the material composition of products
subsequent steps if the recyclate mixtures are

Policy
>> Process metallurgy must be under-
compatible with Carrier Metal process metal-
stood by all actors
lurgy with a Product-Centric context. However,
it is constrained by stream values and collecting
17
Collection
Collection as part of the recycling system

This is possible due to the fact that informal Collection infrastructure


recycling practices tend to avoid costs by just
extracting the valuable components from the Collection infrastructure can be set up by the
waste. However, the leftovers could cause con- authorities, by product manufacturers and re-
siderable harm to human beings and environ- tailers (corresponding to their enhanced pro-
ment if they are not treated properly. This is why ducer responsibility) or by companies, individu-
formal recyclers are obliged to comply with par- als or charities wishing to earn money from the
tially costly environmental standards. value in the waste or to reduce environmental
Some critical metals, e. g. present in WEEE, are impact. One crucial part for setting up that infra-
recoverable at high rates in high-tech indus- structure is the knowledge base, the motivation
trial plants. With a view to material efficiency it and the availability of physical infrastructure for
is hence desirable that corresponding fractions dealing with separate streams of collected waste.
reach these plants which offer BAT for the recy- Another part is the incentive structure: some col-
cling of low-concentrated critical metals. How- lectors may act out of ethical or environmental
ever, in order to offset high initial investment considerations, but nearly all work because they
costs, these plants are often large-scale so that earn money from collection, or face penalties for
their supplies need to be sourced from a large failing to collect.
pool of countries requiring a concentration to a
few global facilities.
Collection systems need to be designed in a way
which channels all components in the collect-
>> Promote the right incentives to collect
ed waste streams into the right pre-processing
and consequently recycling routes, ensuring in- >> Benefit from existing distribution

Messages
creased material recovery rates as well as eco- structures for consumer goods to
logical harmlessness. design collection schemes

Policy
18
Consumer behaviour
The collection of consumer waste (as opposed to
e. g. industrial waste) forms an especially difficult
logistical challenge. While there are the collec-
tors on the side where the waste streams enter
the recycling chain, there are billions of consum-
ers where products leave their use phase and
become waste. One aspect to facilitate increased
collection is to improve the performance of this
interface: educating and changing the behaviour
of individuals can lead to better recycling.
The keys are convenience and awareness. The
opportunities and infrastructure of the system
need to be transparent and accessible. As an
example, to enable the consumer to contribute
to source segregation, clear guidance is need-
ed concerning the composition of End-of-Life
products and the corresponding adequate fate
in the (separated) waste streams. Marketing and
social media can be used to influence personal
attitudes and motivate individuals towards recy-
cling.
In different countries different ways of commu-
nicating, providing incentives and motivating
consumers are established. Thus, even if recy-
cling is a global issue it needs local execution.

>> Increase consumer awareness

Messages
towards recycling

Policy
>> Guarantee convenient collection,
e. g. by easy access to collection points

19
Design
Designfor Resource
for Resource Efficiency
Efficiency (DfRE)

Recycling starts with product design during mechanical pre-processing. Apart from
technical design, economic realities play a cru-
Design for Resource Efficiency (DfRE) describes cial role here: if careful dismantling becomes
a holistic technology- and economy-driven con- too costly, e. g. because labour costs exceed
cept which aims at utilizing the combined capa- the value that can be recovered for the extract-
bilities of the production and the complete re- ed components, the lack of economic incen-
cycling chain in order to maximize resource ef- tives becomes critical/counter-productive to in-
ficiency. It requires a Product-Centric approach creased recycling.
which takes into account the complexity of prod-
ucts to allow for the optimized recovery of all el-
ements contained within. As it is impossible to Design for Recycling
optimize one factor without considering the oth- Design for Recycling takes into account the
ers a lifecycle perspective is required: product physical and chemical realities of metallurgy as
designers, as well as collectors and processors well as the technological and economic possibil-
of End-of-Life products must be aware of the ities of recycling and refining operations. Based
whole system. Modern product design should thereon it tries to avoiding incompatible material
consider the complexity of recycling multi-mate- mixes so that the elements contained in the dif-
rial products, and avoid designs that hinder re- ferent metal streams can be recovered as pure
cycling. This is not always possible because the metals or in alloys by BAT practices to a maxi-
primary function of the product will always pre- mum extent. Of course, this approach is equally
vail but, if necessary, policy should reinforce this limited by the functionality demands of a prod-
point. Moreover, product designers should scru- uct which might dictate that certain metals and
tinize their designs within realistic boundaries of materials must be combined. Joints/constructs
product functional demands. affect dismantle-ability and therefore material
liberation. Linked materials in turn affect their
Design for Dismantling respective recovery during process metallurgy.

As one sub-aspect of DfRE Design for Disman- Tools to aid decision making
tling aims at designing products so that com-
patible groupings of metals are easy to disman- Metallurgical realities are concisely reflected by
tle so that they can be directed into the correct the Metal Wheel, which indicates the possibili-
metallurgical processes. This means, for ex- ties of combined metal recycling, refining and
ample, constructing bondings or joints between recovery for various metallic elements. Physics-
components in a way that they can be opened based recycling simulation tools capture the ef-
20
Example of
existing software
for flowsheet
design, based on
compositional
data for a
product, which
lead to simulated
resource
efficiency data
that, in turn, lead
to a recyclability Product + Dismantling & + Metallurgical = Recyclability
index based on Composition Physical Separation Recovery Index & Rate
environmental Design & functionality Physics, economics & Thermodynamics, Sum of recovery
analysis – a flow sheet controls technology & econo- of all elements
Detailed composition
losses mics & materials
metallurgical of all materials
Connection and material Non-linear interac- Link to GaBi deter-
processing liberation affect srap tions determine mines true environ-
qualitiy recovery mental impact
infrastructure is
prerequisite.

fects of design/material choices and linkages


on recycling, based on how products break up
and separate in recycling processes. Pinpoint-
ing critical issues and providing the information >> Support recycling friendly product de-
in an understandable format, these tools should sign using suitable Computer Aided De-
hence be used to assist product design. For a sign (CAD) and linked process simula-
given product, these tools identify recycling so- tion tools
lutions and achievable recycling rates based on
>> Assist the adoption of lifecycle manage-
data on its compositional structure. In order to
identify BAT operations they need to be coupled
ment by manufacturers

Messages
interactively with ecological (LCA) and economic >> Set realistic recycling targets based on
assessments tools which evaluate the proposed the interactive physics-based simulation

Policy
processes from a lifecycle perspective. Thus of production and recycling systems
DfRE should drive the creation of a BAT-based
recycling system.
21
Bulk
materials
(Steel, stainless
steel, plastics,
glass, copper)

Steel, stainless steel, copper, glass, and plas-


tics make up over 95 % of the mass of EoL devices
like washing machines. Electronic components
amount to less than 5 %. Thus under existing,
Electronic
mass-based recycling targets their recycling is
components often neglected. However, they contain specialty
(Special and
and precious metals, the recovery of which should
precious metals)
be increased. The definition of the recycling tar-
gets should hence be refined using a Product-
Centric approach.
22
Systemic material
Systemic material efficiency
efficiency targets

Material efficiency targets


Policy tries to improve the recovery of valuable
resources from End-of-Life products by setting
physics and economics based material efficien-
cy targets. These targets oblige the responsi-
ble industries to ensure that certain quantities
of materials (metals and others) are recovered.
However, their effectiveness is under debate.

Mass-based rates and critical


metals Key performance indicators
Existing mass-based End-of-Life recycling tar- To overcome this bottleneck the establishment
gets are often counterproductive concerning of economics-based and environmentally be-
critical metals embedded in complex products. nign key performance indicators (KPI) is sug-
Due to their generally low quantities in many gested. These should adopt a Product-Centric
End-of-Life flows their contribution to mass perspective and provide additional incentives for
based End-of-Life recycling rates for entire End- the recovery of critical metals by taking into ac-
of-Life products is marginal while the recycling count their criticality and relevance despite their
of mass materials like steel, aluminium or cop- low volumes. The KPI could be calculated based
per quickly increases the rates. Stakeholders in on interactive simulation tools which model
the recycling chain get the clear message to fo- the proposed recycling processes from techni-
cus on the recovery of bulk materials to fulfil the cal, economic and environmental points of view.
minimum End-of-Life recycling rates and the Subsequently they should be used to define BAT
recycling of critical metals like indium, gallium, processes.
rare earths etc. is often neglected.

>> Define key performance indicators on


the basis of physics, technology and

Messages
economics

Policy
>> Adapt the legislative framework
accordingly

23
Metal & Energy Recovery

Heat
100°F 50°F
Heat

Thermodynamics Technologies Metallurgy Economics

24
Education, Information
Education, Information and R&D and R&D

The basis for recycling Improved research


Better education, information and R & D are For the processing of key metals and for driving
global key challenges to enhance the overall re- innovation, improved research is critically im-
cycling rates of metals. Multidisciplinary sys- portant. It must be nurtured to preserve know-
temic education approaches, improved research how, especially of the processing of the key met-
as well as activities to quantify the metal poten- als, and for driving innovation that maximizes
tial embedded in the techno-sphere are essen- resource efficiency. Dissemination of the phys-
tial building blocks to achieve this objective. ics-based system simulation approach to recy-
cling is a need to identify the true crucial needs
for R&D, product design and system innovation.
Multidisciplinary education
Following the Product-Centric approach multi-
disciplinary systemic education must be applied
Quantification of the urban orebody
that is based on a thorough understanding of The stock of products in society - the designed
thermodynamics, process engineering, physics, minerals - constitutes an “urban orebody”. The
chemistry as well as social sciences, econom- quantification of the metals contained in this
ics and law. Existing tools and knowledge from stock, their locations and fate in waste flows is
primary metallurgy have to be used consistent- crucial to allow for high recovery rates and a
ly to close the recycling loops. This ambitious prerequisite to support decisions on R&D ac-
approach will be a key challenge to gain suc- tivities and investments in metal recycling in-
cess with optimized metal recycling in the future frastructure and technologies. In this context
which could address the increasing complexity policies should be developed based on geologi-
of EoLproducts composition. The effect of metal cal approaches known from primary metallurgy.
substitution and future material combinations Databases must include similar structures as
must be continually evaluated with rigorous used for processing of minerals enabling rigor-
simulation tools. ous process simulation.

>> Apply multi-disciplinary systemic engineering education

Messages
>> Quantify the metals and their “mineralogy” in market products

Policy
>> Deep process metallurgy and technology knowledge is critical for recycling and a
sustainable society
25
The figure presents information for the metals in whatever form (pure, alloy, etc.) recycling occurs.
To reflect the reliability of the data or the estimates, data are divided into five bins: > 50 %, > 25 – 50 %,
> 10 – 25 %, 1 – 10 % and < 1 %. It is noteworthy that for only eighteen of the sixty metals the experts es-
timate the End-of-Life recycling rate to be above 50 %. Another three metals are in the 25 – 50 % group,
and three more in the 10 – 25 % group. For a very large number, little or no End-of-Life recycling is oc-
curring today. To increase these Material-Centric determined recycling rates, an in-depth understand-
ing of physical separation, process metallurgy, metallurgical infrastructure, product design and com-
position/mineralogy and economics is required. The Product-Centric approach discussed in this report
shows how to increase recycling rates using process simulation and other deep technological know-how.
1 2

H He

3 4 5 6 7 8 9 10

Li Be B C N O F Ne
Lithium Beryllium Boron

11 12 13 14 15 16 17 18

Na Mg Al Si P S Cl Ar
Magne- Aluminum
sium

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36

K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Scandium Titanium Vanadium Chromium Manga- Iron Cobalt Nickel Copper Zinc Gallium Germani- Arsenic Selenium
nese um

37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Strontium Yttrium Zirconium Niobium Molybde- Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium
num

55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Barium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismut

87 88 89–103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118

Fr Ra Rf Db Sg Sg Hs Mt Ds Rg Uub Uut Uug Uup Uuh Uus Uuo

> 50 % 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71

> 25–50 % La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Lantha- Cerium Praseo- Neodymi- Samarium Europium Gadolini- Terbium Dysprosi- Holmium Erbium Thulium Ytterbium Lutetium
> 10–25 % num dymium um um um

1–10 % 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103

< 1 % Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

26
Outlook
Outlook

Resource efficiency: a joint mission The role of the metallurgical


of industry, science and policy industry
Increasingly complex products in the 21st cen- The role of the metallurgical industry to en-
tury need to be addressed by a Product-Centric hance the overall recycling rates of many met-
approach to foster recycling results for many als in the future is two-fold. First, based on the
metals. The previous UNEP Report 2a: Recy- comprehensive experience of the sector dealing
cling Rates of Metals has confirmed that mainly with complex natural orebodies since many de-
for many specialty metals the current Materi- cades, this essential knowledge should be used
al-Centric EoLrecycling rates are very poor or and transferred to other stakeholders within the
almost zero. The Report 2b: Metal Recycling – recycling chain so as to build their capacity to
Opportunities, Limits, Infrastructure also shows take the right decisions regarding collecting and
that recycling rates of different metals are prod- sorting procedures of increasingly complex EoL-
uct-dependent and that a Product-Centric ap- products (or “designed minerals”). Taking the
proach is required to increase recycling rates lessons from the metal wheel into account, the
above their, in some cases, low values. Deep knowledge about the relevance of carrier metals
metallurgical knowledge and associated realis- and other important metallurgical issues should
tic product design will – among other interven- be disseminated to promote optimized recycling
tions – help to increase these values to accept- infrastructure for metals.
able levels. Even in the case of base metals and
Second, the metallurgical industry could con-
precious metals there is still considerable room
tribute to better EoLrecycling rates of many
for improvement.
metals – especially critical metals – in the fu-
The current pre-treatment of complex products ture by fostering R & D and subsequently invest-
which can contain many different base, specialty ment decisions regarding new metallurgical
and precious metals (more than 40 different ele- processes which could deal with new material
ments) can fail Best Available Techniques (BAT) compositions. Interesting examples are for in-
requirements if there is a mismatch between stance the recycling of rare earths from discard-
recyclate and carrier metal process metallurgy. ed neodymium-iron-boron magnets or the re-
The recycling challenges posed by increasingly cycling of cobalt, lithium and other metals from
complex products need to be jointly addressed lithium-ion batteries.
by combined efforts from policy and legislation,
research and education, and the metallurgical
industry.

27
28
Outlook
Outlook

The role of research and education Policy actions across the global system are
necessary to overcome the bottlenecks that
Research and education are key for addressing currently hold back optimized recycling. That
the increasing variability and complexity of prod- means that the existing legislative systems for
ucts and hence (metals) recycling in the future. waste management and recycling have to be
Quantification of the “urban orebody” and its monitored regarding room for improvement
“mineralogy” in products needs to be simulat- to enhance the End-of-Life recycling for many
ed on the basis of rigorous simulation as used metals, namely critical metals like rare earths
in the metallurgical processing industry. This which show significant environmental impacts in
should be consequently linked to the design of the primary production routes by the generation
recycling tools that provide physics based re- of radioactive waste streams and by hazardous
cyclability indexes. Rigorous understanding of emissions into air, soil and groundwater.
thermodynamics, kinetics, metallurgical pro-
cess engineering as well as physical separation This includes enhancing the availability of in-
physics and process economics is a pre-requi- formation on material composition of products.
site to increase recycling rates. Recycling-friendly product design has to be sup-
ported as well as the setting of realistic recy-
cling targets based on the interactive physics-
The role of policy and legislation based simulation of production and recycling
systems. A better quantification of the metals
Policy and legislation have to create a global
contained in market products is a necessary
level playing field for all stakeholders and have
policy action to promote recycling.
to promote the use of Best Available Techniques
(BAT) on a Product-Centric basis (equivalent to Policy should apply multidisciplinary systemic
geological minerals based processing), multi- education and should promote a robust systemi-
material/metal system economics, and efficient cally linked metallurgical infrastructure without
collection systems. In addition, Design for Re- which no metal recycling is possible.
source Efficiency capturing all inherent material
and metal connections and non-linearities (e. g.
by adoption of life cycle management) and defi-
nition of suitable key performance indicators for
recycling capturing the multi-material intercon- >> Maintaining deep process metallurgy

Messages
nections that maximize resource efficiency, is and technology knowledge at
essential. engineering faculties is critical for

Policy
recycling and a sustainable society

29
Categories
Categories of of Metals
Metals

Ferrous Metals Specialty Metals


V  – Vanadium Li – Lithium Ta – Tantalum
Cr  – Chromium Be – Beryllium W – Tungsten
Mn  – Manganese B – Boron Re – Rhenium
Fe  – Iron Sc – Scandium Hg – Mercury
Ni  – Nickel Ga – Gallium Tl – Thallium
Nb  – Niobium Ge – Germanium Bi – Bismuth
Mo – Molybdenum As – Arsenic
Se – Selenium
Sr – Strontium
Non-Ferrous Metals Y – Yttrium
Zr – Zirconium
Mg – Magnesium Cd – Cadmium
Al – Aluminum In – Indium
Ti – Titanium Sb – Antimony
Co – Cobalt Te – Tellurium
Cu – Copper Ba – Barium
Zn – Zinc La – Lanthanum
Sn – Tin Ce – Cerium
Pb – Lead Pr – Praseodymium
Nd – Neodymium
Sm – Samarium
Precious Metals Eu – Europium
Gd – Gadolinium
Ru – Ruthenium Tb – Terbium
Rh – Rhodium Dy – Dysprosium
Pd – Palladium Ho – Holmium
Ag – Silver Er – Erbium
Os – Osmium Tm – Thulium
Ir – Iridium Yb – Ytterbium
Pt – Platinum Lu – Lutetium
Au – Gold Hf – Hafnium

30
31
THIS BOOKLET SUMMARIZES Report 2b: Metal Recycling – Opportunities, Limits, Infra-
structure of the Global Metal Flows Working Group. The full report is available on CD-Rom (see page 31
of this summary booklet). UNEP’s International Ressource Panel addresses the metals recycling chal-
lenge comprehensively.

A Product-Centric approach is necessary to promote metals recycling in the 21st century. This means
the application of economically viable technology and methods throughout the recovery chain to ex-
tract metals from the complex interlinkages within designed “minerals”, i. e. products, derived from the
thorough know-how of recovering metals from complex geological minerals. These products can be re-
garded as designed “minerals”, which provide the basis for recycling as geological minerals provide the
basis for extracting metals from minerals. Adaptive and robust recycling and metallurgical infrastruc-
ture, systems and technology as well as thorough knowledge are essential to gain economic success
and the required resource efficiency. It is therefore essential to use and evolve existing thorough eco-
nomically viable metallurgical process knowledge and infrastructure. Both are available in the primary
and secondary metals processing industry, which thus needs to be preserved in order to allow for the
most resource efficient recycling of increasingly complex End-of-Life products.

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