6088 MSDS

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Revision date: 22.05.

2010
Safety Data Sheet according to Regulation (EC) No. 1907/2006
MEC Holding GmbH UK Revision no.: 1,10

SDS 03395 EutecTrode 6088

1. Identification of the substance/mixture and of the company/undertaking

Identification of the substance or mixture


EutecTrode 6088
Use of the substance/mixture
Welding rod, welding wire
Company/undertaking identification

Responsible for the safety data sheet: sds@gbk-ingelheim.de


Emergency telephone :+49 (0) 6132 / 84463 (GBK Gefahrgut Buero GmbH, Ingelheim)

Castolin Eutectic Limited. MEC Holding GmbH


Unit 10, Merse Road Messer Platz 1
North Moons Moat D-65812 Bad Soden
Redditch Germany
Worcestershire
B98 9NZ

Telephone: +44 (0) 1527 5822 00 + 49 (0) 6196 7760-555


Telefax: +44 (0) 1527 5822 01 + 49 (0) 6196 7760-561
castolin@castolin.co.uk
2. Hazards identification
Classification
Indications of danger : Harmful
R-phrases:
Limited evidence of a carcinogenic effect.
May cause sensitization by skin contact.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Brazing/welding vapours and fumes from brazing/welding may cause metal fumes fever. Symptoms can
appear 4 to 12 hours after. (headache, dizziness, dryness, cough, nausea and fever)
May cause irritation by prolonged inhalation of brazing/welding fumes.
Welding fumes (not otherwise specified) are considered to be carcinogenic with no further categorization by
EutecTrode 6088 > stevenson@messer-eutectic.com.sg : 2/22/2012 (F17030U1030V1.10)

NIOSH (National Institute for Occupational Safety and Health) and IARC (International Agency for the
Research on Cancer).
IARC - International Agency for Research on Cancer
NIOSH - National Institute for Occupational Safety and Health
GHS:
Hazard categories:
Respiratory/skin sensitization: Skin Sens. 1
Carcinogenicity: Carc. 2
Specific target organ toxicity - repeated exposure: STOT RE 2
Hazard Statements:
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
Explication of special hazards for human health and environment
Welding and brazing processes can cause spatter, melting metal and UV/IR heat can cause burns or start
fires.
During welding- and brazing processes formed metallic fumes are suspected of being cancer causing
agents.

Page 1 of 6
GB - EN
Revision date: 22.05.2010
Safety Data Sheet according to Regulation (EC) No. 1907/2006
MEC Holding GmbH UK Revision no.: 1,10

SDS 03395 EutecTrode 6088

3. Composition/information on ingredients
Chemical characterization ( Mixture )
Hazardous components
EC No. CAS No. Chemical name Quantity
Classification
GHS classification
231-111-4 7440-02-0 Nickel 0,1-5 %
Carc. Cat. 3, T R40-48/23-43
Carc. 2, STOT RE 1, Skin Sens. 1; H351 H372 ** H317

Full text of each relevant R phrase can be found in heading 16.

4. First aid measures


After inhalation
Take affected person into fresh air.
Consult a physician if necessary.
After contact with skin
Wash off immediately with plenty of water for at least 15 minutes.
In the event of persistent symptoms receive medical treatment.
After contact with eyes
Rinse thoroughly with plenty of water, also under the eyelids.
In the event of persistent symptoms receive medical treatment.
After ingestion
Rinse mouth.
Consult a physician.
5. Fire-fighting measures
Suitable extinguishing media
Use fire fighting measures that suit the environment and products stored
Special protective equipment for fire-fighters
In case of fire, wear suitable respiratory equipment with positive air supply.
6. Accidental release measures
EutecTrode 6088 > stevenson@messer-eutectic.com.sg : 2/22/2012 (F17030U1030V1.10)

Personal precautions
Breathing apparatus (particle filter) only if dust is formed.
Environmental precautions
Do not discharge into the drains or bodies of water.
Methods for cleaning up/taking up
Take up mechanically and collect in suitable container for disposal.
7. Handling and storage

Handling
Advice on safe handling
Keep container tightly closed.
Avoid contact with skin, eyes and clothing.
Use only in well-ventilated areas.
ANSI Z49.1 Safety in Welding, Cutting and allied processes.
Storage
Requirements for storage rooms and vessels
Keep in a dry place.

Page 2 of 6
GB - EN
Revision date: 22.05.2010
Safety Data Sheet according to Regulation (EC) No. 1907/2006
MEC Holding GmbH UK Revision no.: 1,10

SDS 03395 EutecTrode 6088

Advice on storage compatibility


Incompatible with strong acids and oxidizing agents.
Storageclass (D): 13

8. Exposure controls/personal protection

Exposure limit values


not available

Occupational exposure controls


Provide appropriate exhaust ventilation at machinery and at places where dust or smoke can be generated.
Protective and hygiene measures
At work do not eat, drink and smoke.
Wash hands and skin before breaks and after work.
Respiratory protection
Use suitable breathing apparatus if there is inadequate ventilation.
Hand protection
Use protective gloves for welders (DIN 4841-4).
Use inner-gloves to prevent from allergic reactions due to direct skin contact.
Protective gloves resistant to chemicals made off polychloropren, Minimum coat thickness 0.6 mm,
Permeation resistance (wear duration) approx. 480 minutes, i.e. protective glove <Camapren 722> made by
www.kcl.de.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the
recommendations given by the manufacturer of protective gloves.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN 374
carried out under lab conditions.
Eye protection
Safety goggles with side protection.
Skin protection
EutecTrode 6088 > stevenson@messer-eutectic.com.sg : 2/22/2012 (F17030U1030V1.10)

Dust resistant protective clothing.

9. Physical and chemical properties


General information
Physical state: Solid
Colour: Product-specific
Odour: Odourless
Important health, safety and environmental information
Test method
pH-Value: n.a.
Changes in the physical state
Boiling point: n.a.
Flash point: n.a.

10. Stability and reactivity

Materials to avoid
Strong acids.

Page 3 of 6
GB - EN
Revision date: 22.05.2010
Safety Data Sheet according to Regulation (EC) No. 1907/2006
MEC Holding GmbH UK Revision no.: 1,10

SDS 03395 EutecTrode 6088

Hazardous decomposition products


Metallic oxides

11. Toxicological information

Acute toxicity
Brazing/welding vapours and fumes from brazing/welding may cause metal fumes fever. Symptoms can
appear 4 to 12 hours after. (headache, dizziness, dryness, cough, nausea and fever)
Irritation and corrosivity
May cause irritation by prolonged inhalation of brazing/welding fumes.
Severe effects after repeated or prolonged exposure
Welding fumes (not otherwise specified) are considered to be carcinogenic with no further categorization by
NIOSH (National Institute for Occupational Safety and Health) and IARC (International Agency for the
Research on Cancer).
Further information
The product was classified on the basis of the calculation procedure of the preparation directive
(1999/45/EC).

12. Ecological information


Ecotoxicity
No data available.
Further information
Do not flush into surface water or sanitary sewer system.

13. Disposal considerations


Advice on disposal
Where possible recycling is preferred to disposal.
Dust and in exhaust systems separated particles dispose of in compliance with local regulations.
Waste disposal number of waste from residues/unused products
160302 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; off-specification batches and unused
products
Waste disposal number of used product
100207 WASTES FROM THERMAL PROCESSES; wastes from the iron and steel industry; solid wastes
from gas treatment containing dangerous substances
Classified as hazardous waste.
EutecTrode 6088 > stevenson@messer-eutectic.com.sg : 2/22/2012 (F17030U1030V1.10)

Waste disposal number of contaminated packaging


150102 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately
collected municipal packaging waste); plastic packaging

14. Transport information

Other applicable information


No hazardous material as defined by the transport regulations.

15. Regulatory information

Labelling

Page 4 of 6
GB - EN
Revision date: 22.05.2010
Safety Data Sheet according to Regulation (EC) No. 1907/2006
MEC Holding GmbH UK Revision no.: 1,10

SDS 03395 EutecTrode 6088

Additional advice on labelling


As an article the product does not need to be labelled in accordance with EC-directives or respective
national laws.
Although this product does not require a hazard warning label, we recommend that the safety advice should
be observed.
Danger symbols: Xn - Harmful

Xn - Harmful

Hazardous components which must be listed on the label


Nickel
R phrases
40 Limited evidence of a carcinogenic effect.
43 May cause sensitization by skin contact.
48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
S phrases
23 Do not breathe fumes and aerosols .
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
38 In case of insufficient ventilation, wear suitable respiratory equipment.
36/37 Wear suitable protective clothing and gloves.
GHS labelling
Signal word: Warning
Pictograms: exclamation mark; health hazard

Hazard statements
EutecTrode 6088 > stevenson@messer-eutectic.com.sg : 2/22/2012 (F17030U1030V1.10)

H317 May cause an allergic skin reaction.


H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P285 In case of inadequate ventilation wear respiratory protection.
P314 Get medical advice/attention if you feel unwell.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P501 Dispose of contents/container to waste treatment facility in accordance with local and
national regulations. .
EU regulatory information
1999/13/EC (VOC): 0%
National regulatory information
Water contaminating class (D): - - not water contaminating

Page 5 of 6
GB - EN
Revision date: 22.05.2010
Safety Data Sheet according to Regulation (EC) No. 1907/2006
MEC Holding GmbH UK Revision no.: 1,10

SDS 03395 EutecTrode 6088

16. Other information


Full text of R-phrases referred to under sections 2 and 3
40 Limited evidence of a carcinogenic effect.
43 May cause sensitization by skin contact.
48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation.
Further Information
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the
product (in this sense consult information on use and on product), but to liberation of major amounts in case
of accidents and irregularities.
The information describes exclusively the safety requirements for the product(s) and is based on the present
level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal
warranty regulations.
(n.a. = not applicable; n.d. = not determined)

IARC - International Agency for Research on Cancer


NIOSH - National Institute for Occupational Safety and Health

Literature:

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
EutecTrode 6088 > stevenson@messer-eutectic.com.sg : 2/22/2012 (F17030U1030V1.10)

Page 6 of 6
GB - EN

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