Densidad T refractometro

N° Vmezcla (ml) Vagua (ml) °GL °GL calculado °Brix (g/cm3) (°C)
1 90 0 96.1 86.4 19.5 0.806 21.32
2 95 5 88 91.2 19.4 0.8364 20.6
3 90 10 87.1 86.4 19.3 0.8372 20.5
4 85 15 82 81.6 19.5 0.8523 20.2
5 80 20 80.6 76.8 19.5 0.8562 20.4
6 70 30 68.9 67.2 18.5 0.8863 20.3
7 60 40 61.9 57.6 17.5 0.9022 20.5
8 50 50 49.4 48 15.3 0.9277 21.2
9 40 60 40.3 38.4 14 0.944 21.4
10 30 70 30.4 28.8 11 0.958 22.1
11 20 80 20.3 19.2 7 0.9703 22.4
12 10 90 10.7 9.6 3.5 0.9827 23.3
13 5 95 18.9 4.8 7 0.9776 24.5
14 0 80 0.3 0 0.1 0.9968 21.5

P ope. ρ etanol PM etanol Teb. Etanol ρ agua PM agua

P ope. [mbar] [mmHg] [g/ml] [g/mol] [K] [g/ml] [g/mol]
717.7 538.31927 0.789 46.069 351.4 0.998 18.015

Constantes de la Ecuacion de Antoine

A B C
Etanol 18.9119 3803.98 -41.68
Agua 18.3036 3816.44 -46.13

Parametros para el modelo NRTL

a (ij) [cal/mol] b (ij) [cal/mol K]

Etanol Agua Etanol Agua
Etanol 0 1332 Etanol 0 0
Agua -109.6 0 Agua 0 0

Psat
X etanol X agua Poperacion Tebullicion Tebullicion (etanol) Psat (agua)
[mmHg] [K] [°C] [mmHg] [mmHg] τ (12)
0.662620808639 0.33737919 538.31927 341.552633 68.4026335 506.022457 218.115149 1.9624690791
0.762127797864 0.2378722 538.31927 341.270012 68.1200124 500.003067 215.433552 1.96409428838
0.662620808639 0.33737919 538.31927 341.548326 68.3983264 505.930268 218.074072 1.96249382646
0.578240862829 0.42175914 538.31927 341.965194 68.8151935 514.91886 222.080264 1.96010148036
0.505782211617 0.49421779 538.31927 342.577466 69.4274663 528.364421 228.076992 1.9565982821
0.387774248791 0.61222575 538.31927 344.171633 71.0216331 564.766107 244.335757 1.9475355249
0.295764710225 0.70423529 538.31927 346.2031 73.0531004 614.188878 266.4622 1.93610768137
0.222014499977 0.7779855 538.31927 348.566761 75.4167611 676.216676 294.309335 1.92297877152
0.161578902324 0.8384211 538.31927 351.183512 78.0335123 750.930046 327.955188 1.90865020286
0.111150784124 0.88884922 538.31927 354.017815 80.8678152 839.530808 367.986454 1.89336935404
0.068434515967 0.93156548 538.31927 357.054327 83.9043273 943.98147 415.34193 1.87726749336
0.031786724564 0.96821328 538.31927 360.294133 87.1441335 1067.15986 471.388417 1.86038688893
0.015348250855 0.98465175 538.31927 362.004906 88.8549064 1137.42244 503.445432 1.8515950203
0 1 538.31927 363.744675 90.594675 1212.77918 537.891286 1.84273895411

Tebullicion [°C] X etanol Y etanol

68.40263346053 0.66262081 0.78378171
68.12001235014 0.7621278 0.80747272
68.39832642729 0.66262081 0.78364124
68.81519352068 0.57824086 0.76188085
69.42746630149 0.50578221 0.74051044
71.0216330625 0.38777425 0.69049675
73.05310042754 0.29576471 0.63131122
75.4167611001 0.2220145 0.56223441
78.03351233101 0.1615789 0.48182731
80.86781518302 0.11115078 0.38835287
83.90432732667 0.06843452 0.27931804
87.14413346381 0.03178672 0.15136677
88.8549064204 0.01534825 0.0789773
90.59467504329 0 0
 T densimetro (°C) Tburbuja
X etanol X agua
T dens(°C) T Gl (°C) T corre (°C) T prom (°C) Tvidrio Ttermocupla Tdigital
21.2 22.1 21.65 70 69.6 69.2 0.66262081 0.33737919
22.9 22.9 69 69.2 68.6 0.7621278 0.2378722
21.1 21.1 70 70.4 70.2 0.66262081 0.33737919
21 20.07 20.535 69.5 70.5 69.7 0.57824086 0.42175914
21.4 20.8 21.1 70 69.5 69.1 0.50578221 0.49421779
22.1 21.2 21.65 71 71.1 71.6 0.38777425 0.61222575
22.9 21.5 22.2 71 70.7 71.2 0.29576471 0.70423529
24.2 22.3 23.25 72.5 72.7 72.4 0.2220145 0.7779855
24.8 22.7 23.75 74 73.8 73.8 0.1615789 0.8384211
26 23.6 24.8 74.5 74.2 74.5 0.11115078 0.88884922
26.2 23.6 24.9 78 77.7 78 0.06843452 0.93156548
24.8 23.1 23.95 82 81.1 80.9 0.03178672 0.96821328
25.3 24.1 24.7 87 87.4 86.3 0.01534825 0.98465175
21.9 22.4 22.15 90 90 90.2 0 1

Teb. Agua R
[K] [cal/mol K]
373.2 1.98721

Calculo de la Presion Atmosferica

T [°C] T [K] P [mmHg]
Agua 90 363.15 525.902915

α (ij)
Etanol Agua
Etanol 0 0.303
Agua 0.303 0

ln ϒ in ϒ
τ (21) G(12) G(21) etanol (1) agua (2) ϒ etanol (1) ϒ agua (2) K1 K2
-0.161476 0.5517677 1.0501441 0.2297984 0.45881961 1.25834635 1.58220527 1.18285104 0.64107484
-0.16161 0.5514961 1.0501866 0.1316326 0.70469002 1.14068916 2.02321942 1.0594978 0.80968557
-0.161478 0.5517636 1.0501447 0.2298014 0.45882156 1.25835007 1.58220836 1.18263904 0.64095535
-0.161282 0.5521637 1.0500821 0.3202422 0.30956042 1.37746131 1.36282591 1.31758391 0.56222535
-0.160993 0.5527501 1.0499904 0.3998992 0.21422869 1.49167426 1.23890595 1.46408953 0.52490401
-0.160248 0.55427 1.0497532 0.5290281 0.10767338 1.69728187 1.11368394 1.78066684 0.50548591
-0.159307 0.5561926 1.0494541 0.626384 0.05576472 1.87083349 1.05734888 2.1345049 0.52337623
-0.158227 0.5584096 1.0491107 0.7011144 0.02873925 2.01599817 1.0291562 2.53242204 0.56265918
-0.157048 0.5608392 1.0487359 0.7597315 0.01419044 2.13770221 1.0142916 2.98199398 0.61792734
-0.155791 0.563442 1.0483365 0.8066353 0.00634788 2.24035726 1.00636807 3.49392832 0.68793714
-0.154466 0.5661977 1.0479157 0.844819 0.0022989 2.32755657 1.00230154 4.08153748 0.77332892
-0.153077 0.5691011 1.0474748 0.8763529 0.00047774 2.40212289 1.00047785 4.76194941 0.87608544
-0.152353 0.5706191 1.0472452 0.8900909 0.00010959 2.43535093 1.0001096 5.1456876 0.93531968
-0.151625 0.5721524 1.047014 0.9027027 0 2.46625976 1 5.55623523 0.99920496
n (etanol) n (agua) n (total) X total
[mol] [mol] [mol] Gráfica Densidad Vs Xet
1.47972823 0.7534166 2.23314483 1 1.05
1.56193536 0.48750486 2.04944021 1
1
1.47972823 0.7534166 2.23314483 1
1.39752111 1.01932834 2.41684945 1 0.95
1.31531399 1.28524008 2.60055406 1 0.9

Densidad
1.15089974 1.81706356 2.9679633 1
0.85
0.98648549 2.34888704 3.33537253 1
0.82207124 2.88071052 3.70278176 1 0.8
0.65765699 3.412534 4.07019099 1 0.75
0.49324274 3.94435748 4.43760022 1
0.7
0.3288285 4.47618096 4.80500946 1 0 0.1 0.2 0.3 0.4 0.5 0.6
0.16441425 5.00800444 5.17241869 1 Xet
0.08220712 5.27391618 5.35612331 1
0 5.53982792 5.53982792 1
Grafi ca Grados Brix Vs Yet
20

15
Brix

10

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
Y et

Gráfi ca T termocupla exp vs

95

90

85
T Termocupla

Y etanol Y agua Sum Y 80

0.78378171 0.21628531 1.00006702 75

0.80747272 0.19260169 1.00007441 70

0.78364124 0.216245 0.99988624
0.76188085 0.23712368 0.99900453 65
0 0.1 0.2 0.3 0.4 0.5 0.6 0
0.74051044 0.2594169 0.99992734
Xe
0.69049675 0.30947149 0.99996824
 65
0 0.1 0.2 0.3 0.4 0.5 0.6 0
Xe

0.63131122 0.36858001 0.99989123

0.56223441 0.43774068 0.99997509
0.48182731 0.51808332 0.99991063
0.38835287 0.61147238 0.99982526 Gráfi ca Tvidrio exp Vs Xe
0.27931804 0.72040653 0.99972457
95
0.15136677 0.84823755 0.99960432
0.0789773 0.92096416 0.99994147 90
0 0.99920496 0.99920496
85

T vidrio
80

75

70

65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
Xe
 Gráfica T-XY
ca Densidad Vs Xet
95

90

85

T(°C)
80

75

70

65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
X-Y
2 0.3 0.4 0.5 0.6 0.7 0.8
Xet
T-X T-Y

Grados Brix Vs Yet Grafi ca Presion Vs Temperatura

1300
1200
1100
1000
900
Presion

800
700
600
500
400
.3 0.4 0.5 0.6 0.7 0.8 0.9 340 345 350 355 360 365
Y et Temperatura

termocupla exp vs Xe
Grafica X-Y
1
0.9
0.8
0.7
0.6
0.5
Y

0.4
0.3
0.3 0.4 0.5 0.6 0.7 0.8 0.9 0.2
0.1
Xe
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X
 0.3
0.3 0.4 0.5 0.6 0.7 0.8 0.9 0.2
0.1
Xe
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X

vidrio exp Vs Xe
Gráfi ca Densidad Vs Yet
1.2

0.8

Axis Title
0.6

0.4

0.2
0.4 0.5 0.6 0.7 0.8 0.9
0
Xe 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Axis Title
 Gráfi ca T teorica Vs Xe
Gráfica Gra
95
100
90
90
85 80
70
80
T teorica

60
75 50

GL
70 40
30
65 20
0.7 0.8 0.9
60 10
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0
0 0.1 0.2 0.3
Xe

100

ura 95
Gráfi ca T
90 95
Temperatura

85 90

85
80

T digital
80
75
75
70
70
60 365 65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 65
0 0.1 0.2
Xe

Grafica T exps Vs Xe Gráfica T Termocupla Vs Xe

Grafica T digital Vs Xe Grafica T Teorica Vs Xe

Grafica Grados Brix Vs Xet

20

15
Brix

10

5
0.8 0.9 1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Xet
 Brix
10

5
0.8 0.9 1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Xet

et
Gráfi ca Grados GL Vs Yet
100
90
80
70
60
Axis Title

50
40
30
20
0.7 0.8 0.9
10
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Axis Title
 Gráfica Grados GL Vs Xet
100
90
80
70
60
50
40
30
20
10
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Xet

Gráfi ca T digital exp Vs Xe

95

90

85
T digital

80

75

70

65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Xe
 𝑇𝑟=𝑇/𝑇𝑐;𝑃𝑟=𝑃/𝑃𝑐

Tc 647.3 K
Pc 22120 Kpa
1 mmHg 0.133322 Kpa Calculo de la Presion por PEC
Tburbuja Tvidrio Ttermocupla Tdigital
Tvidrio Ttermocupla Tdigital 273.15 90 90 90.2
70 69.6 69.2
69 69.2 68.6 Temp. Kelvin
70 70.4 70.2 363.15 363.15 363.35
69.5 70.5 69.7
70 69.5 69.1 Calculo de Tr
71 71.1 71.6 0.56102271 0.56102271 0.56133169
71 70.7 71.2
72.5 72.7 72.4 Leer de tablas Pr
74 73.8 73.8 0.0032 0.0032 0.0033
74.5 74.2 74.5
78 77.7 78 Calcular P
82 81.1 80.9 70.784 70.784 72.996
87 87.4 86.3 530.925129 530.925129 547.516539
90 90 90.2
 Calculo de Ps por tablas

N° T °C TK Ps Kpa Ps mmHg
1 90 363.15 70.14 526.10261
2 90 363.15 70.14 526.10261
3 90.2 363.35 70.72 530.453045
Tc 647.3 K
Pc 22120 Kpa Calculo de la Presion por PEC
1 mmHg 0.133322 Kpa Tvidrio Ttermocupla Tdigital
Tburbuja 90 90 90.2
Tvidrio Ttermocupla Tdigital
70 69.6 69.2 Temp. Kelvin
69 69.2 68.6 363.15 363.15 363.35
70 70.4 70.2
69.5 70.5 69.7 Calculo de Tr
70 69.5 69.1 0.56102271 0.56102271 0.56133169
71 71.1 71.6
71 70.7 71.2 Calculo de X
72.5 72.7 72.4 0.43897729 0.43897729 0.43866831
74 73.8 73.8
74.5 74.2 74.5
78 77.7 78
82 81.1 80.9
87 87.4 86.3
90 90 90.2
𝑒^(( 〖 1−𝑋) 〗 ^(−1)∗(𝐴∗𝑋+𝐵∗𝑋^1.5+𝐶∗
𝑋^3+𝐷∗𝑋^6))∗𝑃𝑐
𝑋=1−𝑇𝑟

Constantes
A B C D
-7.7645 1.45838 -2.7758 -1.23303

Calculo de Ps
0.70149252 0.70149252 0.706838583380119
70.1492517 70.1492517 70.6838583380119
526.164112 526.164112 530.174002325287

63.099
473.289829
-0.01513226 -1.5132259
 Ps= 𝑒^((𝐴−(𝐵/(𝑇+𝐶))))

Constantes de la Ecuacion de Antoine

A B C
Etanol 18.9119 3803.98 -41.68
Agua 18.3036 3816.44 -46.13
 Calculo de la Presion Atmosferica
90 90 90.2
363.15 363.15 363.35
525.902915 525.902915 529.909699
 Calculo de error 538.319
Ecuaciones Presiones Error%
530.925129 1.37351113
Ecuacion de PEC 530.925129 1.37351113
547.516539 1.70856665
526.10261 2.26935883
526.10261 2.26935883
Por tablas 530.453045 1.46120696
526.164112 2.2579341
526.164112 2.2579341
Hendrich 530.174002 1.51304295
525.902915 2.3064549
525.902915 2.3064549
Antoine 529.909699 1.56214076

lee Kesler

Harlacher