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Porosity and Pore Size Distribution in Recycled Concrete
Porosity and Pore Size Distribution in Recycled Concrete
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The reuse of construction and demolition wastes as replacement for natural coarse aggregate in the production
of recycled concrete has been spreading worldwide as a method for recycling waste materials. However, recycled
aggregates are of higher porosity than natural aggregates, which can decrease the mechanical properties and
durability of recycled concrete. The study reported in this paper compared the porosity and pore size distributions
of a control concrete and concretes made with different replacement levels of natural coarse aggregates. The
research intended to relate the influence of the aforementioned aspects on mechanical and durability characteristics
by assessing the compressive strength and the capillary water absorption of each concrete mix. Although there was
a decline in compressive strength, the recycled concretes exceeded the design strength grade of 25 MPa. It was also
found that recycled concrete possessed a higher capillary water absorption, which was more pronounced in the short
term due to the presence of capillary pores but was less significant in the long term as the presence of macropores in
both concrete mixes was very similar.
1
Magazine of Concrete Research Porosity and pore size distribution
in recycled concrete
García-González, Rodríguez-Robles, Juan-
Valdés, Morán-del Pozo and Guerra-Romero
The porosity of concrete is one of the most important factors Parameter Standard
in order to achieve optimum durability, as it depends on the
porosity of the cement, pores due to the compaction process, Density EN 1097-6 (AENOR, 2006)
entrapped air and the porosity of the aggregate. The use of Water absorption EN 1097-6 (AENOR, 2006)
mixed recycled aggregates in concrete manufacture must thus Particle size EN 933-1 (AENOR, 2012a),
address the porosity problems of recycled aggregate in order to EHE-08 (PCC, 2008)
not adversely affect the durability of the recycled concrete. Fines quantity EHE-08 (PCC, 2008)
Fines quality (sand equivalent) EN 933-8 (AENOR, 2012b)
In the study reported here, both the porosity and the pore size Resistance to fragmentation EN 1097-2 (AENOR, 2010a)
distribution of different concrete mixes were evaluated in order (Los Angeles test)
to compare the effect of partial and total replacement of Shape (flakiness index) EN 933-3 (AENOR, 2012c)
natural coarse aggregate with mixed recycled aggregate on Composition content EN 933-11 (AENOR, 2010b)
compressive strength and capillary water absorption.
Table 2. Characterisation of the aggregates
2
Magazine of Concrete Research Porosity and pore size distribution
in recycled concrete
García-González, Rodríguez-Robles, Juan-
Valdés, Morán-del Pozo and Guerra-Romero
100
90
80
70
Percentage passing: %
60
50
40
30
20
10
0
0·01 0·10 1 10 100
Sieve size: mm
0·75% 3·64%
0·44% CC RC-50 RC-100
Figure 2. Composition of the mixed recycled aggregate according Capillary water absorption test
to EN 933-11 (AENOR, 2010b) With the aim of assessing the influence of porosity on concrete
durability, a capillary water absorption test was conducted.
3
Magazine of Concrete Research Porosity and pore size distribution
in recycled concrete
García-González, Rodríguez-Robles, Juan-
Valdés, Morán-del Pozo and Guerra-Romero
Evaluation of this parameter was carried out on 100100 phenomenon also depends on the composition of the recycled
50 mm prismatic specimens according to Spanish standard aggregate (very heterogeneous when dealing with mixed
UNE 83982 (AENOR, 2008). Water uptake was measured recycled aggregates) and the size of pores and their distri-
by weighing the specimens at fixed time intervals (Figure 3). bution. In this study, the concrete with 100% replacement (RC-
100) showed a total porosity lower than that of the concrete
with 50% substitution (RC-50). It is worth noting that
Results and discussion although mixed recycled aggregate has a total porosity greater
Concrete porosity than that of natural aggregate, the pore size and distribution
have a lesser impact on the mechanical properties and dura-
Recycled aggregates show higher porosity than natural aggre-
bility of concrete than when recycled concrete aggregates are
gates, meaning that recycled concretes have a higher porosity
used as the replacement.
when recycled aggregates rather than natural aggregates are
used in the concrete manufacture. Several studies have shown
Kou et al. (2011) studied the influence of recycled aggregates
that a higher porosity of components used in the manufacture
on concrete porosity, and concluded that normal aggregate
of concrete results in poorer performance with regard to com-
concrete and recycled aggregate concrete made with two differ-
pressive strength, modulus of elasticity, shrinkage, resistance
ent sources of recycled aggregates had similar values of poros-
to freeze–thaw cycles and so on (Angulo et al., 2010; Gökçe
ity at 28 d of curing. The porosity after 5 years of water curing
and Şimşek, 2013; Li and Aubertin, 2003; Tam et al., 2007).
was essayed, and significant differences in porosity were
However, when studying the different mechanical properties of
observed: the concrete made with 100% crushed concrete ag-
concrete that can be influenced by the porosity of the material,
gregate had the lowest porosity, and the porosity was reduced
it is not sufficient to analyse the total porosity: other aspects
such as the size of the pores and their distribution must also be
taken into account
4
Magazine of Concrete Research Porosity and pore size distribution
in recycled concrete
García-González, Rodríguez-Robles, Juan-
Valdés, Morán-del Pozo and Guerra-Romero
0·08
0·07
0·06
Cumulative mercury intrusion: ml/g
0·05
0·04
0·03
CC
0·02 RC-50
RC-100
0·01
0
1000 100 10 1 0·1 0·01 0·001
Pore size diameter: µm
by 45% between 28 d and 5 years. Medina et al. (2012) evalu- 45 Compressive strength Porosity 16
ated the effect of substituting 15%, 20% and 25% of natural 40 14
coarse aggregate with recycled ceramic coarse aggregate and
Compressive strength: MPa
35 12
concluded that total porosity values increased with an increase
30
Porosity: %
in ceramic replacement ratio. Furthermore, Medina et al. 10
25
studied pore sizes and observed that the inclusion of ceramic 8
aggregate resulted in refinement of the pore system, increasing 20
6
the volume of capillary pores and decreasing the volume of 15
macropores. 10 4
5 2
This effect was also noticeable in the samples tested in the
0 0
current study. As can be seen in Figure 4, the cumulative intru- CC RC-50 RC-100
sion of mercury into pores of diameter greater than 1 μm was
not significantly different for the three concretes, but the quan- Figure 5. Relationship between concrete porosity and
tity of pores of smaller size was greater in the recycled con- compressive strength
cretes than in the control. Nonetheless, the quantity of pores
of size less than 0·1 μm (mesopores and micropores) has been
shown to have no negative effect on the mechanical and dura- with CC, RC-50 showed an increase of up to 27% in total por-
bility properties of concrete (Gómez-Soberón, 2002; Kumar osity and only a 6% decline in compressive strength. However,
and Bhattacharjee, 2003). comparing RC-100 with CC, the compressive strength
decreased by 19% while the total porosity was 14% greater.
Compressive strength test
Figure 5 shows the relationship between concrete total porosity Kou et al. (2011) demonstrated that from 28 d to 5 years, the
and maximum compressive strength achieved (38·46 MPa increases in compressive and splitting tensile strengths for the
in CC, 36·02 MPa in RC-50 and 31·13 MPa in RC-100). recycled aggregate concretes were more than in normal aggre-
Comparing CC and RC-50, the results obtained concur with gate concrete and, after 5 years of water curing, the recycled
the findings reported by Yudenfreund et al. (1972), Auskern aggregate concretes had lower compressive strength but higher
and Horn, (1973) and Popovics (1981), as expected: compared splitting tensile strength than the normal aggregate concrete.
5
Magazine of Concrete Research Porosity and pore size distribution
in recycled concrete
García-González, Rodríguez-Robles, Juan-
Valdés, Morán-del Pozo and Guerra-Romero
Pacheco-Torgal and Jalali (2011) achieved compressive analysis of recycled concrete samples with replacement of
strength increases in recycled concretes by using recycled natural aggregate by recycled aggregate originating from con-
coarse aggregates with water absorption values of 6%, addres- crete, and concluded that the absorption of the recycled con-
sing possible cement hydration problems by pre-saturation of crete increased proportionally with recycled concrete aggregate
the aggregates. content while the density decreased slightly. Water porosity,
like absorption, increases proportionally with recycled concrete
Even though the compressive strength of the recycled concretes aggregate content. However, the velocity of the water uptake
declined in comparison with the control, achieving the decreased over time, and after 24 h the water absorption/time
designed 25 MPa strength grade was not a problem for either curve displays a lower slope, so the negative effect of the
of the recycled concretes. greater capillary water absorption lessens with time.
Capillary water absorption in hardened concrete Figure 4 shows the distribution and pore size for each concrete
The water uptake values reported in Figure 6 are average batch. Both CC and RC-50 showed similar patterns, although
values calculated from the results obtained from three speci- RC-50 exhibited an appreciable increase in micropore content,
mens of the same concrete mix, according to UNE 83982. The whereby the growth model of capillary water absorption gain
capillary water absorption was higher in the recycled concretes was similar but with higher values for recycled concrete.
than the control throughout the entire essay, but was more RC-100 presented a higher mesopore volume than the other
significant in the first 24 h. This finding was expected as the two concretes, which translates into a greater capillary water
porosity study (Figure 4) showed a greater quantity of pores absorption in the initial hours of the test. However, as the
larger than 0·1 μm in diameter in the recycled concretes than value of micropore content of this sample was in between that
in the control, and these pores play a major role in the capil- of the CC and RC-50 concretes, the superior capillary water
lary water absorption test. Kanellopoulos et al. (2014) demon- gain tendency in the first 6 h was slowed, even to the point of
strated that properties such as liquid capillary absorption, showing a capillary water gain similar to that of CC at the end
porosity and rapid chloride permeability are increased as the of the test.
percentage of natural aggregate replacement is increased, and
they concluded that this effect is more evident when higher Conclusions
percentages of recycled aggregates of large sizes are used in the Although the total porosity of the recycled concretes was
mixtures. Gómez-Soberón (2002) presented an experimental found to be higher than that of the control concrete, this
300 000
250 000
200 000
Water uptake: g/m2
150 000
CC
RC-50
100 000
RC-100
50 000
0
0 2000 4000 6000 8000 10 000 12 000
Time: min
6
Magazine of Concrete Research Porosity and pore size distribution
in recycled concrete
García-González, Rodríguez-Robles, Juan-
Valdés, Morán-del Pozo and Guerra-Romero
parameter was significantly higher in the fraction of pores of AENOR (2009b) EN 12390-3: Testing hardened concrete.
diameter smaller than 0·1 μm. Therefore, the mechanical and Part 3: Compressive strength of test specimens. AENOR,
durability properties of the concrete were not negatively Madrid, Spain.
affected. AENOR (2010a) EN 1097-2: Tests for mechanical and physical
properties of aggregates. Part 2: Methods for the
An increase in recycled aggregate replacement does not necess- determination of resistance to fragmentation. AENOR,
arily entail an increase in the total porosity of the resulting Madrid, Spain.
recycled concrete. When mixed recycled aggregates from con- AENOR (2010b) EN 933-11: Tests for geometrical properties of
struction and demolition wastes are used, total porosity may aggregates. Part 11: Classification test for the constituents
even decrease with increasing substitution percentage. of coarse recycled aggregate AENOR, Madrid, Spain.
AENOR (2011) EN 197-1: Cement – Part 1: Composition,
As expected, there was an inverse relationship between mixed specifications and conformity criteria for common cements.
recycled aggregate content and the compressive strength of the AENOR, Madrid, Spain.
produced recycled concretes. However, an increase in replace- AENOR (2012a) EN 933-1: Tests for geometrical properties
ment percentage did not result in proportional increases in the of aggregates. Part 1: Determination of particle size
total porosity of the recycled concrete. distribution – Sieving method. AENOR, Madrid, Spain.
AENOR (2012b) EN 933-8: Tests for geometrical properties of
Capillary water absorption was higher in the recycled concretes aggregates. Part 8: Assessment of fines. Sand equivalent
than in the control concrete. This is due to the greater presence test. AENOR, Madrid, Spain.
of pores of size greater than 0·1 μm, which are primarily AENOR (2012c) EN 933-3: Tests for geometrical properties of
responsible for capillary water absorption. Nevertheless, con- aggregates – Part 3: Determination of particle shape –
crete batches with higher recycled aggregate contents may Flakiness index. AENOR, Madrid, Spain.
exhibit better capillary water absorption behaviour due to the AENOR (2013) UNE 80303-1: Cements with additional
influence of the size of the pores and their distribution. characteristics. Part 1: Sulphate resisting cements.
AENOR, Madrid, Spain.
In conclusion, although mixed recycled aggregates have high Angulo SC, Carrijo PM, Figueiredo AD et al. (2010) On the
values of water absorption, meaning that recycled concretes classification of mixed construction and demolition waste
have higher total porosities than conventional concretes, mixed aggregate by porosity and its impact on the mechanical
recycled aggregates are a suitable option in recycled aggregate performance of concrete. Materials and Structures 43(4):
concrete manufacture, and no significant mechanical or dura- 519–528.
bility issues were found related to their use. Arredondo F (1968) Dosificación de hormigones. Series
manuales y normas del Instituto de las Ciencias de la
Construcción Eduardo Torroja, 3rd edn. Madrid, Spain
Acknowledgements (in Spanish).
This article was made possible by a university teacher training Auskern A and Horn W (1973) Capillary porosity in hardened
grant (FPU AP2010-0613) and research staff training grant cement paste. Journal of Testing and Evaluation 1(1):
(FPI BES-2011-047159) awarded to Julia García-González, 74–79.
associated with project BIA2010-21194-C03-02. The authors BSI (2012) BS 8500-2:2006+A1:2012: Complementary British
would like to acknowledge the contribution of mixed recycled Standard to BS EN 206-1 – Specification for constituent
aggregate samples from the TEC-REC S.L. construction and materials and concrete. BSI, London, UK.
demolition waste treatment plant. Di Maio A and Traversa LP (2003) Evaluación de hormigones
reciclados mediante ensayos no destructivos. Materiales de
Construcción 53(1): 37–46 (in Spanish).
REFERENCES Djerbia A (2012) Determining the water absorption of
AENOR (Spanish Association for Standardization and recycled aggregates utilizing hydrostatic weighing
Certification) (2006) EN 1097-6: Tests for mechanical and approach. Construction and Building Materials 27(1):
physical properties of aggregates. Part 6: Determination of 112–116.
particle density and water absorption. AENOR, Madrid, Gökçe HS and Şimşek O (2013) The effects of waste concrete
Spain. properties on recycled aggregate concrete properties.
AENOR (2008) UNE 83982:2008: Concrete durability. Test Magazine of Concrete Research 65(14): 844–854, http://
methods. Determination of the capillary absorption in dx.doi.org/10.1680/macr.12.00181.
hardened concrete. Fagerlund method. AENOR, Madrid, Gómez-Soberón JMV (2002) Porosity of recycled concrete
Spain. with substitution of recycled concrete aggregate: an
AENOR (2009a) EN 12620: Aggregates for concrete. AENOR, experimental study. Cement and Concrete Research 32(8):
Madrid, Spain. 1301–1311.
7
Magazine of Concrete Research Porosity and pore size distribution
in recycled concrete
García-González, Rodríguez-Robles, Juan-
Valdés, Morán-del Pozo and Guerra-Romero
HKWB (Hong Kong Works Bureau) (2002) Works Bureau Research 62(7): 519–530, http://dx.doi.org/10.1680/macr.
Technical Circular 12/2002: Specifications Facilitating the 2010.62.7.519.
Use of Recycled Aggregates. HKWB, Hong Kong. PCC (Permanent Commission on Concrete) (2008) EHE-08:
Kanellopoulos A, Nicolaides D and Perou MF (2014) Mechanical Code on structural concrete. Ministry of Public Works,
and durability properties of concretes containing recycled Madrid, Spain.
lime powder and recycled aggregates. Construction and Poon CS, Kou SC and Lam L (2007) Influence of recycled
Building Materials 53(1): 253–259. aggregate on slump and bleeding of fresh concrete.
Kou SC, Poon CS and Etxeberria M (2011) Influence of recycled Materials and Structures 40(9): 981–988.
aggregates on long term mechanical properties and pore Popovics S (1981) New formulas for the prediction of the
size distribution of concrete. Cement and Concrete effects of porosity on concrete strength. ACI Materials
Composites 33(2): 286–291. Journal 78(2): 127–129.
Kumar R and Bhattacharjee B (2003) Porosity, pore size Ramos D (2009) El empleo de aditivos en la confección de
distribution and in situ strength of concrete. Cement and hormigones de alta durabilidad. Zuncho 20(1): 29–37
Concrete Research 33(1):155–164. (in Spanish).
Li L and Aubertin MA (2003) A general relationship between Sánchez-de Juan M and Alaejos-Gutierrez P (2009) Study on the
porosity and uniaxial strength of engineering materials. influence of attached mortar content on the properties of
Canadian Journal of Civil Engineering 30(4): 644–658. recycled concrete aggregate. Construction and Building
Medina C, Frías M and Sánchez-de Rojas MI (2012) Materials 23(2): 872–877.
Microstructure and properties of recycled concretes using Tam VWY, Tam CM and Le KN (2007) Removal of cement
ceramic sanitary ware industry waste as coarse aggregate. mortar remains from recycled aggregate using pre-soaking
Construction and Building Materials 31(1): 112–118. approaches. Resources, Conservation and Recycling 50(1):
MoP (Ministry of the Presidency) (2008) Royal Decree 956/2008: 82–101.
Instruction for Cement Reception. Ministry of the Yang J, Du Q and Bao Y (2011) Concrete with recycled concrete
Presidency, Madrid, Spain. aggregate and crushed clay bricks. Construction and
Pacheco-Torgal F and Jalali S (2011) Compressive strength and Building Materials 25(4): 1935–1945.
durability properties of ceramic wastes based concrete. Yudenfreund M, Hanna KM, Skalny J et al. (1972)
Materials and Structures 44(1): 155–167. Hardened Portland cement paste of low porosity
Paine KA and Dhir RK (2010) Recycled aggregates in concrete: V. Compressive strength. Cement and Concrete Research
a performance related approach. Magazine of Concrete 2(6): 731–743.
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