Download as pdf or txt
Download as pdf or txt
You are on page 1of 18

Revision date: 29/09/2015 Revision: 01

SAFETY DATA SHEET


NITOBOND EP SLOW SET BASE

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name NITOBOND EP SLOW SET BASE

Product number M1711000

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Supplier FOSAM COMPANY LTD
Phase 4,Road 414 , Street 82
Post Box 11081 Jeddah 21453
K.S.A
+966126375345
+966126080999
+966126375891

1.4. Emergency telephone number


Emergency telephone +966 126375345 , +966216080999

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Repr. 1B - H360

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

Classification (67/548/EEC or Repr. Cat. 2;R61. Repr. Cat. 3;R62. Xi;R36/38. R43. N;R51/53.
1999/45/EC)

2.2. Label elements

Pictogram

Signal word Danger

Hazard statements H410 Very toxic to aquatic life with long lasting effects.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H360 May damage fertility or the unborn child.

1/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET BASE

Precautionary statements P273 Avoid release to the environment.


P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.

Contains EPOXY RESIN (Type A) (Number average MW <= 700 )

Supplementary precautionary P201 Obtain special instructions before use.


statements P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing vapour/spray.
P264 Wash contaminated skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P321 Specific treatment (see medical advice on this label).
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with national regulations.

2.3. Other hazards


SECTION 3: Composition/information on ingredients

3.2. Mixtures

EPOXY RESIN (Type A) (Number average MW <= 700 ) 60-100%


CAS number: 25068-38-6 EC number: 500-033-5

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

TITANIUM DIOXIDE 10-30%


CAS number: 13463-67-7 EC number: 236-675-5

Classification Classification (67/548/EEC or 1999/45/EC)


Not Classified -

DIBUTYL PHTHALATE: DBP 5-10%


CAS number: 84-74-2 EC number: 201-557-4
M factor (Acute) = 10 M factor (Chronic) = 10

Classification
Repr. 1B - H360
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

2/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET BASE

METHANOL <1%
CAS number: 67-56-1 EC number: 200-659-6

Classification Classification (67/548/EEC or 1999/45/EC)


Flam. Liq. 2 - H225 F;R11 T;R23/24/25,R39/23/24/25
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
STOT SE 1 - H370

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media Carbon dioxide, powder foam or water fog - Do not use water jets.

5.2. Special hazards arising from the substance or mixture


Hazardous combustion Toxic fumes. For further information see Section 10.
products

5.3. Advice for firefighters


Protective actions during Fire-fighters should wear appropriate protective equipment and self-contained breathing
firefighting apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Personal precautions Wear rubber boots in addition to the recommended protective clothing.
Immediately issue NO SMOKING and NO NAKED FLAMES warnings.

6.2. Environmental precautions


Environmental precautions Prevent entry into drains, sewers and water courses.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Soak up with inert absorbent or contain and remove by best available means. Gather into
containers.

6.4. Reference to other sections


SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions Maintain good standards of personal hygiene. Handling: Avoid breathing vapours. Maintain
good standards of personal hygiene. In case of insufficient
ventilation, wear suitable respiratory equipment. Avoid skin and eye contact.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Store in conformity with local fire regulations. Store away from sources of ignition. Store in
cool, dry area. Store out of direct sunlight. Store away from acids.

3/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET BASE

7.3. Specific end use(s)


SECTION 8: Exposure Controls/personal protection

8.1. Control parameters


Occupational exposure limits
TITANIUM DIOXIDE
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³
DIBUTYL PHTHALATE: DBP
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL 10 mg/m³
METHANOL
Long-term exposure limit (8-hour TWA): WEL 200 ppm(Sk) 266 mg/m3(Sk)
Short-term exposure limit (15-minute): WEL 250 ppm(Sk) 333 mg/m3(Sk)
WEL = Workplace Exposure Limit

EPOXY RESIN (Type A) (Number average MW <= 700 ) (CAS: 25068-38-6)

DNEL Workers - Inhalation; Short term systemic effects: 12.25 mg/m³


Workers - Inhalation; Long term systemic effects: 12.25 mg/m³

PNEC - Fresh water; 0.006 mg/l

TITANIUM DIOXIDE (CAS: 13463-67-7)

DNEL Industry - Inhalation; Long term local effects: 10 mg/m³


Consumer - Oral; Long term systemic effects: 700 mg/kg/day

PNEC - Fresh water; 0.127 mg/l


- Sediment (Freshwater); >=1000 mg/kg
- Marine water; 1 mg/l
- Sediment (Marinewater); >= 100 mg/kg
- Soil; 100 mg/kg
- STP; 100 mg/l

DIBUTYL PHTHALATE: DBP (CAS: 84-74-2)

Ingredient comments WEL = Workplace Exposure Limits

DNEL Workers - Inhalation; Long term systemic effects: 0.13 mg/m³


Workers - Dermal; Long term systemic effects: 0.19 mg/kg bw/day

PNEC - Fresh water; 10 µg/l


- Marine water; 1 µg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Avoid inhalation of dust. Observe any occupational exposure
controls limits for the product or ingredients.

Hygiene measures Use engineering controls to reduce air contamination to permissible exposure level.

4/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET BASE

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties


Appearance White colour viscous liquid

Colour White.

Odour Typical

Flash point >250°C

Relative density 1.19 @ °C

Solubility(ies) Insoluble in water.

9.2. Other information


SECTION 10: Stability and reactivity

10.1. Reactivity
10.2. Chemical stability
Stability Contains volatile solvent. Stable. Stable: reacts with compounds containing amino, hydroxyl or
carboxyl groups to give stable, cross linked materials.

10.3. Possibility of hazardous reactions


10.4. Conditions to avoid
10.5. Incompatible materials
Materials to avoid Strong oxidising agents. Strong acids. Strong alkalis.

10.6. Hazardous decomposition products


Hazardous decomposition Thermal decomposition:- Oxides of carbon. Irritant fumes.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects


Acute toxicity - oral
ATE oral (mg/kg) 33,333.33

Acute toxicity - dermal


ATE dermal (mg/kg) 100,000.0

Acute toxicity - inhalation


ATE inhalation (gases ppm) 233,333.33

ATE inhalation (vapours mg/l) 1,000.0

ATE inhalation (dusts/mists 166.67


mg/l)

Inhalation May cause respiratory system irritation. Vapour may affect central nervous system. Symptoms
following overexposure may include the following: Headache. Nausea, vomiting. Intoxication.
May cause discomfort.

Ingestion Ingestion may cause severe irritation of the mouth, the oesophagus and the gastrointestinal
tract.

Skin contact May cause sensitisation by skin contact.

5/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET BASE

Eye contact Irritating and may injure eye tissue if not removed promptly.

SECTION 12: Ecological Information

12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Disposal methods Disposal must be in accordance with local and national legislation.
Unused Product: Dispose of through an authorised waste contractor to a licensed site.
Used/Contaminated Product: As for Unused Product.
Packaging: Must be disposed of through an authorised waste contractor.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (ADN) 3082

14.2. UN proper shipping name


Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
(ADR/RID) RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP)

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
(IMDG) RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP)

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP)

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP)

14.3. Transport hazard class(es)


ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9

6/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET BASE

Transport labels

14.4. Packing group


ADR/RID packing group III

IMDG packing group III

ADN packing group III

ICAO packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user


EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number 90


(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

7/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET BASE

Guidance Hazard Label Data:-


Named Ingredients: cement powders
Symbol(s): Xi
Risk Phrases: Irritating to eyes, respiratory system and skin.
Safety Phrases: Do not breathe dust
Avoid contact with skin and eyes
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing, gloves and eye/face protection
EC Directives: Dangerous Substances Directive, 67/548/EEC and adaptations.
Dangerous Preparations Directive, 88/379/EEC.
Safety Data Sheets Directive, 91/155/EEC.
Statutory Instruments: Chemicals (Hazard Information and Packaging for Supply)
(Amendment) Regs. 1996 (SI
1092).
Health & Safety at Work, etc. Act 1974.
Control of Substances Hazardous to Health Regs. 1994 (SI 3246).
Codes of Practice: Waste Management. The Duty of Care.
Guidance Notes: Occupational skin diseases: health and safety precautions (EH 26).
Dust in the workplace: general principles of protection. (EH44).
Occupational exposure limits (EH 40).
The above publications are available from HMSO

15.2. Chemical safety assessment


SECTION 16: Other information

General information The data and advice given apply when the product is used for the stated application or
applications. The product is not sold as suitable for any other application. Use of the product
for applications other than as stated in this sheet may give rise to risks not mentioned in this
sheet. The product should not be used other than for the stated application or applications
without seeking advice from Fosam Company ( Fosroc).
If this product has been purchased for supply to a third party for use at work, it is the
purchaser's duty to take all necessary steps to secure that any person handling or using the
product is provided with the information in this sheet.
It is the responsibility and duty of the employer to inform employees and others who may be
affected of any hazards described in this sheet and of any precautions which should be taken.
This sheet does not constitute or substitute for the users own assessment of workplace risk,
as required by other health and safety legislation.
Further copies of this Safety Data Sheet may be obtained from Fosroc Fosam Compamy.

Revision date 29/09/2015

Revision 01

Risk phrases in full NC Not classified.


R11 Highly flammable.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R36/38 Irritating to eyes and skin.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact
with skin and if swallowed.
R43 May cause sensitisation by skin contact.
R50 Very toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R61 May cause harm to the unborn child.
R62 Possible risk of impaired fertility.

8/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET BASE

Hazard statements in full H225 Highly flammable liquid and vapour.


H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H360 May damage fertility or the unborn child.
H370 Causes damage to organs .
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

9/9
Revision date: 29/09/2015 Revision: 01

SAFETY DATA SHEET


NITOBOND EP SLOW SET HARDENER

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name NITOBOND EP SLOW SET HARDENER

Product number M1711102

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Supplier FOSAM COMPANY LTD
Phase 4,Road 414 , Street 82
Post Box 11081 Jeddah 21453
K.S.A
+966126375345
+966126080999
+966126375891

1.4. Emergency telephone number


Emergency telephone +966 126375345 , +966216080999

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification
Physical hazards Not Classified

Health hazards Skin Sens. 1 - H317 Carc. 1B - H350 Repr. 1B - H360

Environmental hazards Aquatic Chronic 1 - H410

Classification (67/548/EEC or T;R39/23/24/25. Carc. Cat. 2;R45,Repr. Cat. 2;R61. Xn;R48/20/21/22. Muta Cat. 3;R68,Repr.
1999/45/EC) Cat. 3;R62. R43. N;R50/53.

2.2. Label elements

Pictogram

Signal word Danger

Hazard statements H350 May cause cancer.


H317 May cause an allergic skin reaction.
H360 May damage fertility or the unborn child.
H410 Very toxic to aquatic life with long lasting effects.

1/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET HARDENER

Precautionary statements P261 Avoid breathing vapour/spray.


P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/container in accordance with national regulations.

Contains DIBUTYL PHTHALATE: DBP

Supplementary precautionary P201 Obtain special instructions before use.


statements P202 Do not handle until all safety precautions have been read and understood.
P272 Contaminated work clothing should not be allowed out of the workplace.
P302+P352 IF ON SKIN: Wash with plenty of water.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P321 Specific treatment (see medical advice on this label).
P391 Collect spillage.
P405 Store locked up.

2.3. Other hazards


SECTION 3: Composition/information on ingredients

3.2. Mixtures

DIBUTYL PHTHALATE: DBP 30-60%


CAS number: 84-74-2 EC number: 201-557-4
M factor (Acute) = 10 M factor (Chronic) = 10

Classification
Repr. 1B - H360
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

4,4'-METHYLENEDIANILINE 1-5%
CAS number: 101-77-9 EC number: 202-974-4
M factor (Acute) = 1 M factor (Chronic) = 10

Classification
Acute Tox. 3 - H301
Acute Tox. 2 - H330
Skin Sens. 1 - H317
Muta. 2 - H341
Carc. 1B - H350
STOT SE 1 - H370
STOT RE 2 - H373
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

2/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET HARDENER

XYLENE <1%
CAS number: 1330-20-7 EC number: 215-535-7

Classification
Flam. Liq. 3 - H226
Skin Irrit. 2 - H315
Acute Tox. 4 - H312
Acute Tox. 4 - H332

METHANOL <1%
CAS number: 67-56-1 EC number: 200-659-6

Classification Classification (67/548/EEC or 1999/45/EC)


Flam. Liq. 2 - H225 F;R11 T;R23/24/25,R39/23/24/25
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
STOT SE 1 - H370

ETHYLBENZENE <1%
CAS number: 100-41-4 EC number: 202-849-4

Classification
Flam. Liq. 2 - H225
Acute Tox. 4 - H332

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media Carbon dioxide, powder foam or water fog - Do not use water jets.

5.2. Special hazards arising from the substance or mixture


Specific hazards Toxic fumes. For further information see Section 10.

5.3. Advice for firefighters


Protective actions during Fire-fighters should wear appropriate protective equipment and self-contained breathing
firefighting apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

3/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET HARDENER

Personal precautions Personal Precautions: Immediately issue NO SMOKING and NO NAKED FLAMES warnings.
Wear self
contained breathing apparatus and protective clothing.
Environmental Precautions: Prevent entry into drains, sewers and water courses.
Decontamination Procedures: Soak up with inert absorbent or contain and remove by best
available means.
Dispose of as waste.

6.2. Environmental precautions


Environmental precautions Prevent entry into drains, sewers and water courses.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Soak up with inert absorbent or contain and remove by best available means. Dispose of as
waste.

6.4. Reference to other sections


SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions Handling: Do not use near sources of ignition. Use only in well ventilated areas. Avoid
breathing vapours. Avoid
skin and eye contact.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Do not store with oxidising agents. Keep container closed and store away from water or
moisture. Store in cool, dry area. Store out of direct sunlight. Store away from acids. Keep
separate from food, feedstuffs, fertilisers and other sensitive material.

7.3. Specific end use(s)


SECTION 8: Exposure Controls/personal protection

8.1. Control parameters


Occupational exposure limits
DIBUTYL PHTHALATE: DBP
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL 10 mg/m³
4,4'-METHYLENEDIANILINE
Long-term exposure limit (8-hour TWA): WEL 0.01 ppm(Sk) 0.08 mg/m3(Sk)
Short-term exposure limit (15-minute): WEL
XYLENE
Long-term exposure limit (8-hour TWA): WEL 50 ppm 220 mg/m³
Short-term exposure limit (15-minute): WEL 100 ppm 441 mg/m³
Sk
METHANOL
Long-term exposure limit (8-hour TWA): WEL 200 ppm(Sk) 266 mg/m3(Sk)
Short-term exposure limit (15-minute): WEL 250 ppm(Sk) 333 mg/m3(Sk)
ETHYLBENZENE
Long-term exposure limit (8-hour TWA): WEL 100 ppm(Sk) 441 mg/m3(Sk)
Short-term exposure limit (15-minute): WEL 125 ppm(Sk) 552 mg/m3(Sk)
WEL = Workplace Exposure Limit
Sk = Can be absorbed through the skin.

4/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET HARDENER

DIBUTYL PHTHALATE: DBP (CAS: 84-74-2)

Ingredient comments WEL = Workplace Exposure Limits

DNEL Workers - Inhalation; Long term systemic effects: 0.13 mg/m³


Workers - Dermal; Long term systemic effects: 0.19 mg/kg bw/day

PNEC - Fresh water; 10 µg/l


- Marine water; 1 µg/l

XYLENE (CAS: 1330-20-7)

DNEL Workers - Inhalation; Long term systemic effects: 77 mg/m³


Workers - Inhalation; Short term systemic effects: 289 mg/m³
Workers - Dermal; Long term systemic effects: 180 mg/kg/day

PNEC - Fresh water; 0.327 mg/l


- Marine water; 0.327 mg/l
- STP; 6.58 mg/l

ETHYLBENZENE (CAS: 100-41-4)

DNEL Workers - Inhalation; Long term systemic effects: 77 mg/m³


Workers - Dermal; Long term systemic effects: 180 mg/kg bw/day

PNEC - Fresh water; 0.1 mg/l


- Marine water; 0.01 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation. Observe any occupational exposure
controls limits for the product or ingredients.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties


Appearance Viscous liquid.

Colour Green.

Odour Amine.

Flash point >130°C CC (Closed cup).

Relative density 1.140 @ 25°C

Solubility(ies) Immiscible with water.

Auto-ignition temperature Not applicable.

Oxidising properties Not determined.

9.2. Other information


SECTION 10: Stability and reactivity

5/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET HARDENER

10.1. Reactivity
10.2. Chemical stability
Stability Stable.

10.3. Possibility of hazardous reactions


10.4. Conditions to avoid
Conditions to avoid Temperatures below 5°C

10.5. Incompatible materials


Materials to avoid Strong oxidising agents. Strong acids. Strong alkalis.

10.6. Hazardous decomposition products


Hazardous decomposition Thermal decomposition:- Oxides of carbon. Nitrogen compounds,
products in some fire circumstances, hydrogen cyanide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects


Acute toxicity - oral
ATE oral (mg/kg) 5,543.71

Acute toxicity - dermal


ATE dermal (mg/kg) 37,500.0

Acute toxicity - inhalation


ATE inhalation (gases ppm) 87,500.0

ATE inhalation (vapours mg/l) 375.0

ATE inhalation (dusts/mists 13.75


mg/l)

General information The following toxicological assessment is based on a knowledge of the toxicity of the
product's components.
Oral LD50, rat >1000 mg/kg
Health Effects
On Eyes: Causes irreversible damage to eye tissue if not removed promptly.
On Skin: Corrosive - causes burns. May cause sensitisation.
By Inhalation: May cause respiratory irritation.
By Ingestion: Corrosive - causes severe damage to mouth, throat and digestive tract.
Chronic: Prolonged skin contact can result in chemical burns.
Other: p-tertiarybutyl phenol can cause a cosmetic effect known as "occupational vitiligo" or
leucoderma. It is
believed that repeated contact with this substance can lead to this depigmentation of the skin
in
sensitive individuals.

SECTION 12: Ecological Information

Ecotoxicity Expected to be ecotoxic to fish/daphnia/algae.

12.1. Toxicity
12.2. Persistence and degradability
Persistence and degradability The product is not biodegradable.

6/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET HARDENER

12.3. Bioaccumulative potential


Bioaccumulative potential Not expected to be bioaccumulative.

12.4. Mobility in soil


Mobility Mobile liquid. Contains volatile components. Partially soluble in water.

12.5. Results of PBT and vPvB assessment


12.6. Other adverse effects
Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Disposal methods Disposal must be in accordance with local and national legislation.
Unused Product: Dispose of through an authorised waste contractor to a licensed site.
Used/Contaminated Product: As for Unused Product.
Packaging: Must be disposed of through an authorised waste contractor.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (ADN) 3082

14.2. UN proper shipping name


Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
(ADR/RID) PHTHALATE: DBP, 4,4'-METHYLENEDIANILINE)

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
(IMDG) PHTHALATE: DBP, 4,4'-METHYLENEDIANILINE)

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
PHTHALATE: DBP, 4,4'-METHYLENEDIANILINE)

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
PHTHALATE: DBP, 4,4'-METHYLENEDIANILINE)

14.3. Transport hazard class(es)


ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9

Transport labels

7/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET HARDENER

14.4. Packing group


ADR/RID packing group III

IMDG packing group III

ADN packing group III

ICAO packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user


EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number 90


(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Guidance Workplace Exposure Limits EH40.
CHIP for everyone HSG228.
Approved Classification and Labelling Guide (Sixth edition) L131.

15.2. Chemical safety assessment


SECTION 16: Other information

General information The data and advice given apply when the product is used for the stated application or
applications. The product is not sold as suitable for any other application. Use of the product
for applications other than as stated in this sheet may give rise to risks not mentioned in this
sheet. The product should not be used other than for the stated application or applications
without seeking advice from Fosam Company ( Fosroc).
If this product has been purchased for supply to a third party for use at work, it is the
purchaser's duty to take all necessary steps to secure that any person handling or using the
product is provided with the information in this sheet.
It is the responsibility and duty of the employer to inform employees and others who may be
affected of any hazards described in this sheet and of any precautions which should be taken.
This sheet does not constitute or substitute for the users own assessment of workplace risk,
as required by other health and safety legislation.
Further copies of this Safety Data Sheet may be obtained from Fosroc Fosam Compamy.

Revision date 29/09/2015

8/9
Revision date: 29/09/2015 Revision: 01

NITOBOND EP SLOW SET HARDENER

Revision 01

Risk phrases in full R10 Flammable.


R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R38 Irritating to skin.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact
with skin and if swallowed.
R43 May cause sensitisation by skin contact.
R45 May cause cancer.
R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through
inhalation, in contact with skin and if swallowed.
R50 Very toxic to aquatic organisms.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R61 May cause harm to the unborn child.
R62 Possible risk of impaired fertility.
R68 Possible risk of irreversible effects.

Hazard statements in full H225 Highly flammable liquid and vapour.


H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H370 Causes damage to organs .
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

9/9

You might also like