PR-EOS ACETYLENE

T 300 K Tc 308.3 K
P 1 bar Pc 61.4 bar
R 83.14 cm3.bar/mol. K ω 0.184
VAPOUR
ac 4892588.487 cm3bar/mol2 z f(z)
m 0.649277428 1 0.006687707
T = 308.3
b 32.47677186 cm3/mol 0.99336536 8.78022E-05
a 4979071.959 cm3.bar/mol2 0.99327591 1.58532E-08
A 0.008003609 0.993275894 4.72392E-16
B 0.001302092 0.993275894 2.57007E-17
α -0.998697908 0.993275894 2.57007E-17
β 0.005394339 0.993275894 2.57007E-17
γ -8.72378E-06 0.993275894 2.57007E-17
a' -10537.23005 cm3bar/mol2K 0.993275894 2.57007E-17
a'' 28.71204127 cm6.bar/mol2.K2
Molar Volume (cm3/mol)

VAPOUR
vdep -167.7126545
gdep -167.4300392
hdep -495.8590518
sdep -1.094763375
pvdep -167.7126545
udep -328.1463973
adep 0.282615289
Cvdep 0.347228771

gvdep-gLdep:

0.003377427

SATURATED VAPOUR
 Tref 298
Pref 1

A 6.132
B 1.95E-03
D -1.30E+05
T1 298
T2 300
Δh, IG 8.75E+02
h1dep 0
Δh 3.79E+02

∆s, IG 2.93E+00
H s1dep 0.00E+00
∆s 1.83E+00

P-h Diagram for Acethylene

CRITICAL POINT
COMPRESSED
LIQUID
REGION
Pressure(bar)

SATURATED REGION

-20000 -15000 -10000

molar volumr (cm
OS ACETYLENE

VAPOUR LIQUID
f'(z) f(z)/f '(z) z f(z) f'(z) f(z)/f '(z)
1.007998522 0.006635 0.001302 -3.39089E-06 0.002798633 -0.00121
0.981574741 8.95E-05 0.002514 -1.4586E-06 0.000392414 -0.00372
0.981220292 1.62E-08 0.006231 -1.36426E-05 -0.006934411 0.001967
0.981220228 4.81E-16 0.004263 -3.8008E-06 -0.003066716 0.001239
0.981220228 2.62E-17 0.003024 -1.5163E-06 -0.000618296 0.002452
0.981220228 2.62E-17 0.000572 -5.96655E-06 0.004253633 -0.0014
0.981220228 2.62E-17 0.001974 -1.95886E-06 0.00146261 -0.00134
0.981220228 2.62E-17 0.003314 -1.77833E-06 -0.00119123 0.001493
0.981220228 2.62E-17 0.001821 -2.20687E-06 0.001767589 -0.00125

ume (cm3/mol) 24774.29 Molar Volume (cm3/mol) 45.41236098

LIQUID
cm3/mol vdep -24896.58764 cm3/mol
cm3bar/mol gdep 90362.96274 cm3bar/mol
cm3bar/mol hdep -144913.7386 cm3bar/mol
cm3bar/molK sdep -784.2556712 cm3bar/molK
cm3bar/mol pvdep -24896.58764 cm3bar/mol
cm3bar/mol udep -120017.151 cm3bar/mol
cm3bar/mol adep -115259.5504 cm3bar/mol
cm3bar/molK Cvdep 126.99639 cm3bar/molK

-90530.39278 PHASE: Vapor

bar/K -12.54950792 bar/K

DATA CALCULATION

TURATED VAPOUR SATURATED LIQUID

 K Tref 298 K
bar Pref 1 bar

A 1.424
B 1.95E-03
D -1.30E+05
K T1 298 K
K T2 300 K
Δh, IG 8.75E+02
h1dep 0
3.79E+01 J/mol Δh -1.44E+05 -1.44E+04 J/mol

∆s, IG 2.93E+00
s1dep 0.00E+00
1.83E-01 J/MOL ∆s -7.81E+02 -7.81E+01 J/mol

h Diagram for Acethylene

80

70

CRITICAL POINT
60
Saturated vapor

SUPERHEATED Saturated liquid

50
VAPOR "Isotherm 308.3 K (C.P)"
REGION Isotherm 250 K
40
250 dwi
250 vapor
30 "Isotherm 290 K"
290 dwi
TURATED REGION
20 290 vapor
"350 K Superheated"

10

0
-5000 0 5000
olar volumr (cm3/mol)
 Tsat Psat vsat(vap) vsat(liq) hsat(v)
300 1 24774.28735 45.41236098 3.79E+01

Tsat Psat vsat(vap) vsat(liq) hsat(v)

240.00 10.00731784 1713.844024 47.39291948 -3111.121405
245.00 11.81254836 1450.536208 48.46687252 -3056.829478
250.00 13.85012833 1232.54762 49.65639581 -3014.751643
255.00 16.13814968 1050.697578 50.98290395 -2987.028251
260.00 18.6952567 897.8811908 52.47394678 -2976.177493
265.00 21.54067168 768.5449519 54.16575276 -2985.245271
270.00 24.69422916 658.3028403 56.10724043 -3.02E+03
273.15 26.84838045 597.0469824 57.48819119 -3053.021098
275.00 28.1764194 563.6503365 58.36665509 -3079.462426
280.00 32.00844171 481.7453844 61.04322396 -3176.192354
285.00 36.21226803 410.2309341 64.28926593 -3317.753142
290.00 40.81071785 347.0710348 68.35673368 -3518.850288
295.00 45.82754544 290.3476466 73.71101171 -3804.800188
300.00 51.28754068 237.8383815 81.38456497 -4227.787422
301.00 52.43497871 227.5559355 83.39446865 -4338.263288
302.00 53.60139161 217.2439999 85.6484691 -4461.319258
303.00 54.78699298 206.8279416 88.21453104 -4600.008275
304.00 55.99200031 196.1978372 91.19612896 -4758.905413
305.00 57.21664401 185.1761524 94.7643187 -4945.457763
308.30 61.4 113 113 -7164.14508

T(K) P(bar) v(cm3/mol) h(J/mol) s(J/mol) v(cm3/mol)

300 1 24774.29 3.789E+01 1.831E-01 4.54E+01
vapor
PHASE Vapor

T= 250K
P (bar) v (cm3/mol) h (J/mol) s (J/mol) phase
65 48.10715661 -15839.6942 -84.14376237
60 48.23852904 -15837.28053 -84.03776259
55 48.37359171 -15834.38516 -83.92956964
50 48.51254771 -15830.98299 -83.81907549
45 48.65561754 -15827.04682 -83.70616335
40 48.80304122 -15822.54713 -83.59070668
LIQUID
35 48.95508066 -15817.45179 -83.47256798
30 49.11202251 -15811.72574 -83.35159751
25 49.27418135 -15805.3306 -83.22763164
 20 49.44190359 -15798.22425 -83.10049111
15 49.61557191 -15790.36028 -82.96997879
13.85013 49.65639581 -15788.43933 -82.93946501
13.85013 1232.54762 -3014.751643 -31.84471425
10 1822.303085 -2683.414818 -28.21482057
5 3912.975265 -2303.721312 -21.43293833
VAPOR
2.5 8075.079634 -2129.654836 -15.21527405
0.5 41334.80302 -1996.492789 -1.491386499
0.1 207615.5138 -1970.448356 11.95608352

P= 15 bar
T (K) v(cm3/mol) h(j/mol) s(J/mol) phase
300 1485.811559 -714.313783 -24.03580608
290 1416.048441 -1201.072309 -25.68595598
280 1344.462383 -1684.205125 -27.38129853
VAPOR
270 1270.613449 -2164.443691 -29.12778693
260 1193.874603 -2643.11988 -30.93431932
252.5836 1134.556293 -2998.488037 -32.32100313
252.5836 50.32315908 -15549.99141 -82.01345793
250 49.61557191 -15790.36028 -82.96997879 LIQUID
240 47.26983985 -16670.59614 -86.56225339

P= 35 bar
T (K) v(cm3/mol) h(j/mol) s(J/mol)
300 514.1500225 -2099.892937 -34.45537873
295 490.6428067 -2434.263029 -35.57940379
290 465.3765483 -2785.40069 -36.78000131
285 437.6243189 -3161.623003 -38.08879033
 hsat(l) s sat(v) s sat(liq)
-1.44E+04 1.83E-01 -7.81E+01

hsat(l) s sat(v) s sat(liq)

-16668.97731 -29.96597963 -86.4570461
-16236.74528 -30.91479144 -84.7103661
-15788.43933 -31.84471425 -82.939465
-15322.49673 -32.7654105 -81.1397967
-14836.93619 -33.6872509 -79.3055536
-14329.21219 -34.62181129 -77.4292336
-1.38E+04 -35.58260321 -75.5009653
-13445.01589 -36.2086614 -74.2536725
-13232.78955 -36.58622039 -73.5074099
-12633.36176 -37.65426916 -71.4298742
-11988.56735 -38.81690329 -69.2408128
-11284.07108 -40.12003128 -66.8966547
-10494.90966 -41.64240565 -64.3207428
-9569.23709 -43.5470754 -61.3519076
-9358.31529 -44.00355453 -60.6814683
-9134.850357 -44.49772522 -59.9729939
-8895.790985 -45.03929013 -59.216791
-8636.564069 -45.64283137 -58.3982878
-8349.732143 -46.33215689 -57.4937123
-7164.14508 -53.76924754 -53.7692475

h(J/mol) s(J/mol)
-1.440E+04 -7.813E+01
liquid

ISOTHERM LINE
T= 290K
P (bar) v (cm3/mol) h (J/mol) s (J/mol) phase P (bar)
65 62.83914117 -11759.9412 -69.08189058 65
60 63.6888441 -11687.1973 -68.72198783 62
55 64.64906322 -11604.505 -68.32622367 61.4
LIQUID
50 65.75323266 -11509.0636 -67.88472354 60
45 67.05349875 -11396.5675 -67.38235047 51
40.81071785 68.35673368 -11284.0711 -66.89665469 50
40.81071785 347.0710348 -3518.85029 -40.12003128 45
40 362.6906324 -3397.60865 -39.6027489 40
35 465.3765483 -2785.40069 -36.78000131 35
 30 591.3869106 -2303.95443 -34.21340935 30
25 760.6026415 -1894.00793 -31.6424098 25
20 1008.521971 -1530.76864 -28.87999498 20
VAPOR
15 1416.048441 -1201.07231 -25.68595598 13
10 2224.599085 -896.944294 -21.59177785 10
5 4639.90154 -613.124694 -15.16801254 5
4 5846.218009 -558.453645 -13.186974 2.5
0.5 48042.37973 -371.984285 4.527128347 1
0.1 240927.4652 -351.129801 17.95526202 0.5
0.1

ISOBAR LINE

P= 45 bar
T (K) v(cm3/mol) h(j/mol) s(J/mol) phase T (K)
300 334.8491975 -3127.63952 -39.27791625 300
VAPOR
294.2040676 299.0277446 -3752.00735 -41.38043395 295
294.2040676 72.7416435 -10627.7962 -64.75124366 290
290 67.05349875 -11396.5675 -67.38235047 285
285 62.57297975 -12140.0764 -69.96789838 280
270 54.57686605 -13918.5795 -76.37095842 LIQUID 275
260 51.22538573 -14916.6701 -80.13655171
250 48.65561754 -15827.0468 -83.70616335
240 46.5943074 -16671.6609 -87.15323374

P= 61.4 bar
T (K) v(cm3/mol) h(j/mol) s(J/mol)
310 73.85434197 -10146.5479 -63.53598065
308.3 124.5877207 -6635.65103 -52.05413709
295 67.70403622 -10993.6048 -66.38245418
290 63.44092042 -11708.4727 -68.82603734
285 60.19454045 -12345.7511 -71.04240023
280 57.58785738 -12930.3729 -73.11167978
275 55.42163163 -13476.0785 -75.07805593
270 53.57728604 -13991.3309 -76.96879052
265 51.97836764 -14481.7396 -78.80201544
260 50.57264549 -14951.2191 -80.59044568
255 49.32283402 -15402.6042 -82.34334653
250 48.20138112 -15838.0039 -84.06765916
245 47.18735123 -16259.016 -85.76868293
240 46.2644659 -16666.8657 -87.45050736
 T= 308.3 CRITICAL POINT T= 350K
v (cm3/mol) h (J/mol) s (J/mol) P (bar) v (cm3/mol)
92.21978131 -8299.351439 -57.56664199 65 316.3118
1.05E+02 -7.540E+03 -5.501E+01 62 338.4115
124.5877207 -6635.651035 -52.05413709 60 354.3582
181.1787167 -4858.169919 -46.21374796 55 399.2264
296.214899 -3069.074609 -39.70612455 50 452.9314
308.5380581 -2946.663837 -39.21100114 45 518.3987
374.8156279 -2411.628912 -36.92266481 40 600.0277
453.1128767 -1962.917179 -34.79789889 37 659.4863
550.3858163 -1569.587417 -32.7115143 30 844.0793
677.2410201 -1215.478989 -30.57242556 25 1038.827
852.2411402 -890.9334613 -28.28780977 17 1587.739
1112.165354 -589.6519394 -25.73301379 13 2114.981
1806.640144 -198.861919 -21.26352907 12 2301.652
2399.835006 -40.60299772 -18.7286897 7 4034.416
4965.639812 212.7229714 -12.40699183 2.5 11517.61
10093.26411 334.9782946 -6.377494774 2 14427.58
25473.20317 407.0364066 1.396812593 1.7 16995.17
51105.49511 430.8485476 7.211130162 1.4 20663.15
256162.1737 449.8252251 20.63298035

P= 25 bar
v(cm3/mol) h(j/mol) s(J/mol)
811.7492559 -1342.526719 -29.77270459
786.5423205 -1616.986737 -30.69529141
760.6026415 -1894.007934 -31.6424098
733.7987093 -2174.435954 -32.61785593
705.9567627 -2459.425254 -33.62672146
676.8391234 -2750.603779 -34.67608085
T= 350K
h (J/mol) s (J/mol)
-696.626 -33.7956
-520.319 -33.0114
-405.165 -32.4845
-125.32 -31.1476
143.6248 -29.7717
402.4334 -28.3401
651.8647 -26.8308
797.3248 -25.8761
1125.433 -23.4479
1350.859 -21.4673
1697.594 -17.5549
1865.063 -14.9874
1906.356 -14.2392
2109.531 -9.35307
2287.934 -0.44031
2307.509 1.453405
2319.23 2.827628
2330.934 4.464835