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Petrobras - Cenpes - Pdab - TFCC: Summary Report Surface Area
Petrobras - Cenpes - Pdab - TFCC: Summary Report Surface Area
Petrobras - Cenpes - Pdab - TFCC: Summary Report Surface Area
Summary Report
Surface Area
Single point surface area at P/Po = 0.205071556: 3.2350 m²/g
Pore Volume
Single point adsorption total pore volume of pores
less than 544.254 Å diameter at P/Po = 0.963378296: 0.006476 cm³/g
Pore Size
Adsorption average pore width (4V/A by BET): 79.0446 Å
00:39 773.695740
0.059961337 46.375172 0.7630 00:42 773.417908
0.099969318 77.353615 0.8279 00:45 773.773560
0.132950982 102.824585 0.8678 00:48 773.402222
0.160445367 124.116478 0.8930 00:51 773.574707
0.205071556 158.626678 0.9349 00:54 773.518677
0.276511254 213.911850 0.9866 00:56 773.609924
0.348991290 269.911896 1.0267 00:59 773.405823
0.398967370 308.447021 1.0480 01:02 773.113403
0.448589241 346.864868 1.0697 01:05 773.234924
0.460611196 356.041687 1.0618 01:08 772.976624
0.517582567 400.056732 1.0859 01:11 772.933167
0.549054925 424.452667 1.0903 01:14 773.060486
0.616857166 476.795349 1.1283 01:17 772.942871
0.671045141 518.602722 1.1738 01:20 772.828369
0.717902654 554.854797 1.2294 01:23 772.883057
0.795941261 615.175781 1.3756 01:26 772.890930
0.818974048 632.923279 1.4484 01:29 772.824585
0.839642666 648.669006 1.5021 01:31 772.553650
0.858676519 663.493225 1.5779 01:34 772.692871
0.874801930 675.675354 1.6640 01:37 772.375244
0.884971228 683.643677 1.7180 01:40 772.503845
0.903437689 697.700378 1.9092 01:43 772.272827
0.923122863 713.042603 2.2021 01:46 772.424377
0.938116953 724.649597 2.5958 01:49 772.451233
0.947625566 731.942078 2.9872 01:53 772.395874
0.953206532 735.955322 3.3223 01:57 772.083801
0.959038436 740.340210 3.7554 02:01 771.960938
0.963378296 743.797546 4.1866 02:04 772.072144
0.967288825 746.816284 4.7142 02:09 772.071655
0.970625726 749.571167 5.2670 02:13 772.255615
0.973501166 751.663696 5.8390 02:17 772.124084
0.976268432 754.049561 6.5823 02:22 772.379333
0.977660341 754.996826 7.0679 02:26 772.248596
0.979322750 756.317200 7.6425 02:30 772.285950
0.979656736 756.281128 7.7953 02:33 771.985840
0.983629395 759.608521 9.7757 02:40 772.250732
0.988805172 763.415833 11.8678 02:43 772.058899
0.990014992 764.431641 14.3520 02:47 772.141479
0.991356354 765.119141 17.8775 02:50 771.790222
0.992018772 765.708374 21.6345 02:53 771.868835
0.992256110 766.192322 25.3374 02:56 772.171936
0.992927180 766.538086 29.0492 02:58 771.998291
0.993553755 766.929504 32.6769 03:01 771.905396
0.992674400 766.307617 29.3728 03:04 771.962708
0.991990904 765.668518 25.7871 03:07 771.850342
0.987665141 762.282898 16.7094 03:14 771.802979
0.980841856 756.829346 11.3828 03:26 771.612000
0.975997462 752.877258 8.7567 03:35 771.392639
0.967392854 746.114197 6.0099 03:43 771.262878
0.957455976 738.734497 4.2994 03:51 771.559753
0.945458933 729.351685 3.1800 03:56 771.426086
PETROBRAS - CENPES - PDAB - TFCC
TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 3
30
25
Quantity Adsorbed (cm³/g STP)
20
15
10
0
0.05 0.1 0.5 1
Relative Pressure (P/Po)
PETROBRAS - CENPES - PDAB - TFCC
TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 5
t-Plot Report
Micropore Volume: 0.000537 cm³/g
Micropore Area: 1.2587 m²/g
External Surface Area: 2.0184 m²/g
Slope: 0.130487 ± 0.008575 cm³/g·Å STP
Y-Intercept: 0.347419 ± 0.036723 cm³/g STP
Correlation Coefficient: 0.989376
Surface Area Correction Factor: 1.000
Density Conversion Factor: 0.0015468
Total Surface Area (BET): 3.2771 m²/g
Thickness Range: 3.2000 Å to 5.5000 Å
Thickness Equation: Harkins and Jura
t = [ 13.99 / ( 0.034 - log(P/Po) ) ] ^ 0.5
t-Plot
Harkins and Jura
AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014 Not Fitted Points
1.4
1.2
1.0
Quantity Adsorbed (cm³/g STP)
0.8
0.6
0.4
0.2
0.0
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0
Thickness (Å)
PETROBRAS - CENPES - PDAB - TFCC
TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 8
-5 -2
603.8 - 540.9 568.8 0.000875 1.3931 x 10 1.8341 x 10 0.062
-5 -2
540.9 - 485.2 509.9 0.000712 1.2772 x 10 1.5073 x 10 0.117
-5 -2
485.2 - 426.4 451.8 0.000711 1.2096 x 10 1.2677 x 10 0.180
-5 -2
426.4 - 382.2 401.8 0.000549 1.2433 x 10 1.1563 x 10 0.235
-5 -3
382.2 - 325.2 348.9 0.000627 1.0992 x 10 8.9326 x 10 0.307
-6 -3
325.2 - 263.5 287.6 0.000606 9.8344 x 10 6.6403 x 10 0.391
-6 -3
263.5 - 211.1 231.2 0.000408 7.7906 x 10 4.2398 x 10 0.462
-6 -3
211.1 - 178.0 191.6 0.000245 7.3811 x 10 3.2989 x 10 0.513
-6 -3
178.0 - 163.8 170.3 0.000040 2.8007 x 10 1.1016 x 10 0.522
-6 -3
163.8 - 145.4 153.4 0.000074 4.0164 x 10 1.4283 x 10 0.542
-6 -4
145.4 - 128.3 135.7 0.000047 2.7266 x 10 8.5809 x 10 0.555
-7 -5
128.3 - 113.7 120.0 0.000003 2.0609 x 10 5.7338 x 10 0.556
-6 -4
113.7 - 100.7 106.3 0.000046 3.5569 x 10 8.7672 x 10 0.574
-7 -5
100.7 - 71.9 81.3 0.000010 3.4273 x 10 6.7480 x 10 0.578
-7 -5
71.9 - 20.8 22.3 0.000017 3.3805 x 10 3.2096 x 10 0.609
PETROBRAS - CENPES - PDAB - TFCC
TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 9
-5
1.2 x 10
-5
1.0 x 10
Pore Volume (cm³/g·Å)
-6
8 x 10
-6
6 x 10
-6
4 x 10
-6
2 x 10
-6
0 x 10
50 100 500
Pore Diameter (Å)
PETROBRAS - CENPES - PDAB - TFCC
TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 10
0.016
0.014
dV/dlog(D) Pore Volume (cm³/g·Å)
0.012
0.010
0.008
0.006
0.004
0.002
0.000
50 100 500
Pore Diameter (Å)
PETROBRAS - CENPES - PDAB - TFCC
TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 11
-5 -2
596.6 - 458.6 509.4 0.002777 2.0122 x 10 2.4304 x 10 0.218
-5 -2
458.6 - 358.4 396.1 0.001790 1.7875 x 10 1.6728 x 10 0.399
-5 -2
358.4 - 223.0 260.1 0.002291 1.6914 x 10 1.1114 x 10 0.751
-5 -3
223.0 - 177.3 194.9 0.000570 1.2484 x 10 5.7284 x 10 0.868
-6 -3
177.3 - 138.0 152.8 0.000342 8.7178 x 10 3.1485 x 10 0.958
-6 -3
138.0 - 108.2 119.5 0.000205 6.8461 x 10 1.9309 x 10 1.026
-6 -4
108.2 - 85.7 94.4 0.000083 3.6807 x 10 8.1789 x 10 1.061
PETROBRAS - CENPES - PDAB - TFCC
TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 12
-5
2.0 x 10
-5
1.5 x 10
Pore Volume (cm³/g·Å)
-5
1.0 x 10
-6
5 x 10
-6
0 x 10
50 100 500
Pore Diameter (Å)
PETROBRAS - CENPES - PDAB - TFCC
TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 13
0.020
dV/dlog(D) Pore Volume (cm³/g·Å)
0.015
0.010
0.005
0.000
50 100 500
Pore Diameter (Å)