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Pradeep 2007
Pradeep 2007
Pradeep 2007
Abstract
Environmental degradation and depleting oil reserves are matters of great concern round the
globe. Developing countries like India depend heavily on oil import. Diesel being the main transport
fuel in India, finding a suitable alternative to diesel is an urgent need. Jatropha based bio-diesel
(JBD) is a non-edible, renewable fuel suitable for diesel engines and is receiving increasing attention
in India because of its potential to generate large-scale employment and relatively low environmental
degradation. Diesel engines running on JBD are found to emit higher oxides of nitrogen, NOx. HOT
EGR, a low cost technique of exhaust gas recirculation, is effectively used in this work to overcome
this environmental penalty. Practical problems faced while using a COOLED EGR system are
avoided with HOT EGR. Results indicated higher nitric oxide (NO) emissions when a single cylinder
diesel engine was fuelled with JBD, without EGR. NO emissions were reduced when the engine was
operated under HOT EGR levels of 5–25%. However, EGR level was optimized as 15% based on
adequate reduction in NO emissions, minimum possible smoke, CO, HC emissions and reasonable
brake thermal efficiency. Smoke emissions of JBD in the higher load region were lower than diesel,
irrespective of the EGR levels. However, smoke emission was higher in the lower load region. CO
and HC emissions were found to be lower for JBD irrespective of EGR levels. Combustion
parameters were found to be comparable for both fuels.
r 2006 Elsevier Ltd. All rights reserved.
Corresponding author.
E-mail addresses: rpsharmaiitm@gmail.com, rpsharma@iitm.ac.in (R.P. Sharma).
0960-1481/$ - see front matter r 2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.renene.2006.04.017
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1. Introduction
Use of efficient diesel engines need encouragement in the future since they consume less
fuel and significantly reduce potent green house gases like carbon dioxide. Ever increasing
diesel consumption, large outflow of foreign exchange and concern for environment have
prompted developing countries like India to search for a suitable environmental friendly
alternative to diesel fuel. The country has to simultaneously address the issues of energy
insecurity, increasing oil prices and large-scale unemployment. It is in this context that
development and use of bio-diesel from Straight vegetable oils (SVO) like Jatropha Curcas
may be looked at.
Straight vegetable oils even though projected as an engine friendly fuel by many
researchers have recently lost its attraction. Being highly viscous and less volatile, SVO’s
will result in poor spray atomization, vaporization, and pose serious threat to the engine
health in the long run. More over many SVO’s are edible oils whose continuous supply
cannot be ensured in India [1–4].
The ‘Jatropha Curcas’ plant can grow in waste lands and consumes less water.
Its cultivation, seed collection, oil extraction, and bio-diesel production can generate
large-scale employment.
The by-products during bio-diesel production can be used in soap and fertilizer
industry.
Vegetable oils are triglycerides and as per ASTM, bio-diesels are mono alkyl esters of
long chain fatty acids derived from renewable fats such as oils and animal fats for use in
diesel engines. Transesterification is an effective process of bio-diesel production in which
straight vegetable oils are treated with methanol in the presence of catalyst. Catalysts like
sodium or potassium hydroxide are generally used [1–5]. Jatropha Curcas oil (SVO) is
chemically modified into bio-diesel through a transesterification process. Bio-diesel thus
obtained has properties close to diesel fuel and is found to be engine friendly [1,4].
In spite of several advantages, Jatropha based bio-diesel (JBD) is found to emit higher
NOx compared to diesel fuel. Higher NOx level in the JBD exhaust as reported by several
researchers [1,2], is a serious issue to be addressed before its wide spread implementation
[1,2]. The authors also found higher NO emissions when the JBD was tested in the
laboratory. Higher NOx emission from JBD is probably due to their higher bulk modulus
and boiling point. Inherent oxygen in its structure can also aggravate the situation [1,6].
Bio-diesel from Jatropha oil is free from sulfur and still exhibits excellent lubricity,
which is an indication of the amount of wear that occurs between two metal parts
covered with the fuel as they come in contact with each other [1].
It is a much safer fuel than diesel because of its higher flash and fire point.
Presence of oxygen in the structure of JBD reduces the energy content of fuel and
significantly contributes to NOx emissions. However, presence of oxygen facilitates
complete combustion and reduces CO and HC emissions.
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Even though some cetane improving additives are capable of reducing NOx, the amount
of reduction is reported to be inadequate. Moreover, most of the additives are expensive
and can promote auto-oxidation in bio-diesel. Extensive studies have revealed that NOx
reduction by altering fuel properties is highly limited [6–8].
Retarded injection is an effective method employed in diesel engines for NOx control.
However, this method leads to increased fuel consumption, reduced power, increased HC
and excess smoke. Water injection on the other hand is prone to corrosion. In addition, it
adds to the weight of the engine system for maintaining a water storage tank. It is also
difficult to retain water at a desired value during cold climate.
Exhaust gas recirculation is an effective method for NOx control. The exhaust gases
mainly consist of inert carbon dioxide, nitrogen and possess high specific heat. When
recirculated to engine inlet, it can reduce oxygen concentration and act as a heat sink. This
process reduces oxygen concentration and peak combustion temperature, which results in
reduced NOx. EGR is not free from demerits. It can significantly increase smoke, fuel
consumption and reduce thermal efficiency unless suitably optimized.
Many researchers have used EGR after cooling to room temperature (COOLED EGR).
This method even though effective, is expensive and difficult to implement. Exhaust gases
being at high temperature, a properly designed gas cooler is necessary for cooling exhaust
to room temperature. Many researchers have reported serious difficulties in maintaining
Table 1
Properties of diesel and Jatropha based bio-diesel
such a system with respect to its cooling capacity, weight etc., especially in higher load
regions [9]. As a cost effective technique of exhaust gas recirculation, HOT EGR is
effectively used in this work to reduce NO emissions. Practical difficulties faced in a
COOLED EGR system viz. corrosion of gas cooler, cooling capacity at higher load, extra
weight are avoided with HOT EGR.
Dilution effect refers to the reduction in oxygen supplied to the engine due to application
of EGR where as chemical effect is due to the participation of carbon dioxide, (present in
the EGR) in the combustion process. Thermal effect refers to the increase in inlet charge
thermal capacity due to the recirculation of exhaust gas [10].
2. Experimentation
The specifications of the engine used are given in Table 2 and the experimental set up
used is shown in Fig. 1.
Exhaust gases were tapped from exhaust pipe and connected to inlet airflow passage. An
EGR control valve was provided in this pipe for EGR control (Fig. 2). The exhaust gases
were regulated by this valve and directly send to the inlet manifold without a gas cooler.
Sufficient distance for thorough mixing of fresh air and exhaust gases were ensured.
Temperature of this exhaust gas-fresh air mixture was measured just before its entry into
the combustion chamber using a K type thermocouple (refer Table 3).
EGR amount was determined using the expression
Mass of air admitted without EGR Mass of air admitted with EGR
% EGR ¼ .
Mass of air admitted without EGR
2.2. Instrumentation
Table 2
Engine specification
16
7
5 6
Exhaust 18 17
10 11 12
gas
8 9
13 14 15
1 2
3 4
Fig. 1. Experimental setup. (1) Air flow meter; (2) air vessel; (3) engine; (4) dynamometer; (5) smoke meter; (6)
CO, HC analyser; (7) NO analyser; (8) EGR valve; (9) thermocouples (inlet/exhaust); (10) exhaust temperature
indicator; (11) intake temperature indicator ; (12) inlet cooling water temperature indicator ; (13) outlet cooling
water temp. indicator; (14) stopwatch; (15) speed indicator; (16) data acquisition system; (17) fuel tank; and (18)
burette.
Exhaust Gas
E
N
EGR Valve G
I
N
Air flow E
and connected to a single fuel pump with change over provision. An AVL piezoelectric
pressure transducer in conjunction with a KISTLER charge amplifier and data acquisition
system were used to measure cylinder pressure. Before mounting on to the cylinder head,
the transducer–charge amplifier combination was statically calibrated using a dead weight
pressure tester. An optical encoder using photo emitter and detector was used to detect
TDC. A non-dispersive infrared analyzer (NDIR), HORIBA-MEXA-324 FB was used for
the measurement of CO and HC. CO was measured as percentage volume and HC was
measured as n-hexane equivalent, ppm. Smoke was measured as percentage opacity using
an AVL 437 Opacimeter. A chemiluminescent analyzer (Rosemount analytical—951 A)
was used for NO measurement. A turbine type air flow meter coupled to a counter was
used to measure the airflow rate. Temperatures were measured using K-type thermo-
couples (refer Table 3).
All the experiments were conducted at a rated speed of 1500 rpm. Injection timing was
optimized w.r.t. brake thermal efficiency (BTE) for both diesel and JBD. An optimized
injection timing of 27 and 28 degree bTDC (static) was used for diesel and bio-diesel
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Table 3
Inlet charge temperatures at various EGR levels
Diesel Bio-diesel
5 38 38
10 40 41
15 45 46
20 53 51
25 61 56
respectively. The cooling water outlet temperature was maintained at 70 1C during all the
experiments. Since most of the modern diesel engines use EGR, JBD performance under
various EGR, levels were compared with corresponding diesel performance also.
3.1. Performance
WITHOUT EGR
35
30
25
Thermal efficiency (%)
20
15
10
diesel bio-diesel
5
0
0 1 2 3 4
Brake power (kW)
35
30
25
Thermal efficiency (%)
20
15
Diesel with 5% EGR
10 Bio-diesel with 5% EGR
Diesel without EGR
5 Bio-diesel wihout EGR
0
0 1 2 3 4
Brake Power (kW)
3.2. Emission
35
30
20
15
Diesel with 15% EGR
10 Bio-diesel with 15% EGR
Diesel without EGR
5 Bio-diesel wihout EGR
0
0 1 2 3 4
Brake power (kW)
13
12
BSEC (MJ/kW-hr)
11
Diesel JBD
10
0 5 10 15 20 25
% EGR
higher smoke emissions were observed for JBD up to 60% load. Smoke emissions at no
load condition are also shown in Fig. 7. Bio-diesel with slightly higher viscosity and lower
volatility can result in poor mixture formation in lower load region were temperatures are
comparatively low. Water content if not removed properly during bio-diesel production
can also result in higher smoke emission especially in the lower load region [2,3]. Smoke
opacity values higher than 60% were observed for EGR levels of 20 and 25% for both
fuels. However, it was still lower for bio-diesel at higher loads. Since opacity values
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100
50
40
30
20
10
0
0 5 10 15 20 25
% EGR
higher than 60% were unacceptable, optimum EGR rate with respect to smoke was found
to be 15%.
2.0
1.5
CO (% Vol)
1.0
Diesel
JBD
0.5
0.0
0 5 10 15 20 25
% EGR
100
Diesel
JBD
80
60
HC (ppm)
40
20
0
0 5 10 15 20 25
% EGR
to higher bulk modulus of bio-diesel resulting in a dynamic injection advance apart from
static injection advance provided for optimum efficiency. Excess oxygen (10%) present in
the bio-diesel would have aggravated the situation. At higher loads, NO levels were higher
by 5–8% compared to diesel.
Figs. 11–13 indicate the variation of NO emissions with EGR rate for the entire
load range. With 5% EGR, the NO level came down to 1105 ppm for bio-diesel and
900 ppm for diesel, at full load operation. However, for JBD, NO levels were found to
be increasing for load range of 0-40% under 5 and 10% EGR operation. These values
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WITHOUT EGR
1500
1300 Diesel
JBD
1100
NO (ppm)
900
700
500
300
100
0 1 2 3 4
Brake power (kW)
1400
1200
NO (ppm)
1000
800
600
0 5 10 15
% EGR
were found to be higher compared to both diesel and bio-diesel, without EGR. This is
probably due to the increased inlet charge temperature because of HOT EGR [10,11].
Dynamic injection advance of bio-diesel fuel can also assist the NO formation. However,
at higher loads NO levels reduced significantly presumably due to the dominant dilution
effect of EGR.
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700
600
NO (ppm)
500
400
300
0 5 10 15
% EGR
250
200
NO (ppm)
150
100
50
0
0 5 10 15
% EGR
With 10% EGR, NO levels were 885 ppm for diesel and 910 ppm for bio-diesel. Since
many modern diesel vehicles run on EGR, experiments were continued for higher levels of
EGR to reduce NO levels significantly. With 15% EGR, NO levels were found to be
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772 ppm for bio-diesel and 780 ppm for diesel at full load. NO emission from bio-diesel at
all loads, for this EGR rate, was lower compared to diesel under no EGR condition also.
Even though 20 and 25% EGR were able to reduce NO by a large amount, reduction in
BTE and large increase in smoke, CO and HC emissions were observed.
60
50
Cylinder Pressure (bar)
40
30
20
Diesel without
EGR
10 Bio-diesel without
EGR
0
340 350 360 370 380 390
Crank angle (deg.)
60
50
30
20
Bio-diesel without
EGR
10 Bio-diesel with
15% EGR
0
340 350 360 370 380 390
Crank angle (deg.)
60
Bio-diesel
50
without EGR
Diesel without
Heat release rate (J / deg.)
40
EGR
30
20
10
-10
340 350 360 370
Crank angle (deg.)
Fig. 16. Comparison of rate of heat release (HRR) (full load, no EGR).
comparable for both fuels without and with optimized EGR of 15% as shown in Figs. 18
and 19.
60
Bio-diesel
without
50 EGR
Bio-diesel
40 with 15%
Heat release rate (J / deg.) EGR
30
20
10
-10
340 350 360 370
Crank angle (deg.)
600
500
Cumulative heat release (J)
400
300
Bio-diesel
200
without EGR
Diesel without
100
EGR
-100
340 380 420 460 500
Crank angle (deg.)
Peak values at full load were found to be 5.8 bar/deg. for diesel and 6.2 bar/deg. for
JBD. With smoke limited EGR of 15%, the rate of pressure rise decreased slightly to
5.7 bar/deg probably due to reduced peak heat release rates. Comparable rate of pressure
rise obtained is indicative of stable and noise free operation of compression ignition
engines with JBD.
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700
300
Bio-diesel
without EGR
Bio-diesel with
100 15% EGR
-100
340 380 420 460 500
Crank angle (deg.)
Fig. 19. Effect of 15% EGR on cum. heat release (full load).
6
Rate of pressure rise (bar / deg.)
Diesel without
EGR
Bio-diesel
4
without EGR
-2
Crank angle (deg.)
Bio-diesel
without EGR
6
Bio-diesel with
Rate of pressure rise (bar / deg.) 15% EGR
-2
Crank angle (deg.)
Fig. 21. Effect of 15% EGR on rate of pressure rise (full load).
85
Diesel
without
75
70
have enhanced flame velocity that resulted in small reduction in the combustion duration
[14]. However, Combustion duration for JBD with optimized value of 15% EGR,
increased by one degree than no EGR condition, probably due to the presence of exhaust
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Table 4
Comparison of full load values for diesel and Jatropha based bio-diesel
gases in combustion chamber resulting in weak combustion. For JBD, the effect of excess
oxygen content might have been nullified under EGR operation (Table 4).
4. Conclusions
Following are our main conclusions based on the experimental work conducted with
diesel and Jatropha based bio-diesel with and without HOT EGR.
BTE with JBD was found to be comparable with diesel, at all loads with and without
EGR.
NO emission from JBD was found to be comparatively higher than the diesel fuel.
HOT EGR of 15% effectively reduced NO emission without much adverse effects on
the performance, smoke and other emissions.
Higher EGR of 20 and 25% resulted in inferior performance and heavy smoke.
Because of the increased inlet charge temperature due to HOT EGR and dynamic
injection advance, 5 and 10% EGR levels were not sufficient to reduce NO emission at
all loads for JBD. However, these EGR levels significantly reduced NO at peak loads.
About 15% of EGR, on JBD was found to be effective in reducing NO emission to
values lower than that of diesel, without EGR, at all loads.
Full load NO emission from JBD with 15% EGR, was found to be lower than that of
corresponding diesel NO emission.
Inherent oxygen present in the bio-diesel structure is believed to have played a
significant role in compensating for oxygen deficient operation under EGR.
JBD was found to be environmental friendly as far as CO and HC were considered.
Smoke emission from JBD was found to be lower than diesel at peak loads with and
without EGR.
Smoke emissions were found to be higher for JBD in the lower load region because of
slightly higher viscosity, low volatility and probably due to the presence of water
content.
Analysis of combustion parameters have also indicated comparable heat release rates
cylinder pressures, cumulative heat release, combustion duration and noise free
operation with and without EGR.
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Acknowledgements
The authors thank Prof. A Ramesh and Prof. Pramod S Mehta of IC Engines
Laboratory, IIT Madras, India for their enthusiastic support and help during this work.
Authors thank Mr. K. Chandrasekhar, Jatropha consultant, Jatropha Oil Seed
Development & Research, Hyderabad, India for the support and help during this work.
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Further reading
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