Technical Bulletin 14v 2-Pumping Non-Newtonian Slurries

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Weir Minerals Division Excellent

Minerals
Solutions

Technical
Bulletin
Bulletin #14 - Version 2 August 2009

Pumping Non-Newtonian Slurries

Introduction
Many slurries in the mineral processing industries can be
described as being non-Newtonian.
If a fluid is in motion, shear stresses are developed when particles
of the fluid move relative to each other. For successive layers of
flow over a flat plate, the velocity of the fluid (u) will vary from
layer to layer as distance from the plate (y) increases, see FIGURE
1. Newton’s law of viscosity relates shear stress () to the velocity

FIGURE 1 - Variation in fluid velocity with distance


from a flat plate

gradient, also known as the rate of shear strain, or simply the rate
of shear (du/dy), using a constant of proportionality known as
the dynamic viscosity () of the fluid, as follows:
 = • du/dy
Fluids which do not obey Newton’s law of viscosity are known as
non-Newtonian. The relationship of shear stress to rate of shear
for non-Newtonian fluids can be usually represented by one of
the curves shown in FIGURE 2.
2 Weir Minerals Technical Bulletin - #14 Pumping Non-Newtonian Slurries

Bingham Plastic behaviour is Newtonian fluids. Many of these presents some empirical Rheogram, or plot of  versus
characterised by its initial shear slurries can be described by the relationships relevant to du/dy, the y intercept can be
or yield stress (0). This means Bingham Plastic model. Even applying centrifugal slurry determined through
that the fluid will not flow slurries with different pumps to a Bingham Plastic extrapolation and 0 the yield
unless a stress greater than the rheological characteristics can slurry. It should be noted that if stress determined. Rotary
yield is appied. The slope of the sometimes be approximated by slurry behaves as a Newtonian viscometers can also be used
linear flow curve is called the the Bingham Plastic model over fluid, it may be treated as for with vane or “paddle” type
coefficient of rigidity (). a limited range of shear rates. water except for its particular sensors to obtain the yield stress
Bingham Plastic behaviour is TABLE 1 gives specific examples density and viscosity. without the need for
described by the equation: of some Bingham Plastic extrapolation.
slurries.
Measurement of viscosity
 = • du/dy Apparent viscosity
The viscosity of a fluid (or more
This bulletin outlines some basic
Centrifugal slurry pumps & correctly shear stress for rate of The difference between
rheological theory, describes
positive displacement pumps shear) cannot be measured apparent viscosity (a), which is
(shear stress) / (rate of shear)
are often used to handle directly, but can be calculated viscosity at a given rate of shear
measurement, and in addition
slurries, which behave as non- from directly measurable assuming Newtonian behaviour,
quantities. Apparatus suitable and the coefficient of rigidity
for such measurements is (), should be emphasised. This
FIGURE 2 - Characteristics of non-Newtonian slurries generally known as a difference is illustrated in
viscometer. Many types of FIGURE 4. A Bingham Plastic
viscometers are available. A slurry will have an infinite
typical rotary viscometer is number of apparent viscosities,
illustrated in FIGURE 3. This depending on the particular
viscometer shows a concentric rate of shear considered.
cylinder (bob) within another Accordingly measurements
concentric cylinder (cup). The should never be taken at a
gap between the two cylinders single rate of shear, and
is filled with slurry and the Newtonian behaviour assumed,
torque required to achieve as the results may be
constant relative velocity misleading. Apparent viscosity
between the two cylinders is will only approach the
measured at a number of coefficient of rigidity at high
speeds. From the torque, rates of shear.
geometry (diameter, surface
area and gap) and speed, the
Slump Plate Testing
shear stress (Nt/m2 or Pascal) The slump plate test provides a
and, the rate of shear ((m/sec)/ useful indication of slurry
TABLE 1 - Examples of Bingham Plastic Slurries sec or sec-1) can be plotted, as rheology. The test itself is very
shown in FIGURE 4 for data simple. The plate has a number
Cw 0  obtained from testing of a red of graduated rings marked on it.
Particle
Slurry mud slurry. From this A small cylinder is placed in the
(%) size (m) (Pa) (Pa s)

Fine Coal 49 50% - 40 1 0.005


Fine Coal 68 50% - 40 8.3 0.04 FIGURE 3 - Typical diagram of a viscometer
Fly Ash 64 50% - 70 8.84 1.304
Kaolin Clay 32 50% - 0.8 20 0.03
Kaolin (+ Sod. Silicate) 53 50% - 0.8 6 0.015
Kimberlite Tails 37 50% - 15 11.6 0.006
Kimberlite Tails 69 28% - 300 132 0.20
Phosphate Tails 37 85% - 10 28.5 0.014
Copper Concentrate 48 50% - 35 19 0.018
Copper Concentrate 64 0.45 0.031
Zinc Concentrate 75 50% - 20 12 0.031
Uranium Tails 58 50% - 38 4 0.015
Gold Tails 50 50% - 50 5 0.087
Minerals Sands Tails 55 50% - 160 30 0.25
Coal Tails 31 50% - 70 2 0.06
Red Mud 39 5% - 150 23 0.03
Red Mud 50 50% - 30 33.2 0.304
Red Mud 53 50% - 3 80 0.08
http://www.weirminerals.com Weir Minerals Technical Bulletin - #14 3

Where:
V = pipeline velocity (m/s) displacement pumps, the clear
FIGURE 4 - Behaviour of a red mud slurry calculated D = Inside pipe diameter (m) water performance of a
from rotary viscometer measurements centrifugal pump is affected
 = Coefficient of rigidity (Pa• s)
when handling non-Newtonian
slurry as shown in FIGURE 7. At
or in terms of head loss (H): low flows (generally less than
20% of the best efficiency point
flow) the developed head on
Where:
slurry may be reduced
g = gravitational cojnstant (m/s2)
compared to the water head.
Experience suggests that this
Alternatively, the pressure drop only occurs for small pumps
for large diameter pipelines may (less than 150mm inlet size).
be scaled up directly from small This can prevent pumps from
bore tube viscometer results. achieving the full system
The wall shear stress (PD/4L) performance. Field and lab test
can be determined from the work has shown that the
rheogram, with the rate of shear Warman froth pump has largely
given by 8V/D. overcame this particular
Pipe friction loss with problem with negligible effects
turbulent flow on head with yield stresses up
to 200Pa.
The rheological properties of
Bingham Plastic slurries do not Pump efficiency on slurry may
greatly influence the pipe be reduced compared with the
centre of the plate concentric to laminar to turbulent flow. water efficiency over the
the rings. The cylinder is filled Experimentally obtained critical friction loss in fully developed
turbulent flow. Turbulence complete flow range. This is not
with slurry and then removed. velocities for a wide range of restricted to small pumps. It is
The ring to which the slurry Bingham Plastic slurries are effectively destroys the yield
structure, causing the slurry to due to the increased apparent
slumps indicates the yield shear plotted against SQR(0/m) in viscosity. Performance has been
stress of the slurry. Slump plate FIGURE 5. The following behave as a Newtonian fluid
with viscosity roughly equal to found to correlate well with a
reading depends of particle relationship can be established: modified version of the pump
sizing and slurry concentration. the coefficient of rigidity. At
high velocities the pressure drop Reynolds Number (Rep) as
The greater the slump the lower follows:
the yield shear stress. This is similar to that for Newtonian
slump plate testing is typically Where :
fluids (FIGURE 6). For many
used to indicate whether a commercial slurries the friction
t0 = yield stress (Pa)
slurry is likely to present loss, expresses in equivalent Where:
m = slurry density (kg/m3)
difficulty in pumping and at units of head, can be taken to be  = pump rotational speed (1/s)
what concentration. 1.1 times the friction loss for Di = Impeller diameter (m)
This relationship allows water. This should give a
System Characteristics calculation of the critical conservative estimate of friction When Rep is less than 1 x 106,
velocity with only the Bingham loss. efficiency is generally
To apply a Warman centrifugal
®
Plastic yield stress and the slurry significantly reduced.
slurry pump or GEHO® positive Centrifugal Pump
density. Using the critical
displacement pump handling a Performance
velocity, it can be determined if Suction Performance
Bingham Plastic slurry, accurate
flow is in the laminar or the
calculation of the pipe friction Unlike Weir Geho positive When pumping Bingham Plastic
partly or full developed
loss is required. It should be
turbulent regime.
noted that S.I. units are
assumed throughout this Operation in laminar flow, at or FIGURE 5 - Critical pipe velocity for Bingham Plastic
bulletin. near the critical or transition Slurries
velocity, can often minimize the
The pipe friction loss will
chance of settling while keeping
depend on whether the flow is
the friction lower than operation
in the laminar or turbulent
in turbulent flow.
regime. It is generally preferable
to operate in the laminar Pipe friction loss with
regime, unless there is laminar flow
possibility of solids settlement
(refer to the Weir Minerals Slurry The laminar pipe friction loss
Pumping Manual, or enquire at can be determined most easily
your nearest Weir Minerals from the Buckingham equation,
office, for calculation of limiting neglecting 4th order terms. The
settling pipeline velocity). pressure drop (P) per metre
length (L) of pipe is given by:
The critical velocity (Vc in m/s) is
defined as the pipe velocity at
which transition occurs from
Weir Minerals
Technical Bulletin
slurries, centrifugal pump
FIGURE 6 - Pipe friction characteristics for a uranium ore suction performance is likely to
slurry (compared with water) be affected as suggested by
some studies. Experimental data
show that NPSH required by the
Contact details
pump increases as compared to
the NPSHr on water. The test
Head Office results obtained for smaller size
Weir Minerals Division pumps handling materials as
2701 S Stoughton Rd diverse as peat and magnetite
Madison, Wisconsin USA slurries can be expressed
53029 approximately as follows:
Tel: +1 608 221 2261
Fax: +1 608 661 8734
www.weirminerals.com
Where:
Regional Headquarters c1 = Average inlet velocity (m/s)
w1 = (C12+u12)0.5, relative inlet veloc.
Weir Minerals Africa u1 = Impeller inlet peripheral veloc.
5 Clarke Street South, Alrode,
Johannesburg, RSA
Tel: +27 11 617 0700 Conclusion
Fax:+27 11 617 0791
Pump users often require
Weir Minerals Africa FIGURE 7 - Performance of special froth pump in centrifugal slurry pumps to
31 Isando Road, Isando
A
A comparison with standard conventional centrifugal A
handle slurries which behave as
Johannesburg, RSA slurry pump non-Newtonian fluids. To
Tel: +27 11 929 2600 successfully apply a centrifugal
Fax: +27 11 929 2950 slurry pump, both system and
the pump performance
Branches
characteristics must be adjusted
to take into account the slurry
Botswana, Francistown
Tel: +267 244 2016 rheology.
Ghana, Accra Weir Mineral Division is
Tel: +233 21 785 105
continuing to research the
Namibia, Swakopmund
influence of slurry rheology on
Tel: +264 64 40 4264
South Africa, Cape Town system and pump performance.
Tel: +27 21 557 5753 This will result in improved
South Africa, Kimberley QU1 = open flow inducer froth impeller performance and reduced
Tel: +27 53 841 0274 STD = conventional slurry pump impeller customer total ownership costs.
South Africa, Mokopane
Tel: +27 13 230 9022 Submitted by Wen-Jie Liu and Kevin
Burgess; Warman Pump Technology
South Africa, Phalaborwa Centre, Artarmon, Australia and Aleks
Tel: +27 15 781 5560/0481 Roudnev and Michael Bootle; Weir
South Africa, Richards Bay Minerals North America, Madison
Tel: +27 35 751 1636 Wisconsin, U.S.A.
South Africa, Rustenburg
Tel: +27 14 596 7739/9400
South Africa, Steelpoort
Tel: +27 13 230 9022
South Africa, Wadeville
Tel: +27 11 383 8700
South Africa, Witbank
Tel: +27 13 655 7720/30
Tanzania, Mwanza
Tel: +254 71 090 0013
UAE, Dubai
Tel: +9714 2996 808
Zambia, Kitwe
Tel:+260 21 221 7743
Zimbabwe, Bulawayo
Tel: +263 9 78840

Web site address:


www.weirminerals.com

Portuguese web site:


http://pt.weirminerals.com

French web site:


http://fr.weirminerals.com Copyright © 2004, 2009, Weir Minerals Division All rights reserved

WARMAN is a registered trademark of Weir Minerals Australia Ltd and Weir Group African IP Ltd; CAVEX and MULTIFLO are registered
trademarks of Weir Minerals Australia Ltd; LEWIS PUMPS is a registered trademark of Envirotech PumpSystems Inc; GEHO and
BEGEMANN PUMPS are registered trademarks of Weir Minerals Netherlands bv; FLOWAY is a registered trademark of Weir Floway Inc.;
VULCO is a registered trademark of Vulco SA; ISOGATE is a registered trademark of Weir do Brasil Ltda. AH and WRT are pending
trademarks of Weir Minerals Australia Ltd. ENVIROTECH is a registered trademark of Weir Minerals Africa (Pty) Ltd
The method of retrofitting a kit of parts comprising a new liner, expeller seal, impeller and front liner is subject to a pending patent
application in African Countries.

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