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Zero Point Energy Scientific Article 1
Zero Point Energy Scientific Article 1
Zero Point Energy Scientific Article 1
Hydrogen negative ion density measurement by laser photodetachment and the effect of H
recombination on the walls
Physics of Plasmas 28, 023505 (2021); https://doi.org/10.1063/5.0027123
© 2021 Author(s).
Physics of Plasmas ARTICLE scitation.org/journal/php
AFFILIATIONS
Department of Mathematics, Burdwan University, Golapbag, Burdwan 713 104, West Bengal, India
a)
Author to whom correspondence should be addressed: arijit98@yahoo.com
ABSTRACT
The scattering of slow electrons from the hydrogen atom embedded in non-ideal classical plasma has been investigated by using the effective
range theory. A pseudopotential, which has been derived from a solution of Bogolyubov’s hierarchy equations, is used to represent the inter-
actions among the charged particles in plasma. A detailed study is made on the effects of non-ideality of plasma on the scattering dynamics
for a wide range of the non-ideality parameter. In particular, the zero-energy resonance phenomenon has been studied in detail by evaluating
the singlet scattering length. It is found that the scattering length suffers significant changes when the non-ideality parameter approaches its
critical value.
Published under license by AIP Publishing. https://doi.org/10.1063/5.0039727
where f ðcÞ is known as the correction function. The values of f ðcÞ are from hydrogen atoms, the cotangent of the S wave phase shift d0 can
known for a discrete set of values of c within 0–4.5.6 The above pseu- be expressed in powers of the incident electron momentum ki as47,48
dopotential describes appropriately the screened interaction potential
1
in classical NIPs for 0 c 4. Note that it reduces to the ki cotðd0 Þ ¼ þ r0 ð2 þ k2i Þ þ oðk4i Þ þ ; (4)
Debye–H€ uckel potential in the form of Eq. (1) for the weak limit of c. 2
So far, a good number of studies have been made on classical NIPs by where is connected with the difference in the ground state energy of
using the above pseudopotential.7–19 It is worthy to mention here that H (EH) and ground state energy of H (EH ) as
the pseudopotential (2) describes the particle interactions in a non- pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
degenerate classical plasma and does not include the effects of quan- ¼ 2ðEH EH Þ; (5)
tum degeneracy. In order to include the quantum effects of diffraction and r0 is constant having the dimension of length, known as the
and symmetry inherent in a semi-classical plasma, it is necessary to “effective range.” Equation (4) can be used to obtain phase shift at low
consider a new model of particle interaction.31,32 energies for which terms of order of k4i can be neglected. In that case,
In this paper, we concentrate mainly on the non-ideality of Eq. (4) reduces to
classical plasmas with ne 2 2:7 ½1023 1026 m3 and Te 2
½1 10 104 K so that c 2 ½0:0; 4:0 approximately. In particular, we 1
ki cotðd0 Þ ¼ þ r0 ð2 þ k2i Þ: (6)
focus on partially ionized hydrogen plasma (PIHP). Our objective is to 2
study the effects of NI of plasma on the scattering of electrons from At sufficiently low energies (ki ! 0Þ, also called the zero-energy, scat-
hydrogen atoms at low incident energies. In particular, our endeavor tering takes place predominantly at the S wave, and it is homoge-
will be to study zero-energy scattering in detail. The scattering of elec- neous and isotropic. In this case, scattering can be described
trons from atoms plays an important role in calculating the various conveniently by the scattering length, defined by
physical properties of a partially ionized dense plasma, such as trans-
port and thermodynamical and optical properties.33 As stated above, tan ðd0 Þ
as ¼ lim : (7)
NIPs exist naturally in various astrophysical objects and are widely ki !0 ki
used in different technical applications. Valid data on transport, ther-
At zero-energy, “as ” gives the scattering amplitude, so the differen-
modynamical, optical, and other properties of dense NIPs are required tial cross section and the total cross section are, respectively, given by
for a correct description of the processes in these systems.32 a2s and 4pa2s . Moreover, for an attractive potential, the scattering
In vacuum, electron scattering from hydrogen atom at low inci- length with a positive sign points toward the existence of bound states
dent energies has been studied extensively. In particular, the scattering of the underlying composite system.51 The scattering length can be
length has also been calculated accurately.34–42 In comparison to computed accurately by using Eq. (6). In order to calculate the phase
vacuum, studies on electron–hydrogen collisions in plasmas using fully shift or scattering length by using (6), we require knowing three quan-
quantum mechanical calculations are relatively small.43–46 In this tities, namely, r0, EH and EH.
paper, we use the effective range theory (ERT)47,48 to study the effects The effective range “r0” can be obtained from the knowledge of
of non-ideality of PIHP on the dynamics of low-energy electron– the ground state wave function W1s ð~ r 1 ;~ r 12 Þ of H and its asymp-
r 2 ;~
hydrogen scattering. totic form, u1s ð~
r 1 ;~ r 12 Þ, at large distances as47
r 2 ;~
1 1 er1 =k er2 =k
H ¼ r21 r22 gðr1 ; cÞ gðr2 ; cÞ
2 2 r1 r2
er12 =k
þ gðr12 ; cÞ ; (3)
r12
pffiffi
where gðr; cÞ ¼ ½10 þ cðe cr=k 1Þð1 e2r=k Þ=½10f1 þ f ðcÞg.
As proposed above, we use the effective range theory (ERT) to study
the effects of NI of plasma on the low-energy electron scattering from
hydrogen atom. ERT is an effective method for computing scattering
phase shifts at low incident energies. It uses the knowledge of the ana-
lytic properties of scattering amplitude and is based on the infinite
expansion of the cotangent of the phase shift in powers of incident
FIG. 1. K(r), as given by Eq. (11), as a function of r.
energy for a certain class of potentials.49 For the scattering of electrons
TABLE I. Singlet S wave phase shifts (in radian) in e–H collisions in vacuum (l ¼ 0 and c ¼ 0) for different values of ki (in a.u.). The row corresponding to represents scat-
tering length. A: Results of the effective range theory of Ghoshal and Ho,43 B: Variational results of Schwartz,37 C: Results obtained by using optical potential (without the use of
projection operators) method, including the effects of polarization with the Shertzer and Temkin cutoff function by Bhatia,36 D: Results of the method of polarized orbitals by
Temkin and Lamkin,38 E: Variational results of Messay and Moiseiwitsch,39 F: Results of post-adiabatic approximation by Klar and Klar,40 G: Results of the adiabatic method (in
hyperspherical coordinates) by Lin,41 H: Results of the complex-correlation Kohn T-matrix method by Bhatia and Temkin.42
ki (a.u.) Present A B C D E F G H
ð
1
W1s ð~
r 1 ;~ r 12 Þ ! u1s ð~
r 2 ;~ r 1 ;~ r 12 Þ
r 2 ;~
r0 ¼ 2 u21s ðr; 0; rÞ W21s ðr; 0; rÞ dr: (8) r1
e er2
0 ¼C /1s ð~ r 2Þ þ /1s ð~
r 1Þ ; (9)
r1 r2
For the weakly bound ground state of H, u1s ð~
r 1 ;~ r 12 Þ can be rep-
r 2 ;~ where /1s denotes the ground state wave function of H, and C is a con-
resented as35 stant to be determined. With such a representation of u1s , r0 is given by
TABLE II. Singlet S wave phase shifts (in radian) in e–H collisions along with the ground state energies of H–1 (EH in a.u.) and H (EH in a.u.) in classical PIHP for various
densities (in m3) and temperatures (in K) at different values of incident electron momentum ki (in a.u.). rD (in a0) and c are, respectively, the Debye length and non-ideality
parameter at the corresponding temperature and density. The row corresponding to stands for singlet scattering length.
ne ¼ 2:7 1023
c 0.125 821 66 0.044 484 67 0.011 253 83 0.005 560 58 0.003 978 83
rD 250.970 411 60 354.925 759 84 561.186 900 68 709.851 519 68 793.638 125 97
EH 0.475 520 97 0.505 760 33 0.520 836 55 0.523 780 03 0.524 652 28
EH 0.450 320 93 0.479 022 37 0.493 356 74 0.496 164 47 0.496 998 50
ki
0.00 5.903 27 6.010 60 5.999 24 6.021 26 5.994 01
0.05 2.850 13 2.844 54 2.845 00 2.843 88 2.845 23
0.20 2.131 79 2.103 26 2.101 53 2.096 95 2.101 62
0.50 1.365 86 1.303 50 1.295 05 1.286 79 1.293 92
0.75 1.034 72 0.968 13 0.958 56 0.950 31 0.957 18
ne ¼ 2:7 1024
c 0.397 883 02 0.140 672 89 0.035 587 74 0.017 584 11 0.012 582 17
rD 79.363 812 60 112.237 380 14 177.462 879 92 224.474 760 27 250.970 411 60
EH 0.388 810 35 0.466 149 16 0.506 609 32 0.515 391 81 0.518 059 64
EH 0.367 827 06 0.441 213 86 0.479 686 63 0.488 063 55 0.490 614 14
ki
0.00 5.895 84 5.941 68 6.000 87 6.102 08 6.032 62
0.05 2.851 52 2.848 27 2.844 99 2.839 91 2.843 34
0.20 2.168 03 2.126 43 2.104 04 2.084 01 2.095 75
0.50 1.490 26 1.359 05 1.303 32 1.268 58 1.286 11
0.75 1.187 06 1.028 21 0.967 62 0.933 22 0.949 92
1 1 X
N0
r0 ¼ : (10) /1s ð~
r 2Þ ¼ Cl0i eai r2 r2li ; (13)
4pC 2
i¼1
So, ultimately, we require determining the constant C to obtain r0.
Setting r1 ¼ r12 ¼ r and r2 ¼ 0 in Eq. (9), we find that the expression where Cl0i and ai, respectively, stand for the expansion coefficient and
re W1s ðr; 0; rÞ0 remains constant for a wide range in the asymptotic
0 r non-linear variational parameter. Expansion of the wave functions
region. Let us define (12) and (13) and calculational procedures have been discussed in
detail in our previous works.16,17 The phase shift, thus obtained, is a
KðrÞ ¼ rer W1s ðr; 0; rÞ (11)
singlet for obvious reason.
so that K(r) remains constant for a wide range in the asymptotic
region. We recognize this constant as C. Upon substituting C in III. RESULTS AND DISCUSSION
Eq. (10), we obtain r0. Using 715 numbers of terms in the wave function (12), we have
It now remains to determine the ground state wave function and been able to obtain EH , correct up to eight places of decimal. EH and
energy of H and H embedded in PIHP. This is accomplished by solv- other parameters have been reported in our previous work.17
ing the corresponding Schr€odinger equation within the framework of
Conversely, we have found that 150 terms are required to be used in the
the Rayleigh–Ritz variational principle. In the case of H, we employ a
wave function (13) to obtain convergent result for EH, correct up to four-
trial function of the form
teenth places of decimal.16 The quantities EH and EH yield according
X
N1 to the formula (5). We have used quadruple precision arithmetic
W1s ð~
r 1 ;~ r 12 Þ ¼
r 2 ;~ Cl1i mi ni eaðr1 þr2 Þ r1li r2mi r12
ni
þ ðr1
r2 Þ; (12) throughout the computation. The overall uncertainty in the reported
i¼1 results lies within 5%. The correction coefficient f ðcÞ in the pseudopo-
where Cl1i mi ni ’s are the expansion coefficients and a is a non-linear tential (2) is calculated quite accurately for 0 c 4:0 by utilizing the
variational parameter. For H, we utilize the following trial wave function: discrete values of f ðcÞ, as given in Ref. 6 in a cubic interpolation scheme.
TABLE III. Singlet S wave phase shifts (in radian) in e–H collisions along with the ground state energies of H–1 (EH in a.u.) and H (EH in a.u.) in classical PIHP for various
densities (in m3) and temperatures (in K) at different values of incident electron momentum ki (in a.u.). rD (in a0) and c are, respectively, the Debye length and non-ideality
parameter at the corresponding temperature and density. The row corresponding to stands for singlet scattering length.
ne ¼ 2:7 1025
c 1.258 216 58 0.444 846 74 0.112 538 31 0.055 605 84 0.039 788 30
rD 25.097 041 16 35.492 575 98 56.118 690 07 70.985 151 97 79.363 812 60
EH 0.234 330 78 0.363 131 21 0.466 784 43 0.490 464 22 0.498 109 97
EH 0.220 827 05 0.342 952 64 0.441 423 75 0.464 001 77 0.471 307 75
ki
0.00 5.074 73 5.875 85 5.892 38 5.995 82 6.013 83
0.05 2.896 71 2.852 79 2.850 64 2.845 32 2.844 37
0.20 2.457 99 2.180 71 2.132 77 2.107 39 2.102 43
0.50 2.356 09 1.530 81 1.365 99 1.312 52 1.301 51
0.75 2.434 90 1.239 78 1.034 49 0.977 57 0.966 05
ne ¼ 2:7 1026
c 3.978 830 17 1.406 728 90 0.355 877 39 0.175 841 11 0.125 821 66
rD 7.936 381 26 11.223 738 01 17.746 287 99 22.447 476 03 25.097 041 16
EH 0.106 501 65 0.191 115 21 0.364 024 89 0.423 011 53 0.442 136 02
EH 0.099 715 99 0.179 318 42 0.342 925 12 0.399 044 35 0.417 275 32
ki
0.00 4.698 17 5.316 83 5.984 97 6.029 41 5.978 28
0.05 2.928 07 2.886 50 2.847 04 2.844 10 2.846 47
0.20 2.758 89 2.460 04 2.149 78 2.116 91 2.120 19
0.50 2.895 17 2.406 88 1.451 27 1.352 32 1.348 83
0.75 2.965 15 2.502 92 1.140 79 1.023 45 1.017 74
TABLE IV. Singlet scattering length (in a.u.) in e–H scattering under PIHP.
l (in a1
0 )
10
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11
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15
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16
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27
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29
ACKNOWLEDGMENTS A. Grinenko, V. Tz. Gurovich, A. Saypin, S. Efimov, Ya. E. Krasik, and V. I.
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30
This work has been supported by the Science and Engineering H. Totsuji, Contrib. Plasma Phys. 52, 74 (2012).
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Research Board, India, through the Research project File No. EMR/ T. S. Ramazanov and K. N. Dzhumagulova, Phys. Plasmas 9, 3758 (2002).
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T. S. Ramazanov, K. N. Dzhumagulova, and Y. A. Omarbakiyeva, Phys.
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