Waktu produksi = 330

24
kapasitas produksi = 40000
= 5050.5051

Spesifikasi Bahan

C6H5Cl = 99.5 %
CH3NH2 = 99.97 %

Neraca Massa Mixer

Arus Masuk
Komponen BM Arus 1 ( CH3NH2)
Kmol/Jam Kg/Jam
CH3NH2 31.0572 104.0984 3233.0044
CuCl 98.9990 0.0000 0.0000
H2O 18.0152 0.0539 0.9702
Total 104.1522 3233.9746
7356.2290
Cek Balance = 0.0000

NM Reaktor 01
Diambil basis per 50 mol methylamine
Reaksi : C6H5Cl + 2CH 3NH2 C 6H5NHCH3 + CH3NH2.HCl
Mula-Mula 52.0492 104.0984
Reaksi 46.8443 93.6885
Sisa 5.2049 10.4098
Konversi = 90%
Rasio mol umpan = Chlorobenzene : Methylaniline
CuCl : C6H5Cl
Menghitung kebutuhuan CuCl
CuCl = 0,4*mol C6H5Cl =
Menghitung kebutuhan H2O
H2O = (0,4/0,6) X Massa CH3NH2 =
Mol H2O =

Arus Masuk
Komponen BM Arus 3
Kmol/Jam Kg/Jam
C6H5Cl 112.5585 0.0000 0.0000
CH3NH2 31.0572 104.0984 3233.0044
CH3NH2HCl 67.5181 0.0000 0.0000
C6H5NHCH3 107.1548 0.0000 0.0000
CuCl 98.9990 41.6394 4122.2544
H2O 18.0152 0.0539 0.9702
 145.7916 7,356.2290
Total 435.3028
13,244.2481
Cek Balance = 0.0000

NM Dekanter

Arus Masuk
Komponen BM Arus 5
Kmol/Jam Kg/Jam
C6H5Cl 112.5585 5.2049 585.8579
CH3NH2 31.0572 10.4098 323.3004
CH3NH2HCl 67.5181 46.8443 3,162.8363
C6H5NHCH3 107.1548 46.8443 5,019.5887
CuCl 98.9990 41.6394 4,122.2544
H2O 18.0152 1.6880 30.4103
152.6307 13,244.2481
Total 435.3028
13,244.2481
Cek Balance 0.0000

NM Centrifuge
Asumsi Efisiensi Centrifuge = 100% 0
Arus Masuk
Komponen BM Arus 6
Kmol/Jam Kg/Jam
CH3NH2 31.0572 10.4098 323.3004
CH3NH2HCl 67.5181 46.8443 3162.8363
CuCl 98.9990 41.6394 4122.2544
H2O 18.0152 0.0539 0.9702
98.9473 7609.3614
Total 215.5895
7609.3614
Cek Balance 0.0000

NM Menara Destilasi
konversi C6H5Cl= 99.7% 0.3%
Efisiensi = 100.0%
Arus Masuk
Komponen BM Arus 7
Kmol/Jam Kg/Jam
C6H5CL (LK) 112.5585 5.2049 585.8579
C6H5NH3 (HK) 107.1548 46.8443 5,019.5887
H2O 18.0152 1.6342 29.4401
53.6834 5,634.8867
Total 237.7285
5,634.8867
Cek Balance 0.0000

Purging 1
Asumsi Purging = 40% 60%
Arus 10 Recycle ke Reaktor (Bottom)
Komponen BM
 Komponen BM
Kmol/Jam Kg/Jam
C6H5CL 112.5585 5.18930449469152 584.1003
C6H5NH3 107.1548 0.0000 0.0000
H2O 18.0152 0.01561475775735 0.2813
5.20491925244887 584.3816
Total 237.7285
584.3816
Cek Balance 0.0000
0.0000
Purging 2
Asumsi Purging = 31% 69%
Arus 8 (Recycle Centrifuge)
Komponen BM
Kmol/Jam Kg/Jam
CH3NH2 31.0572 10.4098 323.3004
CH3NH2HCl 67.5181 0.0000 0.0000
CuCl 98.9990 41.6394 4122.2544
H2O 18.0152 0.0539 0.9702
52.1030466236357 4446.5250
Total 215.5895
4446.5250
Cek Balance 0.0000

Recycle

Diambil basis per 50 mol methylamine

Reaksi : C6H5Cl + 2CH 3NH2 C 6H5NHCH3 + CH3NH2.HCl
Mula-Mula 52.0492 104.0984
Reaksi 46.8443 93.6885
Sisa 5.2049 10.4098

Spesifikasi Bahan

C6H5Cl = 99.5 %
CH3NH2 = 99.97 %

Recycle
Komponen BM
Arus 13 ( Recycle MD )
kmol/jam kg/jam
C6H5Cl 112.5585 3.1136 350.4602
CH3NH2 31.0572 0.0000 0.0000
CH3NH2HCl 67.5181 0.0000 0.0000
C6H5NHCH3 107.1548 0.0000 0.0000
CuCl 98.9990 0.0000 0.0000
H2O 18.0152 0.0884 1.5923
3.2020 352.0525
Total 435.3028

Cek Balance 0.0000

Diambil basis per 50 mol methylamine
Reaksi : C6H5Cl + 2CH 3NH2 C 6H5NHCH3 + CH3NH2.HCl
Mula-Mula 52.0492 104.0984
Reaksi 46.8443 93.6885
Sisa 5.2049 10.4098

Neraca Massa Mixer

Arus Masuk
Komponen BM Arus 1 ( CH3NH2)
Kmol/Jam Kg/Jam
CH3NH2 31.0572 104.0984 3233.0044
CuCl 98.9990 0.0000 0.0000
H2O 18.0152 0.0539 0.9702
104.1522 3233.9746
Total 148.0714
7356.2290
Cek Balance = 0.0000

Ne

Freshfeed
Komponen BM
Arus 3
kmol/jam kg/jam
C6H5Cl 112.5585 0.0000 0.0000
CH3NH2 31.0572 96.9327 3010.4571
CH3NH2HCl 67.5181 0.0000 0.0000
C6H5NHCH3 107.1548 0.0000 0.0000
CuCl 98.9990 12.9765 1284.6571
H2O 18.0152 0.0501 0.9034
109.9593 4296.0176
Total 435.3028

Cek Balance 0.0000

Arus Masuk
Komponen BM Arus 5
Kmol/Jam Kg/Jam
C6H5Cl 112.5585 5.2049 585.8579
CH3NH2 31.0572 10.4098 323.3004
CH3NH2HCl 67.5181 46.8443 3,162.8363
C6H5NHCH3 107.1548 46.8443 5,019.5887
CuCl 98.9990 41.6394 4,122.2544
H2O 18.0152 1.6880 30.4103
 152.6307 13,244.2481
Total 435.3028
13,244.2481
Cek Balance 0.0000

Ne
Asumsi Efisiensi Centrifuge = 100% 0
Arus Masuk
Komponen BM Arus 6
Kmol/Jam Kg/Jam
CH3NH2 31.0572 10.4098 323.3004
CH3NH2HCl 67.5181 46.8443 3162.8363
CuCl 98.9990 41.6394 4122.2544
H2O 18.0152 0.0539 0.9702
98.9473 7609.3614
Total 215.5895
7609.3614
Cek Balance 0.0000

NM Menara Destilasi
konversi C6H5Cl= 99.7% 0.3%
Efisiensi = 100.0%
Arus Masuk
Komponen BM Arus 7
Kmol/Jam Kg/Jam
C6H5CL (LK) 112.5585 5.2049 585.8579
C6H5NH3 (HK) 107.1548 46.8443 5,019.5887
H2O 18.0152 1.6342 29.4401
53.6834 5,634.8867
Total 237.7285
5,634.8867
Cek Balance 0.0000

Purging 1
Asumsi Purging = 40% 60%
Arus 10 Recycle ke Reaktor (Bottom)
Komponen BM
Kmol/Jam Kg/Jam
C6H5Cl 112.5585 5.18930 584.10033
C6H5NH3 107.1548 0.00000 0.00000
H2O 18.0152 0.01561 0.28130
5.20491925244887 584.3816
Total 237.7285
584.3816
Cek Balance 0.0000

Purging 2
Asumsi Purging = 31% 69%
Arus 8 (Recycle Centrifuge)
Komponen BM
Kmol/Jam Kg/Jam
CH3NH2 31.0572 10.4098 323.3004
CH3NH2HCl 67.5181 0.0000 0.0000
CuCl 98.9990 41.6394 4122.2544
H2O 18.0152 0.0539 0.9702
52.1030466236357 4446.5250
Total 215.5895
4446.5250
Cek Balance 0.0000

Neraca Massa Total

Input
Komponen BM Arus 3 Arus 4
kg/jam kg/jam
C6H5Cl 112.5585 0.0000 5,858.5790
CH3NH2 31.0572 3233.0044 0.0000
CH3NH2HCl 67.5181 0.0000 0.0000
C6H5NHCH3 107.1548 0.0000 0.0000
CuCl 98.9990 4122.2544 0.0000
H2O 18.0152 0.9702 29.4401
7356.2290 5,888.0191
Total 435.3028
13244.2481
Cek Balance = 0.0000
 NERACA MASSA
hari
jam
ton/tahun
kg/jam

Sebelum Recycle
Impuritas
Massa Impuritas (Kg) Mol Impuritas (Kmol)
Air 29.4401 1.6342
Air 0.9702 0.0539

Neraca Massa Mixer

Arus Masuk Arus Keluar

Arus 2 ( CUCl) Arus 3 ( ke Reaktor )
Kmol/Jam Kg/Jam Kmol/Jam
0.0000 0.0000 104.0984
41.6394 4122.2544 41.6394
0.0000 0.0000 0.0539
41.6394 4122.2544 145.7916
7356.2290 7356.2290

NM Reaktor 01

C 6H5NHCH3 + CH3NH2.HCl
- -
46.8443 46.8443
46.8443 46.8443

= 1 :
= 0.4000 :

20.8196770097955 kmol/jam

2155.3362 Kg/Jam
119.6399 Mol/jam

Arus Masuk Arus Keluar

Arus 4 (C6H5Cl) Arus 5 (Ke Dekanter)
Kmol/Jam Kg/Jam Kmol/Jam
52.0492 5,858.5790 5.2049
0.0000 0.0000 10.4098
0.0000 0.0000 46.8443
0.0000 0.0000 46.8443
0.0000 0.0000 41.6394
1.6342 29.4401 1.6880
 53.6834 5,888.0191 152.6307
13,244.2481 13,244.2481

NM Dekanter

Arus Keluar
Arus 6 ke Centrifuge Arus 7 ke Menara Destilasi
Kmol/Jam Kg/Jam Kmol/Jam
0.0000 0.0000 5.2049
10.4098 323.3004 0.0000
46.8443 3162.8363 0.0000
0.0000 0.0000 46.8443
41.6394 4122.2544 0.0000
0.0539 0.9702 1.6342
98.9473 7609.3614 53.6834
13244.2481

NM Centrifuge
(perry's 6; 19-87)
Arus Keluar
Arus 8 ke Mixer Arus 9
Kmol/Jam Kg/Jam Kmol/Jam
10.4098 323.3004 0.0000
0.0000 0.0000 46.8443
41.6394 4122.2544 0.0000
0.0539 0.9702 0.0000
52.1030 4446.5250 46.8443
7609.3614

NM Menara Destilasi

Arus Keluar
Arus 10 Recycle ke Reaktor (Bottom) Arus 11 ke Tangki penyimpanan (Destilat)
Kmol/Jam Kg/Jam Kmol/Jam
5.18930449469152 584.1003 0.0156
0.0000 0.0000 46.8443
0.015614757757347 0.2813 1.6186
5.20491925244887 584.3816 48.4785
5634.8867

Purging 1

Arus 12 (Purging 1) Arus 13 ( Recycle MD )

 Kmol/Jam Kg/Jam Kmol/Jam
2.0757 233.6401 3.1136
0.0000 0.0000 0.0000
0.0062 0.1125 0.0094
2.0820 233.7527 3.1230
584.3816

Purging 2

Arus 14 (Purging 2) Arus 15 ( Recycle Centrifuge )

Kmol/Jam Kg/Jam Kmol/Jam
3.2441 100.7532 7.1657
0.0000 0.0000 0.0000
12.9765 1284.6571 28.6629
0.0168 0.3024 0.0371
16.2374 1385.7126 35.8657
4446.5250

Recycle

C 6H5NHCH3 + CH3NH2.HCl
- -
46.8443 46.8443
46.8443 46.8443

Sebelum Recycle
Impuritas
Massa Impuritas (Kg) Mol Impuritas (Kmol)
Air 29.4401 1.6342
Air 0.9702 0.0539

Arus Masuk
Recycle Freshfeed
Arus 15 ( Recycle Centrifuge ) Arus 4 (C6H5Cl)
kmol/jam kg/jam kmol/jam
0.0000 0.0000 48.9356
7.1657 222.5473 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
28.6629 2,837.5973 0.0000
0.0131 0.2356 1.5364
35.8417 3,060.3801 50.4720
13,244.2481
 NERACA MASSA SETELAH RECYCLE

C 6H5NHCH3 + CH3NH2.HCl
- -
46.8443 46.8443
46.8443 46.8443

Neraca Massa Mixer

Arus Masuk Arus Keluar

Arus 2 ( CUCl) Arus 3 ( ke Reaktor )
Kmol/Jam Kg/Jam Kmol/Jam
0.0000 0.0000 104.0984
41.6394 4122.2544 41.6394
0.0000 0.0000 0.0539
41.6394 4122.2544 145.7916
7356.2290 7356.2290

Neraca Massa Reaktor 1

Arus Masuk
Freshfeed Recycle
Arus 4 (C6H5Cl) Arus 13 ( Recycle MD )
kmol/jam kg/jam kmol/jam
48.9356 5,508.1188 3.1136
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
1.5364 27.6790 0.0884
50.4720 5,535.7978 3.2020
13,244.2481

Neraca Massa Dekanter

Arus Keluar
Arus 6 ke Centrifuge Arus 7 ke Menara Destilasi
Kmol/Jam Kg/Jam Kmol/Jam
0.0000 0.0000 5.2049
10.4098 323.3004 0.0000
46.8443 3162.8363 0.0000
0.0000 0.0000 46.8443
41.6394 4122.2544 0.0000
0.0539 0.9702 1.6342
 98.9473 7609.3614 53.6834
13244.2481

Neraca Massa Centrifuge

(perry's 6; 19-87)
Arus Keluar
Arus 8 ke Mixer Arus 9
Kmol/Jam Kg/Jam Kmol/Jam
10.4098 323.3004 0.0000
0.0000 0.0000 46.8443
41.6394 4122.2544 0.0000
0.0539 0.9702 0.0000
52.1030 4446.5250 46.8443
7609.3614

NM Menara Destilasi

Arus Keluar
Arus 10 Recycle ke Reaktor (Bottom) Arus 11 ke Tangki penyimpanan (Destilat)
Kmol/Jam Kg/Jam Kmol/Jam
5.1893 584.1003 0.0156
0.0000 0.0000 46.8443
0.0156 0.2813 1.6186
5.20491925244887 584.3816 48.4785
5634.8867

Purging 1

Arus 12 (Purging 1) Arus 13 ( Recycle MD )

Kmol/Jam Kg/Jam Kmol/Jam
2.07572 233.64013 3.11358
0.00000 0.00000 0.00000
0.00625 0.11252 0.00937
2.0820 233.7527 3.1230
584.3816

Purging 2

Arus 14 (Purging 2) Arus 15 ( Recycle Centrifuge )

Kmol/Jam Kg/Jam Kmol/Jam
3.2441 100.7532 7.1657
0.0000 0.0000 0.0000
12.9765 1284.6571 28.6629
 0.0168 0.3024 0.0371
16.2374 1385.7126 35.8657
4446.5250

Neraca Massa Total

Output
Arus 12 & Arus 14 (Purging) Arus 9 Arus 11
kg/jam kg/jam kg/jam
233.6401 0.0000 1.7576
100.7532 0.0000 0.0000
0.0000 3162.8363 0.0000
0.0000 0.0000 5,019.5887
1284.6571 0.0000 0.0000
0.4149 0.0000 29.1588
1619.4653 3162.8363 5,050.5051
13244.2481
RACA MASSA

Setelah Recycle
Massa Impuritas (Kg) Mol Impuritas (Kmol)

Arus Keluar
s 3 ( ke Reaktor )
Kg/Jam
3233.0044
4122.2544
0.9702
7356.2290
7356.2290

2
1

Arus Keluar
s 5 (Ke Dekanter)
Kg/Jam
585.8579
323.3004
3,162.8363
5,019.5887
4,122.2544
30.4103
 13,244.2481
13,244.2481

ke Menara Destilasi
Kg/Jam
585.8579
0.0000
0.0000
5,019.5887
0.0000
29.4401
5,634.8867

Arus 9
Kg/Jam
0.0000
3162.8363
0.0000
0.0000
3162.8363

ngki penyimpanan (Destilat)

Kg/Jam
1.7576
5019.5887
29.1588
5050.5051

13 ( Recycle MD )
 Kg/Jam
350.4602
0.0000
0.1688
350.6290

( Recycle Centrifuge )
Kg/Jam
222.5473
0.0000
2837.5973
0.6678
3060.8124

Setelah Recycle
Massa Impuritas (Kg) Mol Impuritas (Kmol)
27.6790 1.5364 0.0978
0.9034 0.0501 0.0037
0.0539

Arus Keluar
Freshfeed
Arus 4 (C6H5Cl) Arus 3 Arus 5
kg/jam kmol/jam kg/jam kmol/jam
5,508.1188 0.0000 0.0000 5.2049
0.0000 96.9327 3010.4571 10.4098
0.0000 0.0000 0.0000 46.8443
0.0000 0.0000 0.0000 46.8443
0.0000 12.9765 1284.6571 41.6394
27.6790 0.0501 0.9034 1.6880
5,535.7978 109.9593 4296.0176 152.6307
13,244.2481
SSA SETELAH RECYCLE

Arus Keluar
s 3 ( ke Reaktor )
Kg/Jam
3233.0044
4122.2544
0.9702
7356.2290
7356.2290

Arus Keluar
Recycle
13 ( Recycle MD ) Arus 15 ( Recycle Centrifuge ) Arus 5
kg/jam kmol/jam kg/jam kmol/jam
350.4602 0.0000 0.0000 5.2049
0.0000 7.1657 222.5473 10.4098
0.0000 0.0000 0.0000 46.8443
0.0000 0.0000 0.0000 46.8443
0.0000 28.6629 2837.5973 41.6394
1.5923 0.0131 0.2356 1.6880
352.0525 35.8417 3060.3801 152.6307
13,244.2481

ke Menara Destilasi
Kg/Jam
585.8579
0.0000
0.0000
5,019.5887
0.0000
29.4401
 5,634.8867

Arus 9
Kg/Jam
0.0000
3162.8363
0.0000
0.0000
3162.8363

ngki penyimpanan (Destilat)

Kg/Jam
1.7576
5,019.5887
29.1588
5050.5051

13 ( Recycle MD )
Kg/Jam
350.46020
0.00000
0.16878
350.6290

( Recycle Centrifuge )
Kg/Jam
222.5473
0.0000
2837.5973
 0.6678
3060.8124

Recycle
kg/jam
350.4602
222.5473
0.0000
0.0000
2837.5973
0.8366
3411.4414
Arus Keluar

Arus 5
kg/jam
585.8579
323.3004
3,162.8363
5,019.5887
4,122.2544
30.4103
13,244.2481
13,244.2481
Arus Keluar

Arus 5
kg/jam
585.8579
323.3004
3,162.8363
5,019.5887
4,122.2544
30.4103
13,244.2481
13,244.2481
 T-01

komponen kg/jam
C6H5Cl 5858.57903676766
H2O 29.440095662149
Total 5888.01913242981

T-02

komponen kg/jam
CH3NH2 3233.0043641431
H2O 0.970192366953016
Total 3233.97455651005
 S-01

komponen kg/jam
CuCl 4122.25440858548
Total 4122.25440858548
 R-01

komponen kg/jam
C6H5Cl 5858.57903676766
CH3NH2 3233.0043641431
CH3NH2HCl 0
C6H5NHCH3 0
CuCl 4122.25440858548
H2O 30.4102880291021
Total 13244.2480975253

M-01

komponen kg/jam
CH3NH2 3233.0043641431
CuCl 4122.25440858548
H2O 0.970192366953016
Total 7356.2290
komponen kg/jam
C6H5Cl 585.8579
CH3NH2 323.3004
CH3NH2HCl 3162.8363 komponen
C6H5NHCH3 5019.5887 CH3NH2
CuCl 4122.2544 CuCl
H2O 30.4103 CH3NH2HCl
Total 13244.2481 H2O
Total

CF-01
DK-01

komponen kg/jam
C6H5NHCH3 585.8579037
C6H5Cl 5019.588734
H2O 29.44009566
Total 5634.886733

MD-01

komponen kg/jam
C6H5Cl 1.757573711
H2O 29.15879268
C6H5NHCH3 5019.588734
Total 5050.5051
 kg/jam
323.30043641431
4122.254408585
3162.836327209
0.970192366953
7609.361364576

CF-01

komponenkg/jam
komponen kg/jam CH3NH2 323.3004
CH3NH2HCl 3162.8363 CuCl 4122.254
Total 3162.8363 H2O 0.970192
Total 4446.525

komponen kg/jam
C6H5CL (LK) 585.857904
C6H5NH3 (HK) 5019.58873
H2O 29.4400957
Total 5634.8867

T-03
 T-03

komponen kg/jam
C6H5Cl 1.75757371
H2O 29.1587927
C6H5NHCH3 5019.58873
Total 5050.5051
 DATA FISIS

Faith dkk, 1957

Komponen BM
C6H5Cl 112.5585
CH3NH2 31.0572
CH3NH2HCl 67.5181
C6H5NHCH3 107.1548
CuCl 98.9990
H2O 18.0152

konversi C6H5NHCH3 = 0.9

Data Viskositas Bahan Baku dan Produk

Yaw's Chemical Properties Handbook
log µ = A+B/T+C*T+D*T^2 T=K
Komponen A B C
C6H5Cl -4.8717 8.2340E+02 9.1981E-03
CH3NH2 -9.467 9.8286E+02 2.8918E-02
CH3NH2HCl 0 0.0000E+00 0.0000E+00
C6H5NHCH3 -13.7299 2.2913E+03 2.7208E-02
CuCl 0.0000 0.0000E+00 0.0000E+00
H2O -10.2158 1.7925E+03 1.7730E-02

Data Densitas Bahan Baku dan Produk

Yaw's Chemical Properties Handbook
Densitas = A*B^-((1-(T/Tc))^n) T=K
Komponen A B n
C6H5Cl 0.3782 0.2765 0.2904
CH3NH2 0.2017 0.2141 0.2275
CH3NH2HCl 0.0000 0.0000 0.0000
C6H5NHCH3 0.3471 0.2740 0.2857
CuCl 0.0000 0.0000 0.0000
H2O 0.3477 0.2311 0.1917

Data Antoine Bahan Baku dan Produk

Yaws' Handbook of Antoine Coefficients for Vapor Pressure
log P = A - B/(T+C) T=C P = mmHg
Komponen A B C
C6H5Cl 7.3041 1669.7073 193.6360
CH3NH2 7.2759 1327.1634 183.9130
CH3NH2HCl 10.4827 3254.6757 179.2790
C6H5NHCH3 8.0557 1723.6425 233.0800
CuCl
H2O

Data Kapasitas Panas Bahan Baku dan Produk

Yaw's Chemical Properties Handbook
Cp = A+ B*T + C*T^2 + D*T^3
Komponen A B C
C6H5Cl 63.2880 9.8960E-01 -2.3583E-03
CH3NH2 -18.9440 1.0971E+00 -2.8921E-03
CH3NH2HCl -54.6630 1.7295E+00 -3.3303E-03
C6H5NHCH3 92.0530 -3.9953E-02 -2.1103E-04
CuCl
H2O

Data Konduktifitas Thermal Bahan Baku dan Produk

Yaw's Chemical Properties Handbook
Inorganik Log k = A + B ( 1 - T/C )^2/7
Komponen A B C
C6H5Cl -1.3485 0.6888 699
CH3NH2 -1.2836 0.5893 592.71
C6H5NHCH3 -1.7347 1.0237 825

Organik k = A + B T + C T ^2
Komponen A B C
C6H5NHCH3 -0.2758 4.61E-03 -5.54E-06

Data Tegangan Muka Bahan Baku dan Produk

Yaw's Chemical Properties Handbook
τ = A ( (1 - (T/Tc ))^n)
Komponen A Tc n
C6H5Cl 77.2600 699.0000 1.0800
CH3NH2 57.0500 592.7100 1.0703
CH3NH2HCl 80.2020 825.0000 1.2570
C6H5NHCH3 132.6740 647.1300 0.9550

Enthalpi Of Vaporizer
Yaw's Chemical Properties Handbook
λ = A ((1-(T/Tc))^n)
Komponen A Tc n
C6H5Cl 72.0380 699.0000 0.4590
CH3NH2 11.5750 592.7100 -0.6500
CH3NH2HCl 91.9580 825.0000 0.3780
C6H5NHCH3 52.0530 647.1300 0.3210

Entalphi of Formation
Pada suhu ref 298 K
Komponen ΔHf (Kj/Mol)
C6H5Cl 86.86
CH3NH2 -434.84
CH3NH2HCl -128.5
C6H5NHCH3 -241.8
 D
-8.6530E-06
-3.5672E-05
0.0000E+00
-2.0020E-05
0.0000E+00
-1.2630E-05

Tc
632.3500
430.0500
0.0000
647.1300
0.0000
461.1500

Tb
183.8494
118.0495
 248.8638
99.9964

duk

D
2.3296E-06
2.9275E-06
2.4823E-06
5.3469E-07

roduk

duk
fungsi : Mereaksikan klorobenzen dan metilamin menjadi metilanilin dan metilamin hidroksida
Jenis : Reaktor Alir Tangki Berpengaduk
Proses : Kontinyu

kondisi operasi
T= 215 C
P= 68,03 atm

Freshfeed
Komponen BM
Arus 3
kmol/jam kg/jam
C6H5Cl 112.5585 0.0000 0.0000
CH3NH2 31.0572 96.9327 3010.4571
CH3NH2HCl 67.5181 0.0000 0.0000
C6H5NHCH3 107.1548 0.0000 0.0000
CuCl 98.999 12.9765 1284.6571
H2O 18.0152 0.0501 0.9034
109.9593 4296.0176
Total 435.3028

Densitas = A*B^-((1-(T/Tc))^n) T=K 488.15

Komponen A B C
C6H5Cl 0.3782 0.2765 0.2904
CH3NH2 0.2017 0.2141 0.2275
CH3NH2HCl 0.0000 0.0000 0.0000
C6H5NHCH3 0.3471 0.2740 0.2857
CuCl 0.0000 0.0000 0.0000
H2O 0.3477 0.2311 0.1917

log µ = A+B/T+C*T+D*T^2 T=K 488.15

Komponen A B C
C6H5Cl -4.8717 823.4000 0.0092
CH3NH2 -9.4670 982.8600 0.0289
CH3NH2HCl 0.0000 0.0000 0.0000
C6H5NHCH3 -13.7299 2291.3000 0.0272
CuCl 0.0000 0.0000 0.0000
H2O -10.2158 1792.5000 0.0177

Komponen Bm ρ (Densitas) (Kg/m3) Fm (Laju Alir Mol) (kmol)

C6H5Cl 112.5585 8.73E+02 52.0492
CH3NH2 31.0572 9.12E+02 104.0984
CH3NH2HCl 67.5181 0.00E+00 0.0000
C6H5NHCH3 107.1548 8.26E+02 0.0000
CuCl 98.999 0.00E+00 41.6394
H2O 18.0152 9.73E+02 1.6880
Total 435.3028 3.58E+03 199.4750

Fv = 10.2838 m3/jam
Ca0 = 5.0613 kmol/m3
Cb0 = 10.1226 kmol/m3
M = 2.0000
3
Densitas Campuran = 1287.8801 Kg/m
Visco Campuran = 0.0813 Pa.Sec
Xa = 0.9000
Ca = 0.5061 kmol/m3
Cb = 5.5674 kmol/m3
T = 215.0000 oC
𝜏 = 0.5000 Jam
maka =

Levenspiel, page. 111

k = 0.091896592774874 m3/kmol.jam
(-rA) = 0.258950262654722 kmol/m3.Jam
1 Reaktor
Reaktor ke- Xa, N-1 Xa, N t (Jam)
1 0 0.9000 0.5000
total 0.5000

2 Reaktor
Reaktor ke- Xa, N-1 Xa, N t (Jam)
1 0.0000 0.7012 3.8852
2 0.7012 0.9000 3.8852
total 7.7704

3 Reaktor
Reaktor ke- Xa, N-1 Xa, N t (Jam)
1 0.0000 0.5709 2.0019
2 0.5709 0.7976 2.0019
3 0.7976 0.9000 2.0019
total 6.0058

http://matche.com/equipcost/Reactor.html
Jumlah Reaktor Volume (m3) Volume (gallon) Harga (US$)/Unit
1 5.14187920841 1358.34051424415 424000
2 39.3282 10389.419267872 1246400
3 61.7625 16315.9176920507 1583300

Dari hasil perhitungan diperoleh bahwa jumlah optimal dari penggunaan reaktor adalah sebanyak 2 reaktor
Jumlah = 1
Bahan = Stainless Steel
Waktu tinggal = 0.5000 Jam
120.1165 Menit

1. Perhitungan Volume dan Ukuran Reaktor

T = 215 C
P = 68,03 atm
t = 0.5 jam
Konversi = 0.9
a. Volume cairan dalam tangki
Vr = Fv x t
= 39.9543675347766 m^3
= 39954.3675347766 Liter

b. Volume Reaktor
Over design = 20%
Total Design = 120.00% 1.2
Volume Reaktor = 47.9452410417319
2. Menghitung Diameter dan Tinggi Reaktor
Bentuk = Silinder
Bahan = Stainless Steel
D:H = ( 1 : 2)

 2 
V D H  D3
4 4

4V
D  3

Maka,
D = 3.93695350297712 m
H = 7.87390700595423 m
in hidroksida

NM REAKTOR

Arus Masuk
Freshfeed Recycle
Arus 4 (C6H5Cl) Arus 13 ( Recycle MD )
kmol/jam kg/jam kmol/jam kg/jam
48.9356 5508.1188 3.1136 350.4602
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
1.5364 27.6790 0.0884 1.5923
50.4720 5535.7978 3.2020 352.0525
13244.2480975253

DATA DENSITAS

Tc Densitas
632.3500 0.87334
430.0500 0.91218 0.043169604 -0.02924866585665
0.0000 0.00000
647.1300 0.82592
0.0000 0.00000
461.1500 0.97273 0.080355781 -0.01096731330299

DATA VISKOSITAS

D Viskositas
0.0000 0.1751
0.0000 0.0145
 0.0000 0.0000
0.0000 0.2985
0.0000 0.0000
0.0000 0.1263

PERHITUNGAN KINETIKA

Fw (Laju Alir Massa) (kg) yi (Fraksi Massa) Fv (Laju Volumetrik) (m3) yi.ρ
5858.5790 0.2609 6.71E+00 2.28E+02
3233.0044 0.5219 3.54E+00 4.76E+02
0.0000 0.0000 0.00E+00 0.00E+00
0.0000 0.0000 0.00E+00 0.00E+00
4122.2544 0.2087 0.00E+00 0.00E+00
30.4103 0.0085 3.13E-02 8.23E+00
13244.2481 1.0000 10.28376 7.12E+02

1 Cp = 0.001 8.12788725620374E-05 kg/m2

OPTIMASI REAKTOR
 Volume (m3) t (Menit)
5.14187920841024 30
5.14187920841024 30

Volume (m3) t (Menit)

19.6641 233.1115
19.6641 233.1114
39.3282 466.2229

Volume (m3) t (Menit)

20.5875 120.1165
20.5875 120.1166
20.5875 120.1166
61.7625 360.3497

Harga Total Waktu

424000 0.5000
2492800 3.8852
4749900 2.0019

adalah sebanyak 2 reaktor

DESIGN REAKTOR
 Arus Keluar
Recycle
Arus 15 ( Recycle Centrifuge ) Arus 5
kmol/jam kg/jam kmol/jam kg/jam
0.0000 0.0000 5.2049 585.8579
7.1657 222.5473 10.4098 323.3004
0.0000 0.0000 46.8443 3162.8363
0.0000 0.0000 46.8443 5019.5887
28.6629 2837.5973 41.6394 4122.2544
0.0131 0.2356 1.6880 30.4103
35.8417 3060.3801 152.6307 13244.2481
13244.2481
V (L/Jam) Viscositas (µ) xi Visco x Fraksi Massa
6.71E+03 0.1751 0.4423 0.0774
3.54E+03 0.0145 0.2441 0.0035
0.00E+00 0.0000 0.0000 0.0000
0.00E+00 0.2985 0.0000 0.0000
0.00E+00 0.0000 0.3112 0.0000
3.13E+01 0.1263 0.0023 0.0003
1.03E+04 0.6144 1.0000 0.0813