Revision date: 24/03/2016 Revision: 4A

SAFETY DATA SHEET

CONPLAST SP439

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name CONPLAST SP439

Chemical name High Range water reducing admixture for concrete

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Superplasticizer for Cement & Concrete

1.3. Details of the supplier of the safety data sheet

Supplier Fosroc Chemical (India) Pvt. Ltd
Embassy Point, No 150, 2nd Floor,
Infantry Road,
Bangalore - 560001
+91 80 2355 1500/ 4252 1900
+91 80 2355 1510

1.4. Emergency telephone number

Emergency telephone +91 80 2355 1500/ 4252 1900

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Elicitation - EUH208

Environmental hazards Not Classified

Classification (67/548/EEC or -
1999/45/EC)

2.2. Label elements

Hazard statements EUH208 Contains FORMALDEHYDE. May produce an allergic reaction.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Move affected person to fresh air at once. Get medical attention if any discomfort continues.

Inhalation Move affected person to fresh air at once. Get medical attention. Move affected person to
fresh air and keep warm and at rest in a position comfortable for breathing. When breathing is
difficult, properly trained personnel may assist affected person by administering oxygen.

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Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Do not
induce vomiting. Remove affected person from source of contamination. Give plenty of water
to drink. Get medical attention immediately. Promptly get affected person to drink large
volumes of water to dilute the swallowed chemical.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention promptly if symptoms occur after
washing.

Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,
clothing or apron, as appropriate. Absorb in vermiculite, dry sand or earth and place into
containers. Avoid the spillage or runoff entering drains, sewers or watercourses.

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Provide adequate ventilation. Avoid inhalation of vapours. Use approved
respirator if air contamination is above an acceptable level. Avoid contact with skin and eyes.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only in
the original container.

Storage class Unspecified storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
FORMALDEHYDE
Long-term exposure limit (8-hour TWA): WEL 2 ppm 2.5 mg/m³
Short-term exposure limit (15-minute): WEL 2 ppm 2.5 mg/m³
METHANOL

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Long-term exposure limit (8-hour TWA): WEL 200 ppm(Sk) 266 mg/m3(Sk)
Short-term exposure limit (15-minute): WEL 250 ppm(Sk) 333 mg/m3(Sk)
WEL = Workplace Exposure Limit

Ingredient comments WEL = Workplace Exposure Limits

Proprietary (CAS: 68585-34-2)

DNEL Workers - Dermal; Long term systemic effects: 2750 mg/kg/day

Workers - Inhalation; Long term systemic effects: 175 mg/m³

PNEC Fresh water; 0,24 mg/l

marine water; 0,024 mg/l
Intermittent release; 0,071 mg/l
Sediment (Freshwater); 5,45 mg/kg
Sediment (Marinewater); 0,545 mg/kg
Soil; 0,946 mg/kg
STP; 10000 mg/l

FORMALDEHYDE (CAS: 50-00-0)

DNEL Workers - Inhalation; Long term systemic effects: 9 mg/m³

Workers - Inhalation; Long term local effects: 0,5 mg/m³
Workers - Inhalation; Short term local effects: 1 mg/m³
Workers - Dermal; Long term systemic effects: 240 mg/kg/day
Workers - Dermal; Long term local effects: 37 µg/cm2

PNEC - Fresh water, marine water; 0.47 mg/l

- STP; 0.19 mg/l
Water, Intermittent release; 4,7 mg/l
Sediment (Freshwater), Sediment (Marinewater); 2,44 mg/kg
Soil; 0,21 mg/kg

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.

controls

Eye/face protection The following protection should be worn: Chemical splash goggles.

Hand protection Use protective gloves.

Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact.

Hygiene measures Do not smoke in work area. Wash at the end of each work shift and before eating, smoking
and using the toilet. Promptly remove any clothing that becomes contaminated. Wash
promptly with soap and water if skin becomes contaminated. Use appropriate skin cream to
prevent drying of skin.

Respiratory protection No specific recommendations. Respiratory protection must be used if the airborne
contamination exceeds the recommended occupational exposure limit.

SECTION 9: Physical and chemical properties

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9.1. Information on basic physical and chemical properties

Appearance Liquid

Odour Odourless.

Odour threshold Not determined.

Melting point 0℃

Initial boiling point and range 100 ℃

Flash point Not applicable.

Evaporation rate Not determined.

Flammability (solid, gas) Not applicable.

Vapour pressure 2.3 kPa(water）

Relative density 1.22 -1.226

Solubility(ies) Soluble in water

Explosive properties Not considered to be explosive.

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information Not determined.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials

Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects No information available.

Acute toxicity - oral

ATE oral (mg/kg) 25,000.0

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Acute toxicity - dermal

ATE dermal (mg/kg) 202,702.7

Acute toxicity - inhalation

ATE inhalation (gases ppm) 472,972.97

General information No specific health hazards known.

Inhalation Not relevant at normal room temperatures.

Ingestion Ingestion of large amounts may cause unconsciousness.

Skin contact May cause an allergic skin reaction.

Eye contact May cause eye irritation.

Acute and chronic health Inhalation No specific health hazards known.

hazards

Route of exposure Inhalation Skin and/or eye contact

Target organs No specific target organs known.

Medical symptoms No specific symptoms noted, but this chemical may still have adverse health impact, either in
general or on certain individuals.

SECTION 12: Ecological information

12.1. Toxicity
12.2. Persistence and degradability
Persistence and degradability The degradability of the product is not known. This product is not expected to be readily
biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil

Mobility The product is miscible with water and may spread in water systems.

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects
Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information When handling waste, the safety precautions applying to handling of the product should be
considered.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

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14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009
No. 716).

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

Guidance Workplace Exposure Limits EH40.

Introduction to Local Exhaust Ventilation HS(G)37.
CHIP for everyone HSG228.
Approved Classification and Labelling Guide (Sixth edition) L131.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information The user must be instructed in the proper work procedure and be familiar with the contents of
these instructions.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 24/03/2016

Revision 4A

SDS number 23777

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Hazard statements in full H225 Highly flammable liquid and vapour.

H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H351 Suspected of causing cancer.
H370 Causes damage to organs .
EUH208 Contains FORMALDEHYDE. May produce an allergic reaction.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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