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Subject Index

A Avrami C
Equation 621 13
Abbe refractometry 799 C NMR 366
Exponent 622
Ab initio calculations 702 Capillary condensation 540
Azopolymer 528
ABS-braking 604 Carbon black 417–418, 442, 595–600,
Absolute units (cm 1 ), scattering 408, 602–604
B
413–415, 418–419 Carbon black formation 537, 542,
Absorption coefficient 943 Babinet compensator 800 543, 544
Activation energy 600, 1011 Ballistic cluster-cluster aggregation Carbon black networking 537
Acrylics 542 Carbon black processing 542, 543, 544
Structural adhesives 481 Ballistic deposition 543, 544 Carbon dioxide, supercritical 320,
Pressure-sensitive adhesives 483 Band assignment 395 328–334
Activation energy 218, 219 Barex 1017 Carbon nanotube composite fibers
Adhesive 477 Barrer 1014 Melt spun 586
Adhesive energy 529 Barrier properties 565 Solution spun 586
Adherend 477 Becke line technique 799 Electro-spun 586
Adhesive bond 477 Bending testing 432 Draw ratio 586
Adhesive joint 477 BET surface area 539 Carbon nanotube composite films
Adhesion 477 Beta-peptides 695 Pressing 586
Adhesion and van der Waals forces Beta relaxation 218, 391 Casting 586
477–478 Biaxial extension 555 Spinning 586
Adhesion and surface roughness 478 Binary blend phase diagrams 342 Carbon nanotubes 11, 583
Adhesion and diffusion Binding free energy 529 Type 583, 589
477–478 Binodal curve 340 Diameter 593
Adhesion and surface energy 477 Biodegradable polymers Mechanical properties 584
Adsorption 529 915–923 Enhancements in composites 588
Adsorption heat 545, 546 Biopolymers 695, 768, 769 Cardo polymer 1021
Adsorption of block copolymers 346 Birefringence 800 Carrrageenan 526
Air-oven test 910 Bisphenol A polysulfone 25 CCA-model 698
Alpha relaxation 391 Blends 408, 414, 416–417, 419 Cellulose 25, 526
Affine network 70 Block copolymers 378 Permeability 1016
Aggregate growth 542 Bond dissociation 905 Cellulose acetate 25, 404
AMBER force field 59 Bond reactivity 905 Permeability 1016
Amorphous carbon 545 Bond rotational potential 69 Solutions of, interaction
Amorphous polymers 607–609 Bond state probability 70 parameter x 235
Density 93–10 Bragg’s Law 407 Cellulose nitrate 25, 1016
Polymer-solvent interaction Braun-Kovacs equation 191 Solutions of, interaction
parameter x 233–257 Brittleness 442 parameter x 235
PVT Properties 91–101 Broadband Dielectric Spectroscopy Ceramic char 963
Amino acids 769 (BDS) 385 Ceramic composition 963
Amplitudon 393 Brownian dynamics 74 Ceramic conversion 977
Amylose 25, 526 Brownian motion 76 Ceramic precursors 958
Andrade creep 193 Buckingham potential 59 Boron-containg 975
Antenna effect 689 Buffer 524 SiC 961
Antiferromagnetism 763, 764 Building blocks for controlled structured Si3 N4 968
Antioxidant 909 materials 578 Ceramic yield 960
ASTM D542 799 Octafunctional POSS 578 CFF force field 60
Atacticity 366 Well-defined nanocomposite 578 Chain collapse 77
Atomic force microscopy (AFM) 523 Hydrosilylation reactions 578 Chain conformation 408
Atom transfer radical polymerization 5 Network structure 581 Chain depolymerization 903

1063
1064 / SUBJECT INDEX

Chain dimensions 407, 445 Contrast 408–411, 417 Density 553


Polyacrylics 448 For X-rays 413 Temperature dependence 93–96
Polydienes 447, 448 For neutrons 411, 413–414, 416 Pressure dependence 95, 98–100
Polymethacrylics 448 Conversion factors 1036 Density definition 607
Polyolefins 447 Copolymer architecture 950 Density fluctuations 410, 413
Temperature dependence 449, 450 Copolymerization 946 Density general trend 607
Thermoplastics 448, 449 Copolymers, solubility in supercritical Density measurement 609
Chain relaxation capability 423 fluids 323–326 Density values (table) 610–613
Chain stiffness 197 Correspondence principles 424, 432, Dendrimers, polymeric 18–20
Chain terminators 909 435, 440 Desorption 529
Chain with fixed bond angles 67 Co-solutes Deuterium labeling 417
Characteristic properties 200 Effect on theta temperature 283 Deuterium substitution effect on
Characteristic ratio 42, 51, 66–68, Core-shell model for polymer latexes thermodynamics 346
260, 445 413 Diads 365
Polyacrylics 448 Correlation length 414–415, 417 Diamagnetism 763
Polydienes 447, 448 Corresponding states theory 540 Diffused-constraint model 73
Polymethacrylics 448 2D-COSY 371 Diffusion 1009
Polyolefins 447 Coulomb forces 59, 764 Diffusion coefficient 1010, 1010, 1011
Characterization techniques 550 Coupling model 204 Doolittle viscosity equation 425
CHARMM force field 59, 61 Crack propagation 664 Dielectric properties 537
Chemical adsorption 524 Rapid 428 Differential scanning calorimetry 554
Chemical potential Slow 429 Dipolar coupling 362
Polymer solutions 233–234 Crankshaft motions 224, 230 Dipolar decoupling 375
Chemical shift 362 Crazes 427 Dipole CH-pi p interaction 701
Chemical shift anisotropy 373 Creep 433 Dipole moments 50, 52, 59
Chemically amplified photoresist 941 Recovery 434 Directly measured solid surface free
Chimeras 705 Creep compliance 193 energy 991
Chloroprene in rubber-based Critical molecular weight 446, 449 Dispersion 799
adhesives 482 Cross-coupling parameters 58 Dispersion of nanotubes 584
Class II force fields 60, 62 Cross-link density dependences 192, Melt mixing 584
Coefficient of thermal expansion 93, 194, 195 Sonication 584, 585
95, 97 Cross-polarization 375 In situ polymerization 584
Coexistence curves 321 Crystal structures 615 Stress concentration 585, 588
Collapse transition 78 Crystalline melting temperature 218 Surfactants 585
COMPASS force field 60, 62 Crystalline polymers 607–609 Functionalization 585
Compliance functions at Tg 204 Crystallinity 608, 609 Nitric acid 585
Composite interfaces, nanotubes Crystallization 410, 414, 416 Epoxide 585
Interfacial sdhesion 588, 589 Kinetics 621–636 Amine 585
Interfacial shear strength 590, 592 Cubic lattice 74 PMMA-grafted 585
Interfacial failure 592 Curie temperature 763, 764, 767 Entanglement 585
Polymer crystallization 591 CVFF force field 62 Bird’s nest 585
Differential scanning calorimetry 591 Cyclic polymers 12, 14–16 Dispersion quality 585
Nanotube-nucleated crystallinity 591 Optimum sonication 585
Polymer sheathing 591, 592 Dissolution inhibition 946, 951
D
Interfacial region 592 Dissolution properties 943
Composites 485, 486 Debye-Bueche model 414, 419 DL_POLY 62
Composition fluctuations 638, 642 Plot 414 DNA 695
Compressibility 95, 100 Decomposition temperature 912 DNA collapse 78
Compressive testing 431 Decoupling (heteronuclear) 367 DREIDING force field 60, 61
Compton scattering 409, 413 Decoupling (homonuclear) 366 Dual-mode sorption 1012, 1013
Concentration dependences 190 Definitions, 1027–1032 DUV (248 nm) resists 943, 948
Condis crystals 650 Degradation 903 Dynamic mechanical analysis 217, 438
Conditional bond state probability 70 Degradation: chemical factors Dynamic mechanical properties 557
Cone calorimeter 564 904, 905 Dynamic process 530
Configurational partition function 69, 71 Degradation mechanism 905, 906
Conformational asymmetry 638 Degradation monitoring 909, 910
E
Conformational partition function 44–45 Degradation: physical factors 904
Constants 1037 Degree of crystallinity 196 Elastic free energy 70
Constrained-chain model 73 Dehydroabietic acid (DHAA) 203 Elastic modulus 486
Constrained-junction model 72 Delta relaxation 391 Elastic scattering 408, 410
Contour length 525 Denaturation 701 Elastic stiffness tensor 766
SUBJECT INDEX / 1065

Elastomers 440 In-situ TEM straining 588 G


Electrets 767 Crack bridging 588
Gamma relaxation 221, 391
Electric field effects 660 Fatigue 439, 569
Gas permeability 218
Electric polarization 765, 767 Fatigue life 589
Gas solubility 1010
Electrochemical potential 528 Ferroelectric liquid crystals 768
Gauche effect 370
Electron microscopy 550 Ferroelectrics 767
Gauche states 370
Electronic wires 9 Ferromagnetic organic polymers 764,
Geminal coupling 366
Elongation 486 765
Genetic algorithm 77
Elongation at break 443, 444 Ferromagentism 763, 764
Gibbs-Adams-DiMarzio (GAD)
End-to-end distance 42, 50 Fick’s law 1010
Model 199
End-to-end distance in the melt 445 Fictive temperature 189
Gibbs free energy 233
Polyacrylics 448 Filler network 537, 595, 597–598,
Glass transition 217, 596, 597, 600
Polydienes 447, 448 600– 601, 603
Head -to-head chains 8
Polymethacrylics 448 Filler-filler bonds 697–698,
Glass transition temperature 187, 588,
Polyolefins 447 601–602
949, 1013
Thermoplastics 448, 449 Fillers 417, 549
Reduction by supercritical fluids 327,
End-to-end vector 42, 50, 66–68, 70 Fingerprinting 526
331–332
Energy conversion 528 Flame retardancy 563, 564
Glassy compliance 194
Engineering strain 431 Flexural strength 492
Glassy polymers
Engineering stress 430 Flexural modulus 492
Density 95, 96
Entanglement criterion 445, 446 Flexure testing 432
Tait equation 95, 99
Entanglement molecular weight 446 Flocculation 595, 597–598,
Glucose 526
Polyacrylics 448 601–604
Goldstone mode 391
Polydienes 447, 448 Flory approximation 85
Graphitic planes 545
Polymethacrylics 448 Flory theta temperature 234
Greek alphabet 1037
Polyolefins 447 Flory-Huggins free energy of mixing
Green tire 597
Temperature dependence 446 340, 700
GROMACS 61
Thermoplastics 448, 449 Flory-Huggins interaction
GROMOS force field 59, 61
Entanglement overlap parameter 446 parameter x 233–257, 339, 637
Guinier plot 409, 411, 413
Polyacrylics 448 Flory-Rehner 567
Gyromagnetic ratio 359
Polydienes 447, 448 Fluctuations of junctions 71, 72
Polymethacrylics 448 Fluorinated materials 700
H
Polyolefins 447 Fluorinated polybutadiene 355
Thermoplastics 448, 449 Fluorinated polyisoprene 355 Half-decomposition temperature 910
Entanglement strand volume 446 Fluorohectorite 568, 569, 570 Halpin-Tsai 561–563
Entanglements 446, 602 Foldamers 20, 696 Havriliak-Negami relaxation 385
Entanglements, trapped 602 Force curve 524 Head-to-head defects 5
Entropic interactions 700 Force field parameterization 57 Head-to-head polypropylene 353
EPDM 602–603 Force induced conformation Heat of condensation 1011
Epoxies as structural adhesives 481 transition 526 Heat of solution 1011
Epoxy resin curing 195, 196 Form factor 409, 411, 413 Heat capacity 145
Epoxy resins 193 Fourier transform (FT) 364, 365 Solid amino acids 105–111
Equation of state 321–326 Fox-Loshaek equation 193 Solid poly amino acids 113–132
E-SBR 600 Fractal analysis 537 Solid proteins 133–136
Ethyl cellulose 1016 Fractals 83 Heat-resistant polymers 905, 907–909,
Solutions of, interaction Fracture 911
parameter x 235–236 Brittle 437 Heat stabilizer 909
Ethylene-propylene copolymers Ductile 437 Hectorite 569
Growth kinetic coefficients 635 Mechanics 426 Hierarchical structures 654
Ethylene-vinyl acetate copolymer as a Free energy 697 Helical nomenclature 703
hot-melt adhesive 482 Free volume 1013 Henry’s law 1010, 1012, 1013
Ewald summation 58 Fracture test for adhesives 479 Henry’s law constant, polymer
Excluded volume effect 75 Freely-jointed chain 66, 525 melts 327–328
Exponents 85 Freely-rotating chain 67 Heptads 369
Free induction-decay (FID) 364, 365 2D-Hetcor 379
Free radicals 904 Hexafluorobisphenol-A
F
Free volume model 199 polycarbonate 1015
Failure mechanisms, nanotube Friction, static and dynamic 658 Hexafluoroisopropylpropylidene
composites Fullerene, dendrimer 12 group 222
Stress transfer 589 Fullerene, side chain 11, 12 HMDS 368
1
Pull-out 589 Fullerenes 543 H NMR 365
1066 / SUBJECT INDEX

Hot-melt adhesives 481 Kratky plot 415 Polymethacrylics 448


Hot-melt adhesive chemistry 481–482 Kuhn length 445, 525 Polyolefins 447
Hot-melt adhesive physical Polyacrylics 448 Thermoplastics 448, 449
properties 482 Polydienes 447, 448 Melting temperature, reduction by
Hydrogen bonding 59, 528 Polymethacrylics 448 supercritical fluids 327, 329–330
Hydrophilic interactions 700 Polyolefins 447 Meso placements 365
Hydrophobic interaction 531, 700 Mesomorphic phases 649
Hydroxypropyl celllose 26 L Meta-PE (phenylene ethynylene) 697
Solutions of, interaction Metallo-polymers 764
Ladder polymer 26, 905–907, 1021
parameter x 236 Methodology 524
LAMMPS 62
Hysteresis 566 Microgels 596, 598
Langevin equation 544
Microstructure 3
Langmuir adsorption isotherm 545
I Microtubules 769
Lap shear test for adhesives 478–479
Misnomers 608
I-line (365 nm) resists 943, 947 Larmor frequency 360
Mixing time 379
Immobilization 524 Lattice chain model 74
Modified freely jointed chain
Immobilized polymer 599 Lauritzen and Hoffman
(M-FJC) 525
Impact Secondary nucleation theory 622, 623
Modulus, intrinsic 596
Strength 443, 444, 486, 557 Growth rate equation 622
Modulus, shear 595, 596, 599
Testing 436 Lennard-Jones potential 58
Moisture absorption 218
Transition temperature 436 Lentz’s law 763
Molar refraction 799, 800
Incroprating 524 Light scattering 408, 411
Molecular conformation 615
Induced polarisation 386 Measurement of chain
Molecular dynamics 74, 385, 664
Inelastic scattering 408–410 dimensions 408
Molecular mechanics 59, 77, 702
Infrared 395, 553 Polarization effects 408
Molecular machine 527
In-situ generation of silica 549 Liquid crystals
Molecular modeling 702
Interaction parameter, polymer- Phases 653
Molecular models 199
solvent 233–257, 418, 419 Theory 662
Molecular recognition 696
Interfacial conformation 529 Liquid-crystalline polymers 390, 768
Molecular structure 197
Interfacial tension 989 Liquid state theory 642
Molecular weight dependence 192
Interfacial tension, polymers/supercritical Liquid surface tension 988
Molecular weights 943
fluids 329, 333 157 nm Lithography 943, 945, 946, 947
Monomer liquid crystals 650
Intermolecular forces 197 Living radical polymerization 5, 943
Monsanto FTF tester 569
Internal plasticization 197, 219 Long plateau 530
Monte Carlo method 57, 75, 76, 1013
Internet portals for materials 912–914 Loop structure 529
Montmorillonite
Inverse gas chromatography 234, 545 Lower critical temperature 260, 342
exchange capacity 560
Ion channels 769 Lubricants 442
structure 560
ISO489 799
Mooney viscosity 570
Isobaric expansivity 655 M
Mori-Tanaka 561–563
Isotacticity 365
Magic angle 363 Morphology 196
Isothermal compressibility 95, 100
Magic angle spinning (MAS) 375 Morse potential 58
Isothermal contraction below Tg 201
Magnetic field effects 442, 661 Multicomponent thermodynamics 348
Isothermal expansion below Tg 201
Mass density 607 Multifunctional materials 593
Isothermogravimetric analysis (IGA)
Mass fractal dimension 538, 542
910
Master curves 433, 435
Isotope effects 418–419 N
Master equation 74
Matrix of rotational transformation 68 Nanoindentation 442
J Mean heat release rate 564 Nanomechanics 532
James and Guth theory 71 Mechanical properties 485, 554 Nanoreinforced Poss-based Polymer and
acrylonitrile-butadiene rubber 570, 571 copolymers 575
butyl rubber 568–569 Monofunctional 576, 577
K
ethylene-propylene- dimer 571 Difunctional POSS 576, 577
Kapton 222 hydrogenated acrylonitrile-butadiene Physical Blending 575, 577
Kel-F 1016 rubber 570, 571 POSS-styrene system 576, 578
Kelly-Bueche equation 191 natural rubber 570, 571 POSS–polynorbornene 576, 578
Kevlar 226, 227 styrene-butadiene rubber 567 POSS–epoxy 576, 578
Kinetic cluster-cluster aggregation 537 thermoplastic 561–563 Siloxane–POSS 576, 578
Kirchhoff matrix 71 thermoset 565, 566 POSS–polyethelene 576, 578
Kohlrausch relaxation function 204 Melt density Polyurethane–POSS 576, 578
Kovacs-Aklonis- Hutchinson-Ramos Polyacrylics 448 Acrylate–POSS 576, 578
(KAHR) model 199 Polydienes 447, 448 Polyimide–POSS 576, 578
SUBJECT INDEX / 1067

Natural rubber Optical properties 943 Polyacetaldehyde 26


Compressibility 95, 98, 100 Optoelectronic materials 645 Polyacetylenes 26, 1020
Density 94, 96 Order-disorder transition 637 Polyacrylamide 26
Solutions of, interaction Osmotic pressure 234 Solutions of, interaction
parameter x 247 Oxidation rate 905 parameter x 236
Thermal expansion coefficient 97 Oxygen bridge 527 Polyacrylates 222
Thermal pressure coefficient 99 Poly(acrylic acid) 26
Néel temperature 763 Polyacrylonitrile 27, 400
P
Negative-tone photoresist 941 Permeability 1017
Network phases 644 Pair correlation function 408 Solutions of, interaction parameter x 236
Neutron Packing length 446 Poly(N- acryloylpyrrolidine)
Kinetic energy 408 Large 449 Solutions of, interaction
Spin 409 Polyacrylics 448 parameter x 236
Neutron scattering 408, 410, 419 Polydienes 447, 448 Poly(alkyl acrylate) 218, 219
Nicalon 960 Polymethacrylics 448 Poly(alkylene oxide) 227
NMR 552 Polyolefins 447 Poly(alkyl methacrylate) 219
NMR (phenomenon) 359, 360 Thermoplastics 448, 449 Poly(n-alkyl methacrylate) 220
2D-NMR 371 Paramagnetism 763 Poly(L-alanine) 27
2D-NOESY 371 Partial charge increments 62 Polyamides 27
Nomex 226 Partial Volume of amino acids 112 Avrami coefficients 628
Nonbonded parameters 62 Payne effect 537, 599–600, 602 Compressibility 95, 98, 100
Nonelectrostatic contribution 531 Pauli exclusion principle 764 Density 94, 96
Nonlinear optical effects 661 PCFF force field 62 Growth kinetic coefficients 632
Normal modes 388 Peak heat release rate 564 Permeability 1018
Normalization 525 Peel test for adhesives 479 Phenyl-substituted 1017
Nuclear Overhauser enhancement Pentads 368 Second relaxations 226
(NOE) 367 Percolation 87, 537 Thermal expansion coefficient 97
Nuclear polarization 367 Permeability 1009, 1013 Polyamide imide 27, 218, 222, 223
Nuclear precession 360 Permeability coefficient 1010, 1013 Poly(amino acids) 34, 917, 923
Nuclear properties 360 Permeation 1009 Poly(6–aminocaproamide) 46
Nuclear shielding 361 Phantom network 71 Polyanhydrides 917, 920–921
Nuclear spin coupling 362 Phase diagrams, polymers/supercritical Thermal properties 917
Nucleation, homogeneous and fluids 321 Polyaniline 27
heterogeneous 622 Phases 485 Polyarylates 60, 218, 228, 229,
Nylon-6 404 Phason 393 1015, 1020
Dynamic mechanical properties 225 Photoacid generator 951 Polyarylene-ether- ether-biphenylsulfide
Permeability 1017 Photolithography process 941 Avrami coefficients 631
Nylon-6, 6 Photonic wires 9 Polyarylene-ether-ether-phenylsulfide
Dynamic mechanical properties 225 Photoresist polymer platforms 943 Avrami coefficients 630
Permeability 1017 Photoresist polymers 941 Growth kinetic coefficients 634
Nylon 11 766, 768, 1017 Phthalocyanine, main-chain Poly(aryl ether) 1020
Nylons polymer 9–11 Poly(aryl ether ether ketone) 60, 228
Compressibility 95, 98, 100 Phthalocyanine, side-chain polymer 9–11 Avrami coefficients 629
Density 94, 96 Physical adsorption 524 Growth kinetic coefficients 633
Thermal expansion coefficient 97 Physical aging 190 Poly(aryl ether ketone) 227, 1020, 1021
Physical properties 486 Polyarylether sulfone 1019
Piezoelectric coefficient 765, 766, 767 Polybenzimidazole 27, 60
O
Piezoelectricity 765, 766 Polybenzobisoxazole 27
Occluded rubber 596 Pivot algorithm 76 Polybenzobisthiazole 27
Off-lattice chain model 74 Plastic crystals 650 Polybenzoxazoles 60
Oligo (poly(ethylene glycol) Plasticization 1013 Polybenzoxazine 49
fumarate) 921, 922 Plateau modulus 446 Poly(g-benzyl-L-glutamate) 28
Oligomers 697 Polyacrylics 448 Polybutadiene, syndio
OPLS force field 61 Polydienes 447, 448 Avrami coefficients 631
Orientation of nanotubes 587 Polymethacrylics 448 Growth kinetic coefficients 634
X-ray diffraction 587 Polyolefins 447 Polybutadienes 28, 46, 352, 397, 411,
Raman spectroscopy 587 Temperature dependence 446 413, 416, 419, 596
Waviness 587, 589 Thermoplastics 448, 449 Force field parameters 60
Orientational polarisation 386 Polyacetal 26 Permeability 1015
Optical configuration parameter 800 Polarizability 799, 800 Solutions of, interaction
Optical data storage 662 Polarization 59, 198, 409 parameter x 236–237
1068 / SUBJECT INDEX

Poly(1,4-trans-butadiene) 46 Poly(chloroethyl methacrylate) 219 Poly(diphenyl siloxane) 30, 46


Poly(butene-1) 28, 46 Poly(1-chloro-2- phenylacetylene) 1020 Poly(2,6-diphenyl-1,4-phenylene
Avrami coefficients 628 Poly(chloropropyl methacrylate) 219 oxide) 223, 223
Compressibility 95, 98, 100 Polychloroprenes 29, 1015 Polydispersivity 86
Density 94, 96 Solutions of, interaction Poly(3-dodecylthiophene) 1020
Growth kinetic coefficients 632 parameter x 239 Polyelectrolyte 530
Solutions of, interaction Poly(o-chlorostyrene) Polyepichlorohydrin
parameter x 237 Solutions of, interaction Solutions of, interaction
Thermal expansion coefficient 97 parameter x 239 parameter x 242
Poly(tert-butylacetylene) 1020 Poly(p-chlorostyrene) 48, 224 Polyetheretherketone 30
Poly(n-butyl acrylate) 218, 220 Solutions of, interaction Compressibility 95, 98, 100
Poly(butylene adipate) parameter x 239 Density 94, 96
Avrami coefficients 631 Polychlorotrifluoro ethylene 29 Thermal expansion coefficient 97
Solutions of, interaction Avrami coefficients 628 Polyester-amide
parameter x 237 Growth kinetic coefficients 632 Avrami coefficients 631
Polybutylene-isophthalate Poly(cyclohexyl acrylate) 218, 220, 354 Growth kinetic coefficients 634
Avrami coefficients 631 Poly(cyclohexyl methacrylate) 220 Polyesters 30
Polyethylene-naphthalate Compressibility 95, 98–100 Aromatic 62
Avrami coefficients 631 Density 94–96 Nematic 229
Growth kinetic coefficients 633 Thermal expansion coefficient 97 Poly(ortho esters) 917, 919–920
Poly(butylene oxide) 353 Poly(10-decanoate) 29 Thermal properties 917
Polybutylene terephthalate 28, 228, 229, Polydichlorophosphazene 46 Mechanical properties 917
354 Poly(N,N-diethylacrylamide) Polyetherimide 222, 223
Avrami coefficients 629 Solutions of, interaction Polyether ketone 30, 227, 228
Poly(n-butyl methacrylate) 219 parameter x 240 Poly(ether ketone) 1020
Compressibility 95, 98, 100 Poly(diethyl siloxane) 29 Polyethersulfone 1019
Density 94–96 Poly(N,N-dimethylacrylamde) Polyether sulfone 30, 60, 222, 224, 225
Solutions of, interaction Solutions of, interaction Polyethers
parameter x 237 parameter x 240 Compressibility 95, 98, 100
Thermal expansion coefficient 97 Poly(dimethyl butadiene) 1015 Density 94–96
Polycaprolactam 28, 617 Poly(3,3-dimethyloxetane) 46 Solutions of, interaction parameter
Avrami coefficients 628 Poly(2,6-dimethylphenylene ether) 220, x 244–245, 252–253
Compressibility 95, 98, 100 223, 353, 378 Thermal expansion coefficient 97
Crystal structure 617 Compressibility 95, 98–100 Thermal pressure coefficient 99
Density 94, 96 Density 94–96 Poly(N-ethylacrylamide)
Thermal expansion coefficient 97 Thermal expansion coefficient 97 Solutions of, interaction
Unit cell 617 Polydimethylsilmethylene 45 parameter x 243
X-ray diffraction 617 Polydimethylsiloxane 29, 45, 46, 354, Poly(ethyl acrylate) 218
Polycaprolactone 28, 917, 918–919 398 Polyethylene 30, 41, 44, 45, 46, 53, 353,
Compressibility 95, 98, 100 Compressibility 95, 98, 100 395, 408, 410–414, 416, 419, 615
Density 94, 96 Density 94, 96 Avrami coefficients 628
Growth kinetic coefficients 632 Force field parameters 60 Carbon-filled 417–418
Mechanical properties 917 Permeability 1016 Compressibility 95, 98, 100
Solutions of, interaction Solutions of, interaction Crystal structure 615
parameter x 237–238 parameter x 240–242 Density 94, 96
Thermal expansion coefficient 97 Thermal expansion coefficient 97 Growth kinetic coefficients 632
Thermal properties 917 Thermal pressure coefficient 99 Linear low density 229, 230
Polycarbonate 29, 49, 53, 380, 403 Poly(dimethylsilmethylene) 1017 Permeability 1014
Compressibility 95, 98–100 Polydimethylsilylene 46 Phases 615
Density 94–96 Polydimethylsilylenemethylene 46 Secondary relaxations 60, 229, 230
Dielectric measurements 220 Poly(3,3-dimethylthietane) 46 Solutions of, interaction
Dynamic mechanical properties 220 Polydioxanones and polyoxalates 922 parameter x 243–244
Force field parameterization 60, 62 Poly(dioxepane) Thermal expansion coefficient 97
Permeability 1015 Density 94 Thermal pressure coefficient 99
Secondary relaxation 218, 221 Poly(1,3-dioxocane) Unit cell 615
Semiemprical MO calculations 221 Solutions of, interaction X-ray diffraction 615
Solutions of, interaction parameter x 242 Poly(ethylene adipate)
parameter x 238–239 Poly(1,3-dioxolane) 46 Solutions of, interaction
Tetrasubstituted 220 Density 94, 96 parameter x 244
Thermal expansion coefficient 97 Thermal expansion coefficient 97 Poly(ethyl butylene) 353
Polycarbosilane 957, 963 Poly(diphenylacetylene) 1020 Poly(ethylene imine) 30
SUBJECT INDEX / 1069

Poly(ethylene-2,6-napthalene Poly(4-hydroxystyrene) 942, 943 Polymer-solvent interaction


dicarboxylate) 1021 Solutions of, interaction parameter x 233–257
Ethylene-octene copolymers parameter x 245 Poly(methacrylamide)
Growth kinetic coefficients 634 Polyimides 31 Solutions of, interaction
Poly(ethylene oxide) See also, Avrami coefficients 631 parameter x 247
polyoxyethylene 30, 353, 403 Force field parameters 60 Poly methacrylates 60, 219
Compressibility 95, 98, 100 Secondary relaxations 223 Tacticity 6
Density 94, 96 Polyisobutylene 31, 60, 1014 Poly(methacrylic acid) 32
Force field parameterization 60, 62 Compressibility 46, 95, 98, 100, 353 Solutions of, interaction
Permeability 1019 Density 94, 96 parameter x 248
Solutions of, interaction Solutions of, interaction Poly(methacrylonitrile) 1017
parameter x 244–245 parameter x 245–247 Poly(methyl acrylate) 32, 48, 218, 220
Thermal expansion coefficient 97 Thermal expansion coefficient 97 Solutions of, interaction
Thermal pressure coefficient 99 Thermal pressure coefficient 99 parameter x 248–249
Poly(ethylene succinate) Poly(isobutyl methacrylate) 219, 220 Poly(methylethylsiloxane) 1016
Solutions of, interaction Polyisocyanate 31 Poly(methyl methacrylate) 33, 48, 53,
parameter x 245 Polyisocyanide 32 354, 365, 401
Poly(ethylene terephthalate) 31, 399, 617 3,4-Polyisoprene 352, 387 Beta relaxation 220
Avrami coefficients 629 Poly(cis-isoprene) 32, 46, 352, 398. 596 Compressibility 95, 98–100
Compressibility 95, 98, 100 Avrami coefficients 629 Density 94–96
Crystal structure 617 Compressibility 95, 98, 100 Force field parameterization 60
Density 94, 96 Density 94, 96 Permeability 1020
Dynamic mechanical properties 228 Force field parameterization 60 Solutions of, interaction
Force field parameters 60 Growth kinetic coefficients 633 parameter x 249
Growth kinetic coefficients 633 Permeability 1015 Secondary relaxations 219, 220
Permeability 1015 Solutions of, interaction Stereo complex 5
Secondary relaxations 229 parameter x 247 Thermal expansion coefficient 97
Thermal expansion coefficient 97 Thermal expansion coefficient 97 Poly(methyloctylsiloxane) 1016
Unit cell 617 Thermal pressure coefficient 99 Poly(4-methyl pentene-1) 33, 1014
X-ray diffraction 617 Poly(trans-isoprene) 32, 46 Compressibility 100
Poly(ethyl methacrylate) 220 Avrami coefficients 629 Density 94, 96
Density 94–96, 1020 Growth kinetic coefficients 633 Thermal expansion coefficient 97
Thermal expansion coefficient 97 Poly(N-isopropylacrylamide) Poly(methyl phenyl siloxane) 48, 386
Poly(ethylmethyl siloxane) 354 Solutions of, interaction Poly(methyl phenyl silylene) 48
Poly(ferrocenyl dimethylsilane) 354 parameter x 247 Poly(methylpropylsiloxane) 1016
Polyglycine 31 Polylactam 32 Poly(a-methyl styrene) 33, 48, 224, 352
Poly(glycolic acid) 915–916, 917 Poly(lactic acid) 49, 399, 916, 917, Solutions of, interaction
Thermal properties 917 1020 parameter x 249
Mechanical properties 917 Thermal properties 917 Poly(o-methyl styrene)
Poly(hexamethylene adipamide) 31 Mechanical properties 917 Compressibility 95, 98–100
Polyhexamethylene adipate) 618 Poly(lactic-co-glycolic acid) Density 94–96
Crystal structure 618 copolymers 916–918 Thermal expansion coefficient 97
Unit cell 618 Thermal properties 917 Poly(p-methyl styrene) 34, 224, 352
X-ray diffraction 618 Mechanical properties 917 Polymethylene See polyethylene
Poly(hexamethylene oxide) 46 Poly(lactic acid) 49, 399 Poly(methylene oxide) 33
Poly(hexamethylene sebacamide) 31 Poly(DL-lactide) Poly(methyl phenyl siloxane) 33
Poly(hexamethylene sebacate) Solutions of, interaction Polynitrile 34
Solutions of, interaction parameter x 247 Polynorbornenes 1021
parameter x 245 Polylactone 32 Polynucleotides 34
Poly(p-hydroxybenzoic acid) 60 Polymer blends 379, 943 Tacticity 7
Poly(hydroxybutyrate) 31, 405 Polymer bridge 524 Polyolefins 1014
Density 96 Polymer chain packing 380 Poly(oxy-1,1-dimethylethylene) 46
Growth kinetic coefficients 632 Polymer conformations (solid) 376 Poly(oxybutylene)
Poly(3-hydroxybutyrate), Polymer conformations (solution) 370 Compressibility 95, 98, 100
copolymer 917, 921 Polymer latexes 413 Density 94, 96
Thermal properties 917 Polymer liquid crystals 650 Solutions of, interaction
Mechanical properties 917 Classification 651, 652 parameter x 252–253
Poly(alpha-hydroxy esters) 915–918 Polymer mobility, dynamics 377, 381 Thermal expansion coefficient 97
Poly(2-hydroxyethyl methacrylate) 220 Polymer morphology 377 Poly(oxyethylene) 45, 46, 237, 1021
Solutions of, interaction Polymer solubility 663 Avrami coefficients 629
parameter x 245 Polymer solutions 408, 410–411 Compressibility 95, 98, 100
1070 / SUBJECT INDEX

Poly(oxyethylene) (Continued) Secondary nucleation analysis 627 Density 94–96nm


Density 94, 96 Secondary relaxations 230 Force field parameterization 60
Growth kinetic coefficients 633 Solutions of, interaction Growth kinetic coefficients 634
Thermal expansion coefficient 97 parameter x 249–250 Permeability 1015
Solutions of, interaction Syndiotactic 5 Secondary relaxations 224
parameter x 244–245 Tacticity 7 Solutions of, interaction
Thermal pressure coefficient 99 Thermal expansion coefficient 97 parameter x 250–252
Poly(oxymethylene) 45, 46, 618 Thermal pressure coefficient 99 Syndiotactic 5
Avrami coefficients 630 Unit cell 616 Tacticity 8
Compressibility 95, 98, 100 X-ray diffraction 616 Thermal expansion coefficient 97
Crystal structure 618 Poly(propylene fumarate) 917, 921, 922 Thermal pressure coefficient 99
Density 94, 96 Thermal properties 917 Polysulfide 37
Growth kinetic coefficients 633 Mechanical properties 917 Polysulfones 402
Thermal expansion coefficient 97 Poly(propylene fumarate-co-ethylene Compressibility 95, 98–100
Unit cell 618 glycol) 917, 921, 922 Density 94–96
X-ray diffraction 618 Thermal properties 917 Permability 1019
Polyoxypropylene Mechanical properties 917 Silyl-modified 101
Avrami coefficients 630 Poly(propylene glycol) 36 Thermal expansion coefficient 97
Growth kinetic coefficients 633 Poly(propylene oxide) 36, 48, 60, 227 Polysulfur 37
Poly(pentamethylene sulfide) 46 Poly(propylene sulfide) 48 Polytetrafluoroethylene 37, 46, 53,
Poly(n-pentene-2) 34 Polypropylene-terephthalate 397, 619
Poly(n-pentene-1) 34 Avrami coefficients 629 Avrami coefficients 630
Poly(n-pentyl methacrylate) 354 Poly(n-propyl methacrylate) 220 Compressibility 95, 98, 100
Poly(phenyl acrylate) 48 Polypyrazine 36 Crystal structure 619
Poly(phenylmethylsiloxane) 1017 Polypyrazole 36 Density 94, 96
Poly(phenyl sulfone) 1019 Polypyrrolones 1021 Dynamic mechanical properties 220
Poly[1-phenyl-2-p-(triisopropylsilyl) Polypyromellitimide 222 Growth kinetic coefficients 634
phenyl acetylene] 1020 Poly(pyromellitimide-1, 4-diphenyl Permeability 1016
Poly(p-phenylene) 34, 60 ether) 36 Phases 619
Poly(p-phenylene isophthalate) 60 Polypyrrole 36, 49, 60 Secondary relaxations 218, 224, 225
Poly(p-phenylene oxide) 35, 222, 223, 1019 Polyquinoxaline 36 Thermal expansion coefficient 97
Poly(p-phenylene sulfide) 35, 60, 230 Polyrotaxanes 13, 17, 60 Unit cell 619
Avrami coefficients 630 Glass temperature 690, 691, 692, X-ray diffraction 619
Growth kinetic coefficients 633 693, 694 Polytetrafluoroethylene-
Poly(m-phenylene terephthalamide) 33 Melt viscosity 692, 693 co- hexafluoropropylene 1016
Poly(p-phenylene terephthalamide) 34, 620 Solubility 689, 693 Polytetrahydrofuran
Crystal structure 620 Solution viscosity 690, 691, 692, Compressibility 95, 98, 100
Unit cell 620 693, 694 Density 94, 96
X-ray diffraction 620 Structures 689, 690, 691, 693 Solutions of, interaction
Poly(p-phenylene terephthalate) 60 Polysaccharide 526 parameter x 252–253
Poly(p-phenylene vinylene) 35 Polysilane 36, 46, 60 Thermal expansion coefficient 97
Polyphenylsulfone 35 Polysilapropylene 48 Poly(tetramethylene oxide) 37, 46, 227
Polyphosphate 35 Polysilastyrene 48 Compressibility 95, 98, 100
Polyphosphazenes 35, 60. 921, 1020 Polysilazane 37 Density 94, 96
Thermal properties 917 Poly(silethylenesiloxane) 1017 Solutions of, interaction
Mechanical properties 917 Poly(silhexylenesiloxane) 1017 parameter x 252–253
Polyphosphonate 35 Poly(siloctylenesiloxane) 1017 Thermal expansion coefficient 97
Polypivalolactone Polysiloxanes 37 Polytetramethyl-p-silphenylene-siloxane
Growth kinetic coefficients 633 Compressibility 95, 98, 100 Growth kinetic coefficients 634
Poly(3-propionate) 35 Density 94, 96 Polythiaethylene 46
Polypropylene 35, 48, 53, 353, 366, Solutions of, interaction Polythiazyl 37
397, 616 parameter x 240–242 Polythienyl vinylene 37
Avrami analysis 626, 630 Thermal expansion coefficient 97 Poly(thiodiethylene glycol) 46
Compressibility 95, 98, 100 Thermal pressure coefficient 99 Polythiopene 38
Crystal structure 616 Poly(m-silphenylenesiloxane) 1017 Poly(trifluorochloroethylene) 1016
Density 94, 96 Poly(p-silphenylenesiloxane) 1017 Polytrifluoroethylene 48
Force field parameters 60 Polysilylenemethylene 46 Poly(trifluoropropylmethylsiloxane)
Growth rate-crystallization Polystyrene 37, 48, 352, 376, 402, 1016
temperature 627, 634 411–412, 414, 417–418, 596 Poly(1-trimethylgermyl-1-propyne) 1020
Isotactic 230 Avrami coefficients 630 Poly(tri methylene ethylene urethane) 38
Permeability 1014 Compressibility 95, 98–100 Poly(trimethylene oxide) 45, 46
SUBJECT INDEX / 1071

Poly(trimethylene sulfide) 46 Thermal expansion coefficient 97 ReaxFF 62


Polytrimethylene-terephthalate Thermal pressure coefficient 99 Reduced residual chemical potential 23
Avrami coefficients 629 Poly(N-vinyl pyrrolidone) 404 Reference volume 340
Growth kinetic coefficients 633 Solutions of, interaction Refractive index 799, 800, 943
Poly[1-(trimethylsilyl)-1-propyne] 60, parameter x 255 Refractory materials 960
1013, 1020 Poly(p-xylylene) 40 Regime plot/Secondary nucleation
Poly(4-trimethylsilyl styrene) 352 Porod’s law 415, 419 plot 623, 624
Polyurea 38 Porphyrin, main-chain polymer 9–11 Reinforced composites 645
Polyurethanes 38, 60, 405 Porphyrin, side-chain polymer 9–11 Reinforcement 595–599, 601–604
Amine-containing 1019 Positron annihilation lifetime Reinforcement, hydrodynamic 595, 596,
Permeability 1019 spectroscopy 568 601, 602
Poly(urethane urea) 1019 Polyhedral Oligomeric Silsesquioxane Relative density 607
Poly(L-valine) 38 (POSS) 575 Relaxation processes 217
Poly(«-valerolactone) Three-dimensional inorganic/organic Reliability 423
Solutions of, interaction hybrids 575 Reptation theory 79
parameter x 253 POSS cages 575 Retardation functions at Tg 207
Poly(vinyl acetate) 38, 48, 401, 1015 Trifunctional organosilicon Retardation spectrum 201
Compressibility 95, 98–100 monomers 575 Rheology 567, 658
Density 94–96 POSS-trisilanols 575 RNA 695
Solutions of, interaction Corner capping 575 Rod-coil copolymers 645
parameter x 253–254 Multifunctional POSS ROMP polymers 1021
Thermal expansion coefficient 97 derivatives 575, 578 Rotational isomeric state model 41–55,
Poly(vinyl alcohol) 38, 48, 400, 1015 Positive-tone photoresist 941 69
Solutions of, interaction Preceramic polymers 958 Rouse bead and spring model 74, 77
parameter x 255 Pressure effects 197 Rubber-based adhesive chemistry 482
Poly(vinyl benzoate) 1015 Pressure-sensitive adhesive Rubber-based adhesive physical
Poly(vinyl bromide) 48 chemistry 483 properties 483
Poly(tert-butyl vinyl ketone) 48 Pressure-sensitive adhesive physical Rubber-based adhesives 482
Poly(vinyl butyral) 38 properties 484
Poly(vinyl carbazole) 39, 48 Pressure-sensitive adhesives 483
S
Poly(vinyl chloride) 39, 48, 399, 766 Pressure-volume-temperature data
Compressibility 95, 98–100 Amorphous polymers 93–101 Sanchez-Lacombe lattice fluid equation of
Dynamic mechanical properties 225, Properties of polymers reinforced with state 321
226 silica 549 SANS (small angle neutron
Force field parameterization 60 Protein folding 78 scattering) 596–597
Density 94, 96 Pseudopoly(amino Acids) 917, 923 Saturated 3,4-polyisoprene 353
Permeability 1015 Thermal properties 917 Saturated polybutadiene 353
Solutions of, interaction Mechanical properties 917 Saturated polyisoprene 353
parameter x 255 Pyroelectric coefficient 766 Saturated polystyrene 352
Thermal expansion coefficient 97 Pyroelectricity 766 Saw-tooth pattern 529
Poly(vinyl fluoride) 39, 48, 766 Pyrolysis 958 Scalar J-coupling 363
Poly(vinyl formal) 39 Pyrolyzability 958 Scattering
Poly(vinyl methyl ether) 48, 353 Calibration 408, 412, 415
Poly(2-vinyl pyridine) 39, 48, 352 Q Neutrons 408, 410, 419
Poly(4-vinylpyridine) 1021 X-rays 408, 418
Quantum yield 952
Poly(N-vinyl pyrrolidone) 39, 48 Scattering cross section
Quasi-liquids 654
Polyvinylidene bromide 46 Absorption 409
Poly(vinylidene chloride) 39, 46, Bound atom 409
R
53, 1015, Coherent 409–413, 418
Poly(vinylidene fluoride) 40, 46, 60, Racemic placements 365 Differential 408, 412
765–768, 1015 Radial distribution function 408 Hydrogen 409–410
Avrami coefficients 631 Radio frequency 364 Incoherent 409–410, 413, 418
Compressibility 95, 98, 100 Radius of gyration 42, 50, 66–68, 341, Single atom 409
Density 94, 96 408, 411–412 Total 409–410, 415
Growth kinetic coefficients 634 Random deposition 543, 544 Scattering form factor 73
Thermal expansion coefficient 97 Random-phase approximation (RPA) 418 Scattering function 52
Poly(vinyl methyl ether) 60, 403 Random scission 903 Scattering length 411, 413
Compressibility 100 Random walks 83 Scattering length density
Density 94, 96 Rate of cooling 188 Neutron 413–414, 416–418
Solutions of, interaction Rayleigh ratio 408, 411 Photon (X-ray) 416, 418
parameter x 255 Reactive ion etch 952 Scattering techniques 551
1072 / SUBJECT INDEX

Scratch resistance 658 Spin-diffusion 377 Tetramethylbisphenol-A


Screening effect 531 Spin-diffusion coefficient (D) 378 polycarbonate 221, 354, 1015
Second virial coefficients 234 Spin-lattice (longitudinal) relaxation Tetramethyl bisphenol-A
Secondary relaxations 217 (T1 ) 361,377 polysulfone 1019
Segmental mode 388 Spin-spin (transverse) relaxation (T2 ) 361 Theoretical models, nanotube
Self assembly 20 Spinodal curve 340 composites 589
Self-avoiding walks 84 Square lattice 75, 76, 77 Rule-of-mixtures 590
Self-consistent field theory 341 S-SBR 597–600, 603 Halpin-Tsai equations 590
Selenium Star-branched poly(cis-1,4-isoprene) 391 Krenchel rule-of-mixtures 591
Avrami coefficients 630 Static gas adsorption 537, 539, 545 Effective modulus 591, 593
Growth kinetic coefficients 634 Statistical Associating Fluid Theory 321 Short fiber composite theory 592
Semicrystalline polymer 608 Statistical weight matrix 43–44, 69 Thermal conductivity 155
Semiflexible chains 77 Stimuli-responsive polymer 527 Definition 155
Separation factor 1011 Strain tensor 765 Effect of
Separation media 645 Stress at break 443, 444 Chain orientation 159
Service performance 423 Stress concentration factor 426 Density 155
Shear 556 Stress-optical coefficient 800 Filler 159
Shear alignment 644, 645 Stress relaxation 432 Temperature 155, 159
Shear yielding 428 Stress softening 595, 601–604 Thermal conductivity units 155
Shoulder-like plateau 526 Stretching velocity 530 Thermal conductivity of foamed
Silanization 524 Strong segregation limit 638 polymers 155, 160
Silica 595, 597–604 Structural adhesive Thermal conductivity of particle
Silicon carbide (SiC) 960 Chemistry 481 reinforced polymers 159, 161–162
Silicon nitride (Si3 N4 ) 960 Physical properties 480 Thermal conductivity of polymers 156
Single chain elongation 525 Structural adhesives 480 Epoxides 156
Single molecule force spectroscopy Styrene-butadiene 596–597, 600 Halogenated olefin polymers 156
(SMFS) 523 Substituent effects 370 Hydrocarbon polymers 157
Slip-link model 73 Substituent reaction 903, 904 Phenolic resins 158
Small-angle neutron scattering Surface activity 545 Polyamides 156
(SANS) 408 Surface anisotropy 544 Polycarbonates 156
Contrast factors for crystalline Surface area/volume ratio 591, 593 Polyesters 156
polymers 411 Surface diffusion 543, 544 Polyimides 157
Small-angle X-ray scattering (SAXS) 408 Surface energy distribution 545, 546 Polyethers 156
Contrast factors for crystalline Surface fractal dimension 538, 539, 540, Polyketones 156
polymers 411 541, 543, 544 Polysaccharides 158
Small-angle scattering 637 Surface growth 538, 542, 543, 544 Polysiloxanes 158
Soft mode 391 Surface roughness 538, 539, 542, Polysulfide 158
Solid-liquid interface 528 543, 545 Polysulfones 158
Solubility Surface tension 540, 541, 542 Polyurethanes 158
Coefficient 1010, 1011 Swelling 441 Vinyl Polymers 158, 159
Polymers in supercritical Symmetry influence 199 Thermal conductivity of thermally-
fluids 320–326 Syndiotacticity 365 conductive polymer
Supercritical fluids in polymers 321, composites 159, 161–162
327–328 Thermal contraction coefficient 189
T
Solubility Thermal expansion coefficient 93, 95, 97,
Solid surface properties 991 Tackifiers in hot-melt adhesives 482 554, 766
Solids NMR 372 In pressure-sensitive adhesives 483 Thermal pressure coefficient 95, 99
Solubility parameter 346 In rubber-based adhesives 482 Thermal properties 553
Solution–diffusion mechanism 1009 Tacticity 4, 199, 411 Thermal stability 903, 911
Solutions Tait equation 95, 98–99 Thermal volatilization analysis
Flory-Huggins theory 233 Tear strength 557 (TVA) 910
Polymer-solvent interaction Teflon-FEP 1016 Thermodynamic parameters of
parameter 233–257 Tensile modulus 443–4, 656 hydration 141–142
Theta temperature 234 Tensile strength 486, 656 Thermodynamic properties
Solvophobic interactions 700 Tensile testing 430 Polymer-solvent interactions 233–257
Space groups 615 Tertiary structure 696, 705 Proteins 138–140
Specific gravity 607 Tetrachlorobisphenol-A PVT data for amorphous
Specific surface 415 polycarbonate 221 polymers 93–101
Specific extinction area 564 Tetrads 366 Thermoelastic measurements 450
Specific volume, 93, 189 Tetramethylhexafluorobisphenol-A Thermogravimetric analysis 553
Specific weight 607 polycarbonate 1015 Thermomechanical analysis (TMA) 910
SUBJECT INDEX / 1073

Thermoplastic elastomer 644 TMS 362 Viscoelastic behavior at Tg 202


Thermoplastics 492 Tool-Narayanaswamy-Moynihan (TNM) Viscoelastic functions of polystyrene,
Thermoset 492 model 199 high molecular weight 206
Theta temperature 234, 259–287 Tortuous path model 565 Viscoelastic functions of polystyrene, low
Definition 260 Torlon 222 molecular weight 205
Poly(alkanes) 261–264 Toughness 588 Viscoelasticity 438
Poly(alkenes) 264–266 Train-like conformation 530 Viscosity, reduction by supercritical
Poly(butene-1) 261 Trans states 371 fluids 329, 334
Polyethylene 261 Transmission Electron Microscopy 637, Volume-temperature dependence 188
Polyisobutylene 262 644
Poly(pentene-1) 263 Transparency 553 W
Polypropylene 263 Triads 366
Polybutadiene 264 Tribology 444, 657, 658 Water absorption 553
Polyisoprene 265 Trifluoroacetylated ethyl cellulose 1016 Weak segregation limit 642
Poly(vinyls) 266, 267 TRIPOS force field 61 Weight density 607
Poly(vinyl acetate) 266 True stress 664 Wide-angle neutron scattering
Poly(vinyl alcohol) 266 Tube diameter 446 (WANS) 407–408
Poly(vinyl chloride) 267 Polyacrylics 448 Wide angle x-ray diffraction 559, 562,
Poly(N-vinyl carbazole) 267 Polydienes 447, 448 567, 568, 570
Polystyrenes 268–271 Polymethacrylics 448 Wide-angle X-ray scattering
Poly(acrylics) 272–276 Polyolefins 447 (WAXS) 407, 410, 419
Poly(methacrylics) 272–276 Temperature dependence 446 White noise 544
Poly(methyl mathacrylate) 274 Thermoplastics 448, 449 Williams, Landel and Ferry (WLF)
Poly(itaconates) 276 Tube model 601, 602 equation 386
Polysiloxanes 276, 277 Tyligomer 696 Work of adhesion 478
Poly(dimethylsiloxane) 276 Worm-like chain model 67, 526
Polyesters 277–279 U
Poly(e-caprolactone) 277 X
Ultracentrifugation 705
Polycarbonate 277
Uniaxial extension 554 X-ray diffraction 615
Polyamides 279
Units 1033–1036 X-ray scattering 538, 542
Polyphosphates 279
Universal force field 60
Polyureas 279
Unperturbed dimension 260 Y
Copolymers 280–282
Unzipping 903
Amylose 282 Yajima process 958
Upper critical temperature 260, 342
Starch 282 Yardstick method/plot 539, 540
Upper use temperature 910
Cellulose 282
Urey-Bradley terms 58
Cellulose derivatives 282 Z
Pullulan 282
V Zero force contribution 531
Thin-film Tg ’s 207
Thompson scattering amplitude 409 van der Waals attraction 540, 541 Zimm plot 411–412
Tread 595, 597, 604 Vapor sorption 234 Zisman wetting criterion 477
Tire rolling resistance 567 Verdier-Stockmayer model 75, 76 Zisman critical wetting tension
Tires 595, 597, 604 Vinyl polymers 40 477–478

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