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CHAIY ~Analy tice! Coemictn4 (Asignvert 3)
CHAPTER 8
Fee. 19-222]
414, The sulfate on concentration in natural water can be determined by measuring the turbidity
that results when an excess of BaC', is added to a measured quantity of the sample. A
turbidimeter, the instrument used for this analysis, was calibrated with a series of standard
‘Na,SO, solutions. The following data were obtained in the calibration for sulfate concentrations,
[| ceme soe. Turbidimeter Reading, R
0.00 0.08
5.00 1.48
10.00 228
1500 3.98
200 461
‘Assume thal there isa linear relationship between the instrument reading and Concentration
(2.)Pot the data. and draw a strinht line therwah the ooinls by eye
0.23 and Ar
Canration wre bk 0
panes
oy
‘thee
R
Y= 0.282 ¥ +0, lon
> 6.9044
aww Peon &
re poi, the teacl cyvares ctoper
leact-eqvares inkrept @ tne
Me
DOR wit > hachepanr
9D oe ash > Jeg qe
Heceo
{¢.) Compute the concentration of sulfate in a sample yielding a turbidimeter reading of
2.84. Find Pee ere genet ae
EEE \ Oe WS mg Int Gekterinus ' at met
TAP Ne WAY
Le = »
belo ee ca 1 | 6 ney
a Bs | 15. e40H
eqs Cae 400 21-863)
Ge oF i Pe Wo
fon
Arte: ne “gendles op Llfale a
i La mglnL 1d we absalle ctondarc! dheiabre 8 iy
ota ee
a22. Copper was determined in a river water sample by atomic absorption spectrometry and the
‘method of standard additions, For the addition, 100.0 yL of a 1000.0-n g/mL. Cu standard was
‘added to 100.0 mL. of solution. The following data were obtained:
‘Absorbance of reagent blank = 0.020
GIMM @} Absorbance of sample = 0.520
‘Absorbance of sample plus addition - blank = 1.020
(2. Caleulate he copper concentration in the sample
Giuen Total volume, oF Lath = 100-0 ub + (100. Onio°at)
ine add ¥en (Up) Ey ooctnL
2 Voleme oF vindest ath the tw = 100.004 /aL
** conanivasion card sl", (008. 0/ty fat
Onli
iarane Oop wnhiown fy to.0 eh
ca = Abemie — Yant)
ten fay LORETO
(0-$20-0.420)
forme;
we
semneite s T-2%0
[Cia 70) H0)]
Tn 00 I al
= 0. 490
(0.419 $0.49)
feu) - 2.470 Costa 0 44 (4)
gSil cy = 0-1097
oy 2
paeihs ttt!
= 9-958
foier Te [tu] in te
Sample i