9

Science
Quarter 2 – Module 4:
The Carbon Compounds
Science 9 – Grade 9
Alternative Delivery Mode
Quarter 2 – Module 4: The Carbon Compounds
First Edition, 2020

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 9

Science
Quarter 2 – Module 4:
The Carbon Compounds
Introductory Message

For the facilitator:

Welcome to the Science - Grade 9 Alternative Delivery Mode (ADM) Module on Carbon
Compounds.

This module was collaboratively designed, developed and reviewed by educators both
from public and private institutions to assist you, the teacher or facilitator in helping
the learners meet the standards set by the K to 12 Curriculum while overcoming their
personal, social, and economic constraints in schooling.

This learning resource hopes to engage the learners into guided and independent
learning activities at their own pace and time. Furthermore, this also aims to help
learners acquire the needed 21st century skills while taking into consideration their
needs and circumstances.

In addition to the material in the main text, you will also see this box in the body of the
module:

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This contains helpful tips or strategies that
will help you in guiding the learners.

As a facilitator you are expected to orient the learners on how to use this module. You
also need to keep track of the learners' progress while allowing them to manage their
own learning. Furthermore, you are expected to encourage and assist the learners as
they do the tasks included in the module.

2
For the learner:

Welcome to the Science - Grade 9 Alternative Delivery Mode (ADM) Module on Carbon
Compounds.

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What I Need to Know competencies you are expected to learn in the
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lesson to take. If you get all the answers
correct (100%), you may decide to skip this
module.
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What’s In the current lesson with the previous one.

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answers to the exercises using the Answer
Key at the end of the module.
This includes questions or blank
What I Have Learned sentence/paragraph to be filled in to process
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3
 knowledge or skill into real life
situations or concerns.
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competency.
In this portion, another activity will be given
Additional Activities to you to enrich your knowledge or skill of the
lesson learned. This also tends retention of
learned concepts.
This contains answers to all activities in the
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this module.

The following are some reminders in using this module:

1. Use the module with care. Do not put unnecessary mark/s on any part of the
module. Use a separate sheet of paper in answering the exercises.
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included in the module.
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We hope that through this material, you will experience meaningful learning and
gain deep understanding of the relevant competencies. You can do it!

4
 What I Need to Know

This is designed and written to help you understand about carbon compounds.
The module brings learning to Grade 9 students in time of the COVID 19
pandemic.

After this module, everyone is expected to learn the following:

1. Explain how the structure of carbon atom affects the type of bonds and its
forms (S9MT-IIg-17).
a. Explain how carbon atoms able to form many organic compounds
b. Recognize common kinds of alkanes, alkenes and alkynes
c. Explain how to name hydrocarbons and how to write the chemical
formula
 What I Know

Multiple Choice. Choose the letter of your correct answer.

Activity 1:

1. Which of the following statements best describe organic compounds?

a. Organic compounds are compounds that contain carbon and
oxygen only
b. Organic compounds are compounds that are produced by living
things
c. Organic compounds are composed mainly of carbon and hydrogen
d. Organic compounds are compounds that contain carbon atoms only

2. How do carbon atoms form many organic compounds?

a. By attracting other elements towards themselves to form the bonds
b. By forming many bonds with other carbon atoms and other
elements
c. By sharing their electrons with other metal and non-metal elements
d. By transferring their electrons to the atoms of surrounding
elements

3. What is the maximum number of bonds a carbon atom can form?

a. 2
b. 3
c. 4
d. 5

4. Which hydrocarbon compound has a triple bond in the molecules?

a. Octane
b. Methane
c. Ethane
d. Ethyne

5. How many types of bonds are there in the following hydrocarbon compound?

H H
\ /
C ==
/ \
H H
 a. 1
b. 2
c. 3
d. 4

6. To which group of hydrocarbon does the molecule with the structure

H - C C -H belong?

a. Alkane
b. Alkyne
c. Alkene
d. None of the above

7. Carbon compounds are stable because..

a. They combine with one another to form carbon to carbon linkages
b. They react slowly except with a catalyst
c. They form covalent bonds
d. They have no lone pairs

8. An organic compound has the formula C 15H32, it is qualified as an?

a. Alkane
b. Alkene
c. Alkyne
d. Alcohol

9. The simpliest hydrocarbon

a. CH2
b. CH3
c. CH4
d. C2H4

10. Which is an alcohol?

a. C6H6
b. CH3 – C – CH3

O
c. CH3 – C – CH3
d. C2H5 – OH

11. The alcohol present in alcoholic beverages is?

a. Methyl Alcohol
b. Denatured Alcohol
c. Ethyl Alcohol
d. Wood Alcohol
12. The IUPAC name for CH3 – CH2 – CH2 – CH3

CH2CH3 is?

a. 3 methylpentane
b. 3 methylbutane
c. 2 ethyl butane
d. 3 ethyl butane

13. A group which both aldehydes and ketones have in common is?
O
//
a. C
\

b. OH
c. O
H
//
d. C
\
H

O
//
14. The C group is called?
\
OH

a. Aldehyde group
b. Hydroxyl group
c. Carbonyl group
d. Carboxylic group

15. The IUPAC name of CH3CH2CHO is?

a. Propanone
b. Propanol
c. Propanal
d. Propionie acid
 Lesson

1 Carbon Compounds

Most materials you use every day are made up of carbon compounds. These include
the rice, fish, meat and vegetables that you eat; the soap, shampoo and detergent that
you use for cleaning; the cotton, wool or nylon fibers in your clothes, or the rubber
materials in your shoes; the glue, wood, paint, and varnishes used in buildings and
houses; the paper and plastic ballpens that you use in you studies; the medicine you
take, like aspirin, paracetamol and penicillin; the chemicals used by farmers such as
urea (a fertilizer). Malathion (a pesticide), and gibberellic acid (a plant hormone), and
many more. Gasoline and other petroleum products which we use as energy sources are
mixtures of carbon compounds.

Carbon compounds are also called organic compounds. This name has its origin from
an earlier belief that only living organisms can produce these compounds. This belief
has been discarded a long time ago. There are now more than seven million synthetic
organic chemicals and the list is still growing. Organic synthesis or stepwise
preparation of carbon compounds is a very exciting activity for many organic chemists.

The carbon atom occupies a special position in the periodic table. It is in the middle of
period 2 (group IV A).

The carbon atom tends to share electrons with its own kind and with atoms like H, O,
N, S, P as well as the halogens. These different combinations have given rise to the
existence of different families or classes. Each class is identified by the nature of the
active group present.

This chapter will introduce you to the more general classes of carbon compounds.
 What’s In

Activity 2
Let us recall the lesson in the previous module about the formation of ions.

Choose the letter of the best answer.

1. Calcium forms an ion with ______ charge.

a. -1 b. +2 c. +1 d. -2

2. What kind of ion does the elements in Group 15 form?

a. anion b. cation c. anion and cation d. molecule
3. Which of the following forms -2 ions?

a. Group 2 b. Group 15 c. Group 16 d. Group 18

4. Why do atoms form ions?

a. to be gases c. to have 10 electrons always

b. to be stable d. to be unstable

5. Most atoms have no net charge because they have ______________.

a. an equal number of charged and non-charged particles

b. an equal number of protons and electrons

c. neutrons in their nuclei

d. an equal number of protons and neutrons
 What’s New

Activity 3
Match column A with the correct answer in column B.

1. a. alkyne

b. alkane

c. ketone
2.

d. alcohol

e. alkene

3.

f. aldehyde

4.

5.

6.
 What is It

Hydrocarbons are the simplest and most commonly encountered class of organic
compounds. Hydrocarbons are organic compounds that contain carbon and hydrogen
only. A hydrocarbon whose carbon atoms are all linked by a single bond is called an
alkane. On the other hand, a hydrocarbon whose carbon atom are linked by at least one
double bond or triple bond are called alkene and alkyne respectively. The presence of a
multiple bond is also another way of classifying hydrocarbons. Hydrocarbons that have
all carbon atoms linked by single bonds are called saturated hydrocarbons, while those
were at least a carbon-carbon double or triple bond is present are called unsaturated
hydrocarbons. Thus, alkanes are saturated hydrocarbons while alkenes and alkynes
are unsaturated hydrocarbons.

Hydrocarbons are also classified as aliphatic hydrocarbons and aromatic hydrocarbons.

When carbons, in a hydrocarbon are linked to form a long, straight or branched chain,
it is classified as chain type. But when the carbons are linked to form a ring, the
hydrocarbon is called cyclic type. These chain type hydrocarbons (alkanes, alkenes and
alkynes) and their cyclic analogs belong to the aliphatic hydrocarbons. The aromatic
hydrocarbons contain the structural unit called benzene, a six-carbon ring with three
alternating double bonds, or closely related rings like naphthalene.
Alkanes are also called paraffins (meaning low affinity), while alkenes are also called
olefins. Hydrocarbons have a predictable number of carbon and hydrogen atoms. They
follow a general formula that makes it easier for us to predict if a certain compound is
an alkane, alkene or alkyne just by looking at the chemical formula of the different
classes of hydrocarbons. The symbol n refers to the number of carbon atoms.

General Formula of Hydrocarbons:

Class of Hydrocarbon General Formula Example

Alkane CnH2n+2 CH4 methane

Alkene CnH2n C2H4 ethene

Alkyne CnH2n-2 C2H2 ethyne

Stems Used for the Different Parent Chain of Hydrocarbons:

Parent Chain Stem

C1 Meth -

C2 Eth -

C3 Prop -

C4 But -
 C5 Pent -

C6 Hex -

C7 Hept -

C8 Oct -

C9 Non -

C10 Dec -

Nomenclature

The system of naming compounds is referred to as nomenclature. In the early history

of organic chemistry, the names of compounds were related to the origin of certain
properties of the compounds. With millions of organic compounds, it became necessary
to develop a system of nomenclature. The system adopted was the one recommended by
the International Union of Pure and Applied Chemistry (IUPAC). The rules of this system
are as follows:

A. For hydrocarbons (alkane, alkene, alkyne)

1. Select the longest continuous carbon chain in the molecule. Refer to the
hydrocarbon name in table 21.3. This becomes the base name.

Names of Hydrocarbons and Alkyl Group

Molecular Condensed Structural Name Alkyl

Formula Formula (C11H2n + 1)

CH4 CH4 Methane Methyl

C2H6 CH3 CH3 Ethane Ethyl

C3H8 CH3 CH2 CH3 Propane Propyl

C4H10 CH3(CH2)2CH3 Butane Butyl

C5H12 CH3(CH2)3CH3 Pentane Pentyl

C6H14 CH3(CH2)4CH3 Hexane Hexyl

C7H16 CH3(CH2)5CH3 Heptane Heptyl

C8H18 CH3(CH2)6CH3 Octane Octyl

C9H20 CH3(CH2)7CH3 Nonane Nonyl

C10H22 CH3(CH2)8CH3 Decane Decyl

2. Add the following endings to the base name

ane – alkane
ene – alkene
une – alkyne

Thus, the IUPAC names of the following hydrocarbons are:

a. CH3 CH2 CH2 CH3 (butane)

b. CH2 CH2 (ethane)
c. CH CH (ethyne)

3. In alkenes and alkynes, number the chain beginning at the end that is closer
to the double or triple bond. To indicate the position of the multiple bond,
use prefix number before the alkene or alkyne name.

Example:

5 4 3 2 1 1 2 3 4 5
CH3 CH2 CH CH CH3 not CH3 CH2 CH CH CH3
2 – pentene not 3 – pentene

In compounds containing two double bonds, the ending -diene is used.

1 2 3 4 5 6
CH3 CH C CH CH2 CH3
2, 3 – hexadiene

4. In branched hydrocarbons, consider the branch as a substituent group and

name it by changing -ane to yl (alkyl).

For alkanes, number the chain starting at the end that is closer to the branch.
To Illustrate the rule, refer to the following example:

5 4 3 2 1 1 2 3 4 5
CH3 CH2 CH2 CH CH3 not CH3 CH2 CH2 CH CH3
 CH3 CH3
2 – methylpentane not 2,3 – dimethylpentene

If identical substituents are present, use the prefixes di - , tri - , tetra - , etc.,
and indicate the numbers. Separate the numbers with a comma. If different
substituents are present, arrange them alphabetically.

Example:

CH3
1 2 3 4 5
CH3 CH CH CH2 CH3 2.3 - dimethylpentane

CH3

C2H5
7 6 5 4 3 2 1 4-ethyl-2.5-
CH3 CH2 CH CH CH2 CH CH3 dimethylheptane

CH3 CH3

For branched alkenes and alkynes, follow rule 3 in numbering the carbon chain.
Thus,

5 4 3 2 1
CH3 CH CH CH CH3 is known as 4-methyl-
2-pentene
CH3

C2H5
1 2 3 4 5 6
CH C CH CH CH CH3 is named 5-ethyl – 3,4-
dimethyl – 1 - hexyne
CH3 CH3
Activity 4.1:

Write the name of the following compounds.

CH3

1. CH3 CH2 CH CH CH CH3

CH3

CH3

2. CH3 CH CH CH2 CH3

CH3

CH3

3. CH3 CH CH2 CH CH CH3

C2H5 CH3

4. CH3 CH CH C CH3

CH3 CH3

5. CH3 C C CH CH CH3

CH3 C2H5

Activity 4.2:

Write the condensed structural formula for each of the following:

1. 3 ethyl – 2 pentene
2. 2 ethy; - 4-5 dimethyl 1-3 heptadiene
3. 2 – butyne
4. 3,5 dimethynonane
5. 3 methyl 1 pentyne
 What’s More

Functional Groups

Organic compounds are classified based on the functional group in the molecule.
Functional groups are atoms or group of atoms and bonds that confer specific
properties on molecule.

There are some functional groups most frequently encountered in organic chemistry.
The symbol R represents the remainder of the molecule.

Types of Functional Group Example

Compound
Alkane R H CH3 CH3
R R H H
Alkene C C C C
R R H H
Alkyne R C C R CH3 C C CH3
Alcohol R O H CH3 CH2 OH
Ether R O R CH3 O CH3
O O
Aldehyde R C CH3 CH2 C
H H
O O
Ketone R C CH3 C
R CH3
O O
Carboxylic Acid R C CH3 C
OH OH
O O
Ester R C R C
OR O CH3
Amine R NH2 CH3 CH2 NH2
O O
Amide R C CH3 C
NH2 NH2
Activity 5:

Name the functional groups of the following formula:

OH

1. CH3 CH2 CH CH3

O
2. CH3 CH2 C
OH

O
3. CH3 CH2 CH2 C
OH CH3

4. CH3 CH CH3

NH2

O
5. HC
H

6. CH3 CH2 CH3

7. CH3 CH CH CH3

O
8. CH3 C
CH3
 What I Have Learned

Activity 6.1:

Complete the concept map of hydrocarbon by filling up the missing data:

Hydrocarbons

May be contains

Or

Examples are An example is

are

contain contain
only
Activity 6.2:

Alkanes – the saturated hydrocarbons

Most compounds in crude oil are alkanes. The five lowest numbers of the group are
presented in table below:

The five lowest members of the alkane family

Name Formula Boiling Point (0C) Source

Methane CH4 -164.0 Biogas, natural
gas
Ethane CH3CH3 -88.0 Cooking gas
Propane CH3CH2CH3 -42.1 Cooking gas,
liquified
petroleum gas
(LPG)
Butane CH3CH2CH2CH3 -0.5 Cooking gas,
cigarette lights
Pentane CH3CH2CH2CH2CH3 -36.1 Dry cleaning
fluids

Each carbon atom in the given compounds is singly bonded to four other carbon atoms.
When carbon forms only single bonds with other atoms, the compound form is said to
be saturated. Alkanes, therefore, are saturated hydrocarbons.

The formula for each successive member of the alkane group increases by one -CH2 –
(methylene) group. The general formula for alkanes is C nH2n+2, where n is a whole
number. To get the formula of methane (a one carbon alkane), for example, substitute
the number of C and H in the general formula. Thus,:

C1(H2(1)+2) or CH4
(Derive the molecular formula of a four carbon atom alkane using the general formula
for alkanes)

Answer the following questions:

1. Why can carbon form numerous and varied organic compound?

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________
 2. Give two reasons for:
the existence of carbon compounds.
A. ________________________________________________________________________

________________________________________________________________________

B. _______________________________________________________________________

______________________________________________________________________

3. Differentiate saturated from unsaturated hydrocarbons.

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________

4. Give the advantages and disadvantages of using plastic.

Advantages Disadvantages
___________________________ _______________________________
___________________________ _______________________________
___________________________ _______________________________

What I Can Do

Activity 7:

Choose a consumer product you have at home and list the different organic compounds
that it contains. Determine its class of organic compound by simply determining its
name. Explain the basis of your classification
 Assessment

Activity 8:

Choose the letter of the best answer.

1. Which is an alcohol?
a. C6H8
b. CH3 C CH3

O
c. CH3 C CH3
d. C2H5 OH

2. What class of organic compound is C20H38?

a. Alkene
b. Alkyne
c. Alcohol
d. Ketone

3. A compound is a colorless gas at 250C. It is insoluble in water and highly

flammable. What kind of compound is it?
a. Inorganic
b. Ionic
c. Hydrocarbon
d. Aromatic

4. Which is an organic compound?

a. NaCl
b. CS2
c. NaHCO3
d. C3H4
5. Emmanuel Juan, a fisherman, went home with some of his catch. He told his son
to cook the fish but his son said, “Father, the stove ran out of fuel. He told him
to buy some so they can start cooking. Which organic compound do you think
the boy will buy?
a. Kerosene
b. Gasoline
c. Lubricating oil
d. Isopropyl alcohol

6. What is the common use of methane?

a. Disinfectant
b. Fertilizer
c. Artificial ripening agent
d. Fuel
7. Maria Paula wants to preserve a fish for her project in Biology Class. What kind
of compound should she use to preserve the animal?
a. Acetic acid
b. Formaldehyde
c. Methyl alcohol
d. Acetone

8. Which of the following compounds is a carbonyl compound?

H O

a. H C C OH

H H

b. H C C OH

H H

c. H C C H

d. All of the above

9. Biogas is mostly
a. Propane
b. Methane
c. LPG
d. Octane

10. Which of the following is not true of unsaturated hydrocarbons?

a. They are soluble in water
b. They have double bonds between carbon atoms
c. They are more reactive than saturated one
d. They derived from fossil fuel

11. Which statement does not describe an aromatic hydrocarbon?

a. It has at least one benzene ring
b. It is present in coal taer
c. It does not decolorize potassium permanganate
d. It is saturated

12. In ethene, the two carbons are joined by a

a. Single bond
b. Double bond
c. Triple bond
d. Ionic bond
13. The aroma associated with this class of compound is regarded as pleasant
a. Amides
b. Esters
c. Carboxylic acid
d. Ketones
 14. How many types of bonds can a carbon atoms form?
a. 1
b. 3
c. 2
d. 4

15. What happens to the boiling point of hydrocarbon compounds when the number
of carbon atoms increases?
a. Remains the same
b. Decreases
c. Increases
d. Increases then decreases

Additional Activities

Activity 9.1:

Why is carbon atom a unique element?

Materials:
Gumdrops
Toothpicks

A carbon atom is unique because it can easily form four bonds with other atoms,
including other carbon atoms. Because of this property, carbon forms many different
compounds.

1. Use gumdrops and toothpicks to make as many different carbon molecules

as you can. Keep these rules in mind:
• Each gumdrop represents one carbon atom.
• Each toothpick represents one chemical bond
• Each molecule must contain four carbon atoms (gumdrops)
• Each carbon atom must have four chemical bonds (toothpick).

2. Make a sketch of each molecule in a piece of paper.

Think about this:

1. How many different molecules were you able to build?

2. If you had five gumdrops, would you be able to build more molecules? Explain
your answer.
3. How do you think a carbon atom bonds with other carbon atoms?
Activity 9.2:

How do carbon atoms bond with carbon and hydrogen atoms?

Materials:
Toothpicks
Gumdrops
Raisins

Models help you see how carbon atoms from so many different compounds.
1. Draw the structural formulas for propane, propene, and propyne in a piece
of paper.
2. Use toothpicks, gumdrops, and raisins to make a ball and stick model of
each compound. Gumdrops represent carbon atoms. Raisins represent hydrogen
atoms. The toothpicks represent bonds between atoms.

Analyze and Conclude:

1. Classify each model as saturated and unsaturated hydrocarbon.
2. Why can carbon atoms form so many different kinds of compounds with other
atoms.

Activity 9.3:

How do functional groups affect compounds?

Materials:
Plastic Spoon
Rubbing Alcohol
Clear Plastic Cup
Glycerin
Distilled Water
Chenille Stems

In some hydrocarbons, a hydrogen atom is removed and another atom or group of atoms
takes its place. Rubbing alcohol and glycerin are two examples:

H H H

H C C C H

H H H
Propane

H OH H

H C C C H

H H H
Rubbing Alcohol

OH OH OH
 H C C C H

H H H
Glycerin

1. Use a plastic spoon to measure two spoons of rubbing alcohol and pour
the liquid into a clear plastic cup. Observe the properties of the alcohol. Use the
wafting method to check the odor. Record your observations in a piece of paper.
2. Repeat step 1 with glycerin using a spoon and cup. Add distilled water to
both cups until they are one third full. Stir gently using the same spoon in each
cup that you used before.
3. Twist three chenille stem to make bubble wands. Deep a clean bubble
wand into each cup. Check to see if a film forms within the circle for each mixture.
Record your observations in a piece of paper.

Think about this:

1. Compare and contrast the properties and structural diagrams of rubbing alcohol
and glycerin.
2. When a hydrogen atom in propane is replaced by an oxygen, atom and a hydrogen
atom, rubbing alcohol forms. What changes occur when this happens?
 What I have learned
(Activity 6.2)
1. Answers may vary
2. Two electron configuration
of carbon accounts for its
ability to form a great
variety of compound such
as long straight chain,
branched chain, ring with
single bond, ring with
double bond
What I have learned What’s more
(Activity 6.1) (Activity 5)
1. Aromatic 1. Alcohol
2. Open chain 2. Carboxyl acid
compound 3. Ester
3. Alkenes 4. Amine
4. Saturated 5. Aldehyde
hydrocarbon 6. Alkane
5. Double or triple 7. Alkene
bond 8. ketone
What is it
(Activity 4.1)
1. 3, 4, 5 trimethyl hexane
2. 2, 3 dimethyl pentane
3. 5 ethyl 2, 3 dimethyl
hexane
4. 2, 4 dimethyl 1, 2
pentene
5. 5 ethyl 4 methyl 2
hexyne
What’s New What’s in What I know
(Activity 3) (Activity 2) (Activity 1)
1. b 1. c 9. c
1. E 2. b 10. d
2. F 2. a
3. c 11. c
3. B 3. c 4. d 12. c
4. D 5. b 13. a
5. A 4. b
6. b 14. d
6. C 5. b 7. b 15. c
8. a
Answer Key
Additional Activ Assessment What I can Do
(Activity 9.1) (Activity 8) (Activity 7)
1. D 9. B
Answers may vary 2. B 10. A
3. C 11. D Answers may vary
4. D 12. B
(Activity 9.2)
5. A 13. B
6. D 14. B
Answers may vary 7. B 15. C
8. A
What I have learned What I have learned
(cont. Activity 6.2) (cont. Activity 6.2)
4. Advantages of plastics: Compounds having the same
They are electrical insulator. molecular formula but different
They can be molded into different structures because of functional
shapes groups
They can be mass produced at a 3. Saturated hydrocarbons have all
cheap price the carbon atoms linked together
Disadvantages of Plastics by single bonds, unsaturated
They are nonbiodegradable hydrocarbons have carbon atoms
They increase pollution of land and linked together either as double or
water triple bond
References

Science Learner’s Module 9 (DepEd)

MAPA, Amelia P., Trinidad B. Fidelino, and Lilia M. Rabago. Chemistry Textbook
Science and Technology Third Year. Department of Education, n.d.

Science and Technology III Third Year High School Textbook. Department of Education,
Culture and Sports, n.d.

Mendoza, Estrella E., and Teresita F. Religioso. Chemsitry Textbook Third Year.
Seconded., n.d.

Alumaga, Marie Jessica B., Echel Simon Antero, Crescencia C. Joaquin, Catherine
Genevieve B. Lagunzad, Ricardo M. Crisostomo, Alicia L. Padua, Thelma R.
Mingoa, and Lilia M. Rabago. Science and Technology. Vibal, n.d.

Integrated IScience Grade 9. Phoenix Publishing House, n.d.

“Formation of Ions - Quiz.” Quizizz. Accessed October 16, 2020.

https://quizizz.com/admin/quiz/5bcfe787c01bc1001a00fc20/formation-of-ions.
For inquiries or feedback, please write or call:

Department of Education – Region III,

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Email Address: bataan@deped.gov.ph