Latihan 1

#Metode diferensiasi
t (jam) CA (mol/l)
0 5 Chart Title
0.04 1.72 6
0.08 1.01
0.12 0.7 5
f(x) = − 5121.24546 x⁵ + 7167.81878 x⁴ − 3754.52797 x³ + 910.630485 x² − 102.85201 x + 4.89
0.16 0.54 R² = 0.989876667875201
4
0.2 0.43
0.24 0.36 3
0.28 0.31
0.32 0.27 2 f(x) = − 5.74313186813187 x + 2.23681318681319
0.36 0.24 R² = 0.461030264950049
0.4 0.21 1
0.44 0.19
0
0.48 0.18 0 0.1 0.2 0.3 0.4 0.5

CA = -5121,2x5 + 7167,8x4 - 3754,5x3 + 910,63x2 - 102,85x + 4,898

-rA =
−dCA/𝑑𝑡
-rA =−( -5121,2𝑥5 + 7167,8𝑥4 - 3754,5𝑥3 + 910,63𝑥2 -
102,85𝑥 + 4,898 )/𝑑𝑡

-rA = -(-25606t^4 + 28671,2t^3 - 11263,5t^2 + 1821,26t - 102,85)

-rA = 25606t^4 - 28671,2t^3 + 11263,5t^2 - 1821,26t + 102,85)

 t (jam) CA (mol/l) -rA ln (CA) ln (-rA)
0 5 102.85 1.609438 4.633272
0.04 1.72 46.25179 0.542324 3.8341
0.08 1.01 15.60477 0.00995 2.747576
0.12 0.7 2.259027 -0.356675 0.814934
0485 x² − 102.85201 x + 4.8979638
0.16 0.54 -0.862087 -0.616186 Err:502
0.2 0.43 0.738 -0.84397 -0.303811
0.24 0.36 3.129094 -1.021651 1.140743
0.28 0.31 3.954233 -1.171183 1.374787
0.32 0.27 2.429689 -1.309333 0.887763
0.36 0.24 -0.655034 -1.427116 Err:502
0.4 0.21 -2.9372 -1.560648 Err:502
0.44 0.19 -0.480839 -1.660731 Err:502
0.4 0.5 0.6 0.48 0.18 12.22325 -1.714798 2.50334

Chart Title
5

4
f(x) = 1.09735951688963 x + 2.47810608933679
R² = 0.524205098234255
3

0
-2 - 1.5 -1 - 0.5 0 0.5 1 1.5 2

-1

y = 1,2432x + 2,2668

Didapatkan : n = 1,2432 ln K= 2.2668

K= eksponen (2,2668)
K= 9.648476
1 1.5 2
Latihan 1
#Metode Integrasi
t (jam) CA (mol/l) ln CA 1/CA
0 5 1.609438 0.2
0.04 1.72 0.542324 0.581395
0.08 1.01 0.00995 0.990099
0.12 0.7 -0.356675 1.428571
0.16 0.54 -0.616186 1.851852
0.2 0.43 -0.84397 2.325581
0.24 0.36 -1.021651 2.777778
0.28 0.31 -1.171183 3.225806
0.32 0.27 -1.309333 3.703704
0.36 0.24 -1.427116 4.166667
0.4 0.21 -1.560648 4.761905
0.44 0.19 -1.660731 5.263158
0.48 0.18 -1.714798 5.555556

Orde 0 orde 1

f(x) = 0 f(x) = 0
R² = 0 Chart Title R² = 0 Chart Title
12 12

10 10

8 8

6 6

4 4

2 2

0 0
0 2 4 6 8 10 12 0 2 4 6

Yang mendekati linier yaitu orde 2

y = 11,463x + 0,0822
ln CA = -Kt + ln CA0
DidapatkanK = - 11,46 ln n = 0.0822
n= eksponen (0,0822)
n= 1.085673
 orde 2
f(x) = 0
Chart Title R² = 0 Chart Title
12

10

0
4 6 8 10 12 0 2 4 6 8 10
Title

8 10 12
Latihan 2
#Metode diferensiasi
CA (mol/liter)
t (jam)
T = 60 °F T = 80 °F T = 100 °F
0 1 1 1
0.5 0.63 0.5 0.38
1 0.45 0.33 0.23
1.5 0.35 0.24 0.16
2 0.29 0.19 0.13
2.5 0.24 0.16 0.1
3 0.21 0.13 0.08
3.5 0.18 0.11 0.07
4 0.16 0.1 0.06
4.5 0.15 0.09 0.06
5 0.13 0.08 0.05

T = 60 °F

Chart Title
1.2

1
f(x) = 0.0062937063 x⁴ − 0.0812898213 x³ + 0.3853263403 x² − 0.8515889666 x
+ 0.99034965035
0.8 R² = 0.998113924556982

0.6 f(x) = − 0.137454545454545 x + 0.688181818181818

R² = 0.743026521060843

0.4

0.2

0
0 1 2 3 4 5 6

CA = 0,0063x4 - 0,0813x3 + 0,3853x2 - 0,8516x + 0,9903

-rA =
−dCA/𝑑𝑡
-rA =−(0,0063𝑥4 - 0,0813𝑥3 + 0,3853𝑥2 - 0,8516𝑥 +
0,9903 )/𝑑𝑡

-rA = -(0,0252t^3 - 0,2439t^2 + 0,7706t - 0,8516)

-rA = -0,0252t^3 + 0,2439t^2 - 0,7706t + 0,8516

T = 80 °F

Chart Title
1.2

1
f(x) = − 0.00425641 x⁵ + 0.0636946 x⁴ − 0.36247669 x³ + 0.9888782 x² − 1.3677045 x
+ 0.9952622
0.8 R² = 0.998841021793538

0.6
f(x) = − 0.131818181818182 x + 0.595909090909091
R² = 0.636057261792396
0.4

0.2

0
0 1 2 3 4 5 6

CA = -0,0043x5 + 0,0637x4 - 0,3625x3 + 0,9889x2 - 1,3677x + 0,9953

-rA =
−dCA/𝑑𝑡
-rA =−(-0,0043𝑥5 + 0,0637𝑥4 - 0,3625𝑥3 + 0,9889𝑥2 -
1,3677𝑥 + 0,9953 )/𝑑𝑡
-rA = -(-0,0215t^4 + 0,2548t^3 - 1,0875t^2 + 1,9778t - 1,3677)

-rA = 0,0215t^4 - 0,2548t^3 + 1,0875t^2 - 1,9778t + 1,3677

T = 100 °F

Chart Title
1.2

1
f(x) = 0.0025098 x⁶ − 0.0444163 x⁵ + 0.31083 x⁴ − 1.09419 x³ + 2.04673 x² − 2.00491 x
+ 0.998235
0.8 R² = 0.999318561426639

0.6

f(x) = − 0.123090909090909 x + 0.518636363636364

0.4 R² = 0.533163882555488

0.2

0
0 1 2 3 4 5 6
 0.6

f(x) = − 0.123090909090909 x + 0.518636363636364

0.4 R² = 0.533163882555488

0.2

0
0 1 2 3 4 5 6

CA = 0,0025x6 - 0,0444x5 + 0,3108x4 - 1,0942x3 + 2,0467x2 - 2,0049x + 0,9982

-rA = −dCA/𝑑𝑡

-rA =−(0,0025𝑥6 - 0,0444𝑥5 + 0,3108𝑥4 - 1,0942𝑥3 + 2,0467𝑥2 -

2,0049𝑥 + 0,9982)/𝑑𝑡
-rA = -(0,015t^5 - 0,222t^4 + 1,2432t^3 - 3,2826t^2 + 4,0934t - 2,0049)

-rA = -0,015t^5 + 0,222t^4 - 1,2432t^3 + 3,2826t^2 - 4,0934t + 2,0049)

t(jam) CA(mol/liter) -rA ln (CA) ln (-rA) Chart Title
0 1 0.8516 0 -0.1606383
0.5 0.63 0.524125 -0.462035 -0.6460251 -2.5 -2f(x) = 1.76073281452646
-1.5 -1
x − 0.02691498965230
R² = 0.944909808212429
1 0.45 0.2997 -0.798508 -1.2049733
1.5 0.35 0.159425 -1.049822 -1.8361817
2 0.29 0.0844 -1.237874 -2.4721879
2.5 0.24 0.055725 -1.427116 -2.8873264
3 0.21 0.0545 -1.560648 -2.9095546
3.5 0.18 0.061825 -1.714798 -2.7834475
4 0.16 0.0588 -1.832581 -2.8336134
4.5 0.15 0.026525 -1.89712 -3.6296676
5 0.13 -0.0539 -2.040221 Err:502

Ea = −ln⁡(−rA/(𝑘 𝑥 "Can
y = 1,0926x - 0,5495
" ))x(RT)
Didapatkann = 1,0926 ln K=
Ea = K=
K=
t(jam) CA(mol/liter) -rA ln (CA) ln (-rA)
0 1 1.3677 0 0.3131305 Chart Title
0.5 0.5 0.620169 -0.693147 -0.4777637
1 0.33 0.2441 -1.108663 -1.4101773
1.5 0.24 0.096769 -1.427116 -2.3354312
2 0.19 0.0677 -1.660731 -2.6926691 -3 -2.5 -2 -1.5 -1
f(x) = 1.05423641586377 x − 0.16804532494699
2.5 0.16 0.078669 -1.832581 -2.5425093 R² = 0.633249368037268
3 0.13 0.0837 -2.040221 -2.4805163
3.5 0.11 0.069069 -2.207275 -2.6726529
4 0.1 0.0533 -2.302585 -2.9318189
4.5 0.09 0.087169 -2.407946 -2.4399094
5 0.08 0.2537 -2.525729 -1.3716028

y = 1,0542x - 0,168

Didapatkann = 1,0542 ln K=
K=
K=

t(jam) CA(mol/liter) -rA ln (CA) ln (-rA)

0 1 2.0049 0 0.6955942 Chart Title
0.5 0.38 0.636856 -0.967584 -0.4512113
1 0.23 0.1579 -1.469676 -1.8457934
1.5 0.16 0.064819 -1.832581 -2.7361604 f(x) = 1.20164816500051 x + 0.26304360582094
-3.5 -3 R² = 0.751915322432655
-2.5 -2 -1.5 -1
2 0.13 0.0749 -2.040221 -2.5916014
2.5 0.1 0.069681 -2.302585 -2.663824
3 0.08 0.0387 -2.525729 -3.2519157
3.5 0.07 0.023244 -2.65926 -3.761719
4 0.06 0.0601 -2.813411 -2.8117454
4.5 0.06 0.125306 -2.813411 -2.0769945
5 0.05 0.0779 -2.995732 -2.5523293

y = 1,2016x + 0,263

Didapatkann = 1,2016 ln K=
K=
K=
 Chart Title
0
-1.5
073281452646 -1
x − 0.026914989652301 -0.5 0
909808212429 -0.5

-1

-1.5

-2

-2.5

-3

-3.5

-4

-0.5495
eksponen (-0,5495)
0.577238
 Chart Title
1
0.5
0
-2 -1.5 -1 -0.5 0
423641586377 x − 0.168045324946995 -0.5
249368037268
-1
-1.5
-2
-2.5
-3
-3.5

-0.168
eksponen (-0,168)
0.845354

Chart Title
1
0.5
64816500051 x + 0.26304360582094 0
5 -2
15322432655 -1.5 -1 -0.5 0
-0.5
-1
-1.5
-2
-2.5
-3
-3.5
-4
 -1.5
-2
-2.5
-3
-3.5
-4

0.263
eksponen (0,263)
1.300827
Latihan 2
#Metode Integrasi
CA (mol/liter)
t (jam)
T = 60 °F T = 80 °F T = 100 °F
0 1 1 1
0.5 0.63 0.5 0.38
1 0.45 0.33 0.23
1.5 0.35 0.24 0.16
2 0.29 0.19 0.13
2.5 0.24 0.16 0.1
3 0.21 0.13 0.08
3.5 0.18 0.11 0.07
4 0.16 0.1 0.06
4.5 0.15 0.09 0.06
5 0.13 0.08 0.05