Exam 1: CHEM 112

CHEM 112
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Exam 1
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Spring 2010 NAME:- - - - -
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Dr. Thomas Berg
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Total Points == 150 Sm
Questions 1-30 : 5 points each
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USEFUL INFORMATION:
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.6.E= q+w
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We provide unlocked studymaterials from popular websites at affordable price, email enquiries to rishabhk28@live.com
1. Which if the correct mathematical expression for the molar solubility (S) of
MgC 2 0 4 ?
b) 4 S3
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c) 7 S2
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d) S7
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e) 27 S4
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2. Consider the following data:
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~Hf· CO2 (g) == -393.5 kJ
~Hf· H 20([) == -285.8 kJ

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Calculate the standard enthalpy change for the combustion of 1.000 mole of benzene,
C6H6(C)' to CO 2(g) and H20(C).
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a) -587 kJ
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b) -1174kJ
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c) -3267kJ
d) -1553 kJ
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e) -1455 kJ
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3. If the heat of vaporization for a particular metal is 297.0 kJ / mol and the heat of
sublimation for the metal is 415.8 kJ / mol, what is the heat of crystallization for
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that same metal?
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a) -118.8 kJ / mol
b) 118.8 kJ / mol
c) 712.8 kJ I mol
d) -712.8 kJ / mol
e) None of these is correct.
4. Consider the fluorination of acetylene, C2H2 :
tl.H" = -1227 kJ
Bond D. kJ I mol
C-H 413
H-H 432
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F-F 159
C-F 453
C-C 347
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Estimate the value for the C-to-C triple bond dissociation energy.
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a) 344 kJ I mol
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b) 614 kJ I mol
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c) 517kJ/mol
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d) 586 kJ I mol Sm
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5. The solubility of which ofthe following salts would be affected the most by the addition
of nitric acid?
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a) AgI
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b) AgCf
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c) AgBr
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e) AgCe04
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6. The Ksp of AgI (MW == 234.8 g I mol) is 1.5 x 10- • What is the solubility of AgI
in g in 250.0 mL of 0.250 M NaI solution?
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a) 1.4 x 10- g
b) 3.5 X 10- 14 g
c) 7.2 X 10-7 g
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d) 5.6 X 10- g

7. If 35.0 mL of 5.5 x 10'5 M AgN0 3 are added to 70.0 mL of2.0 x 10'3 M K2C0 3 ,
will a precipitate occur? (Ksp of Ag2C03 = 8.1 x 10,12)
a) No, because the ion product is greater than Ksp.
b) Yes, because the ion product is less than Ksp.
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c) No, because the ion product is less than Ksp.
d) Yes, because the ion product is greater than Ksp.
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e) Not enough information is given.
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8. At constant pressure, the combustion of 11.3 g of C2H6 releases 585 kJ of heat.
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What is L'lH for the reaction shown below (as written)?
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2 C 2H 6(g) + 7 02(g) -+ 4 C02(g) + 6 H20CI:)
a) -1.56 x 103 kJ / rxn

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b) -51.8 kJ / rxn
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c) -3.l1 x 103 kJ I rxn
d) -6.61 x 103 kJ / rxn
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9. How many of the following should have their standard heat of formation, L'lH f, to
be zero at 25°C?
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O(g) 02(g) 02(C) 03(g)

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a) 0
f
b) 1
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c) 2
d) 3
e) 4
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What is ilH for the reaction below?
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a) -499 kJ
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b) -166 kJ
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c) 166 kJ
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d) -364 kJ
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e) None of there is correct.
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1 L What is the pH of a saturated solution ofBa(OH)2 ifthe Ksp is 5.0 x 1O-3?
a) 7.34
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b) 13.03
c) 13.33
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d) 12.85
a

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12. A solution consists of 0.50 M Mg.2+ and 0.020 M Cu-"+. A solution ofNaOH is
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added slowly without changing the volume. What is the concentration of Cu~+ ion
when Mg(OH)::. just begins to precipitate? (Ksp = 1.8 x 10- 11 for Mg(OH)2 and
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Ksp = 2.2 x 10-20 for CU(OH)2 )
a) 6.1 x lO- i oM
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b) 6.0 x 10-6 M
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c) 3.6 X 1O- 1i M
d) 3.7 X 10- 15 M
13. What is molar solubility of thallium chloride in 0.30 M NaCe at 25°C? Ksp for
TlC( is 1.7 x 10-4 .
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a) 5.1 x 10- M
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b) 5.7 X 10- M
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c) 7.1 X 10-3 M
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d) 1.3 X 10-2 M
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e) 7.1 x 10- M
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14. A 25.0 g piece of aluminum, which has a molar heat capacity of 24.03 J / mol·
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DC, is heated to 82.4 °c and dropped into a calorimeter containing water, specific
heat capacity of 4.184 J / g . DC, initially at 22.3 DC. The final temperature of the
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water is 24.9 dc. What was the mass of water in the calorimeter?
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a) 118 g
b) 6.57 g
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c) 3180 g
d) 2120 g
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e) 318 g
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15. For a particular process q = - 67 kJ and w = 29 kJ. Which of the following
statements is true?
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a) Heat flows from the system to the surroundings.
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b) The system does work on the surroundings.
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c) i1E = 96 kJ.
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d) Two of the above are true.
e) All of the above (a, b, and c) are true.
16. Consider the following numbered processes:
1. A ---> B LlH I
2. 2 B ---> C + 2 D LlH2
3. C + 2 E ---> 2 D + F LlH3
What is LlH for the process: 2 A + F 2 C + 2 E?
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--+
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17. In which of the following solutions would solid PbCt2 be expected to be the least soluble
at 25°C?
a) 0.1 M HCt
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b) 0.10 M LiCt
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c) 0.10 M CaCt2
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d) 0.10 MN"'fh
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e) All have the same solubility.

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18. A process is carried out at constant pressure. If LlH is negative and LlE is greater
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than LlH:
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a) the system absorbs heat and expands during the process.

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b) the system absorbs heat and contracts during the process.

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c) the system loses heat and contracts during the process.
d) the system loses heat and expands during the process.
19. If 4.87 x 10-4 g of CaC03 (MW = 100.1 g / mol) can dissolve in 100.0 mL of
water, what is the Ksp value for this salt?
a) 2.37 x 10-9
b) 4.87 X 10-5
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c) 2.37 X 10-5
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d) 2.39 X 10.
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20. Which of the following salts is the least soluble in water?
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a) CaC03 (Ksp = 4.8 x 10.9)
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b) PbI (Ksp = 1.1 x 10.9) Sm
c) AgBr (Ksp = 5.0 x 10-13 )
d) Fe(OHh (Ksp = 8.0 x 10-16)

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e) CO(OH)2 (Ksp = 2.5 x 10- 16 )

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21. What is the total quantity of heat required to convert 25.0 g of liquid cce4(C) from
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25.0 °C to gaseous CCi4(g) at its normal boiling point of 76.8 °C? The specific
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heat ofCCe4(C) is 0.857 J / (g. K), its heat of fusion is 3.27 kJ / mol and its heat
of vaporization is 29.82 kJ / moL
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a) 1.11 kJ
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b) 4.85 kJ
c) 5.96 kJ
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d) 1.64 kJ
22. What is the equilibrium constant for the folloVv1ng reaction?
AgCt(s) + 2 NaCN(aq) -4 Ag(CN)2-(aq) + 2 Na+(aq) + Ct-(aq)
Ksp for AgCt = 1.8 x 10-\0 ; Krfor Ag(CN)2 = 1.0 X 1021
a) 1.0 x 1021
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b) 1.8 X 1011
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c) 5.6 X 10- 12
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d) 1.8 X 10-31
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23. What is the correct equation for the standard enthalpy of formation of CO(g),
where gr indicates graphite? Sm
a) 2 C(g) + 02(g) -4 2 CO(gl
b) C(grl + O(g) -4 CO(g)
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c) C(gr) + 12 02(g) -4 CO(g)
d) C(grl + C02(g) -4 2 CO(g)
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e) CO(g) -4 C(gr) + O(g)
a
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24. Which of the following complexes would be considered most stable?

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a) CO(NH3)6 2+ Kf 2.5 X 104

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b) AgCt2 Kf= 1.8 X 10 5 .
c) Cu(NH3)l+ K.i 9.1 X 10- 13

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Kf= 3.0 X 10 10
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d) CO(OH)3
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e) Cu(OH)l- K.i 3.3 x 10-
25. In a solution in which the fluoride ion concentration is 0.20 M, what is the equilibrium
concentration of Ca2+? Ksp for CaF2 := 3.9 x 10'11.
. a) 3.9 x 10'11 M
b) 9.8 X 10,11 M
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c) 2.4 X 10,10 M
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d) 9.8 X 10,10 M
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26. The heat of vaporization of water at 373 K is 40.7 kJ I moL When 9.00 g of steam
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condenses at 373 K, what is the value for t..H?
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a) 4.52 kJ
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b) -4.52 kJ
c) -20.3 kJ
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d) 20.3 kJ
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27. How many mol of Fe(OH)2, Ksp = 2.0 X 10. 15 , will dissolve in 2.0 L of water
buffered at pH = 12.00?
a) 2.0 x 10,11 mol
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b) 2.0 x 10'9 mol
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c) 4.0 x 10,11 mol
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d) 1.0 x 10,11 mol
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e) 4.0 x 10,9 mol
28. \Vhich of the following is true for a isolated system?
a) q = 0, w = 0, and ~E =0
b) w= oand ~E=q
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c) q =Oand~ w
d) q -w and ~E 0
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e) None ofthese is correct.
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29. The concentration of Ca2+ in a sample is 0.087 M. At what pH ""rill 95.0 % of the
Ca2+ be precipitated as the hydroxide? (Ksp for Ca(OHh 6.5 x 10-6).
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a) 12.59
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b) 10.96 Sm
c) 9.87
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d) 11.94
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30. High purity benzoic acid (C6H5COOH ; ~Hcomb = -3227 kJ I mol) is used as a standard
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for calibrating bomb calorimeters. A 1.221 g sample burns in a calorimeter (heat

capacity::: 1365 J I·C) that contains exactly 1.200 kg of water (specific heat capacity
4.184 Jig' K). What temperature change is observed?
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a) 6.427 ·C
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b) 4.795 ·C
c) 7.579 'c
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d) 3.113 ·C
e) ~ one of these is correct.
PERIODIC CHART OF THE ELEMENTS
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VilA VIII)
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1.0079 ....
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2
IIA
l
IliA
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nBb C
4.00200
3 4 5 6' 7 8 9 10
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Li Be N () F Ne
6.941
11
9.01218
12 r
a ,AI
10.811 12.011 14.0067 15.9994 18.9994Q3 ZO.179
13 14 15 16 17 18
Na Mg
m Si P 5 cr Ar
22.98911 24.305
19
Sc Ti V Cr Mn Fe Co ia
20
K Ca 44.9559
21 22 23 24
I
25 26 27
Ni Cu Zn Ga Ge As Se Br Kr
28 S 29 30
26.981539 28.0855 30.97316 32.066 35.453 39.948
31 32 -33 34 35 36
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47.88 50.9415 51.996 54.9380 55.847 ~8.9332( 58.69 63.546 65.39 69.723 72.61 74.9216 78.96
Nb Mo Tc Rued
39.0983 40.078 79.904 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr
85.4678 87.62 88.9059
a
91.224 92.9064 95.94 r n
Rh Pd Ag Cd
' (96) 101.07 102.905~ 106.42 107.86~ 112.41
In Sn Sb Te I
114.82 118.710 121.75 127.60
Xe
~ 26.'045 131.29
Reh Os Ir opt Au
55 56 57 72 73 74 75 76 78 79 80 81 82 83 64 85 86
Ta W S TI Pb Bi Po At Rn
Cs Ba *La HI
~.~
132.9054 137.33 138~9055
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178.49 180.9479 183.85 186.207 190.2 192.22 195.09 196.9665 ~04.383~ 207.2
208.9804 (ZO~ (ZtOI IZZZf
Dble59 Bh Hs Mt
87 08 09 104 105 106 107 108 109
fi
Fr Ra 227.0111
(223)
'Ac (261Rf)
226.02~ (Z6Z) (263) (262) (265) (266)
h is 58 59 60 61 62 63 64 65 . 66 67 68 69 70 71
T Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er, Tm Yb Lu
140.115 140.90n 144.24 (1~5' 150.36 151.96 157.25 168.926-4 162.50 164.9304 '167.26 168.~2 173.04 114.9€1 j
90 91 92 93 94 95,,96 97 96 ,99 100 101 102 103
Th Pa U Np Pu Am"m Ok Cf Es Fm Md No Lr I
llZ.0J81 131.0359 138.029 137.04112 (244) (243) (247) (247) (25t' 1251/ (257) (1511/ (259/ (2 601 I
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CHEM 112
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Exam 2
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Spring 2010 NAME:
Dr. Thomas Berg
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Questionsl-30: 5 points each
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USEFUL INFORMATION:
6.G=6.GO + RTlnQ k = 1.381 x 10-23 J I K
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m [K21 K1 ] = - [MIo I R] [(1 j T2) - ( 11 T1) ]
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m [k2 /k1 ] =- [Ea/R][(l 1T2)-(1/Tl)]
k = A e-(Ea I RT)
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R = 8.315 J I (mol • K)
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[ ] = -let + [ ]0
m[ ] = -let + In[ ]0
1. Which of the following is true?
a) A spontaneous process must be exothermic and must have an increase in

entropy.
b) A spontaneous process must be endothermic and must have an increase in
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entropy.
c) A spontaneous process must be exothermic and must have a decrease in
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entropy.
d) A spontaneous process must be endothermic and must have a decrease in
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entropy.
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e) None of these need be true.
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2. "Average rate" is defined as the:
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a) change in concentration at a particular time.
b) equation showing how the rate depends on the concentration of each

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reactant.
c) rate of reaction at a particular time.
d) rate of reaction during a time interval.
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3. Which ofthe following statements is true?

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a) As long as the disorder of the surroundings is increasing, a process will be

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spontaneous.
b) For any process, ,6.Ssurr and ,6.SsYS have opposite signs.

is
c) If ,6.Ssurr = - ,6.Ssys , the process is at equilibrium.

Th
d) ,6.So is zero for a chemical reaction at constant temperature.
e) None of these is true.
4. Consider the following initial rates:
-MA] I ~t 0.020 Mis
-~[B] / ~t = 0.015 Mis
~[C] / ~t = 0.10 M / s
m
~[D] / ~t = 0.0050 M / s
co
What is the balanced chemical reaction for the above species?
rr.
a) 3 A + 3 B -4 5C + D
blu
b) 3 A + 5B -4 10 C + 5 D
n
c) 4A + 3 B 20C + D
tu
-4
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d) 4A + B -4 10 C + 5 D

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2
5. The value of Kp is 1.35 x 10 at 182°C for a particular reaction. Assuming the
via
value of Mfo is 43.1 kJ / mol and is independent of temperature over this
temperature range, at what temperature will the value ofKp equal 2.11 x 104?
ed
a) 544°C
ar
b) 221 °C
Sh
c) 411 °C
d) 359°C
is
file
6. The first order reaction: S02Cf2(g) - 4 S02(g) + Cf2 (g) ,has a half-life of
is
8.75 hours at 593 K. How long will it take for the concentration ofS0 2Cf2 to fall
to 20.5 % of its initial value?
Th
a) 0.128 hr
b) 2.90 hr
c) 7.81 hr
d) 20.0 hr
7. Consider the following set of data that was obtained by the method of initial rates
for the reaction:
- -
S20{(aq} + 3 I (aq) ~ 2 SOl-(aq) + 13 (aq)
What is the rate law for the reaction?
lli60l12 M Initial Rate 2 M . 8 1
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Expt [I ]2 M
j
1 0.25 0.10 9.00 x lO-
2 0.10 0.10 3.60 x 10-3
2.16x 10-2
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'"'
j 0.20 0.30
a) Rate = k[S20l-] [I ]
r
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b) Rate = k[S20{] [f]3
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c) Rate k[S20l] [ff
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d) Rate = k[S20l]2 [f]
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Sm
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2 HCt(g) + A~O(s) -r 2 AgCt(s) + H20(t) .6,.0° = 61.00 kcal

d
2 HCt(g} + Ag2C03 (s) ~ H20«() + 2 AgCt(s) + CO 2 (g) .6,.0° = -53.37 kcal

re
What is the standard free energy • .6,.0°, for the following reaction?
ha
A~C03(S) ~ Ag20(s) + C02 (g)

S
a) 7.63 kcal
is
b) -7.63 kca1
ile
c) -114.37 kcal
f
is
d) -68.63 kcal
Th
e) 114.37 kcal
9. Consider the conversion of white tin to gray tin:
Sn(s ,white) ~ Sil(s, gray) L'lH' = -2.090 kJ I mol L'lSO = -7.410 J ! (K' mol)
Based on these data:
om
a) white tin is stable below 8.90 °C and grey tin is stable above 8.90 DC.
b) gray tin is stable below 8.90 DC and white tin is stable above 8.90 DC.
r.c
c) gray tin is stable below 15.3 °C and white tin is stable above 15.3 DC.
lur
d) white tin is stable below 15.3 °C and gray tin is stable above 15.3 DC.
nb
tu
10. If~he units for the rate are M . min- 1, what are the units for the rate constant, k, if
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the overall order of the reaction is four?
Sm
a) min- I
b) M-1 'mm
·-1
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c) M'min- I
d) M-2 'mm
d
·-1
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a
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II. Which ofthe following processes has the correct sign for L'lSo?
is
I 2 S02(g) + 02(g) ~ 2 S03(g) L'lSo > 0
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II KBr(s) + H 2O«() ~ KBr(aq) ASo <0
III 2 K(s) + Br2(c) ~ 2 KBr(s) AS <0
is
a) II only
Th
b) III only
c) II and III only
d) I and II only
e) I, II, and III
12. Using the data below, what is the value of flGo for the following reaction?
flGorfor S02(g) = -300.4 kJ I mol and flGcrfor S03(g) = -370.4 kJ I mol
a) -70.0 kJ
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b) 70.0 kJ
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c) -670.8 kJ
lur
d) 670.8 kJ
nb
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13. Iodide and hypochlorite ion react in aqueous solution according to the reaction
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below: - - - -
I (aq) + oce (aq) ---+ 01 (aq) + ce (aq)
Sm
If the concentration of OH in the solution is doubled, the rate of the reaction is
halved. What is the order of the reaction with respect to OH-?
via
a) 0
b) -2
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c) -1
a
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d) 1
e) 2
is
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14. Which of the following is not true?
a) A spontaneous process is one that occurs on its own without outside
is
interference.
Th
b) A spontaneous process may be slow as well as fast.
c) The reverse of a spontaneous process is always nonspontaneous.
d) A spontaneous process leads to an increase in entropy for the universe.
e) All of the above are true.
15. The following data were collected for the decay of H02 radicals:
Time, s [H0 6], molec I cm3

o 1.0 x lOll
10
2 5.0x 10
6 2.5 X 10 10
14 1.25 x 10 10
30 6.225 X 109
m
co
Which of the following statements is true?
rr.
a) The decay ofH02 occurs by a first order process.
blu
b) The half-life ofthe reaction is 4 s.
c) A plot of In [H02] versus time is linear with slope of -k.
n
tu
d) The rate of the reaction increases with time.
ar
e) A plot of 1 I [H02] versus time is linear with a slope ofk.
Sm
16. For the hypothetical zero order reaction: A -.... products, the general rate law
is rate = k. How long is the third half-life of the reaction if [AJo is 0.150 M and
via
the first half-life is 15.0 min?
a) 5.00 min
ed
b) 7.50 min
ar
c) 3.75 min
Sh
d) 15.0 min
is
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17. What is the value of L'lSoSUlT for the following reaction at 25°C?
L'lHO = -826 kJ
is
Th
a) 857 J I K
b) 2.77 x 103 J I K
c) -3.30 x 104 J IK
d) -2.77 x 103 J I K
18. Consider the following equation:
CaO(s) + C02(g) ~ CaC0 3(s) L).H' -177.6 kJ I molrxn
Which of the following statements best describe the thermodynamic conditions

under which the reaction is spontaneous?
a) The reaction is spontaneous at all temperatures.
om
b) The reaction is expected to be spontaneous under conditions of relatively
high temperature.
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c) The reaction is not spontaneous at all temperatures.
lur
d) The reaction is expected to be spontaneQus under conditions of relatively
nb
low temperature.
tu
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19.
Sm
Consider the following hypothetical reaction:
2 A(g) + 3 B(g) + C{g) ~ products

via
If the rate law is: Rate = k[A]2 [B]3, what is the order with respect to C?
a) zero
ed
b) first
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c) second
Sh
d) third
is
e) Cannot be determined from this rate law.

file
20. In the Boltzmann formula is S = k In W. A perfectly ordered crystal at absolute

zero has a molar entropy of 0 because:
is
a) W = o.
Th
b) k = O.
c) W = 1.
d) k 1.
e) W = NA ( Avogadro's number ).
21. For the conversion of water to ice at ~ 15°C and 1 atm:
a) l>.G is positive and l>.H is negative.
b) l>.G is negative and l>.S is positive.
c) l>.G is negative and l>.H is positive.
om
d) l>.G is positive and l>.S is negative.
r r.c
blu
22. The mechanism for the following reaction has 3 steps:
C4H 9Br + 2 H20 - C4H9OH + Br + H30+
n
tu
Mechanism:
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(step 1) C4H9Br - C 4H 9+ + Br (slow)
(step 2) C4H9+ + H 20 -
SmC 4H90 H 2+ (fast)
(step 3) C4H90H2+ + H 20 - C4H90H + H30 + (fast)

via
What is the rate law predicted from this mechanism?
a) Rate = k[C4H9Br]
d
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b) Rate = k[C4H9Br] [H20f

ha
c) Rate = k[C4H9+] [Br-]

S
d) Rate = k[C4H9Br] [C 4H9+]

is
e) Rate = k[C 4 H90H2+] [H2O]

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23. Which of the following is a criterion for spontaneity that holds for any process?
f
is
a) l>.G < 0
Th
b) l>.G > 0
c) l>.Go < 0
d) l>.Stotal < 0
e) l>.Stotal > 0
24. At 2200 K the reaction CaO(s) + S03(g) ~ CaS04(s) is nonspontaneous,
whereas it is spontaneous at room temperature. Which ofthe following
statements is not true?
a) ~G is negative at room temperature.
b) Both ~H and ~S are negative for the reaction.
om
c) ~G becomes zero at a temperature between 300 K and 2200 K.
r.c
d) The change in enthalpy is the main driving force of the reaction.
lur
e) The change in entropy is the main driving force of the reaction.
nb
25. The decomposition of cyclopropane was observed at 500. °C and its concentration
tu
was monitored as a function of time. The data set is shown below. What is the
order ofthe reaction with respect to cycloprapane?
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Time, min [cyclopropane!, M
Sm
o 1.00 x 10'
60. 0.51 X 10'2
120. 0.33 X 10'2
0.24 X 10'2
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180.
240. 0.20 X 10'2
a) zero
d
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b) first
a
c) second
Sh
d) third
is
e) Cannot be determined from the limited data.

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26. Arrange the following substances in order of increasing molar entropy, So, at
25°C.
is
Th
27. Hydrogen iodide decomposes at 800 K via a second order process to produce
hydrogen and iodine according to the following chemical equation:
At 800 K, it takes 471 s for the initial concentration ofRI to decrease from
4.75 x 10.2 M to 1.50 x 10'z M. What is the rate constant for the reaction at this
temperature?
om
a) 4.65 x 10-5 M· l . S·l
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b) 9.68 X 1O.Z M· l • S·l
lur
c) 10.3 M· l . S·l
nb
tu
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28. The rate constant, k, for the first order reaction is equal to 4.88 x 10.3 min· l • What
Sm
is the half-life for the reaction?
a) 134 min
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b) 233 min
c) 79.8 min
e d
d) 142 min
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Sh
29. When heated, mercury(II) oxide decomposes into elemental mercury and oxygen:
is
2 HgO(s) 2Hg(C) + ~Ho 181.6kJ ~So=216J/K

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-+ OZ(g)
What is the approximate temperature at which HgO should begin to decompose if

the partial pressure ofOz(g) is constant at 1.00 atm?
is
Th
a) -34.9°C
b) 34.8°C
c) 568 ·C
d) 643°C
e) 840 °C
30. i\rcheologists can detennine the age of artI-'iacts made of wood or bone by
measuring the concentration of the radioactive isotope 14C present in the object.
If 15.5 % of the original amount of 14C present in a wooden tool at the time of
analysis, what is the age of the tool? (tU2 of 14C is 5730 yr.)
'a) 2.27 x 104 yr
m
b) 9.79 X 10 yr
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4
c) 1.54 x 10 )'T
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d) 1.07 X 104 yr
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e) 7.73 x 103 yT
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PERIODIC CHART OF THE ELEMENTS
IA - H
1 "
VilA Vlllt
I~
1.0079
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IIA
r
lilA
r IVA
.c VA ViA
He
4.00260
Blu C
J 4 5 6 7 8 9 10
Be
Li 9.01218
n,AI b N () F Ne
10.811 12.011 14.0067 15.9994 18.99S403 20.119
u
6.941
rt
11 12 13 14 15 16 17 18
Na Mg Si P S CI Ar
a 26.981539 28.0655 30.97376 32.066 35.453 39.948
m
22.98911 24.l05
19 20 21 24 25 26 27 20 29 33 35 36
S Cu Zn Ga Ge As Se
22 23 30 31 32 J4
K Ca Sc Ti V Cr Mn Fe Co Ni Br Kr
39.0983 40.078
37 38
44.9559 47.88
39 40 41
Ru
42 43 44 45
Rh
i a
50.9416 51.996 54.9380 55.847 59.9332~ 58.69
46
63.546
v Pd Ag Cd In Sn Sb Te
47
65.39
48
69.723
49
72.61
50
74.9216 78.96
51 52
79.904 83.80
53 54
Rb Sr
85.4678 87.62
Y Zr Nb Mo " Tc
e dn
(98)
88.9059 91.224 92.9064 95.94 101.07 102.905~ 106.42 ~O7.868~ 112.41 114.02 110.710 121.75
I Xe
127.60 26.'045 131.29
55
Ba *La HI Ta W ReaOs
56 57 72
r Ir 'Pt Au ra!JI TI
73 74 75 76 78 79 80 81 82 83
Pb Bi Po At Rn
04 85 86
Cs
S h
132.9054 137.33 138',9055 178.49 180.9479 183,85 186,207 190.2 192.22 195.09 196.9665 204.38Y 207.2 208.9804 (209) (Z101 FZZ)
is Bh Hs Mt
87 68 89 104 105 106 107 108 109
Fr Ra 'Ac Rf Db 59
if le
(tlJ) 226.02504 227.0211 (261) (262~ (26J) (262) (265) (266)
s
58 63 . 66 67
i
59 60 61 62 64 65 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Vb Lu
T h 140.115 140.9Qn 144.24 (145) . 150,36 151.9& 151.25 168.9264 162.50 164.9304 161.26 168,9342 173.04 174.%1
[90 Pa U Np Pu Am em Bk Cf91 92 93 94 95 .96 97 98 ,99 100

Es Fm Md No Lrl
101 . 102 10J
1!~1 131.0359 138.029 237.MB1 (244) (243) (247) (247) (2 51 1 {251,

(151) (2Sn) (259) (Z601
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'::f.1l<f¥It ~ I + <~
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f<.J::i..2... 3.(,0 ~JtJ k(o.JO~)?- (o.~ (f
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~6°= r4.AG-f~P) ~ 2/?1·4.Gt~(R)

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:::; -I¥().o KJ
c.. /3 t<~~:: k fait:] '\l
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tai -1.111.. ':. .;?.s =) Je~ i ;/O,z <4 ~tP.. dLJ.e.r -

'<JlJ. --I. liz. ::. '-/S (J
31'J. tl/I...':: £- S
t/ 4 tIll.. ::' JI..s
1uv ~'--«r- dl.1.<:.;'; ~z.". . ~ flu jv-J(AJ r .
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A JCJ
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t:.~ >0 /dU oJJl.~
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4 G- AH - T ~s
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(_) = AH t (r)
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~~ K'IJ1 ~ SjJ~ d ;:rr (')'$0<' Sm vv ;/9f)<:.) =.) A G- ~ -)
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2'-10. t) .20 x/t)- 2..

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~ Hi (if) -) r4 <(j) + 1z.t~)
Rv.L...::: k 1Hzl '

( JI[HIlt):; kt -r ( Y[HIJu)
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I.S"0 x/o :<m :: k ( .II? I .s) 1- "I. ?J" X/() -"fdt
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1-
~ 9) - <. J?l. . /. ..s-t
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C 60 9.1f( 4!)" -~-t wh~ k;, ,b'o/tl/l.

a
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o ' b<fJ I _ - t./ - t

~=. IS?Jo (Jr' - I.;(o~ X/O if"
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J'1(ISS) .: -UO<:t'~/tJ'ri'(tJ
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-1').4; X'O'<l .20
CHEM 112
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Exam 3
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Spring 2010 NAME: -

-----
nb
Dr. Thomas Berg
tu
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Questionsl-30: 5 points each
via
USEFUL INFORMATION:
ed
6.G = 6.GO + RT In Q amp = coulomb I s

ar
In[K2 IK l] =-[Lillo/R] [(lJT 2) -(lIT I ) ]

}1 = 96,486 C
Sh
S= SO - (0.0592 V / n) log Q
In [k2/kJ] =- [Ea/R][(l IT2)-(1 IT l ) ]
is
S= SO - (0.0257 V I n) In Q
k = A e-{Eal RT)
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R= 8.315 J I (mol· K)
6
is
kwh = 3.6 x 10 J
Th
Sox::::: -1.4 V
2 H 2 0(e) + 2 e- ----7- H 2(g) + 2 OH-(aq) Sred ::::: -1.0 V
2 SOl-(aq) ----7- .S2082-(aq) + 2 e- SO ox = -2.00 V
1. Consider a reaction that occurs by the following mechanism:
Step 1: A + BC -+ AC + B EaJ = 125.0 kJ
Step 2: AC + D -+ A + CD Ea2 = 35.0 kJ
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t 2
~
e
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-a
•.:;:t
5
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'0
r:l.I 5
nb
1
tu
Reaction progress .....
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If ~Hoverrall = 20.0 kJ and the energy at stage 3 is 55.0 kJ, what is the activation energy
for step I? Sm
a) 90.0 kJ
b) 70.0kJ
via
c) 105.0 kJ
ed
d) 35.0 kJ
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Sh
2. The decomposition of ozone in the stratosphere can occur by the following two
step mechanism:
is
Step 1: Br + 03 -+ BrO + 02
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Step BrO + 0 -+ Br + 02
is
Which species is an intermediate in this mechanism?
Th
a) Br
b) BrO
c) 0
The aq.uation of tris(l, 1.0-phenanthroline)iron(II) in acid solution takes place
accordmg to the followmg equation:
Fe(phen)/-'-(aq) + 3 H3 0+(aq) + 3 H2 0([) -.. Fe(H 2 0)l+(aq) + 3 phenH\aq}
If the activation energy is 126 kJ I mol and frequency factor is 8.62 x 10 17 -I t

h . h s ,a
w at. temperature 1S t e rate constant equal to 3.63 x 10-3 S·l for the first-order
reactIOn?
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a) O°C
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b) 36°C
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c) 50.·C
nb
d) 71°C
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e) 94 °C
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4. The decomposition of hydrogen iodide:
Sm
. Ifthe rate constant is 9.51 x 10.9 M· l • S-1 at 500. K and 1. 10 x 10-5 M- 1 • S-I at 600. K,
via
what is the activation energy for this reaction?
a) 3.41 x 102 kJ I mol

e d
b) 5.39 x 102 kJ .I mol

ar
c) 2.73 x 102 kJ I mol

Sh
d) 4.32 x 102 kJ I mol
is
e) 1.76 x 102 kJ I mol
file
5. A certain biologically important reaction is quite slow at physiological temperature,

37. 0 'c, in the absence of a catalyst. Assuming that the value of A is constant, by how
is
much must an enzyme (biological enzyme) lower the activation energy of the reaction in
Th
order to achieve a 1.00 x 105 fold increase in the reaction rate at the same temperature?
a) 14.5 kJ I mol
b) 11.5 kJ I mol
c) 53.5 kJ I mol
d) 37.3 kJ I mol
6. Consider the following reaction diagram:
/
m
co
[R]
rr.
[P]
blu
Step _ is the fastest step while step ~ is the slowest.
a) 1 ; 2
n
tu
b) 1 ; 3
ar
c) 2 3 Sm
d) 3 1

via
7. How many of the following are correct matches of the element in bold and its
ed
oxidation number?
-
ar
As0 2 ; +3
Sh
2
Cr207 ; +6
Cu(N03)2 +2
is
uol+ ; +4
file
a) 0
is
b) 1
Th
c) 2
d) 3
e) 4
8. Consider the following standard reduction potentials:
-
C r 3+ (aq) + 3e ---+ Cr(s) ~o = -0.73 V

Mn 2+ (aq) + 2e ---+ Ml1{s) ~·=-1.18V
-
2+ ~.
Ca (aq) + 2e ---+ Cacs) -2.76 V
om
Which of the following reactions should be spontaneous under standard
conditions?
r.c
I Mn2+ (aq) + C acs)
lur
II 2 Cr3+(aq) 3 Ml1{s) ---+ 3 M n 2+ (aq) + 2 Cr(s)
nb
a) I and II are both nonspontaneous.
tu
b) I is nonspontaneous and II is spontaneous.
ar
c) I is spontaneous and II is nonspontaneous.
Sm
d) I and II are both spontaneous.

via
9. Use the data below to calculate Ksp at 25 ·C for PbS04 •

ed
SO/-(aq) + 4W(aq) + 2 e- ---+ H2S03(aq) + H 20 Cf) ~o = 0.20 V

ar
~o -0.13 V
Sh
-
PbS04 (s) + 2 e -0.36 V
is
a) 2.6 x 10-4
file
b) 5.9 X 10-7
c) 3.9 X 10-6
is
Th
d) 1.3 X 10-4
10. When the following half reaction is properly balanced in basic aqueous solution,
what is true?
ceo (aq) -+ Cf (aq)
a) 2e on the left
b) 3 e on the left
om
c) 3 e on the right
r.c
d) 2 e on the right
lur
nb
tu
11. Consider the following standard reduction potentials:
ar
~o = 0.80 V
Sn4+ (aq)

+ 2e
Sm
-+
Sn2+(aq) ~o = 0.15 V
What is the standard cell potential for the cell shown below, and determine
whether or not this reaction is spontaneous under standard conditions?
via
4+ 2+ 2+
Sn (aq) + 2 Hg(c) -+ Hg2 (aq) + Sn (aq)
ed
a) 0.65 V ; spontaneous
ar
b) 0.65 V ; nonspontaneous
Sh
c) -0.65 V nonspontaneous
d) -0.65 V spontaneous
is
file
12. Which of the following is not a correct matche of the reactant molecule and its
is
identity?
Th
a) N2~ -+ N2 ; reducing agent
b) Cr02 -+ CrOl- ; oxidizing agent
d) Ag+ -+ Ag ; oxidizing agent
e) Two ofthe above are not correct matches.
13. When the following reaction is properly balanced in acidic aqueous solution, what
is the coefficient in front of water?
a) 1
om
b) 2
c) 3
r.c
d) 4
lur
e) 5
nb
14. What is the shorthand notation that represents the following galvanic cell
tu
reaction?
2 At(s) + 3 Ni(N03)2(aq) ---+ 3 Ni(s) + 2 At(N03)3(aq)
ar
a) At cs) I At3+(aq) I Ni2+(aq) I Ni(s)
Sm
b) At3+(aq) I At(s) I Ni(s) I Ni2+(aq)
Ni2+(aq) I Ni(s) I At(s) I At3+(aq)
via
c)
3
d) Ni(s) I Ni2+(aq) I At +(aq) I At(s)
e
ar
Sh
15. Consider the cell based on the following reaction:
2 Hg(c) + H202(aq) + 2 H\aq) ---+ Hgl+(aq) + 2 H 2 0(c)

is
The cell potential,~, is 0.70 V. If the [Hgz2+] is 0.10 M and [H20 2] == 0.085 M,·
file
what is the pH of the cell solution?
a) 5.17
is
b) 7.36
Th
c) 1.82
d) 3.68
16. Which statement is true?
a) The cathode is positive for a galvanic cell and negative for an electrolytic
celL
b) Oxidation occurs at the anode in a galvanic cell and at the cathode in an

electrolytic cell.
om
c) Electrons flow through the external circuit to the cathode in a galvanic
cell and to the anode in an electrolytic cell.
r.c
d) Oxidation occurs at the cathode in a galvanic cell and at the anode in an
electrolytic celL
lur
e) None of thee is correct.
nb
tu
17. What is the relationship between the standard cell potential, ~o, for the following
two galvanic cell reactions?
ar
Sm
via
a) ~O(I) ~'(II)
b) ~O(I) = ~ ~'(II)
ed
c) ~O(I) = 2 ((II)
ar
d) ~'(I) = -~'(II)
Sh

is
18. When the following half reaction is properly balanced in acidic aqueous solution,
what is true?
file
N0 3 (aq) -+ N2 0 3(aq)
is
a) 2e on the right
Th
b) 3 e on the left
-
c) 4 e on the left
d) 5 e on the right
19. Consider the following cell:
Cr(s) I Cr3+(aq, 0.055 M) II Cr3+(aq, 1.435 M) ICr(s)

What is the cell potential, ~?
;a) 0.080 V
om
b) 0.000 V
c) 0.131 V
r.c
d) 0.028 V
lur
nb
tu
20. How many grams of cadmium metal are plated out when a constant current of
9.55 A is passed through an aqueous CdBr2 solution for 75.0 min?
ar
a) 1.1Og
Sm
b) 50.1 g
via
c) 27.3 g
d) 25.0 g
e d

ar
Sh
21. If the cell reaction involves gases in solution, as the cell reaction in a
galvanic cell continues:
is
a) ~ for the cell increases but ~. remains constant.

file
b) both ~ and ( decrease.

is
c) ~ for the cell decreases but ~' remains constant.

Th
d) both ~ and ~' increase.
e) N one of these is correct.
22. Consider the galvanic cell made up by the two half cell reactions:
N2(g} + 5 H~(aq) + 4 e - N2HS7(aq) (= -0.23 V

2
Pb +(aq) + 2 e - Pb(s) ~'= -0.13 V
Which of the following changes to the cell would cause the cell potential to
m
increase (become more positive)?
co
a) increase the concentration ofN2Hs+
rr.
b) increase the concentration of Pb2+
blu
c) increase the pressure of N2
d) decrease the pH
n
tu
e) Two of the above would increase the cell potential.
ar
Sm
23. When the following reaction is properly balanced in basic aqueous solution, what
is the coefficient in front of water?
Sees) + Cr(OH)3(aq)
- Cr(s) + Se03
2
(aq)
via
a) 5
ed
b) 7
ar
c) 9
Sh
d) 11
e) 13
is
file
24. What is the standard cell potential for the reaction below?
2 ~s) + 3 Br2(C)
3
- 2 M \aq) + 6 Br-(aq)
is
3
The standard reduction potential is -1.76 V for the M + / M half cell.
Th
a) 0.69 V
b) 2.83 V
c) -0.69 V
d) -2.83 V
25. Based on the following infonnation,
(= 1.61 V
~'= 2.08 V
which of the following chemical species is the strongest reducing agent?
om
a) HCfO
b) O2
r.c
lur
nb
tu
ar
26. Consider the reaction:
Sm
If the standard free energy is -540. kJ, what is ~. for a standard cell based on this
via
reaction?
a) 2.80V
e d
b) 1.40 V
ar
c) 0.932 V
Sh
d) 1.87 V
is

file
27. What is the length of time required to electroplate 5.39 g of Ag from a 3.50 M
KAg(CN)2 solution at a current of2.00 amps?
is
a) 6.89 x 102 s
Th
b) 1.69 X103 S
c) 2.41 X 103 s
d) 4.82 X 103 s
3
e) 8.44 x 10 s
28. What is the cell potential, ~, at 25 'c for the reaction,
where [Au3+] 0.450 M, [H+] 0.100 M, and PH2 = 0.500 atm?
a) 1.50 V
om
b) 1.58 V
r.c
c) 1.42 V
lur
d) 1.55 V
nb
tu
29. A current is passed through two 'cells connected in series. The half-reactions
occurring at the cathode of each cell are:
ar
AUC(4 (aq) + 3e Sm~ Al1(s) + 4 C.(aq)
2 -
Cu +(aq) + 2e ~ Cl1(s)
via
If 11.5 g of copper is deposited in the second cell, how much gold is formed in the
first cell?
a) 17.3 g
b) 35.6 g
ar
Sh
c) 53.5 g
d) 7.67 g
is
file
30. \Vhat is the charge on rhodium (Rh) where a current of3.00 A is passed through a
is
solution of this ion for 1.00 hr to produce 3.84 g ofRh?

Th
a) +1
b) +2
c) +3
d) +4
e) +5
Standard Eleetrode (BaU..£eIJ) Potentials (298 K)*
HALF-REACTION
F2 (o) + 2e- ~ 2F-(aq) +2.87

0;(0) + 2H+(aq) + 2e- ~ 02(S) + H2 0(l) +2.07
Co 3+(aq) + e- ~ Co2+(aq)
+ 1.82
Hp2(aq) + 2H+(aq) + 2e- ~ 2H 2 0(l)
+1.77
Pb0 2(s) + 4H+(aq) + SO/-(aq) + 2e- ~ PbS0 4 (s) + 2H z0(l)
+1.70
Ce4+(aq) + e- ~ Ce3+(aq)
+ 1.61
om
Mn0 4 -(aq) + 8H+(aq) + 5e- ~ Mn2+(aq) + 4R.O(l)
+ 1.51
AuH(aq) + 3e- ~ Au(s)
+ 1.50
C12 (o) + 2e- ? 2Cl-(aq)
+1.36
r.c
Cr 2 0,z-(aq) + 14H+(aq) + 6e- ~ 2Cr3+(aq) + 7H z0(l)
+1.33
Mn0 2(s) + 4H+(aq) + 2e- ~ Mn2+(aq) + 2H:PU)
+1.23
lur
02(0) + 4H+(aq) + 4e- ~ 2H 2 0(l)
+ 1.23
Br 2 (l) + 2e- ~ 2Br-(aq) +1.07
nb
N0 3 -(aq) + 4H+(aq) + 3e- ~ NO(S) + 2H2 0(l) +0.96
2Hg2+ (aq) + 2e- ~ Hg 2 2- (aq) +0.92
tu
Hg/+(aq) + 2e- ~ 2Hg(l)
+0.85
Ag+ (aq) + e- ~ Ag(s)
+0.80
ar
Fe H (aq) + e- ~ FeH (aq)
+0.77
02(0) + 2H+(aq) + 2e- ~ H20 2 (aq)
Sm +0.68
Mn0 4 -(aq) + 2H 20(l) + 3e- ~ MnOz(s) + 40H-(aq) +0.59
I 2 (s) + 2e- ~ 2I-(aq) +0.53
02(0) + 2H20(l) + 4e- ~ 40H-(aq)
+0.40
Cu2+(aq) + 2e- ~ CUls)
+0.34
via
AgCl(s) + e- ~ Ag(s) + Cnaq)

+0.22
SO/-(aq) + 4H+(aq) + 2e- ~ S02(S) + 2H 2 0(/)
+0.20
Cu2+(aq) + e- ~ Cu+(aq)
+0.15
d
Sn4+(aq) + 2e- ~ Sn2+(aq)

+0.13
e
2H+(aq) + 2e- ~ H:z(g)

0.00
ar
Pb2+(aq) + 2e- ~ Pb(s)

-0.13
Sn2+(aq) + 2e- ~ Sn(s)
-0.14
Sh
Nl(s) + 5H+(aq) + 4e- ~ NlH5 +(aq)

-0.23
Ni2+(aq) + 2e- ~ Ni(s)
-0.25
Co2+(aq) + 2e- ~ Cots)
-0.28
is
PbS0 4 (s) + 2e- ~ Pb(s) + SO/-(aq)

-0.31
Cd2+(aq) + 2e- ~ Cd(s)
-0.40
file
Fe2+(aq) + 2e- ~ Fe(s)

-0.44
Cr3+(aq) + 3e- ~ Cr($)
-0.74
Zn2+ (aq) + 2e- ? Zn(s)
-0.76
is
2H2 0(l) + 2e- ? Hl(S) + 20H-(aq)

-0.83
Mn2+(aq) + 2e- ? Mn(s)
-1.18
Th
Al3+(aq) + 3e- ? Al(s)

-1.66
Mg2+(aq) + 2e-' ~ Mg(s)
-2.37
Na+(aq) + e- ~ Na(s)
-2.71
Ca2+(aq) + 2e- ~ Cats)
-2.87
Sr2+(aq) + 2e- ? Sr(s)
-2.89
Ba 2 + (aq) + 2e- ~ Ba(s)
-2.90
K+(aq) + e- ~ K(s)
-2.93
U+(aq) + e- ~ Li(s)
-3.05
"Written as reductions: £0 value refers to all components in their standard states: 1 M for
dissolved species: I atm pressure for gases; the pure substance for solids and liqUids.
PERIODrc CHART OF THE ELEMENTS
IA - H
1 .....
- om VilA VIII)
~
'.OOl9
r r .c -;} He
2
IIA
l u
lilA IVA VA V(A
nBb C
4.00260
J 4 5 6 7 8 9 10
tu
Li Be N 0 F Ne
6.941
11
9.01218
[12 r
a AI
10.011 12.011 14.0067 15.9994 18,9964Q3 20.179
13 14 15 16 17 18
Na Mg
21.98971 24,305
S m 26.981539
Si P 5
28.0655 30.91316 32.066
CI Ar
35.453 39.948
a
19 20 21 22 23 24 25 26 27 28 29 30 31 32 J3 J4 35 36
39.0983
TI
Sc 47.88
K Ca 44.9559
40.078
V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
v
50.9415 51.996 54.9380 55.847 ~8.9332C 58.69i
63.546 65.39 69.723 72.61 74.9216 78.96 79.904 83.80
Sr Y Zr Nb Mo ,'laf RuedRh Pd A9 Cd In
37 38 39 40 41 42 43 ' 44 45 46 47 48 49 50 51 52 53 54
Rb
85.4678 87.62
a r n
88.9059 91.224 92.9064 95.94 101.07 102.905~
Sn Sb 127.60
106.42 107.869' 112.41 114.82 118,710 121.75
Te I Xe
131.29 120.'1'045
Ba *La HI Ta W Reh Os Ir 'PI Au

55 56 57 72 73 74 75 76 78 79 BO 01 B2 03 64 85 86
Cs
s S fo!JI TI Pb Bi Po At Rn
i
132.9054 137.33 133'.9055 178.49 180,9479 183.85 186.207 190,2 192.22 195.09 196.9665 ~04.383J 207.2 206.9604 (2091 (ltOI (llll
104 107 108 109
Ra lAc Rf DbleS9 Bh Hs Mt
87 88 89 105 106
Fr
(223)
f i
226.025-4 221.01!! (261) Jl6l, (263) (262) (265) ~661_
h is 58 59 60 61 62 63 64 65 . 66 67 66 69 70 71
T Ce Pr Nd Pm Sm Eu Gd Tb Dy
140,115 140.90n 144.24 _ 151.25 168.9264 162.5(1 ~304,~167.26
(145J ' 150~ -_._Uf.96..............
Ho Er Vb
Tm 173.0.4
168.~2
Lu
f14.%1 j
90 91 92 93 94 95 ,00 97 96 ·99 100 101 102 103

Th Pa U Il7.04111 Np Pu Am em Bk Cf Es Fm Md No LrJ
lJl.0J31 231.llJ59 2J8.019 (244) (243) (247) (247) (251 1 fl52J (1 57 1 (259) (l60) (25D~
C(JlJIJ Qi4(J
&:1111--.
J3 I
fJ ~
m
co
c 3
rr.
n blu
tu
ar
Sm
via
ed
ar
Sh
E ~
is
file
is
Th
om
r r.c
n blu
tu
ar
Sm
via
d
re
S ha
is
f ile
is
Th
~~~ ;:; -I, IJ- V
o
~:. -.;: 'ito J/
Gsto ~
&1L
(~Ctm/r4t&-)
om
r.c
lur
nb
tu
ar
Sm
via
d
a re
Sh
is
file
is
Th
om
r.c
lur
nb
tu
ar
Sm
via
ed
ar
Sh
is
file
is
Th
-- IJlj '" (c(.~ >Vb ?)(;?,ll.f-J~ - '1J)Vcl
J. 6./b #( -- - .-11
[I-/:j .;.- ~()t)</6'-1;?(

pil : : 3.6lf
om
A Ifq
/1 I C"--~~1)
r.c
!) + CJ U ) -) GA.(.!) 1- ('J-<tQr)
lur
...<+ :<r
~G" (J ) f,iZ c~ ( 9)
...r':
+;JS'J..(-V
1
JL .? (IA
nb
Ct -;> (CI.'j)
-
tu
C IJ-- AJI13 (4f) -) "o..l03 (ap)
ar
d.{){)j (4 'i) -) 4 ()~ (u'f) Sm
d.Q8- (4 1) -;> J.J",? ~ ('1) -f 3~ O(eJ
via
6)/1(tHi )-1 ;{m; -4 ~ (41) t- 6~ Ore)

'"' (Q y) -)
d
1c.~ -t b~,) r o?AJ~~q7) -) ,t),,/6](4j) t-3~()4)

a re
.b /~ r. - ~d .6S1d,U ![J;Q.;/e~]\
Sh
. _
fcdl -! cell /( Qif ,-[C(IJ1(. s£rJ)

is
:;,. C). 00 V - ,{)Sqdil

. ). ( / -,
\.. O.lJ_ /II))
file
.3 0- (/;</3) #/
is
::: O.06V - ().r<t~

3 1/' (-/, ~ )
I
Th
::: O,CdJ -t , 0 r2 Er V
::: 61~V
Ct~t4. ) +;t e.- ....::::> Cj (J) 0( 1 ~ II.VI .
'l'S ~U(, (_@)(

(J{CJ)" (7 l4!t~
y;~Sc..11 i t )(.;(//~
S J( 7'fI %fc.
~Jt{LflU
~L
(}.() C(J)1 kt it ~
C JI
om
r.c
lur
nb
tu
ar
Sm
via
ed
ar
~-
3 :;~~t J./C(Mb (4f) 1c;.~) 3 J(:~
Sh
-) 1- (47 I
'OH~f>.~) -t3J~!)-t </('r(~II~atJ -) 1<1-uJ +- 3Sc::03~;)

is
-> -1 r:r(J J +3Sc::6.J~~f) 1- '116

file
0())-h,,) 13 SC::(.s) t 1C'r(0II)3(4r)

(6)q 3 el'<I~) ;- ('e -) G:>.er("~) ~J /'MII
is
0:
Th
J.ti1(i) -)~q3c4y) fbe.~_ ; ; ;:- //Jt> V
3iJr;, (Q.) +;,~-n - J (, &(dt) t7..IJJ~;) h '";J.gj II

e af O~) T ot H~{"t) -t~~ -) Dol.~) + tiL 0 (Q) ~~ ~ ).Of-V
"Ulce 0("'1) t"lI~1"'i) t J,e -) o..zg) t- ,) l/2. (J Ii) ;;:J.. '< /,('1 V
m
co
rr.
n blu
tu
ar
Sm
via
ed
ar
Sh
is
file
is
Th
Cvw J/1Lf1/-I
,(Q.d Jt
-
E 29
om
C 30
r.c
lur
nb
tu
ar
Sm
via
ed
ar
Sh
is
file
is
Th
CHEM 112
om
Exam 4
r.c
lur
Spring 2010 NAME: - - - - - -
nb
Dr. Thomas Berg
tu
ar
Questions 1-30 : 5 points each
via
USEFUL INFORMATION:
ed
nm = 10-9 m
ar
ao= 0.529 A
e= 2.998 x 108 m's-1
Sh
h = 6.626 X 10-34 J·s

me = 9.109 x 10-31 kg
= 1.673 X 10-27 kg
is
J = kg'm2 's-2 mp
file
Ry = 2.180 X 10-18 J e = 1.602 X 10-19 C
NA = 6.022 X 1023 mor1 1= he I eVthr

is
Th
Ll(position) Ll(veloeity) ~ hI (41tm ) 1 = h I (2meV)~
En = _Z2 I n 2 (Ry) 1= h I mv
I. How many orbitals are there with the designation n 5 and t = 4?
a) 3
b) 5
c) 7
om
d) 9
r.c
lur
2. \Vhich of the following is a reasonable criticism of the Bohr model of the
nb
atom?
tu
a) It makes no attempt to explain why the negative electron does not
eventually fall into the positive nucleus.
ar
Sm
b) It does not adequately predict the line spectrum of hydrogen.
c) It does not adequately predict the ionization energy of the valence

electron(s) for elements other than hydrogen.
via
d) It does not adequately predict the ionization energy of the 1st

energy level for hydrogen.
ed
e) It shows the electrons to exist outside of the nucleus.

ar
Sh
14
3. What is the wavelength ofa photon of red light whose frequency is 4.60 x 10
Hz?
is
a) 652nm
file
b) 153 nm
is
c) 460. nm
Th
d) 351 nm
4. Which orbital filling diagram violates Hund's rule?
a)
[Ar] tJ.. L L L t
4s 3d
b) [Ar] tt L t L t
m
4s 3d
co
c) [Ar] L L L t L L
4s 3d
rr.
d) tJ.. tJ.. L L
blu
[Ar] -
4s 3d
n
tu
ar
5. Which of the following quantum numbers describes the shape of an
orbital?
Sm
a) principle quantum number
via
b) magnetic quantum number
c) Schrodinger quantum number
ed
d) spin quantum number
ar
e) angular momentum quantum number
Sh
6. What is the energy required to remove the electrons from the third radius of one
is
mole of He+ ions?

file
a) 4.29 x 103 kJ
b) 2.63 X 103 kJ
is
c) 5.25 x 103 kJ
Th
d) 1.75 X 103 kJ
7. Which of the following represent electron configurations that are allowed but do not
represent ground state atomic configurations?
I [Ne] 3s23d4 3p6
II [Ar] 4s2 4 p l
III [Kr] 5s24d 85p6
om
a) I only
r.c
b) III only
lur
c) I and II only
nb
d) I and III only
tu
e) I, II, and III
ar
8. Which of the following has the least energy per photon?
Sm
a) A = 4.35 X 10 12 nm
4.35 10-5 S-l
via
b) v X
c) V = 4.35 X 103 S·l
ed
d) A= 4.35 X 106 run
ar
e) v = 4.35 X 106 S·l
Sh
9. The number of orbitals in a particular subshell is determined by the number of
is
possible values of:
file
a) f.
b) ms·
is
c) me
Th
d) n.
e) None ofthese is correct
10. Which of the following is true?
I All moving objects have wave characteristics.
II For objects moving at a constant speed, the smaller the mass, the shorter
the wavelength.
om
III The Heisenberg uncertainity principle applies to only small particles.
a) I only
r.c
b) III only
lur
c) IandIIonly
nb
d) I and III only
tu
e) I, II, and III
ar
11.
Sm
Light with a A 345.5 nm strikes the surface of a metal with a work function of
19
3.34 x 10- J. What is the maximum kinetic energy of the ejected electrons?
a) 2.41 x 10- 19 J
via
b) 5.41 X 10- 19 J
ed
c) 3.34 X 10- 19 J
d) 9.09 X 10- 19 J
ar
Sh

is
12. Which of these elements has the highest (most negative) first electron affinity?
file
a) Ca
b) N
is
c) Ne
Th
d) S
e) ce
13. Consider the following electron configurations for the neutral atoms:
II Is22s22 p 63s23p4
III 1s22s22p6 3s23p6
om
Which atom would be expected to have the :largest third ionization energy?
r.c
a) atom I
b) atom II
lur
c) atom III
nb
d) All of these would be expected to have equal third ionization energies.
tu
e) ~ot sufficient information to answer.
ar
Sm
14. What is the final value ofn in a hydrogen atom transition, if the electron
starts in n = 1 and the atom absorbs a photon of light with an energy of
2.044 x 10- 18 J7
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a) 3
b) 4
e d
c) 2
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d) 5
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e) 6
is
15. Which of the following occur as the wavelength of a photon increases?
file
a) the frequency decreases
is
b) the energy increases
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c) the speed decreases
d) the amplitud~ gets smaller
e) None of the above occur as the wavelength of a photon increases.
16. \Vhich of the following statements is true?
a) We can sometimes know the exact location and speed of an

electron at the same time.
b) All orbitals in a particular atom are roughly the same size.
om
c) Since electrons have mass, we must always consider them to have
particular properties and never wavelike properties.
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d) Atoms are roughly spherical because when all of the different
shaped orbitals are overlapped, they take on a spherical shape.
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e) None of the above is true.
nb
17. Which of the following ground state species has the largest radius?
tu
ar
b) Ar
Sm
via
d) Ct:
ed
ar
18. Suppose photons of blue light (4.85 x 10.7 m) are used to locate the position ofa
Sh
uranium atom of 3.95 x 10.22 g to an accuracy of two wavelengths. What is the

minimum uncertainity in the speed of this atom?
a) 1.38 x 10.4 m / s
is
7
file
b) 2.75 x 10. m / s
c) 1.38 X 10.7 m/ s
is
d) 2.76 X 10-4 m / s
Th
19. Which of the following represents electron configurations that violate the Pauli
exclusion principle?
I [Ne] 3s 13p 5
12
II [Kr] 4d Ss2Sp3
m
III [Ar] 3d104s24p2
co
a) I only
rr.
b) II only
blu
c) I and II only
n
d) II and III only
tu
e) I and III only
ar
Sm
20. Which of the following spectral regions has the lowest frequencies?
a) uv
via
b) microwave
c) visible
ed
d) IR
ar
e) X-rays
Sh
is
21. Who determined that no two electrons may have the same set offour quantum
numbers?
file
a) Plank
is
b) Pauli
Th
c) Born
d) Heisenberg
e) Hund
22. Which of the following sets of quantum numbers does not specify an
orbital?
n t IDt
a) 2 1 -1
b) 4 2 0
m
c) 3 3 -2
co
d) 0 0
rr.
e) 3 1 -1
n blu
23. The first three quantum numbers are due to the work of _ _~. while the fourth
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quantum number is due to the work
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a) Erwin Schrodinger ; Albert Einstein
Sm
b) Erwin Schrodinger ; Werner Heisenberg
c) Werner Heisenberg ; Erwin Schrodinger

via
d) Erwin Schrodinger ; Paul Dirac
e) Max Plank ; Erwin Schrodinger
ed
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24. A compound that is diamagnetic (repelled from the magnetic field) has the
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following number of unpaired electrons?
a) 0
is
b) 1
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c) 2
is
d) 3
Th
e) Any of these could be correct.
25. Consider an atom traveling at 3.00 % of the speed of light. The de Broglie
wavelength is found to be 6.98 x 10- 16 m. Which element is this?
a) Ca
b) Mg
m
c) Cu
co
d) Sn
rr.
e) Mo
blu
26. Which ofthe follo\\ing atoms or ions has 3 unpaired electrons in its
n
ground state?
tu
a) N
ar
b) 0 Sm
c) At
d) S2
via
ed
ar
27. A sodium vapor lamp has yellow light at Iv = 589 nrn. What is the total energy
released by 1.00 x 106 photons at this wavelength?
Sh
a) 3.37 x 10-25 J
is
b) 1.12 X 10-30 J
file
c) 3.37 X 10- 13 J
d) 3.37 X 10-22 J
is
Th
28. \\'hat is the third Bohr radius of a Be3+ ion?
a) 0.397 A
b) 1.19 A
c) 1.59 A
om
d) 0.705 A
r.c
lur
nb
29. How many subshells are in a single shell?
a) n
tu
ar
b) 2n - 2
c) 2n
Sm
2
d) n
via

ed
30. A 3dxy orbital should have a total of _ _ nodes.

ar
a) 0
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b) 1
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c) 2
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d) 3
e) 4
is
Th
PERIODJC CHART OF THE ELEMENTS
- 1
om
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-- -
I-
IA H VilA VIII)
1.0019
r r ...
,,,A luIvA
/ 2
I~ --}
He
IIA
n b VA V(A 4.00100
rtu B C
3 4 5 6 7 8 9 10
Li Be N () F Ne
6.941 9.01218
a 10.811 12.011 14.0061 15.9994 18,998403 20.179
m
11 12 13 14 15 16 17 18
AI Si Ar
Na Mg
S P 5 CI
a
21.98977 24.305 26.981539 28.0855 30.97376 32.066 35.453 39.940
Ca Sc Ti V Cr Mn Fe CoviNi Cu Zn Ga Ge As Se Br Kr
'9 20 21 22 23 24 25 26 27 28 29 30 31 32· ·33 34 35 36
K
39.0983 40.078 44.9559 41.88
e d
50.9415 51.996 54.9380 55.847 58.9332( 58.69 63.546 65.39 69.123 72.61 14.9216 78.96 79.904 83.00
r
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb
65.4676 67.62
Sr Y Zr Nb Mo Tc Ru
h a n Rh Pd Ag Cd In Sn Sb Te I Xe
68.9059 91.224 92.9064 95.94 . (96) 101.01 102.905! 106.42 h07.868~ 112.41 114.62 116,710 121.15 127.60 ~ 24.9045 131.29
I 55 56 57 72
S 73 74 75 76 78 79 00 01 02 83 84 85 86
is
Ba *La HI Ta W Re Os Ir 'Pt Au TI Pb Bi Po At Rn
Cs
132.~ 138~9055 ~JI
178.49 180.9419 183.85 186.207 190.2 19~.22 195.09 1.96.966~ 204.383~ 201.2 208.9804 (209, (Z10) (2221
if le59 Bh Hs Mt
137.33
87 88 89 104 105 106 107 108 109
Fr Ra lAc Rf Db
(ZZ3)
h i s
226.025-4 227.0111 (261 ) fZU) (263) (262) (265) (266)
T Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er, Tm Vb LU
58 59 60 61 62 63 64 65 . 66 67 68 69 70 71
t.
140,115 140.901! J44.24 ( 145 150.36 151.96 151.25 168.9264 162.50 164.9304 167.26 168.9342 17J.P4 114. IJ€1 j
92 93 . 95
Th Pa U Np Pu Am c7n Bk Cf Es Fm Md No Lr
90 91 94 97 98 ·99 100 101 102 103
132.038t 131.0359 138.029 2l1.0482 (244) (243) (241) (247) (251, (Z521 (2S1) (lsnJ (2!i9) (l60) j
om
A. 3
r.c
lur
nb
tu
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Sm
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e
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B ?( E::h-)) ; smail."-o»,!:t.- Jl~ ~ {J"-u rR.,fC+--'

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E~h(fJ )(!O-vJ.., Ii,.. f~~ ;O~~,;/CA--

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J//Ul<J ~ 10 CTlJ 0.... ~ ~~.

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L/JS x/o 1J.."'!If

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II B it1U a:!C-»1. I , t£,... IE.>,;'" tk ~ ~ ¢r~ 0
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(0'tsL e..~ .
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13 Ji- £1 = - :2. (.J..J1Cj'j../O-It'J) .: -:?l?<j X/D -tcf.J
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EJ'[ -= -;(.I1e; XIV .-YJ--j- -:t :<. () '1'1 /cJ-J =-1 J.f x/() -/'1..7
x/() ....
n
I:z. (
fil :; -1.!Sx/{j-JC1j .: - -;;z ;·/1<7 X/(J yrJJ
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/( ~ .::; /~. -).1{ =.t.J
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C =-/l).} I
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k-t ~ t1. P Irf-~-

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Exam 1: CHEM 112

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Exam 1: CHEM 112

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CHEM 112

R = 8.314 J. mor l • K-1

~Hf· H 20([) == -285.8 kJ

that same metal?

e) None of these is correct.

e) None of these is correct.

a) No, because the ion product is greater than Ksp.

b) Yes, because the ion product is less than Ksp.

d) Yes, because the ion product is greater than Ksp.

a) -1.56 x 103 kJ / rxn

c) -3.l1 x 103 kJ I rxn

d) -6.61 x 103 kJ / rxn

e) None of these is correct.

O(g) 02(g) 02(C) 03(g)

e) None of these is correct.

Ksp = 2.2 x 10-20 for CU(OH)2 )

e) None of these is correct.

15. For a particular process q = - 67 kJ and w = 29 kJ. Which of the following

a) Heat flows from the system to the surroundings.

b) The system does work on the surroundings.

d) Two of the above are true.

e) All of the above (a, b, and c) are true.

What is LlH for the process: 2 A + F 2 C + 2 E?

e) All have the same solubility.

a) the system absorbs heat and expands during the process.

b) the system absorbs heat and contracts during the process.

c) the system loses heat and contracts during the process.

d) the system loses heat and expands during the process.

e) None of these is correct.

d) Fe(OHh (Ksp = 8.0 x 10-16)

e) CO(OH)2 (Ksp = 2.5 x 10- 16 )

e) None of these is correct.

AgCt(s) + 2 NaCN(aq) -4 Ag(CN)2-(aq) + 2 Na+(aq) + Ct-(aq)

Ksp for AgCt = 1.8 x 10-\0 ; Krfor Ag(CN)2 = 1.0 X 1021

b) C(grl + O(g) -4 CO(g)

c) C(gr) + 12 02(g) -4 CO(g)

d) C(grl + C02(g) -4 2 CO(g)

e) CO(g) -4 C(gr) + O(g)

24. Which of the following complexes would be considered most stable?

a) CO(NH3)6 2+ Kf 2.5 X 104

b) AgCt2 Kf= 1.8 X 10 5 .

c) Cu(NH3)l+ K.i 9.1 X 10- 13

e) None of these is correct.

a) 2.0 x 10,11 mol

b) 2.0 x 10'9 mol

c) 4.0 x 10,11 mol

d) 1.0 x 10,11 mol

e) 4.0 x 10,9 mol

e) None of these is correct.

for calibrating bomb calorimeters. A 1.221 g sample burns in a calorimeter (heat

e) ~ one of these is correct.

90 91 92 93 94 95,,96 97 96 ,99 100 101 102 103

M e S O ;Jlc <+ U. C ,J.­

~,o ;: ['!Itl [(lOy.~:l '" (.s)(s} = ~ ~

~J-I0:: I~ ·L)I¥(,0) .- 2.IJI· /jI-lf~1( )

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::: /Ir. f k.fIn/ire

1.l/-IVrt = - .!J.J/:fI.iJ -- -/1 f. fi /<J/4'0(

if-c..=-(-t((~) t ,;( F-n.if) -) 1Ih..( -CF;.if ('j) &-I~ -/.)J7 kJ­

~J1o= ZI1' 8£(1<) - 2.,/1112£(10)

-/J.J.. r; Ki =')1J1~(Ct1) r I'lf~ (-'3£Co( ) +,) I1lce(i5cr -F )

= I Q?(/t (.&:c::c \ T )'m'l/e..(/J~1 Jd//II(1el

I//l{,( (l3c =c ) -If <I I 1(5­

M e S O ;Jlc <+ U. C ,J.

if-c..=-(-t((~) t ,;( F-n.if) -) 1Ih..( -CF;.if ('j) &-I~ -/.)J7 kJ

I//l{,( (l3c =c ) -If <I I 1(5

6£ ~ 1 TW := -~1 kS t~7 KJ -- -3f KJ

ksp : ; [Co..1. tJ (0)/ j 1

lli60l12 M Initial Rate 2 M . 8 1