CHEMISTRY DPP 2

BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

THERMODYNAMICS
1 Internal energy change during a reversible isothermal expansion of an ideal gas is
(a) Always negative (b) Always positive
(c) Zero (d) May be positive or negative

2 Under which of the following conditions is the relation, Δ𝐻 = Δ𝐸 + 𝑃Δ𝑉 valid for
a system
(a) Constant pressure
(b) Constant temperature
(c) Constant temperature and pressure
(d) Constant temperature, pressure and composition

3 For a gaseous reaction,

𝐴(𝑔) + 3𝐵(𝑔) → 3𝐶(𝑔) + 3𝐷(𝑔)
Δ𝐸 is 17 Kcal at 270 𝐶 assuming R = 2 cal 𝐾 −1 𝑚𝑜𝑙 −1 , the value of Δ𝐻 for the above
reaction is
(a) 15.8 Kcal (b) 18.2 Kcal (c) 20.0 Kcal (d) 16.4 Kcal

4 Which of the following statements is correct for the reaction; 𝐶𝑂(𝑔) +

1
𝑂2 (𝑔) → 𝐶𝑂2 (𝑔) at constant temperature and pressure
2
(a) Δ𝐻 = Δ𝐸 (b) Δ𝐻 < Δ𝐸
(c) Δ𝐻 > ΔE (d) None of the above

1
5 For the reaction 𝐴𝑔2 𝑂(𝑠) → 2𝐴𝑔(𝑠) + 𝑂2 (𝑔), which one of the following is
2
true
1
(a) Δ𝐻 = Δ𝐸 (b) Δ𝐻 = Δ𝐸
2
(c) Δ𝐻 < Δ𝐸 (d) Δ𝐻 > Δ𝐸

6 A mixture of 2 moles of carbon monoxide and one mole of oxygen in a closed

vessel is ignited to get carbon dioxide. If Δ𝐻 is the enthalpy change and Δ𝐸 is the
change in internal energy, then
(a) Δ𝐻 > Δ𝐸 (b) Δ𝐻 < Δ𝐸
(c) Δ𝐻 = Δ𝐸 (d) Not definite
 CHEMISTRY DPP 2

BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

7 For the gaseous reaction involving the complete combustion of isobutene –

(a) Δ𝐻 = Δ𝐸 (b) Δ𝐻 > Δ𝐸
(c) Δ𝐻 = Δ𝐸 = 0 (d) Δ𝐻 < Δ𝐸

8 For the reversible isothermal expansion of one mole of an ideal gas at 300 K, from
a volume of 10 𝑑𝑚3 𝑡𝑜 20 𝑑𝑚3 , Δ𝐻 is –
(a) 1.73 KJ (b) – 1.73 KJ (c) 3.46 KJ (d) Zero

9 For 𝐶𝑎𝐶𝑂3 (𝑠) → 𝐶𝑎𝑂(𝑠) + 𝐶𝑂2 (𝑔) 𝑎𝑡 9770 𝐶, Δ𝐻 = 174 𝐾𝐽/𝑚𝑜𝑙 ; then Δ𝐸 is
(a) 160 KJ (b) 163.6 KJ (c) 186.4 KJ (d) 180 KJ

1
10 Heat of reaction for, 𝐶𝑂(𝑔) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔) at constant V is −67.71 𝐾 cal
2
at 170 𝐶 . The heat of reaction at constant P at 170 𝐶 is
(a) – 68.0 K cal (b) + 68.0 K cal (c) – 67.42 K cal (d) None

11 The reaction
3
𝑁𝐻2 𝐶𝑁(𝑆) + 𝑂2(𝑔) → 𝑁2(𝑔) + 𝐶𝑂2(𝑔) + 𝐻2 𝑂(𝑙)
2
was carried out in a bomb calorimeter. The heat released was 743 KJ 𝑚𝑜𝑙 −1 . The
value of Δ𝐻300 𝑘 for this reaction would be
(a) −740.5 𝐾𝐽 𝑚𝑜𝑙 −1 (b) −741.75 𝐾𝐽 𝑚𝑜𝑙 −1
(c) −743.0 𝐾𝐽 𝑚𝑜𝑙 −1 (d) −744.25 𝐾𝐽 𝑚𝑜𝑙 −1

12 The enthalpy of vaporisation of water at 1000 𝐶 is 40.63 𝐾𝐽 𝑚𝑜𝑙 −1 . The value

Δ𝐸 for this process would be
(a) 37.53 𝐾𝐽 𝑚𝑜𝑙 −1 (b) 39.08 𝐾𝐽 𝑚𝑜𝑙 −1
(c) 42.19 𝐾𝐽 𝑚𝑜𝑙 −1 (d) 43.73 𝐾𝐽 𝑚𝑜𝑙 −1

13 For the system (𝑠) + 𝑂2 (𝑔) → 𝑆𝑂2 (𝑔) :-

(a) Δ𝐻 = Δ𝐸 (b) Δ𝐻 > Δ𝐸 (c) Δ𝐸 > Δ𝐻 (d) Δ𝐻 = 0

1
14 For the reaction 𝐶𝑂(𝑔) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔) Which one of the statements is
2
correct at constant T and P?
(a) Δ𝐻 = Δ𝐸 (b) Δ𝐻 < Δ𝐸
(c) Δ𝐻 > Δ𝐸 (d) Δ𝐻 is independent of physical state of reactants
 CHEMISTRY DPP 2

BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

15 Which is true for the combustion of sucrose (𝐶12 𝐻22 𝑂11 ) 𝑎𝑡 250 𝐶 :-
(a) Δ𝐻 > Δ𝐸 (b) Δ𝐻 < Δ𝐸
(c) Δ𝐻 = Δ𝐸 (d) None

16 For which change Δ𝐻 ≠ Δ𝐸 :-

(a) 𝐻2 (𝑔) + 𝐼2 (𝑔) ⇀
↽ 2𝐻𝐼(𝑔)
(b) 𝐻𝐶𝑙 (𝑙) + 𝑁𝑎𝑂𝐻 (𝑙) → 𝑁𝑎𝐶𝑙(𝑠) + 𝐻2 𝑂(𝑙)
(c) 𝐶(𝑠) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔)
(d) 𝑁2 (𝑔) + 3𝐻2 (𝑔) → 2𝑁𝐻3 (𝑔)

17 The heat of combustion of ethanol determined in a bomb calorimeter is – 670.48

K. Cals 𝑚𝑜𝑙𝑒 −1 𝑎𝑡 250 𝐶 . What is Δ𝐻 𝑎𝑡 250 𝐶 for the reaction
(a) – 335.24 K. Cals. (b) – 671.08 K. Cals.
(c) – 670.48 K. Cals. (d) + 670.48 K. Cals.

18 The difference in Δ𝐻 𝑎𝑛𝑑 Δ𝐸 for the combustion of methane at 250 𝐶 would be

(a) Zero (b) 2 × 298 × −2 𝐶𝑎𝑙𝑠.
(c) 2 × 298 × −3 𝐶𝑎𝑙𝑠. (d) 2 × 25 × −3 𝐶𝑎𝑙𝑠.

19 For which of the following reactions Δ𝐻 is less than Δ𝐸 :-

(a) 𝐶12 𝐻22 𝑂1 (𝑠) + 6𝑂2 (𝑔) → 6𝐶𝑂2 (𝑔) + 6𝐻2 𝑂(𝑙)
(b) 2𝑆𝑂2 (𝑔) + 𝑂2 (𝑔) → 2𝑆𝑂3 (𝑔)
(c) 𝑁2 𝑂4 (𝑔) → 2𝑁𝑂2 (𝑔)
(d) 𝑁2 (𝑔) + 𝑂2 (𝑔) → 2𝑁𝑂(𝑔)

20 For a reaction 2𝑋(𝑠) + 2𝑌(𝑠) → 2𝐶(𝑙) + 𝐷(𝑔)

The 𝑞𝑃 𝑎𝑡 270 𝐶 𝑖𝑠 − 28 𝐾 𝐶𝑎𝑙. 𝑚𝑜𝑙 −1
The 𝑞𝑉 is ……………. K. Cal. 𝑜𝑙 −1 :-
(a) – 27.4 (b) + 27.4 (c) – 28.6 (d) 28.6

ANSWER KEYS
1.C 2. A 3.B 4.B 5.D 6.B 7.B 8.D 9.B 10.A
11.B 12.A 13.A 14.B 15.C 16.D 17.B 18.B 19.B 20.C