Mittal Sir Chemistry TEST-1 Liquid Solution Page 1

Test – 1 Liquid Solution

06.04.2020
Max Marks : 60 Time : 25 Min. + 5 Min.
25 minutes for Test
5 minutes for Submission
Roll No : ______________ Name : _____________________________

1. Equal masses of isobutyl alcohol (P° = 100 mmHg) and tert-butyl

alcohol (P° = 120 mmHg) are mixed. If solution is ideal, mole fraction
of isobutyl alcohol in vapour phase would be
(a) (b) (c) (d)

2. A 6.2% w/w aqueous solution of ethylene glycol was filled in a car

radiator. Select the name (s) of area (s) where car can be parked.
kf H2O = 1.86
Temperature
City ‘A’ ⇒ 0°C
City ‘B’ ⇒ –1.5°C
City ‘C’ ⇒ –2.5°C
City ‘D’ ⇒ –3.5°C
(a) A & B (b) A, B & C (c) A only (d) A, B, C & D all

3. The freezing point of benzene decreases by 0.45°C when 0.2 g

CH3COOH is added to 20 g benzene. If acetic acid associate to form
dimer in benzene, percentage association of acetic acid in benzene
will be – (kf benzene = 5.12)
(a) 64.6 % (b) 80.4 % (c) 74.6 % (d) 94.6 %

4. In a 1 m solution of benzoic acid in benzene, molecular weight of

benzene was found to 162.67 g/mol. The freezing point of this
solution is
(kf = 5.0 km–1, T0f benzene = 5.5°)
(a) 7.5°C (b) 4.5°C (c) 2.95°C (d) 1.75°C

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5.
He + O2 In a closed flask
(as shown in figure) at 300 K
A gaseous mixture containing
10 lit equal masses of Helium and O2
water were colletcted over 10 lit water.
If total pressure of gaseous
mixture is 4.5 bar, than ratio of mols of O2 to mols of Helium gas
present inside water at 300 K is –
(kH He = 145 K bar, kH O2 = 45 K bar)
Neglect aqueous tension of water.
(a) 1 : 8 (b) 17 : 32 (c) 29 : 32 (d) 29 : 72

6. In which case molecular weight of benzoic acid, when calculated

using depression in freezing point colligative property would be
greater than actual molecular weight (122)
(a) solution of benzoic acid in water
(b) solution of benzoic acid in benzene
(c) solution of benzoic acid in C2H5OH
(d) All of these

7. The tanks used by scuba divers are filled with air diluted with - - - -
(a) Helium as Henry law constant of helium is very high in
comparison to Nitrogen
(b) Helium as Henry law constant of helium is very low in comparison
to nitrogen
(c) Hydrogen as Henry law constant of hydrogen in very high in
comparison to nitrogen
(d) Hydrogen as Henry law constant of hydrogen is very low in
comparison to nitrogen

8. Statement (s) which is (are) correct for an azeotrop of C2H5OH and

H2O (95% C2H5OH, 5% H2O)
(I) It is a minimum boiling azeotrop
(II) This azeotropic mixture can be further concentrated by fraction
distillation
(III) The composition of vapour phase is equal to composition of liquid
phase
(a) I & III (b) III only (c) I & II (d) I, II & III all

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9. A solution of Acetic acid in benzene was prepared by adding 30 g of

acetic acid in 500 g benzene. The solution was kept in a refrigerator
having constant temperature of 0°C. If kf of benzene is 5 km–1, what
mass of frozen benzene will be formed after a long time if CH3COOH
forms a dimer with extent of 70%
(Freezing point of benzene = 5.5 K)
(a) 204.5 g (b) 295.5 g (c) 156.8 g (d) 354.2 g

10. If Aceton is mixed with n-Hexane, the solution formed would be –

(a) Ideal
(b) Non ideal with positive deviation
(c) Non ideal with negative deviation
(d) Ideal with decrease in entropy

11. When 2 mols of a non volatile solute were dissolved in 1000 gm of

an organic solvent (kf = 5 km–1) the depression in freezing point was
found to be 3.33 K. Considering complete association, the Van’t Hoff
factor is –
(a) (b) (c) 1 (d) 3

12. Boiling point of pure benzene is 80°C. The vapour pressure of

0.1 m solution of benzoic acid in benzene at 353 K is –
(If benzoic acid form dimer in benzene to an extent of 60%)
(a) 1.12 atm (b) 0.852 atm
(c) 0.987 atm (d) 0.905 atm

13. If red blood cells are placed in following liquids, The solution(s) in
which red blood cells will swell up
(I) 0.9 % w/v NaCl solution (II) 2% w/v NaCl solution
(III) 1% w/v glucose solution (IV) 2% w/v glucose solution
(a) III (b) II & IV (c) III & IV (d) II, III & IV

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14. When 10 mols of a non volatile solute ‘A’ were dissolved in 20 mols
of a solvent B (Vapour pressure of pure ‘B’ at 300 K = 100 mmHg) at
300 K, 50 % of ‘A’ get dimerised and 30 % of ‘A’ get trimerised.
Considering complete dimerisation and trimerisation, the final vapour
pressure of solution is –
(a) 78.4 mmHg (b) 82.5 mmHg (c) 90.2 mmHg (d) 93.4 mmHg

15. An aqueous solution of 0.1M CH3COOH is also 0.1M for HCl. The
osmotic pressure of this solution at ‘T’ K temperature is –
(a) 0.3 RT (b) 0.4 RT (c) 0.2 RT (d) 0.1 RT

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