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Materi - Bayu Setiyo Raharjo
Materi - Bayu Setiyo Raharjo
Materi - Bayu Setiyo Raharjo
• ICPs have the following advantages for both ICP-OES and ICP-MS:
• High efficiency ion source:
• High sensitivity
• Wide elemental coverage
• High matrix tolerance
• Atmospheric ion source – high flexibility for coupling of sampling devices
Ar, Air
(O, N, C)
H2O,
Ca, Na,
K, Mg,
Cl, etc
Reactants
4 Proprietary & Confidential
…Comes OUT !
Ar, Air
(O, N, C)
Products Reaction
Reactants
5 Proprietary & Confidential
Typical spectra interference of ICP-MS
Element m/z Interfences
K 39 ArH
Ca 40 Ar
V 51 ClO, ArC
Cr 52 ArC, ClOH
Mn 55 ClO
Fe 56 ArO
Co 59 ArNa
Cu 63 ArNa
Zn 66 ArMg
As 75 ArCl
Se 80 ArAr
M+ only out
M+ and
XnYn’+
* ArAr+ + He ArAr+ + * He
*
*
Ar
40Ar16O
He He
He
O
56Fe He
O He
He
Ar
40Ar16O KED
Flatapole
Flatapole
Ar m/z = <39
He He
He
O
56Fe He
O He
He
Ar
40Ar16O KED
Flatapole
Flatapole
Sample
Gas lines
Torch
holder
Peltier
cooled
Spray
chamber
Torch and
Injector
Nebulizer
Spray
Chamber
• Sample Cones
• Skimmer Cones
1. Take Sample cone, Skimmer and Insert cones in different beaker glass and fill with Formic Acid 10%
and ultrasonic for ±5 mins
2. Rinse Sample cone, skimmer and insert cones with DI water
3. Put sample cone, skimmer and insert cones in different beaker glass again and fill with DI water,
ultrasonic for ±5 mins
4. Repeat step 2 and step 3, and Dry Sample, Skimmer and insert cones in Fiberles tissue
• Tuning always fail booth in STD mode or Gas mode (KED mode in
Thermo)
• Check Sample peristalic pump, apakah ada bubble ?
Jika Ya, maka coba cek sambungan antara sample peristaltic pump, apakah ada kotoran atau
debu yang menyumbat ?
Jika Ya bersihkan debu tersebut.
Apabila aliran sudah lancar dan tuning masih dibawah spesifikasi, matikan plasma atau cek
melalui camera plasma.
Cek apakah sample cones dalam keadaan kotor ? Jika Ya, maka bersihkan
• Intensity didn’t stable when tuning, stability higher than spesification but
insensity already meet requirement
• Check aliran pada sample peristaltic pump, jika aliran ada bubble lakukan seperti arahan
sebelumnya.
Jika lancar maka buka bagian pendingin spray chamber apakah aerosol terbentuk ?
Jika tidak, maka kemungkinan nebulizer tersumbat.
Lakukan Back Flush pada nebulizer menggunakan gas argon pada nebulizer