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2 Supplementary Exercise Microscopic World I (Question)
2 Supplementary Exercise Microscopic World I (Question)
True or false
18 Silicon is a metalloid. T
Part 24
23
A sodium atom (11Na) contains 11 F Element State at room temperature
A
and pressure
U neutrons.
n
it
5 25 A fluorine atom contains 9 electrons. T
O
x
y
g
e
n
S
i
l
i
c
o
n
2
37 Consider the following information: Which of the following solids is likely to be a
metal?
Substance Melting point (°C) Boiling point (°C) A W
W –50 5 B X
C Y
X 4 81 D Z C
Y 68 104
42 Which of the following statements concerning
Z –95 69
silicon is INCORRECT?
Which of the following substances is / are in liquid A Properties of silicon are in between metals
Part
state at room temperature and pressure? and non-metals. A
U
B Silicon is brittle. n
A W only it
C Silicon can be used to make semi- 5
B X only conductors.
C X and Z only
D Silicon is soluble in water. D
D Y and Z only C
3
45 An atom has 28 electrons and 30 neutrons. Which of the following atoms are isotopes?
Which of the following combinations concerning
A I and III
the atom is correct?
B II and III
Atomic number Mass number C I and IV
D II and IV D
A 28 30
B 28 58
50 The following table shows the relative abundance of
C 30 28
isotopes of lithium:
D 58 28 B
Number of Number of Number of
Isotope Relative abundance (%)
46 Whichprof the
otons following combinations
neutrons concerning
electrons
Part 51 6
A the atomic structure of the atom 23X is correct? The relative atomic Li 7.4
mass of lithium is A 6.07.
U A 51 23 51
n
B 28 51 23 B 6.93. 7
Li 92.6
it
5 C 23 28 23 C 6.07 g
D 23 23 28 B D 6.93 g
C
47 Which of the 51 Element X has
16
following two isotopes, X
85
particles 87
and X. The
contains the
table below lists
same number
the relative
of neutrons as
32 abundance of
S?
each isotope.
23
11 A Na
24
12 B Mg
2
14 C
8
D P D
S
i
Isotope Relative abundance (%)
3
1 85
X 72.1
15
87
X 27.9
48 Which of the
following What is the
combinations
relative atomic
concerning
isotopes of an mass of X? A
element is
85.2
Number of Number of Number of correct?
B 85.6
neutrons protons electrons
C 86.2
A different same different D 86.6 B
B same different same
C different same same 52 Metal X has three isotopes, 18 1 19
9 9 X
D same same same 2
0
an X
X
d
.
,
following
informati
on of
49 Consider the four
atoms: The graph below
shows the relative
Atomic
Atom abundance of the
number
isotopes.
I
III 20 4
5
IV 4
4 0
3
5
3
0
2
5
2 189190 192
0
1
5
1
0
5
0
9 9 9
What is the relative atomic mass of X? 58 The electron diagram of an atom of element X is
A 189.7 shown below:
B 190.3
C 190.7
D 191.3 C
53 Element X occurs in
(Only electrons in
nature as two
79 81 the outermost shell
isotopes, X and X. If
are shown.)
the relative atomic
mass of X is 79.9, X could be
A 30.0% what is the relative Part
B 35.0% 81 A Cl. A
abundance of the X B P. U
C 40.0% isotope? n
D 45.0% C S. it
5
D Si. C
D
5
62 Which of the following statements concerning 65 The atomic number of element X is 15. It has
isotopes of an element is / are correct? only one isotope with a mass number 31.
(1) They have different number of neutrons. Which of the following statements concerning X
(2) They have different atomic numbers. is / are correct?
(3) They have the same mass.
(1) X is a gas at room temperature and
A (1) only pressure.
B (2) only (2) There are 5 electrons in the outermost
C (1) and (3) only shell of an atom of X.
D (2) and (3) only A (3) There are 15 neutrons in the nucleus of
an atom of X.
Part
A 63 Consider the following information concerning
U A (1) only
n atoms P and Q:
it
B (2) only
5 C (1) and (3) only
Number of Number of Number of
Atom D (2) and (3) only B
protons neutrons electrons
P 15 16 15
66 An atom of element X has an electronic
Q 16 16 16 arrangement 2,8,1. Which of the following
statements concerning X are correct?
Which of the following statements concerning P (1) It is a metal.
and Q is / are correct? (2) Its atom has 11 protons.
(1) P is an atom of a non-metal. (3) Its symbol is K.
(2) Q is an atom of a metal. A (1) and (2) only
(3) P and Q are isotopes of the same B (1) and (3) only
element. C (2) and (3) only
A (1) only D (1), (2) and (3) A
B (2) only
60
C (1) and (3) only 67 The isotope cobalt-60 ( 27Co) is used to destroy
D (2) and (3) only A cancer cells in the human body. Which of the
60
following statements concerning a Co atom
27
Part
A
U
1st statement 2nd statement n
it
5
68 Carbon is a solid at room temperature and Carbon is a non-metal. B
pressure.
69 Atoms are electrically neutral. Atoms have the same number of protons A
and electrons.
54 54
54 54
72 24 X and 26 Y are isotopes. X and 26Y have the same mass number
24 C
but different atomic numbers.
73 Isotopes of a given element have different Isotopes of a given element have different A
relative isotopic masses. numbers of neutrons.
75 Isotopes of an element have the same mass. All atoms of an element contain the same C
number of electrons.
8 The r e a c ti v i t y of Gr oup I elements 15 The octet rule states that atoms become
increases as we move down the group. stable by having eight electrons in their outermost
shells.
9 Sodium reacts with water to give hydrogen
gas and sodium hydroxide . 16 Argon is used to fill electric light bulbs.
10 Group II elements are called alkaline earth 17 When an atom of an element loses one or more
metals. electrons, it forms a positive ion.
11 Group VII elements are called halogens . 18 When an atom of an element gains one or more
electrons, it forms a negative ion.
12 There is a gradual change in the intensity of
the colour of Group VII elements. Chlorine 19 A magnesium atom tends to lose 2 electrons
is greenish yellow in colour, bromine to form an ion. A magnesium ion has
is reddish brown in colour while iodine 12 protons and 10 electrons.
is black in colour.
20 A nitrogen atom tends to gain 3 electrons
to form an ion. A nitride ion has 7 protons
and 10 electrons.
True or false
9
X belongs to 50 Lithium and sodium show similar chemical
properties because they
A Group II.
B Group IV. A are both metals.
C Group VI. B have the same atomic number.
D Group 0. C C have the same electronic arrangement in their
atoms.
46 An atom of element X has 2 completely filled D have the same number of outermost shell
Part
A shells only. X is in electrons in their atoms.
U
n D
it A Group 0.
6
B Group II.
51 Which of the following pairs of atomic numbers
C Group IV.
corresponds to elements with similar chemical
D Group VI. A properties?
10
55 Elements X and Y are in the same period of the C D
.FMUJOH QPJOU
NFMUJOH QPJOU
periodic table. Which of the following statements
concerning X and Y is correct?
A They have the same relative atomic mass.
B Their atoms have the same number of
occupied electron shells.
C Their atoms have the same number of
outermost shell electrons.
"UPNJD OVNCFS "UPNJD OVNCFS
D They have similar chemical properties.
B A
.FMUJOH QPJOU
A
cold water. 65 Argon is used to fill electric light bulbs because it
A is cheap.
B is unreactive.
63 Which of the following graphs shows the trend
C glows when hot.
in the boiling points of the halogens?
D is colourless. B
U argon.
n
it C
6
x + 16. A
#PJMJOH QPJOU
(SPVQ (SPVQ
* ** *** *7 7 7* 7** 0
"UPNJD OVNCFS "UPNJD OVNCFS B C 2 D E F
1FSJPE 3 G
C H I 4 J K
101 Elements are arranged in order of their atomic Atomic numbers are always whole numbers B
numbers, rather than relative atomic masses, while there are fractional relative atomic
in the periodic table. masses.
102 Lithium and neon belong to the same period Atoms of lithium and neon have the same A
of the periodic table. number of occupied electron shells.
103 Nitrogen and oxygen belong to the same period Nitrogen and oxygen are colourless B
gases. of the periodic table.
104 Across the second period of the periodic table, Across the second period of the periodic D
the elements show a gradual increase in table, the elements show a gradual
melting point. increase in the number of occupied electron
shells in their atoms.
105 Across the third period of the periodic table, Across the third period of the periodic table, B
the atomic size of the elements. the metallic character of the elements
decreases.
106 Sodium and potassium show similar chemical Atoms of sodium and potassium have the A
properties. same number of outermost shell electrons.
107 The density of Group II elements decreases The reactivity of Group II elements decreases D
down the group. down the group.
108 The reactivity of halogens increases down the The atomic size of halogens increases down C
group. the group.
109 The elements in Group 0 of the periodic table The outermost shell of an atom of a A
are very unreactive. Group 0 element is completely filled.
110 A chloride ion and an argon atom show similar A chloride ion and an argon atom have the C
chemical properties. same electronic arrangement.
Unit 7 Ionic and metallic bonds 5 A sulphate ion is formed from one sulphur atom
P and four oxygen atoms. The whole group
a
rt
A Fill in the blanks of atoms carries two negative charges.
U
n
it 1 Substances can be classified into groups according 6 A sulphite ion is formed from one sulphur atom
7
to how they conduct electricity. and three oxygen atoms. The whole group
of atoms carries two negative charges.
a) Substances which conduct electricity but are
not chemically changed during conduction are 7 An aqueous solution of potassium permanganate
conductors . is purple in colour. This colour comes from
b) Compounds which conduct electricity in molten the permanganate ions.
state or aqueous solution and are
8 The green colour of jade is due to the presence
decomposed by electricity during conduction
of chromium(III) ions.
are electrolytes .
2 When metal atoms combine with non-metal 10 A metallic bond is a type of bond in which
atoms, ionic bonds result. positive metal ions are held together by a ‘sea’
of mobile electrons.
3 When electricity is passed through molten
lead(II) bromide, lead(II) ions move towards the
negative electrode while bromide ions move
towards the positive electrode.
Decide whether each of the following statements is 21 Which of the following substances is a non-
true or false. conductor of electricity?
A Alcohol
11 An ionic bond is the strong forces of F
B Copper
attraction between ions of the same
C Graphite
charge.
D Molten potassium chloride A
13 When calcium combines with fluorine, T The circuit shown below is set up and the solid lead(II)
each calcium atom loses two electrons bromide is heated until it becomes molten.
and each fluorine atom gains one electron.
CVMC
14 Element X (atomic number 11) combines F
P
with element Y (atomic number 16) to a
form a compound with the chemical JOFSU FMFDUSPEF JOFSU FMFDUSPEF 9 rt
A
formula XY2. : U
n
it
7
15 Magnesium combines with oxygen to T
form a compound with the chemical
formula MgO.
MFBE(**) CSPNJEF
16 Element X (atomic number 20) reacts T
with element Y (atomic number 7) to
form a compound with the chemical IFBU
forumla X3Y2.
17 The chemical formula of the compound F 22 Which of the following statements concerning
formed between astatine (At) and the experiment is INCORRECT?
potassium is KAt2.
A The bulb lights up.
18 An aqueous solution of iron(II) sulphate is B Nichrome wires can be used as electrodes.
F
yellow-brown in colour. C A reddish brown gas is evolved at electrode
Y.
D The experiment should be carried out in a
19 An aqueous solution of potassium T
fume cupboard.
dichromate is orange in colour.
C
A Copper
28 Which of the following is an electron diagram of
B Copper(II) sulphate
potassium oxide?
A + m
A A
Element a b c d
, , 0
Atomic number 6 9 10 11
A a and b , 0 0
B a and c
C b and d
D c and d C
C
2+
D sodium chloride.
9
3m
: 34 The atomic number of an element X is 7. What
is the chemical formula of the compound Part
formed between magnesium and X? A
U
n
A MgX it
7
B MgX2
C
Mg2X3 D D
Mg3X2
+
(Only electrons in the outermost shells are
9
shown.)
How many electrons are there in the outermost
shell of an atom of X and that of Y?
(Only electrons in the outermost shown.)
shells are
Which of the following combinati ons is 41 Which of the following ions is responsible for the
correct? greenish blue colour of turquoise?
X Y A Copper(II) ion
A B H B Dichromate ion
B Li N C Iron(III) ion
C Mg Cl D Manganese(III) ion A
D Na O B
42 Which of the following ions is responsible for the
purple colour of amethyst?
37 Which of the following pairs of elements would
2+
react with each other most vigorously? A Cu
2+
A Chlorine and lithium B Fe
3+
B Chlorine and potassium C Mn
2+
C Fluorine and lithium D Ni C
D Fluorine and potassium D
43 Which of the following solids dissolves in water
to form a colourless solution?
38 Consider the information given in the table
Part below: A CrCl3
A
U B CuCl2
n
it Element Atomic number C FeCl3
7 ZnCl2
D D
w 9
WZ blue
Which of the following pairs of elements would D Potassium permanganate
react with each other most readily? XY orange
A w and y XZ colourless
B w and z
C x and y
D x and z B
A Cr.
B F. 52 Strontium (Sr) belongs to Group II of the
C Mg. periodic table. Which of the following statements
D S. concerning strontium is correct?
A
A Strontium is an alkali metal.
47 How many elements does ammonium sulphate B Strontium is less reactive than calcium.
consist of? C The chemical formula of strontium chloride is
SrCl.
A 3
D The density of strontium is higher than that
B 4
of sodium.
C 5
D
D 6 B
48 Rubidium (Rb) is in the same group as sodium. 53 Astatine (At) is a Group VII element. Which of
the following statements concerning astatine is
What is the chemical formula of rubidium
correct?
carbonate?
A Astatine is a solid at room temperature and
A RbCO3
pressure.
B Rb(CO3)2
B Astatine is more reactive than chlorine.
C Rb2CO3
D Rb3(CO3)2 C Astatine is in Period 4 of the periodic table.
C
D The formula of the compound
formed between astatine and
calcium is Ca2At. A
+
54 Element X can form a cation X with an electronic 58 Rubidium (Rb) is a Group I element
arrangement 2,8. Which of the following below potassium in the periodic table.
statements concerning X is correct? Which of the following statements about
A It is a gas at room temperature and rubidium are correct?
pressure. (1) Its oxide is a crystalline solid.
B It is in Period 2 of the periodic table. (2) Metallic bonding exists in it.
C It reacts vigorously with water. (3) The chemical formula of its sulphate is
D It reacts with oxygen to form a compound Rb2SO4.
with the chemical formula XO2.
A (1) and (2) only
C
B (1) and (3) only
C (2) and (3) only
55 Which of the following pairs of elements will
D (1), (2) and (3) D
combine to form ionic compound(s)?
(1) Calcium and fluorine 59 Barium (Ba) is a Group II element below calcium
(2) Neon and nitrogen in the periodic table. Which of the following
(3) Potassium and sodium statements concerning barium are correct?
Part A (1) only (1) It forms a stable ion carrying 2 positive
A
U B (2) only charges.
n
it C (1) and (3) only (2) It is less reactive than calcium.
7
D (2) and (3) only A (3) It forms a sulphide with the chemical
formula BaS.
2+
56 Element X can form a cation X with an electronic
A (1) and (2) only
arrangement 2,8,8. Which of the following
B (1) and (3) only
statements concerning X are correct?
C (2) and (3) only
(1) It can react with hydrogen to form a D (1), (2) and (3) B
compound with the chemical formula
XH2. 60 Strontium (Sr) is a Group II element. Which of
(2) It is in Period 3 of the periodic table. the following statements concerning strontium
(3) It burns with a brick-red flame. carbonate are correct?
A (1) and (2) only (1) Its chemical formula is SrCO3.
B (1) and (3) only (2) It conducts electricity in solid state.
C (2) and (3) only (3) It is insoluble in water.
D (1), (2) and (3) B
A (1) and (2) only
B (1) and (3) only
57 Caesium (Cs) belongs to Group I of the periodic
C (2) and (3) only
table. Which of the following statements
D (1), (2) and (3) B
concerning caesium is / are correct?
61 The atomic number room
(1) It reacts with water vigorously. of element X is temperature
(2) It has a high density. 7. Which of the and pressure.
(3) The chemical formula of caesium hydroxide following
is Cs(OH)2. statements
A (1) only concerning X are
B (2) only correct?
C (1) and (3) only (1) X is a
D (2) and (3) only A gas at
25
64 Consider the JOH DPQQFS(**) JPOT
BOE EJDISPNBUF JPOT
following experiment:
+
(2) X is in D D
Period B
3 of the S
periodic C
table. P
E O
(3) X reacts
J
with M
F
magnesiu V
M
m to form U
F
F
a D
T
U
compound V
S
with the M
P
Q
chemical E
IV
formula F
S
Mg3X2. J
D :
A (1) and (2) B
only D
E
B (1) and (3) J
only M
C (2) and (3) V
only U B
F
D (1), (2) and
(3)
T
V
62 An ionic M
compound has Q
I
the chemical V
formula X2Y S
where X and Y J
represent the D
cation and
B
D
J
E
H
F
M
D
P
O
U
B
J
O
24
anion respectively. Which of the about sitive
If both X and Y following the ions.
have the same statements metallic (2) Outer
electronic concerning most
bonding
arrangement, the the shell
compound could experiment in a electr Part
be are correct? solid ons A
U
are of n
(1) lithium (1) A it
oxide. correct? atom 7
green
(2) potassium s are
colour (1) T
sulphide. deloc
gradua h
(3) sodium alized
lly e
oxide. throu
develo s
ghout
A (1) only ps o
the
B (2) only near li
solid.
C (1) and (3) only electro d
(3) This
D (2) and (3) only de X. D c
type
(2) Gas bubbles are o
evolved at of
63 Which of the n
electrode Y. bondi
following ions t
(3) The ng
are green in a
experi exists
colour? i
ment in
3+ n
(1) Cr (aq) can be some
2+ s
(2) Ni (aq) used ionic
a
–
(3) MnO (aq) 4 to comp
r
show ounds
A (1) and (2) only e
that .
B (1) and (3) only g
C (2) and (3) only ions u A (1) and (2) only
migrat l B (1) and (3) only
D (1), (2) and (3) A
e a C (2) and (3) only
toward r D (1), (2) and (3)
A
s a
opposi r
tely r
charge a
d n
electro g
des. e
A (1) and (2) only m
B (1) and (3) only e
C (2) and (3) only n
D (1), (2) and (3) t C
o
65 Which of the f
following p
o
statements
27
ether each of the two statements is true or false; if both are true, then decide whether or not the second statement is a correct explanat
67 Atoms of helium and neon have 8 outermost Helium and neon are noble gases. C
P
a shell electrons.
rt
A
U 68 Magnesium is in Period 2 of the periodic table. Atoms of magnesium form ions carrying two C
n
it positive charges.
7
69 Element X (atomic number = 20) reacts Each atom of X loses two electrons and each A
with element Y (atomic number = 7) to form atom of Y accepts three electrons to form a
an ionic compound. compound with the chemical formula X3Y2.
70 A metal M which forms a chloride MCl3 must Only metals in Group III of the periodic table D
belong to Group III of the periodic table. form ions with three positive charges.
26
Unit 8 Covalent bonds True or false
3 The pair of electrons in the outermost shell of an 13 Carbon combines with silicon to form a T
atom that is not involved in bonding is called covalent compound.
lone pair electrons.
14 Neon and nitrogen combine to form a F
4 Each hyd rogen molecule consists of covalent compound.
two hydrogen atoms. Hydrogen forms
15 The total number of electrons in a water F
diatomic molecules.
molecule is 8.
B 9 9
99
C
D 9 9
22 An element exists as diatomic molecules. The In which group of the periodic table is this element
atomic number of the element could be likely to be found?
Part
A
U A 9. A II
n
it B 10. B III
8
C 11. C IV
D 13. A D V D
23 Which of the following pairs of elements will 27 Which of the following diagrams best represents
combine to form a covalent compound? the electron diagram of a compound formed
A Lead and bromine between nitrogen and fluorine?
B Potassium and chlorine (Only electrons in the outermost shells are
C Sodium and hydrogen shown.)
D Sulphur and oxygen D
A
24 Which of the following pairs of elements will
combine to form a covalent compound? / '
Element a b c d
Atomic number 3 14 17 18
C 29 Which of the following substances exists as atoms
at room temperature and pressure?
' / '
A Ammonia
B Hydrogen
' C Neon
D Nitrogen C
B A 2
B 4
' ' C 6
D 8 C
: 9 :
D
)
(Only electrons in the outermost shells are
shown.)
) 4J )
Which of the following combinations concerning
X and Y is correct?
)
X Y
D A Carbon sulphur
B Silicon oxygen
C Oxygen lithium
D
D Oxygen fluorine
33 The electron diagram of a compound formed 3–
37 Element X can form an anion X with an electronic
from element X and hydrogen is shown below: arrangement 2,8. Which of the following
statements concerning X is correct?
) )
9 9) ) A It is in Group III of the periodic table.
B It is a solid at room temperature and
pressure.
(Only electrons in the outermost shells are
C It exists as diatomic molecules.
shown.)
D It can react with fluorine to form
How many electrons are there in the outermost an ionic compound. C
shell of an atom of X?
A 3 38 Which of the following electron diagrams is
B 4 correct?
C 5 (Only electrons in the outermost shells are
D 6 C shown.)
B HCN
$M'
C NH 3
D SCl2 D
D
36 Elements X and Y have 5 and 7 outermost shell $M0$M
electrons in their atoms respectively. Which of
the following combinations concerning the
D
compound they form is correct?
Chemical formula Type of 39 In which of the following groups of substances
bond A XY3 covalent there exists a difference in bonding type among
B X3Y covalent the substances?
C X3Y ionic A Aluminium, mercury, sodium
D XY3 ionic A B Calcium chloride, hydrogen chloride, silver
chloride
C Carbon dioxide, nitrogen, oxygen
D Iodine, methane, sulphur dioxide B
40 X is an element in the third period of the diagrams best represents the compound formed
periodic table. The chemical formula of the between X and hydrogen?
compound formed between aluminium and (Only electrons in the outermost shells are
X is Al2X3. Which of the following electron
shown.) What would be the chemical formula of
A the compound formed between X and
calcium?
H X H
A CaX
B CaX2
H
C Ca2X3
B D Ca3X2 D
H
42 Consider the elements from lithium to fluorine
H X H in the second period of the periodic table.
Which of the following statements is correct?
H
A They show a gradual change from
having metallic property to having
C
non-metallic property.
H X H B They show a gradual increase in the
number of occupied electron shells in their
atoms.
D
C They show a gradual decrease in
H X melting point.
D Their oxides change from covalent to ionic.
A
C
Part
43 Which of the following diagrams best A
U
41 The electron diagram of a compound represents the arrangement of particles in a n
formed between an element X and chlorine metal?
it
8
is shown below.
$M 9 $M
$M B
D
(Only electrons in the outermost shells are
shown.)
44 Consider the following table: 47 A portion of the periodic table is shown below.
(SPVQ
Atomic Relative * ** *** *7 7 7* 7** 0
Element
number atomic mass 2 B C
1FSJPE
X 9 19.0 D E 3 F G
Y 13 27.0
Which of the following pairs of elements will form
covalent compound(s) upon combination?
The formula mass of the compound formed
(1) a and f
between X and Y is
(2) b and d
A 40.0. (3) c and e
B 84.0.
A (1) only
C 100.0.
B (2) only
D 111.0. B
C (1) and (3) only
D (2) and (3) only A
45 Consider the following table:
48 Which of the following molecules have single
Atomic Relative covalent bonds only?
Element
number atomic mass
Part
(1) CH4
A
X 6 12.0
(2) CO2
U
n Y 16 32.1 (3) H2O
it
8 A (1) and (2) only
The relative molecular mass of the compound
B (1) and (3) only
formed between X and Y is
C (2) and (3) only
A 38.1. D (1), (2) and (3) B
B 44.1.
C 56.1. 49 Which of the following molecules contain multiple
D 76.2. bond(s)?
D
(1) CO2
(2) N2
46 Which of the following elements can react
(3) HCN
together to form a covalent compound?
A (1) and (2) only
(1) Magnesium
B (1) and (3) only
(2) Phosphorus
C (2) and (3) only
(3) Oxygen
D (1), (2) and (3) D
(4) Helium
A (1) and (2) only 50 Which of the following statements concerning
B (1) and (4) only chlorine and bromine are correct?
C (2) and (3) only
(1) They form ions with 1 negative charge.
D (3) and (4) only C
(2) They exist as diatomic molecules.
(3) They can react with sodium sulphite
solution.
A (1) and (2) only 51 Which of the following statements concerning a
B (1) and (3) only methane molecule is / are correct?
C (2) and (3) only
(1) The number of bonding electrons contributed
D (1), (2) and (3) D
by each hydrogen atom in the molecule is 2.
(2) The number of bonding electrons 53 X and Y are two different elements. The
contributed by the carbon atom in the electron diagram of a compound formed
molecule is 4. between X and Y is shown below:
(3) The total number of electrons in the
molecule is 8.
A (1) only : 9 9 :
B (2) only
C (1) and (3) only
D (2) and (3) only B (Only electrons in the outermost shells
are shown.)
52 Which of the following electron diagrams
Which of the following statement is /
are correct?
are correct?
(1) There are 6 electrons in the
outermost shell of an atom of X.
(2) There are 8 electrons in the
outermost shell of an atom of Y.
(3) Each atom of X in the above
compound has 4 lone pairs of
electrons.
A (1) only
B (2) only Part
A
C (1) and (3) only U
D (2) and (3) only n
A it
8
(1) m
+
54 X, Y and Z are three different elements. The
/B electron diagram (showing electrons in the
)
outermost shells only) of the compound
formed by X, Y and Z is shown below:
+ m
2m 9
(2)
;
2+ 9 : 9
.H #S
9
C (2) and (3) only
B D (1), (2) and (3)
(3)
4 $ 4
61 Bromine and chlorine belong to the same group Both bromine and chloride exist as diatomic B
of the periodic table. molecules.
62 Neon and nitrogen combine to form a covalent Neon and nitrogen are non-metals. C
compound.
63 Phosphorus forms a covalent compound with Phosphorus and chlorine belong to the same B
chlorine. period of the periodic table. P
a
rt
A
64 When hydrogen combines with chlorine, an During the reaction, every electron released D U
ionic compound is formed. by a hydrogen atom is accepted by a n
it
chlorine atom. 8
Unit 9 Relating the properties 12 Metals are good conductors of electricity due to
of substances to the movement of mobile electrons .
structures and bonding
Fill in the blanks True or false
6 Molten ionic compounds can conduct electricity atom is joined to three carbon atoms
because they contain mobile ions. by covalent bonds. Van der Waals’
35
forces exist between the layers. Decide whether each of the following statements is
true or false.
10 Substances with simple molecular structures are
usually slightly soluble or insoluble in water but 13 Quartz and graphite are allotropes. F
very soluble in non-aqueous solvents.
14 The strcuture of silicon is similar to that
T
11 Bromine has a simple molecular structure. The of diamond.
atoms in each molecule are held together by a
15 Silicon carbide (SiC) has a simple F
covalent bond . The separate molecules are held
molecular structure.
together by van der Waals’ forces .
16 Silane (SiH4) has a simple molecular T
structure.
37
43 Which of the following substances is the most stable 47 Which of the following substances consists of
in moist air? separate molecules?
A Ca A Calcium oxide B
B Na Graphite
C SiO2 C Iodine D
D SO2 C Sodium C
Part
A
44 Graphite can be used as a lubricant. This is 48 Which of the following oxides has a simple
U because graphite has
n
molecular structure?
it
9 A mobile ions. A MgO
B delocalized electrons. B Al2O3
C covalent bonds between atoms in the C SiO2
layers. D Cl2O D
D van der Waals’ forces between the layers of
atoms. 49 In which of the following substances do van der
D Waals’ forces exist?
A Quicklime B
45 Which of the following correctly describes the
Silicon
structure of dry ice?
C Solid carbon dioxide
A Giant covalent structure B D Solid ammonium chloride C
Giant ionic structure
C Giant metallic structure 50 Bromine is a liquid at room temperature and
D Simple molecular structure D pressure because
A bromine has a giant covalent structure.
B bromine molecules are diatomic.
C bromine molecules are held together by weak
intermolecular forces only.
D bromine atoms within the molecules are held
by strong covalent bonds.
C
46 Which of the following substances has a simple 52 Which of the following substances is insoluble in
molecular structure? water but soluble in non-aqueous solvents?
38
A Diamond A Common salt
B Mercury B Sugar
C Nitrogen C Sulphur
D Quartz C D Sodium nitrate C
53 An element X combines with chlorine to form Which of the following statements concerning X,
a compound with a simple molecular structure. Y and Z is correct?
The atomic number of X could be
A X has a high melting point.
A 10. B Y has a giant covalent structure.
B 11. C Z gives an apple green flame in flame test.
C 16. D X and Z combine to form a compound with
D 20. C a simple molecular structure.
B
54 The atomic number of element X is 15. It has only
one isotope with a mass number 31. Which of the 57 Consider the following substances:
following statements concerning X is correct?
carbon dioxide (CO2), silicon dioxide (SiO2) and
A X is a gas at room temperature and sodium oxide (Na2O)
pressure.
The ascending order of the melting points of
B The chemical forumla of the hydride of X is
these substances is
XH3.
C There are 16 electrons in an atom of X. A CO2 < Na2O < SiO2
D Covalent bonds hold the molecules of X B CO2 < SiO2 < Na2O
together. C SiO2 < CO2 < Na2O
B D Na2O < SiO2 < CO2 A
55 Consider the following information about three Directions: Questions 58 – 59 refer to the following
elements, X, Y and Z. information of four elements:
59 Element Y is likely to be
56 Consider the following information about three
elements, X, Y and Z. A magnesium.
39
Element X Y Z
Atomic number 7 14 20
B
mercury
.
C
sili B
co
n.
D
so
di
u
m.
40
60 Consider the information below: 63 X and Y are elements. The melting points of their
chlorides are given below:
Melting Electrical Solubility in
Substance
point (°C) conductivity water
W –7 non-conducting slightly soluble
X 46 non-conducting insoluble
41
71 Which of the ure. 75 Selenium (Se) is a
following group VI element
A (1) and (2) only
substances of the periodic
B (1) and (3) only
can conduct table. Which of the
C (2) and (3) only
electricity? following
A D (1), (2) and (3)
statements
(1) Graphi
Which of concerning
te 74 A certain form of
the following selenium are
(2) Molte solid carbon is
statements correct?
n zinc composed of C60
chlori concerning molecules. Each C60 (1) Selenium
de silicon molecule is formed forms a
(3) Magnesium carbide are by 60 carbon atoms covalent
sulphate correct? bonded together hydride.
solution like a football as (2) The chloride
(1) Its
A (1) and shown in the of selenium
chemi
(2) only diagram below: is a solid
cal
B (1) and formu with a
(3) only la is network
C (2) and SiC2. structure.
(3) only (2) It has (3)
D Selenium 2–
D (1), (2) a high forms Se
and (3) meltin ions when
g reacted
72 The structure point. with Group
of silicon (3) It is insoluble in I elements.
Part
A carbide is water.
U
n shown below: A (1) and
it
9 (2) only
LFZ: Which of the
B (1) and P
following a
(3) only rt
statements is / A
C (2) and
are correct? U
(3) only C n
it
D (1), (2) (1) The solid is 9
and (3) insoluble in
73 Germanium is oid. water.
a Group IV (2) It has (2) The solid is
element a harder than
below silicon high diamond.
in the melti (3) The melting
periodic table. ng point of the
Which of the point. solid is
following (3) I ts higher than
statements fl uori that of
concerning de graphite.
germanium is has
A (1) only
/ are probably a
B (2) only
correct? giant
C (1) and (3) only
coval
(1) It is a A D (2) and (3) only
ent
metall
struct
42
A (1) and (2) electricity. (2) Magnesium NOT conduct electricity at
only From these chloride has room temperature. It may
B (1) and (3) information it a giant ionic have a
only can be structure. (1) giant covalent
C (2) and (3) deduced that (3) Both sodium structure.
only chloride and B
(1) X has a (2) giant ionic
D (1), (2) and magnesium
simple structure.
(3) chloride
molecula (3) giant metallic
r conduct structure.
76 Which of the structure. electricity
following properties of A (1) and (2) only
(2) the when heated
graphite is B (1) and (3) only
attractiv to 750 °C.
/ are C (2) and (3) only
e
evidence(s) to A A (1) and (2) only D (1), (2) and (3)
forces
support that B (1) and (3) only
betwee
covalent bonds C (2) and (3) only
n
are strong? A D (1), (2) and (3)
molecul
(1) It is es of X
slippery. 79 The following table
are
shows the melting
(2) It has a weak.
points of three
high (3) the compounds.
melting attractiv
point. e
(3) It can Compound
forces
conduct
betwee NaH
electricity.
n the
SiH4
A (1) only atoms
B (2) only of X H2S
C (1) and (3) are
only weak. Which of the following B
D (2) and (3) statements can be
only A (1) and (2)
deduced from the
only
above data?
B (1) and (3)
77 Element X exists only (1) NaH is a solid
as diatomic C (2) and (3) at 700 °C.
molecules. only (2) SiH4 has a A
Solid X has a D (1), (2) and giant covalent
very low (3) structure.
melting point. (3) H2S is a solid
It is insoluble at room
78 Refer to the
in water but temperature
information of
soluble in non- some chlorides and pressure.
aqueous shown in the A Chloride
(1) only Melting point (°C) Boiling point (°C)
solvents. X does following table.
not conduct B (2) NaCl
only 808 1 465
C (1) and (3) only
Which of the following ride is a
D (2)MgCl
and2 (3) only 712 1 418
statements are correct? liquid atA
room SiCl4 –68 57
(1) Silicon
temperature 80 X has a very high
tetrachlo
and pressure. melting point and does
43
81 The no giant covalent X2O3. Which of
atomi n- structure. the following
c aq (2) Its chemical statements are
numb ue formula is XY2. correct?
ers of ou (3) It is very
(1) The
two s soluble in
chemical
eleme sol water.
formula
nts X ve A (1) only of the
and Y nts B (2) only chloride Part
are . C (1) and (3) only of X is A
U
19 (3) I t D (2) and (3) only XCl3. B n
it
and co (2) X2O3 has a giant9
16 nd 83 Metal X ionic structure.
respe uct reacts with (3) X2O3 conducts
ctively s oxygen to electricity in molten
. ele form a state.
Which ctr compound A (1) and (2) only
of icit with a
B (1) and (3) only
the y chemical
C (2) and (3) only
follow in formula
D (1), (2) and
D (3)
ing aq
84 Consider the 85 Consider the
state ue
following elements: following elements:
ments ou
conce s
rning sol Element Atomic number Element Atomic nu
the uti
comp on. P 9 P 7
ound Q 17
A (1) and (2) only Q 12
forme
B (1) and (3) only
d Elements P and Q
C (2) and (3) only Elements P and Q
betwe combine to form a combine toB form a
D (1), (2) and (3)
en X compound compound
and Y X. Which of the X. Which of the
82 The atomic
are following statements following statements
numbers of elements X
correc about X are correct? about X are correct?
and Y are
t? 8 and 9 (1) X is formed (1) X is formed by
(1) Its respectivel by electron electron
chemical y. They sharing. transfer.
formula combine (2) The relative (2) X is a solid
is X2Y. to form a molecular at room
(2) It compound mass of X temperature
is Z. Which of is 54.5. and pressure.
ve the (3) X is a solid (3) The
ry following at room
so formula
statements temperature
A (1)
lu and (2) only B (1) and (3) only
concerning and pressure. mass of X
B (1)
bl and (3) only C (2) and (3) only
Z is / are is 90.6. A A
C (2)
e and (3) only correct? D (1), (2) and (3)
D (1),
in (2) and (3) A (1) and (2)
(1) It has a
44
ether each of the two statements is true or false; if both are true, then decide whether or not the second statement is a correct explanat
1st statement is false but the 2nd statement is true.
only
1st statement
45
1st statement 2nd statement
90 Both diamond and graphite conduct electricity. Diamond and graphite are allotropes of C
carbon.
91 The solubility of calcium carbonate in water is Calcium carbonate is an ionic compound whileC
much greater than that of ammonia. ammonia is a covalent compound.
92 The aqueous solution of sugar conducts Sugar reacts with water to form ions. D
electricity.
93 When iodine sublimes, it absorbs heat. Large amount of heat is required to break B
the strong covalent bonds between iodine atoms.
94 Carbon dioxide and silicon dioxide have similar Both carbon and silicon belong to Group IV C
physical properties. of the periodic table.
1 The following ideas were those underlying John A Y exists in the liquid state. Part
Dalton’s atomic theory, published in 1803. B
B Z exists in the liquid state.
Which idea is known to be correct? C X and Y exists in the liquid state.
D X, Y and Z exist in the gaseous state. B
A Atoms are indivisible.
B Atoms are very small. 39
3 The representation K indicates that this atom
19
C Atoms of an element are identical.
has
D Atoms of one element always differ in mass
from those of another element. A 19 protons, 19 neutrons and 20 electrons.
B B 19 protons, 20 neutrons and 19 electrons.
C 20 protons, 20 neutrons and 19 electrons.
2 The melting and boiling points of three substances D 20 protons, 19 neutrons and 20 electrons.
X, Y and Z are given in the table below: B
A 84.9.
B 85.0. 12 Consider the following atoms:
C 85.1.
D 85.5. Atom W X Y Z C
Atomic number 7 17 8 18
7 Iodine
Number
(relative neutrons
of 7 18 8 20
atomic mass
= 126.9) Which of the
consists of a following
mixture of statements is
two INCORRECT?
126
isotopes: I A W and Y belong to
127
and I. the same period.
What is the B X and Z have
relative similar chemical
abundance properties but
127
of I in different physical
iodine? properties.
A 10.0% C W is a gas at
B 30.0% room
C 70.0% temperature B
D D 90.0% and pressure.
D X is a non-metal.
8 A and B are
two
halogens. If
the atomic
number of A
is x, then
the atomic
number of
B could be
13 ion
number
is
neutr
34
P A x – 4. 79 2–
a
rt B x – 10.
B
C x + 6.
D x + 18. D
9 Which of the A 32.
following pairs of
B 34.
atoms have
C 36.
similar chemical
D 45. D
properties?
14 140
Cerium
3+ (Ce) forms
the Ce ion. The
58 number
4 20
A 2X of
an electrons
d
in this ion
10Y
B
12 is
anX A 55.
d
24
6
Y
12
23
35
C 11
40
X and 17
40
Y
D 18
X and 20
Y B 58. A
C 61.
10 Which of the D 140. A
following pairs of
elements in 15 When an atom of
Groups I and VII a Group I element
of the periodic X forms an ion,
table would A its
react with each mass
other most number
vigorously? increases.
B the
Group I
charge of
VII
the
A Rb Cl nucleus
B Rb Br increases.
C Na Cl C Its
D Na Br atomic A
number
46
decreases
.
D the number
of occupied
electron D
shells
decreases.
–
16 X is an element and the ion X has an electronic 19 Which of the following diagrams best represents
arrangement 2,8,8. Which of the following the arrangement of particles in a sample of
statements concerning X is correct? chlorine at room temperature and pressure?
A X is a halogen.
B X is a transition metal.
C X is a Group 0 element. A
D X is a Period 4 element. A
18
I C
n
t
h
e
c
i
r
c
u
i
t
s
h
o
w
n
b
e
l
o
w
,
t
h
e
47
u 3 BLFS
m
l C .
b F H
3m
Part
9
Which of the following changes would cause the B
d
o bulb to light up?
e A Add more solid copper(II) chloride to the
s beaker. What would be
B Add water to the chemical
N dissolve the formula of the
O solid compound
T copper(II) formed between
chloride. X and chlorine?
l C Replace the
i A XCl2
carbon
g B XCl3
electrodes
h C X2Cl3
with copper
D X3Cl2 B
t electrodes.
D Reverse the
21 Element E forms a
u connections to the
B sulphate with the
p electrodes.
chemical formula
.
E2(SO4)3. Element
Z forms a
20 The molecular
electr hydride with the
on chemical
DBSCP DBSCP
diagr formula H2Z. The
O O am chemical formula
FMFDUS FMFDUS of a of the compound
PEF PEF comp formed from E
ound and Z is likely to
forme be
d
betw A EZ
een B EZ2
magn C E2Z3
esium D E3Z2 C
and 22 X, Y and Z are three 25 The table below shows
elem different elements. A the colour of the
ent X compound formed aqueous solutions of
is between these elements three ionic
Compound Colour of aqueous solution
show has the following compounds.
n WX structure:
electronic green
below
YX colourless
.
YZ purple
2 9 : ;
+
.
H
MJE DPQQFS(**) DIMPSJEF
TP (Only electrons 9 in the
48
Melting Electrical Solubility
Solid
point conductivity in water
outermost non- 26 Consider the
W very high insoluble
shells are Which of the conducting information below:
shown.) following non-
P X very low soluble
a combinations conducting
rt
How many
B electrons are about the non-
Y
24 high soluble
colours of the conducting
there in the DPMPVSFE
outermost ions involved Z DSZTUBM
high good insoluble
shell of an is most likely
atom of Y? to be correct?
2+ 2– 2+ Which of the
A 4 W (aq) X (aq) Y (aq) Z (aq) following solids is
+ m
B 5 A Colourless green purple likely to be zinc
colourless 20 7 E.D. QPXFS TVQQMZ chloride?
C 6 B Colourless colourless A W
colourless colourless A A colour moved B X
D 7 C Greentowardscolourless
the right colourless C purple
Y
D Greenin the above
greenset- purple purple
D ZC
23 Element X compoun up. The coloured C
forms an d. crystal on the
3–
27 Which of the
anion X filter paper could following solids
with an be has a low melting
electronic
point and a high
arrangemen
electrical
t 2,8. Which
conductivity?
of the
following A copper(II) sulphate.
statements B potassium chromate.
concerning X C sodium permanganate.
is correct? D zinc sulphate. A
A It is in
Group III 28 Which of the and silicon dioxide
of the following have similar physical
periodic statements properties.
table. concerning carbon
B It is a dioxide is correct?
solid at 29 Which of the following
A Solid carbon
room substances has the highest
dioxide has a
temperat melting point?
covalent
ure and network A
pressure. structure.
C It exists B Carbon M
as e
C dioxide is
diatomic
used to fill t
molecules.
weather h
D It can
balloons. a
react
C Carbon dioxide n
with C
dissolves in e
neon to
water to give an
form a
acidic solution. B
covalent
D Carbon dioxide
49
C
S 33 An r
o element m i
d (melting o u
i point l m
u above 3 e
m 000 °C) c c
forms an u h
C oxide l l
which is a o
S a gas at r r
i room i
l temperat D d
i ure. e
c What C
o type of o B
n structure v
is likely a C
D to be l a
present e e
S in the n s
u element? t i
l A u
p n m
h I e
u o t c
r n w h
i o l
c r o
k r
B i
34 Which d
M of the e
e followin
t g C
a chloride
l s is C
l most a
i likely to l
c be c
C soluble i
in u D
C tetrachl m
o oromet
v hane, c
a CCl4? h
l l
A
e o
n r
B
t i
a D
50
d l r
e propertie n
D s of i
Phosphorus three n
trichloride substanc g
es X, Y
35 The and Z
v
phy are
a
sica shown
n
below.
30 W d
Electrical
h e conductivity
Melting Boiling
r Substance
i point (°C) point (°C) in solid in molten
c state state
h W
a X 801 1 413 poor good
41 Which of the
following species
53
A (1) and (2) only 46 Which of the following properties of Group II
B (1) and (3) only elements increase with relative atomic mass?
C (2) and (3) only
(1) Atomic size
D (1), (2) and (3) D
(2) Melting point
(3) Reactivity with water
43 In moving from Group I to Group VII across the
third period of the periodic table, which of the A (1) and (2) only
following physical properties of the elements show B (1) and (3) only
a gradual change? C (2) and (3) only
D (1), (2) and (3) B
(1) Atomic size
(2) Metallic character
47 Caesium (Cs) belongs to Group I of the periodic
(3) Melting point
table. Caesium reacts with bromine to form a
A (1) and (2) only compound. Which of the following statements
B (1) and (3) only concerning the compound are correct?
C (2) and (3) only
(1) Its chemical formula is CsBr.
D (1), (2) and (3) A
(2) I t is very soluble in non-aqueous
solvents.
44 The elements, sodium to chlorine, in the third (3) It is a crystalline solid at room temperature
period of the periodic table show a gradual change and pressure.
in properties. Which of the following descriptions
are correct? A (1) and (2) only
B (1) and (3) only
(1) The number of outermost shell electrons
C (2) and (3) only
in their atoms increases.
D (1), (2) and (3) B
(2) Their ability to gain electrons increases.
(3) Their chlorides change from covalent to
48 Strontium (Sr) is a Group II element. Which of
ionic.
the following statements concerning strontium is
A (1) and (2) only / are correct? Part
B
B (1) and (3) only
(1) Strontium does not burn in air.
C (2) and (3) only
(2) Strontium reacts with water to liberate
D (1), (2) and (3) A
hydrogen.
(3) All its compounds are coloured.
45 A small piece of potassium is dropped into a
trough of water. A piece of red litmus paper is A (1) only
used to test the water after the experiment. Which B (2) only
of the following observations are correct? C (1) and (3) only
D (2) and (3) only B
(1) The potassium moves on the water
surface with a hissing sound.
(2) The potassium burns with a lilac flame. 49 Germanium (Ge) is a Group IV element below
silicon in the periodic table. Which of the following
(3) The water turns the red litmus paper
statements concerning germanium are correct?
blue.
(1) It has a giant covalent structure.
A (1) and (2) only
(2) Its atomic size is larger than that of
B (1) and (3) only
silicon.
C (2) and (3) only
(3) Its fluoride has a chemical formula GeF4.
D (1), (2) and (3) D
A (1) and (2) only
B (1) and (3) only
C (2) and (3) only
D (1), (2) and (3) D
50 Which of the following statements concerning A (1) only
chlorine are correct? B (2) only
C (1) and (3) only
(1) It exists as diatomic molecules.
D (2) and (3) only D
(2) It is denser than air.
(3) It is used to sterilize swiming pool
water. 54 Which of the following bonds or attractive forces
exist in calcium carbonate?
A (1) and (2) only
B (1) and (3) only (1) Ionic bond
C (2) and (3) only (2) Covalent bond
D (1), (2) and (3) D
(3) Van der Waals’ forces
A (1) and (2) only
51 Which of the following statements concerning B (1) and (3) only
halogens are correct? C (2) and (3) only
(1) Compounds of fluorine are added to tap D (1), (2) and (3) A
i a
s r
e
/
s
a t
r r
e o
n
e g
v ?
i
(1) I
d
t
e Part
B
n
c
c
a
e
n
(
s
c
)
o
n
t
d
o
u
c
s
t
u
p
e
p
l
o
e
r
c
t
t
r
t
i
h
c
a
i
t
t
y
i
o
i
n
n
i
c
m
o
b
l
o
t
n
e
d
n
54
s
t
a
t
e
.
(2) It has a high melting point.
(3) It is soluble in water.
A (1) only
B (2) only
C (1) and (3) only
D (2) and (3) only B
55
ether each of the two statements is true or false; if both are true, then decide whether or not the second statement is a correct explanat
61 Isotopes of an element have the same chemical Isotopes of an element have the same number A
properties. of outermost shell electrons.
62 Argon is used to fill electric light bulbs. Argon exists as monoatomic molecules. B
B
63 Nitrogen is used to fill the packets of potato Nitrogen is a gas at room temperature and
chips. pressure.
68 The boiling point of bromine is higher than that The van der Waals’ forces between bromine A
of chlorine. molecules are stronger than those between
chlorine molecules.
69 The melting point of hydrogen chloride is lower Hydrogen chloride is a covalent compound B
than that of zinc chloride. while zinc chloride is an ionic compound.
70 In ammonia, the mass of hydrogen is three An ammonia molecule contains one nitrogen C
times that of nitrogen. atom and three hydrogen atoms.
Short questions
Argon Ar non-metal
Carbon C non-metal
Calcium Ca metal
Fluorine F non-metal
Germanium Ge metalloid
Lithium Li metal
Magnesium Mg metal
Neon Ne non-metal
Nitrogen N non-metal
Potassium K metal
Phosphorus P non-metal
Answer the following questions. Choose all your answers from the list. Each element can be used once,
more than once or not at all. (6 marks)
chlorine (1)
b) Write down the name of an element that forms compounds that are blue in colour.
copper (1)
c) Write down the name of the element whose atom contains 15 protons.
phosphorus (1)
d) Write down the name of the element whose atom has an electronic arrangement 2,5.
nitrogen (1)
boron (1)
f) Write down the name of an element that forms ions which is green in aqueous solution.
nickel (1)
Part
B Atomic Mass Number of Electronic
Species
number number protons neutrons electrons arrangement
(0.5 x 40)
b) Which species in the above table is / are negatively charged? (1 mark)
Species (vi) & (viii) / nitride ion and fluoride ion (0.5 x 2)
c) In which group of the periodic table should species (iii) be placed? Explain your answer. (2 marks)
Species (ix) is the cation of species (x) / (ix) and (x) are the ion and atom of the same element. (1)
75 a) Write down the chemical formula for each of the following compounds. (8 marks)
Part
b) Write down the names of the following compounds. (8 marks) B
aluminium 3+
Al iodide I
– aluminium iodide All3 colourless
–
chromium(III) Cr
3+ chloride Cl chromium(III) chloride CrCl3 green
2–
sodium Na
+
dichromate Cr2O7 sodium dichromate Na2Cr2O7 orange
–
zinc Zn
2+ bromide Br zinc bromide ZnBr2 colourless
(0.5 x 42)
77 a) Use an electron diagram to show the electron transfer when each of the following pairs of elements
combine, showing electrons in the outermost shells only. (3 marks)
m
P
a
rt
B
2+
$B
m
(1)
ii) Magnesium and nitrogen
3m
2+
.H
2+
H
3m
2+
.H
(1)
+
2m
/B
P
a
+ rt
B
/B
(1)
b) Use an electron diagram to show the sharing of electrons when each of the following pairs of elements
combine, showing electrons in the outermost shells only. (3 marks)
(1)
ii) Oxygen and hydrogen
(1)
(1)
78 Calculate the formula masses or relative molecular masses of the following substances. (5 marks)
Formula mass /
Relative atomic
Substance Chemical formula relative molecular
mass(es)
mass
Oxygen O2 O = 16.0 32.0
Part C = 12.0
B Carbon dioxide CO2 44.0
O = 16.0
N = 14.0
Potassium nitrate KNO3 O = 16.0 101.1
K = 39.1
H = 1.0
Calcium hydroxide Ca(OH)2 O = 16.0 74.1
Ca = 40.1
O = 16.0
Iron(III) sulphate Fe2(SO4)3 S = 32.1 399.9
Fe = 55.8 (1 x 5)
79 Phosphorus and nitrogen are in Group V of the periodic table and both elements form hydrides. Phosphine,
+
PH3, reacts to form phosphonium ions, PH4 , in a way similar to that by which ammonia, NH 3, forms ammonium
+
ions, NH4 .
+
a) Give the name of the type of bond formed when PH reacts with an H
3 ion. (1 mark)
80 Arrange the following substances into four groups according to their structures:
carbon dioxide, chlorine, copper, copper(II) sulphate, diamond, magnesium fluoride, nitrogen, quartz, sodium,
sodium sulphide (5 marks)
(0.5 x 10)
81 Write down the type of forces of attraction (ionic bond / covalent bond / metallic bond / van der Waals’
forces) present in each of the following cases: (5 marks)
Forces of attraction
Between carbon dioxide molecules in dry ice van der Waals’ forces Part
B
a) Classify each of the above liquids in one of the following three ways according to its response to a direct
current: (4 marks)
b) For each of the above liquids which are conductors, state the particles responsible for the conduction of
electricity. (2 marks)
molten potassium chloride — mobile potassium ions and chloride ions (1)
Structured questions
107 109
83 Silver occurs in nature as two isotopes: Ag and Ag. The relative abundance of these isotopes is shown
below.
Part
B
Isotope Relative abundance (%)
107
Ag 55
109
Ag 45
The relative atomic mass of an element is the weighted average relative isotopic mass of all the naturally occurring
12
on the C = 12.00 scale. (1)
100 (1)
= 107.9 (1)
c) Is it possible to separate the isotopes of silver by chemical means? Explain your answer. (2 marks)
84 Silicon occurs naturally in three isotopic forms. The relative abundance of each isotope is shown in the table
below:
Isotope 28
Si
29
Si
30
Si
Relative abundance (%) ? ? 3.1
Isotopes are different atoms of an element which have the same number of protons (1)
28
b) The relative atomic mass of silicon is 28.09. Calculate the relative abundance of the Si isotope.
(2 marks)
28 29
Let the relative abundance of Si and Si be y% and (96.9 – y)% respectively.
28 x y + 29 x (96.9 – y) + 30 x 3.1
28.09 =
100 (1)
y = 94.1 (1)
Part
c) Suggest ONE use of silicon. (1 mark) B
d) Silicon combines with carbon to form silicon carbide (SiC). The structure of silicon carbide is similar to
that of diamond. Draw the three-dimensional structure of silicon carbide. (2 marks)
LFZ:
DBSCPO
BUPN TJMJDPO
BUPN
(1 mark for the correct arrangement of atoms;
1 mark for the correct labelling of silicon and
carbon atoms) (2)
e) Silicon combines with chlorine to form silicon tetrachloride (SiCl4). Draw an electron diagram of the
chloride, showing electrons in the outermost shells only. (1 mark)
(1)
f) Explain why silicon carbide has a higher melting point than silicon tetrachloride in terms of their structures.
(3 marks)
Silicon carbide has a giant covalent structure while silicon tetrachloride has a simple molecular structure. (1)
To melt silicon carbide, a lot of heat is needed to overcome the strong covalent bonds between the atoms. (1)
Weak van der Waals’ forces exist between molecules of silicon tetrachloride. Little heat is needed to separate the
molecules. (1)
Part
B 85 Boron occurs naturally in two isotopes. The relative abundance of each isotope is shown in the table
below:
Isotope 10
B
11
B
Relative abundance (%) 19.7 80.3
a) Compare these two isotopes in terms of the subatomic particles they contain. (2 marks)
10 11
• B has 5 neutrons while B has 6 neutrons. (1)
OR
10 11
• B and B have different number of neutrons. (1)
The weighted average relative isotopic mass of all the naturally occurring isotopes of that element (1)
12
on the C = 12.00 scale. (1)
c) Calculate the relative atomic mass of boron. (2 marks)
10 x 19.7 + 11 x 80.3
100 (1)
= 10.8 (1)
10
d) BCl3 and 11BCl are compounds formed respectively from the two isotopes of boron with chlorine.
3
10
BCl 3 reacts with water to give steamy fumes. State, with explanation, the expected observation
11
when BCl 3 reacts with water. (1 mark)
11
BF3 would give steamy fumes because the chemical propertries of isotopes are the same. (1)
f) The equation below shows the reaction between boron trifluoride and a fluoride ion.
– –
BF + F
3 BF4
–
i) In terms of the electrons involved, explain how the bond between the BF molecule and the F
3 ion is
formed. (1 mark)
–
The bond pair electrons are provided by the F ion. (1)
2 -J #F # $ / 0 ' /F
4 , $B #S ,S
c) Name TWO elements which are mainly obtained from the sea. (1 mark)
e) Which metal and non-metal in the above table would react most vigorously with each other? (1 mark)
f) Which element in the third period has the highest melting point? Explain in terms of the structure of the
element. (3 marks)
To melt silicon, a lot of heat is needed to overcome the strong covalent bonds between the atoms. (1)
g) The atomic number of krypton (Kr) is 36. The electronic arrangement of a krypton atom is 2,8,x,y. What
are the values of x and y? (1 mark)
x = 18 (0.5)
y = 8 (0.5)
P
a
rt
B h) Rubidium (Rb) is a Group I element. Its relative atomic mass is larger than that of potassium.
87 With reference to the part of the periodic table shown, answer the following questions.
(SPVQ
* ** *** *7 7 7* 7** 0
2 -J #F # $ / 0 ' /F
4 , $B #S
a) Name ONE metalloid in the above table. (1 mark)
An argon atom has 8 electrons in its outermost shell. A special stability is obtained when this happens. (1)
An argon has very little tendency to share electrons with other argon atoms. Therefore argon is monoatomic. (1)
e) In what way are the electronic arrangements of atoms of lithium and sodium
f) Point out the gradual change in the reactivity of Group II elements down the group. (1 mark)
There is a gradual increase in the melting / boiling point of the elements. (1)
There is a gradual change in the intensity of the colour of the elements. (1)
h) Describe the structure and bonding in aluminium with the help of a diagram. (3 marks)
Aluminium has a giant metallic structure. It consists of tightly packed positive ions surrounded by a sea of delocalized
electrons. (1)
The attractive forces between the electrons and positive ions hold the particles of aluminium together. (1)
(1)
(SPVQ
* ** *** *7 7 7* 7** 0
2 -J #F # $ / 0 ' /F
4 , $B #S ,S
P
a 5 *
rt
B
a) How are
the elements arranged in the periodic table? (1 mark)
b) What is the similarity in the electronic arrangement of atoms of elements in the same period? (1 mark)
Lithium / Li (1)
Potassium / K (1)
ii) Suggest how the most reactive metal should be stored. (1 mark)
iii) State ONE hazard warning label that should be displayed on a reagent bottle containing that metal.
(1 mark)
Silicon / Si (1)
h) Balloons filled with different noble gases were tied to a bar. They were held horizontally at the same
height and then released. The positions of two of the balloons 5 seconds after release are shown in the
diagram.
/F
/F
"S
,S "S
89 The following questions refer to the incomplete periodic table shown below.
(SPVQ
* ** *** *7 7 7* 7** 0
2 B C D E F
1FSJPE 3 G H
4 I
Noble gases
d and h
2+ 2+
G .H
m
2+ 2+
G PS .H
3m
2+
2+
P G .H
a
rt
B
90 The circuit shown below is set up and the solid lead(II) bromide is heated until it becomes motlen.
CVMC
MFBE(**) CSPNJEF
IFBU
When the lead(II) bromide becomes molten, the bulb lights up.
d) Suggest a place in the laboratory where this experiment could be carried out safely. Briefly explain your answer.
(2 marks)
e) State what will happen to the bulb when heating is stopped and the molten lead(II) bromide is allowed
to cool down gradually to room temperature. Explain your answer. (3 marks)
As the temperature drops, movement of ions in molten lead(II) bromide slows down. Therefore a smaller current flows
When the molten lead(II) bromide becomes solid, there are no mobile ions. Hence no current flows through the external
circuit. (1)
P
a
rt
B
91 A tiny potassium permanganate crystal was placed at the centre of a piece of filter paper moistened with
sodium sulphate solution. A d.c. power supply was then applied. Within a few minutes, a coloured patch
was seen to develop on the filter paper.
+ m
E.D. QPXFS TVQQMZ
a) What was the purpose of moistening the filter paper with sodium sulphate solution? (1 mark)
Purple (1)
ii) Sketch the position where the coloured patch would be expected to develop. (Positive and negative
electrodes must be shown.) (2 marks)
DPMPVSFE QBUDI
+ m
c) The positive and negative electrodes were then reversed after some time. Briefly explain what would be
observed. (2 marks)
The coloured patch would move towards the new position of the positive electrode (1)
because the negative permanganate ions would be attracted towards the positive electrode. (1)
92 The diagram shows an experimental set-up for studying the reaction of lithium with water.
Part
B
MJUIJVN
XBUFS XJUI
VOJWFSTBM JOEJDBUPS BEEFE
a) Describe what you would observe when the lithium reacts with the water in this
experiment. (3 marks)
• The universal indicator turns blue / purple (alkaline colour). (1) • The water level in the test tube goes down (or gas
fills the test tube). (1) • Lithium moves around on the surface of water. (1) • Lithium dissolves. (1)
b) Write a word equation for the reaction of lithium with water. (1 mark)
c) Caesium is another Group I element. Suggest whether caesium or lithium is more reactive. (1 mark)
d) The graph shows the melting points of the Group I metals plotted against the atomic numbers.
20 0
18 0
.FMUJOH QPJOU ($)
160
14 0
12 0
100
8 0
6 0
40
2 0
0
010 20 30 40 50 60 70 80 90
" UPNJDOVNCF S
i) Describe fully how the melting point changes as the atomic number increases. (2 marks) Part
B
The melting point decreases as the atomic number increases (1)
26 °C (1)
C (1)
ii) Explain your answer in (i) by describing the reactivity trends in the periodic table. (2 marks)
The reactivity of Group I elements increases as we move down the group (i.e. potassium is more reactive than
lithium). (1)
The reactivity of Group VII elements decreases as we move down the group (i.e. chlorine is more reactive than
iodine). (1)
93 The following table lists the atomic numbers of some elements in Group II.
Be 4
Mg 12
Ca 20
Sr 38
a) In what way are the electronic arrangements of atoms of magnesium and calcium
b) A student added a few pieces of calcium granules into a beaker of cold water. Calcium gave a colourless
Part
B gas with cold water.
i) State ONE more observation when calcium reacted with water. (1 mark)
ii) The student recorded the following observation in her laboratory report:
‘Evolution of the colourless gas was at first slow but became faster after some time.’
Suggest an explanation for the student’s observation. (2 marks)
Reaction between calcium and water starts only when the oxide layer dissolves. (1)
c) The electronic arrangement of a strontium (Sr) atom is 2,8,x,8,y. What are the values of x and y?
(1 mark)
x = 18 (0.5)
y = 2 (0.5)
d) Suggest whether strontium or calcium is more reactive. (1 mark)
90
e) Strontium-90 ( Sr) is a radioactive isotope of strontium, and is one of the dangerous by-products of
nuclear fission.
Isotopes are different atoms of an element which have the same number of protons (1)
ii) Children’s teeth require a large amount of calcium to grow. Scientists found that in areas where nuclear
90
weapon tests were conducted above the ground, children’s teeth contained a higher level of Sr.
Suggest a reason for the findings of the scientists. (2 marks)
94 The following table shows the melting and boiling points of chlorides of some Period 3 elements of the
periodic table.
a) Draw an electron diagram of magnesium chloride, showing electrons in the outermost shells only.
(1 mark)
2+
75
.H
m
(1)
76
b) i) Draw an electron diagram of sulphur dichloride, showing electrons in the outermost shells
only.
(1 mark)
(1)
ii) Suggest the physical state of sulphur dichloride at room temperature and pressure. (1 mark)
Liquid (1)
c) Explain the difference in the melting points of the above four chlorides in terms of their structures.
(4 marks)
Sodium chloride and magnesium chloride have giant ionic structures. (1)
To melt them, a lot of heat is needed to overcome the strong ionic bonds between the ions. Hence sodium chloride
Phosphorus trichloride and sulphur dichloride have simple molecular structures. (1)
The attractive forces between the molecules are weak. Little heat is needed to separate the molecules. Hence
phosphorus trichloride and sulphur dichloride have low melting points. (1)
Part
B
d) Discuss, with explanation, the electrical conductivity of magnesium chloride with reference to the type
and property of the particles in it. (3 marks)
Magnesium chloride conducts electricity in molten state or aqueous solution but not in solid state. (1)
In solid state, the ions in magnesium chloride are held together by strong ionic bonds. They are not free to move. (1)
Strong attractive forces exist between ions in sodium chloride and water molecules. (1)
These forces cause the ions to move away from the solid and go into the water. (1)
95 X, Y and Z are three elements in the periodic table, with the sum of their atomic numbers equal to 46.
Moreover, both X and Y are Group VII elements, while the atomic number of X is smaller than that of Y.
X fluorine (1)
Y chlorine (1)
Z calcium (1)
c) Draw an electron diagram of the compound P formed from X and Y, showing electrons in the outermost
shells only. (1 mark)
PS
(1)
d) Draw an electron diagram of the compound Q formed from X and Z, showing electrons in the outermost
shells only. (1 mark)
m m P
a
rt
2+ 2+
B
; PS $B
m m
(1)
To melt Q, a lot of heat is needed to overcome the strong ionic bonds between the ions. (1)
The attractive forces between the molecules of P are weak. Little heat is needed to separate the molecules. (1)
F) X combines with nitrogen to form a nitride. Draw an electron diagram of the nitride, showing electrons
in the outermost shells only. (1 mark)
PS
(1)
g) Z combines with nitrogen to form a nitride. Draw an electron diagram of the nitride, showing electrons
in the outermost shells only. (1 mark)
2+ 2+
; $B
3m 3m
2+ 2+
; PS $B
3m 3m
2+ / 2+
; $B
(1)
Part
B
96 The following table shows some information about some species. They can be atoms or ions.
A 8 16 8 8 8
B 8 18 8 8 10
C 8 16 8 10 8
D 9 19 9 9 10
E 12 24 12 10 12
F 12 24 12 12 12
(0.5 x 12)
C is an anion of A. (1)
E is a cation of F. (1)
(1)
i) Draw an electron diagram of X, showing electrons in the outermost shells only. (1 mark)
(1)
Part
B
ii) Draw an electron diagram of Y, showing electrons in the outermost shells only. (1 mark)
2+ 2m
'
(1)
iii) Compare the melting points of X and Y. Explain your answer. (3 marks)
To melt Y, a lot of heat is needed to overcome the strong ionic bonds between the ions. (1)
The attractive forces between the molecules of X are weak. Little heat is needed to separate the molecules. (1)
97 The electron diagram of ammonium chloride is shown below:
+ m
) / ) $M
a) Identify the type of bond which exists between the two ions. (1 mark)
b) Identify the type of bond which exists between nitrogen and hydrogen. (1 mark)
c) When a hydrogen ion reacts with an ammonia molecule, an ammonium ion is formed.
i) Give the name of the type of bond formed when a hydrogen ion reacts with an ammonia
molecule. (1 mark)
ii) Describe how this bond is formed in the ammonium ion. (1 mark)
The nitrogen atom supplies both bonding electrons to the hydrogen ion. (1)
Part
B
d) Explain whether ammonium chloride is soluble in water. (3 marks)
Strong attractive forces exist between ions in ammonium chloride and water molecules. (1)
These forces cause the ions to move away from the solid and go into the water. (1)
e) Describe a chemical test to show the presence of chloride ions in a solid sample. State the expected
observation(s). (3 marks)
Dissolve the sample in water. (1)
Then add excess dilute nitric acid, followed by silver nitrate solution. (1)
A special stability is obtained when this happens. Hence argon seldom forms compounds with other elements. (1)
Atoms of magnesium and calcium have the same number of outermost shell electrons. (1)
c) A sulphur atom tends to form an ion carrying two negative charges. (1 mark)
A sulphur atom has an electronic arrangement 2,8,6. It obtains a stable electronic arrangement (2,8,8) by gaining
The ions in copper are packed closely and the metallic bonds holding them together are very strong. (1)
To melt a piece of copper, a lot of heat is needed to overcome the strong attractive forces. Hence copper has a high
P
e) Quartz is a solid which melts at a high temperature while carbon dioxide is a gas at room a
temperature. (4 marks) rt
B
To melt quartz, a lot of heat is needed to overcome the strong covalent bonds between the atoms. Hence quartz has a
The attractive forces between the molecules are weak. Little heat is needed to separate the molecules. Hence carbon
a) For each case, choose ONE substance from the above list which has arrangement of particles as shown
under room temperature and pressure. (3 marks)
b) Name the attractive forces that exist between particles in substance Y. (1 mark)
i) hardness; (2 marks)
P X is hard (1)
a
rt
B
due to the strong ionic bonds between the ions. Relative motion of the ions is restricted. (1)
X does not conduct electricity in solid state but it does in molten state. (1)
In solid state, the ions in X are held together by strong ionic bonds. They are not free to move. (1)
The attractive forces between molecules of non-aqueous solvents are similar to those between molecules of Z. Hence
100 A new element X has been recently discovered. It is a solid with a low melting point. It reacts violently with
water and catches fire in the reaction. An alkaline solution is formed.
Group I (1)
XBr (1)
iii) Discuss, with explanation, the electrical conductivity of the compound with reference to the type and
property of the particles in it. (3 marks)
The compound conducts electricity in molten state or aqueous solution but not in solid state. (1)
In solid state, the ions in the compound are held together by strong ionic bonds. They are not free to move. (1)
The ions become mobile in molten state or aqueous solution. (1)
101 The diagrams below show the structures of diamond and graphite. Diamond and graphite are allotropes.
LFZ:
DBSCPO BUPN
EJBNPOE HSBQIJUF
.
Allotropes are two (or more) forms of the same element (1)
This is because the atoms are held together by strong covalent bonds. It is very difficult to separate the atoms. (1)
Part c) Based on the structure of diamond, suggest ONE use of it. (1 mark)
B
In graphite, the layers of carbon atoms are held by weak van der Waals’ forces. The layers can easily slide over each
In diamond, each carbon atom is bonded to other carbon atoms by strong covalent bonds. Relative motion of the
Graphite has a layered structure. Weak van der Waals’ forces exist between the layers. (1)
Graphite has a layered structure. Within each layer, each carbon atom uses three outermost shell electrons in
The remaining electron is delocalized between the layers of carbon atoms. (1)
102 Diamond and graphite are different forms of the same element. The structure of diamond is shown below.
LFZ:
DBSCPO BUPN
Part
B
b) Explain why carbon dioxide is a gas at room temperature and diamond is a solid which melts at a high
temperature. (2 marks)
The attractive forces between carbon dioxide molecules are weak. Little heat is needed to separate the molecules. Hence
Diamond consists of a network of covalent bonds. A lot of heat is needed to overcome the strong covalent bonds
between the atoms. Hence diamond has a high melting point. (1)
c) Graphite is mixed with clay to make pencil leads.
LFZ:
DBSCPO (1 mark for the hexagonal arrangement of atoms;
BUPN 1 mark for labelling the van der Waals’ forces between
the layers of atoms) (2)
ii) Suggest why this crystal structure of graphite enables it to leave a mark when a pencil is drawn across
a sheet of paper. (2 marks)
When graphite is pressed onto a peice of paper, the layers of atoms slide over each other (1)
103 Silicon (Si) and germanium (Ge) have the same crystal structure, as shown below:
Part
B
a) What
type of structure do silicon and germanium have? (1 mark)
LFZ:
r the correct labelling of silicon and oxygen
PYZHFO BUPN TJMJDPO BUPN atoms) (2)
(
1
m
a
r
k
f
o
r
t
h
e
c
o
r
r
e
c
t
a
r
r
a
n
g
e
m
e
n
t
o
f
a
t
o
m
s
;
1
m
a
r
k
f
o
c) Silicon combines with chlorine to form silicon tetrachloride (SiCl4). Draw an electron diagram of the
chloride, showing electrons in the outermost shells only. (1 mark)
(1)
d) Explain why silicon dioxide has a higher melting point than silicon tetrachloride in terms of their
structures. (2 marks)
To melt silicon dioxide, a lot of heat is needed to overcome the strong covalent bonds between the atoms. (1)
The attractive forces between silicon tetrachloride molecules are weak. Little heat is needed to separate the molecules.(1)
Part
B
e) The table below gives the relative abundance of each isotope in a sample of germanium, Ge.
Isotope 70
Ge
72
Ge
74
Ge
Relative abundance (%) 24.4 32.4 43.2
100 (1)
= 72.4 (1)
104 At room temperature, both sodium metal and sodium chloride are crystalline solids.
i) In this diagram, mark all sodium ions with a positive (+) sign and all chloride ions with a negative (–)
sign. (1 mark)
+ m
m +
m +
+ m (1)
ii) What is the number of neighbouring chloride ions directly attached to each sodium ion in crystalline
sodium chloride? (1 mark)
6 (1)
P
a
rt
B b) i) Explain how the
particles are held together in solid sodium metal. (1 mark)
The particles in solid sodium metal are held together by a ‘sea’ of mobile electrons. (1)
ii) Explain how the particles are held together in solid sodium chloride. (1 mark)
The particles in solid sodium chloride are held together by ionic bonds. (1)
iii) The melting point of sodium chloride is much higher than that of sodium metal. What can be deduced
from this information? (1 mark)
The ionic bonding in sodium chloride is stronger / requires more heat to break than the metallic bonding in
sodium. (1)
c) Compare the electrical conductivity of solid sodium metal with that of solid sodium chloride. Explain your
answer. (3 marks)
Solid sodium conducts electricity but solid sodium chloride does not. (1)
but the ions in solid sodium chloride are not free to move. (1)
d) Using sodium as an example, describe the bonding in metals. Hence explain why metals are malleable.
(2 marks)
As the metal is struck by a hammer, the ion layers slide through the ‘sea’ of electrons to new positions. The metal does
not break because the ions are still bound together by the ‘sea’ of electrons. (1)
105 The symbols p, q, r, s, t, u, v and w represent eight consecutive elements in the second and third periods
of the periodic table. The table below lists their boiling points:
Element p q r s t u v w
Boiling point (°C) 2 480 3 930 4 830 –196 –183 –190 –246 890
P
a
Answer: Be B C N O F Ne Na rt
B
a) Deduce from the above information which elements r and s represent respectively. (3 marks)
q (1)
d) State, with explanation, which of the elements is stored in paraffin oil. (2 marks)
f) X is a compound formed from elements t and u. Draw an electron diagram of X, showing electrons in
the outermost shells only. (1 mark)
PS
(1)
g) Y is a compound formed from elements t and w. Draw an electron diagram of Y, showing electrons in
the outermost shells only. (1 mark)
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B
To melt Y, a lot of heat is needed to overcome the strong ionic bonds between the ions. (1)
The attractive forces between the molecules of X are weak. Little heat is needed to separate the molecules. (1)
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106 The diagram below shows the relative electrical conductivities of the first three elements in Period 3.
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a) Describe the bonding in magnesium. Hence explain why magnesium is a good conductor of electricity.
(3 marks)
The outermost shell electrons of each magnesium atom are free to move randomly in magnesium. (1)
Thus, magnesium consists of positively charged ions surrounded by a ‘sea’ of electrons. (1)
Magnesium is a good conductor of electricity due to the movement of mobile electrons in the metal. (1)
Part
B
b) Explain why the electrical conductivity of aluminium is higher than that of magnesium. (2 marks)
Each aluminium atom has three outermost shell electrons while a magnesium atom has two. (1)
not break because the ions are still bound together by the ‘sea’ of electrons. (1)
107 Read the passage below and answer the questions that follow.
The table below is part of the table of elements devised by the English chemist John Newlands in 1864. He arranged
the elements in order of their relative atomic masses. He found a repeating pattern, with elements having similar
properties in the vertical columns (Groups).
H Li Be B C N O
F Na Mg Al Si P S
Cl K Ca Cr Ti Mn Fe
Co / Ni Cu Zn Y In As Se
Br Rb Sr Ce / La Zr Di / Mo Ro / Ru
Part
B Many scientists were critical of the pattern suggested by Newlands.
The diagram below shows a version of Mendeléev’s Periodic Table. Mendeléev placed most of the elements in order
of relative atomic mass. This table became accepted by other scientists.
Period 2 Li Be B C N O F
Period 3 Na Zn Al Si P S Cl
K Ca ? T V Cr Mn
Period 4 i Fe Co Ni
Cu Zn ? ? As Se Br
Rb Sr Y Zr Nb Mo ?
Period 5 Ru Rh Pd
Ag Cd In Sn Sb Te I
a) i) Which group of elements, present in the modern periodic table, is missing from Newlands’ table
above? (1 mark)
Group 0 (1)
ii) Explain why this group was missing from Newlands’ classification of elements. (1 mark)
b) Newlands put hydrogen, fluorine and chlorine in the same group. Give ONE property of hydrogen which
makes it similar to fluorine and chlorine. (1 mark)
Exists as diatomic molecules / exists as a gas at room conditions / any other general property of non-metals (1)
You should give examples from the table and use your knowledge of the chemistry of the elements.
(4 marks)
• Many elements in the groups have very dissimilar properties, e.g. K and Cu. (2)
• Two elements were put in one place, e.g. Ce and La. (2)
• Metals and non-metals were mixed up, e.g. Cl and Co in the same group. (2)
d) Give TWO ways in which Mendeléev’s table improved on Newlands’ table. (2 marks)
• A new group created / iron, cobalt and nickel put in a group. (1)
The carbon allotropes, diamond and graphite, have been known for centuries. In 1
– buckminsterfullerene – was discovered. This new form of carbon contains C60 molecules. Each C60 molecule is formed by 60 car
The new form of carbon is virtually insoluble in water, but soluble in non-aqueous solvents, such as
toluene.
Interest in buckminsterfullerene has led to the discovery of a related group of carbon structures referred to as nanotube
Part Carbon nanotubes have a high strength. Carbon nanotube-based materials are b
B develop ultra lightweight and extremely strong materials.
a) What is
meant by the term ‘allotropes’? (2 marks)
Allotropes are two (or more) forms of the same element (1)
b) What type of structure does buckminsterfullerene have? Expain your answer. (3 marks)
It can be deduced that the attractive forces between molecules of buckminsterfullerene are similar to those
Diamond has a giant covalent structure. The carbon atoms are held together by strong covalent bonds. (1)
There are weak van der Waals’ forces between the buckminsterfullerene molecules. (1)
More heat is needed to break the strong covalent bonds between atoms in diamond. Hence diamond has a higher
melting point.
d) Explain the high strength of carbon nanotubes with reference to the bonding in them. (1 mark)
The carbon atoms are held together by strong covalent bonds. (1)
e) Graphite is used to make electrodes in dry cells. It is also used to make strong but lightweight fishing
rods.
i) Explain why graphite can conduct electricity with reference to its structure. (3 marks)
In graphite, the carbon atoms are arranged in flat parallel layers. (1)
Within each layer, each carbon atom uses three electrons in forming covalent bonds with three other carbon
atoms. (1)
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The remaining outermost shell electron of each carbon atom is delocalized between the layers of carbon atoms. (1) B
ii) Explain why graphite can bend so that it is suitable for making a fishing rod. (2 marks)
Graphite has a layered structure. Weak van der Waals’ forces exist between the layers. (1)
The layers of atoms can slide over each other easily. (1)
f) Suggest and explain how you would distinguish between buckminsterfullerene and graphite by a physcial
95
method. (3 marks)
Adding a non-aqueous solvent to each solid separately, buckminsterfullerene is soluble while graphite is insoluble. (1)
Buckminsterfullerene has a simple molecular structure and is soluble in non-aqueous solvents. (1)
96
109 Read the passage below and answer the questions that follow.
Aerial shells are the most common types of fireworks for public displays. A shell consists of a paper tube filled with stars and a bl
Upon ignition, the potassium nitrate, sulphur and carbon (in the black powder) in the lift charge react to form carbon dioxide and
a) Explain
the meaning of the term ‘mixture’. (2 marks)
b) Draw an electron diagram of a nitrate ion, showing electrons in the outermost shells only. (1 mark)
Part
B
m
(1)
c) Explain how the lift charge sends the shell into the air. (2 marks)
The pressure from the expanding gases propels the shell into the air (2)
d) i) What solid residue is left behind when the black powder explodes? (1 mark)
ii) Wht is the chemical formula of the solid suggested in (i)? (1 mark)
K2S (1)
e) i) Name the group to which strontium (Sr) and barium (Ba) belong. (1 mark)
Sr(NO3)2 (1)
f) A manufacturer wants to produce fireworks giving a yellow colour. Suggest a metal salt the manufacturer
may add. (1 mark)
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Discuss how the melting points of the elements are related to their bondings and structures. (9 marks)
(For this question, you are required to give answers in paragraph form.)
Part
B
Sodium, magnesium and aluminium are metals. The strength of the metallic bond depends on the number of delocalized
Sodium has one outermost shell electron per atom, magnesium has two while aluminium has three. The strength of metallic
bond and hence the melting point increase from sodium to aluminium. (1)
Silicon has a giant covalent structure. Each silicon atom is covalently bonded to four other silicon atoms. (1)
To melt silicon, a lot of heat is needed to overcome the strong covalent bonds between the atoms. Hence it has a very high
Phosphorus, sulphur and chlorine exist as simple molecules. The molecules are attracted to one another by weak van der
Little heat is needed to separate the molecules. Hence they have low melting points. (1)
(3 marks for organization and presentation)
111 ‘When atoms combine, they can obtain the electronic arrangements of atoms of noble gases.’
Discuss, with reference to suitable examples, how atoms of Group VI elements obtain the electronic
arrangements of atoms of noble gases. (9 marks)
(For this question, you are required to give answers in paragraph form.)
Atoms of Group VI elements have six outermost shell electrons. They can obtain the electronic arrangements of atoms of
Oxygen is a Group VI element. Take the combination of oxygen and sodium as an example. An oxygen atom has
an electronic arrangement 2,6. It tends to gain two electrons to obtain the electronic arrangement of a stable neon atom
(2,8). (1)
Sodium is a Group I element. A sodium atom has an electronic arrangement 2,8,1. It tends to lose one electron to
When sodium and oxygen react, two sodium atoms would combine with one oxygen atom. (1)
Take the combination of oxygen and carbon as another example. An oxygen atom has an electronic arrangement
One carbon atom forms a double bond with each of the two oxygen atoms. (1)
The melting point of potassium chloride is higher than that of silicon tetrachloride. (1)
To melt potassium chloride, a lot of heat is needed to overcome the strong ionic bonds between the ions. Hence potassium
The attractive forces between the molecules are weak. Little heat is needed to separate the molecules. Hence silicon
Potassium chloride conducts electricity in molten state or aqueous solution while silicon tetrachloride does not conduct
electricity. (1)
In the solid state, the ions in potassium chloride are held together by strong ionic bonds and are not free to move.
The ions become mobile when potassium chloride is in molten state or aqueous solution. Hence potassium chloride can
Silicon tetrachloride does not conduct electricity because it does not contain mobile electrons or ions. (1)
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