Write your name here Edexcel Certificate cenveNumber Candidate Number tle CLP TOt Ltt International GCSE = \—— Chemistry Unit: KCHO/4CHO Paper Reference KCHO/2C 4CHO/2C _ Wednesday 16 January 2013 ~ Morning Time: 1 hour — Total Marks: Instructions © Use black ink or ball-point pen. © Fill in the boxes at the top of this page with your name, centre number and candidate number. © Answer all questions. ‘© Answer the questions in the spaces provided = there may be more space than you need. © Show all the steps in any calculations and state the units. Information © The total mark for this paper is 60. © The marks for each question are shown in brackets use this as a quide as to how much time to spend on each question. Advice @ Read each question carefully before you start to answer it. © Keep an eye on the time. © Write your answers neatly and in good English © Tiyto answer every question. © Check your answers if you have time at the end. cosom MMMM gen er ‘Scanned with CamScannerLL jons. ' ‘answer ALL questi f s sare ‘ ints of three relatedd compound: 1 The melting ve formicacid = 8°C palmiticacid 63°C the boiling point of all these compounds is above 100°C {a} Use the grid to draw a bar chart of the melting points. 1004 80 60+ Temperature in °C 40 Room temperature 20h capric formic palmitic acid acid acid (b) Room temperature has been marked on the grid | Use your bar chart to give the physical state of each acid at room temperature. | | capric acid Sovud. formic acid Vguid palmitic acid “old. (Total for Question 1 = 4 marks) AAA ‘Scanned with CanScanner2 Astudent produces this chromatogram for four dyes, A, B, Cand D. Bue Red Yelow AB COO (a) Put a cross (BR) in a box to indicate your answer. (i). Which one of the dyes contains three colours? Oa Os Oc Ro (ii) Which one of the dyes contains one colour only? a o Qa on wD {b) Each dye is made from one or more of the colours blue, red and yellow. The student thinks that the result for one dye is incorrect. Suggest which result is incorrect. Explain your answer. The incorrect result is % because. Wun. 70th JO. WAY Vin ud wr dw, rpelorte 0) (Total for Question 2 = 4 marks) TVR — ‘Scanned with CanScannerthat hasa rocket Motor son the aeroplane contains liquid oxygen, {a) One of the tank plete the diagram to show the arrangement of the particles in aliquid, icle has been drawn for you. (i) Com One part (i) Much more oxygen can be stored in the tank when the oxygen is a liquid rather than a gas. Give a reason for this in terms ofthe arrangement of the particles VOW We PoHidedr ow Joly qoolud. = art » UNIT 0 & ‘Scanned with CanScanner(b) Magnesium burns in oxygen to form magnesium oxide magnesium burning oxygen (i) State two observations that can be made when magnesium burns in oxygen. Ware Mom, Wy Yousdare (id) Give the formula of magnesium oxide. Mo (0) A small amount of magnesium oxide is dissolved in water. When universal indicator is added to this solution, the indicator turns blue. (i) What does the observation with the indicator show about magnesium oxide? (ii) Identify the fon that is responsible for the universal indicator turning blue. \agpsoride, ow (Total for Question 3 = 8 marks) {OOO NO 0A A ae ‘Scanned with CanScannerAn 1 dilute hydrochloric aciel was added to a lump OF calcium, c 4 Anexcoss of dilute Arbon, The mass ofthe beaker and contents was recorded every 39 seconds Me, 4 The graph shows the results ao 100 oY Mass of 99 beaker and contents in grams 98 1 made when dj én to calcium carbonate. lute hydrochloric acids added | (b) Give the test for carbon dioxide gas. oe Nima sioXe, | Resute Bou uy il ‘Scanned with CanScanner(c) Describe the relationship between the mass of the beaker and contents, and the time, Xe nanan LOOLE Guakemps, (A) (After how many minutes did the reaction stop? Dy ow Ai) State why the reaction eventually stopped. Deomte wre wlsiamy wAdoro}e meri deoehed.. (2) Identify the compounds, other than water, present in the solution in the beaker (i) after two minutes Clem UWhLovide, Sh. Hatin, Ded. (ii) after five minutes 4 (0 The experiment was repeated using the same mass of calcium carbonate’but as a Powder instead of a single lump. On the graph, sketch the curve you would expect to obtain from this second experiment. Sugen Ww word} We omeie (Total for Question 4 = 11 marks) {TAA Tne ‘Scanned with CanScanner ml5 acid with a metal hydroxide, a mopay ; be made by reacting & e salts can be m0 5 Solu borate, made by using a precipitation reaction, Its can be macke Insoluble sal ble to show which acid or metal compound is used to Make each ate the table to sho 2) Complete th @ salt listed Iumetal compound state whether it would be used asa sold on For each metal c , aqueous solution, Metal compound Acid used ; salt made aie Name Solid or aqueous solution copper(ti) sulfate Liha Copper(tl) oxide . a Wig | silver chloride hydrochloric aca Nw aqueous solution Nicol, Potassium carbonate | | potassium nitate shi, . . HUA (©) An acidis a source of hydrogen ions, AGL Scanned with CanScanner(c) Lead{l) chloride is an insoluble salt that can be prepared by reacting lead({l) nitrate with sodium chloride. Describe how you would prepare a pure, dry sample of lead(li) chloride starting from solid leaditl) nitrate and solid sodium chloride. We Wik gispewy Voda 0 parole Gy AOsnw WWokd we Woks yee Avan Yofeely y vow dew . WOR em wily Gintiled woke: ulin VY & oY (Total for Question 5 = 12 marks) n NIA Turnover ~ — Scanned with CanScanner {A. 399999 Dissolve 1.5 kg of sugar in 5 dm*of warm water, i 5 Add yeast and 8 kg of plums, Pour the mixture into a flask, Leave the flask for several weeks until the Feaction has Stoppeg, Remove the Solid yeast and pour the cleay "uid into bottes ee airlock flask, —— heater — temperature o f mixture Pt between 3 O-ao°c (a) Sia Cnhs suas 0, When yeast is added, water reacts with suctose to form Slecose, CH.0, Write a chemical "Uation for this reaction, vty Ko MWe Wu 0b ANH OTN a Scanned with CanScanner(b) The glucose is then converted into ethanol by the yeast C,H,,0,(aq) > 2C,H,OH(aq) + 2CO,(g) (i) How would you know when the reaction has stopped? bavaning with 9 (i) How could the solid yeast be removed from the mixture? {wong \Wookio~ (c) Ethanol can be converted into chloroethene,, CH =CHCl, in three stages. Stage 1 Ethanol is dehydrated to form ethene, CH=CH, Stage 2 Ethene is converted into 1,2-dichloroethane, CH,CICH,CI Stage 3 1,2-dichloroethane is converted into chloroethene and hydrogen chloride (i) Why is the reaction in Stage 1 described as dehydration? wor © aymored (ii) Identify the catalyst used in the reaction in Stage 1 Dunainiomn Oxide A1,0,, (iii) Suggest the name or formula of the substance used to react with ethene in Stage 2 VUadetins Oy (iv) Write a chemical equation for the reaction in Stage 3. Oka ud > Chyoacy Hil 3 UANUQVVA VN AU 0 A oe ‘Scanned with CanScannerake the polymer polyichloroethene also kny Onn Many, The displayed formula for part of the PVC molecule iy awa cay et C—C—C_¢_¢_¢ Mrr dy df HOM WW 0 Draw a displayed formula fora chlotaethene molecule \ uw (i) Describe, in terms of structure and chloroethene mol, Sonding, what happens when lecules are conver ‘ted into poly(chloroethene WW deadly dod (pany, (Total for Question 6 = 11 marks) AMMAN ANA A A ‘Scanned with CanScanner 4anparatis to mestsute the volume of carbon diowle ponate OF GIOUP 2 Metal was reacted with df le given off Ne iti aeig Atotwery tube | bung b dilute nitric acid — 250 cms Measurin, cylinder metal carbonate She weighed our some ofthe carbonate and put itin a coni an excess of dilute nitric acid, mical flask. She then added After adding the acid she placed the bung and d She measured the total vol lume of gas collected in the measuring cylinder. Her results are shown in the table. Mass of Group 2 carbonate 0.888 9 Volume of gas collected 144 cm? ‘The equation for the reaction is XCO,(s) + 2HNO (aq) X(NO,) (aq) + 4,000 + Co,(9) where X's the symbol for the Group 2 metal. ‘ ; CAAT 0 ‘Scanned with CanScanner(2) (i) Calculate the amount, in moles, of carbon dioxide gas collected. {Assume that one mole of gas has a volume of 24 000 cm’ at rtp) vy 2000 Amount of carbon dioxide gas collected = 6.006. mol (ii) Deduce the amount, in moles, of the carbonate that reacted. Amount of carbonate reacted= 0-006 mol (ii) Using the mass of the carbonate and your answer to (a)(i), calculate the relative formula mass (M) of this carbonate. Give your answer to the nearest whole number. ow 6.006 Relative formulamass=. \U (iv) Calculate a value for the relative atomic mass of the Group 2 metal, X, and use the Periodic Table on page 2 to suggest its identity. (D,, + 0 Relative atomic mass of X = 8 Identity of X= HOW (NANA EA A A 3 Turn aver ‘Scanned with CanScanner(b) After the stuclent had completed! the experiment she was told that the metal \ carbonate was calcium carbonate. She calculated that 0.888 g of calcium’ c: ‘arbonate would produce 213 cm? of carbon dioxide, She was certain that she had measured the mass of the metal carbonate correctly, Suggest two reasons why the volume of gas she collected was less th, ‘ Ave comoorate omigal You mae aN 213 em 2 Bwucee Gs kumflatiors (Total for Question 7 = 10 marks) (TOTAL FOR PAPER = 60 MARKS) I Scanned ith CanScanner