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PROGRAM STUDI TEKNIK KIMIA

JURUSAN TEKNOLOGI INDUSTRI DAN PROSES

INSTITUT TEKNOLOGI KALIMANTAN

Matakuliah : Pengantar Teknik Kimia


Semester : Gasal 2020/2021
Dosen : 1. Memik D. Pusfitasari, S.T., M.T.
2. Asful Hariyadi, S.T., M.Eng
Hari/Tanggal : Selasa, 22 Desember 2020
Waktu : 13.30 – 16.00 WITA

QUIZ

1. Convert :
a. 98 ℉ = ℃
b. 𝑐𝑎𝑙 𝐽
20 ⁄𝑔 𝐾 = ⁄𝑔𝑚𝑜𝑙 𝐾
if the molecular weight (MW) is 15 g/gmol

2. The ideal gas law applies as follows :


𝑃𝑉= 𝑛𝑅𝑇
where :
𝑃 = pressure of gas (Pa)
𝑉 = volume of gas (m3)
𝑛 = moles of gas (gmol)
𝑀𝑊 = molecular weight of gas = 28 (g/gmol)
𝑇 = temperature of system (K)

Calculate the gas constant R (SI Unit) for the following case :
𝑃 𝑉 𝑚 𝑇
1 bar 0,582 m3 560 gram 77 oC

3. The pressure drop for flow through a circular pipe may be calculated from the
darcy formula :
𝐾𝑓𝐿𝜌𝑣̇
∆𝑝 =
2𝐷
where :
∆𝑝 = pressure drop
𝑓 = friction factor, dimensionless
𝐿 = length
𝑣̇ = velocity of fluid
𝐷 = diameter
𝜌 = density

What are the unit of the constant, K ?


4. If dibromopentane (DBP) has a spesific gravity of 1,57. What is its density in kg/m3 and
o
API ?

5. Most processes for producing high-energy content gas or gasoline from coal include some
type of gasification step to make hydrogen or synthesis gas. Pressure gasification is
preffered because of its greater yield of methane and higher rate of gasification.

Given that a 50 kg test run of gas averages 10 % H2 ; 40 % CH4 ; 30 % CO and the rest is
CO2. What is the avarage molecular weight of the gas ?
Clue : choose the convenient basis that suits with the gas composition
SOLUTION
1. Convert :
a. 98 ℉ = ℃
5 ∆℃ 5 ∆℃
𝑇 (℃) = (𝑇 (℉) − 32) ( ) = (98 ℉ − 32) ( ) = 36,667 ℃
9 ∆℉ 9 ∆℉
𝐽
b. 20 𝑐𝑎𝑙⁄𝑔 𝐾 = ⁄𝑔𝑚𝑜𝑙 𝐾

𝑐𝑎𝑙 1𝐽 15 𝑔 𝐽
= 20 × × = 1255, 199 ⁄𝑔𝑚𝑜𝑙 𝐾
𝑔𝐾 0,239006 𝑐𝑎𝑙 1 𝑔𝑚𝑜𝑙

2. Calculate R !

105 𝑃𝑎
𝑃 = 1 𝑏𝑎𝑟 × = 105 𝑃𝑎
1 𝑏𝑎𝑟
𝑇 = 77 ℃ + 273 = 350 𝐾
𝑚 560 𝑔
𝑛= = 𝑔 = 20 𝑔𝑚𝑜𝑙
𝑀𝑊 28
𝑔𝑚𝑜𝑙
3
𝑉 = 0,582 m
𝑃𝑉= 𝑛𝑅𝑇
𝑃𝑉 105 𝑃𝑎 × 0,582 𝑚3 𝑚3 𝑃𝑎 𝐽
𝑅= = = 8,314 = 8,314
𝑛𝑇 20 𝑔𝑚𝑜𝑙 × 350 𝐾 𝑔𝑚𝑜𝑙 𝐾 𝑔𝑚𝑜𝑙 𝐾

3. Consistensy of dimension :
𝐾𝑓𝐿𝜌𝑣̇
∆𝑝 =
2𝐷

𝑘𝑔 𝑚
𝐾 (𝑚) ( 3 ) ( 𝑠 )
𝑚
𝑃𝑎 =
𝑚

𝑘𝑔 𝑚
𝑘𝑔 𝐾 (𝑚) ( 3=2 ) ( )
𝑚 𝑠
2
=
𝑚𝑠 𝑚
𝑘𝑔 𝑘𝑔
= 𝐾
𝑚 𝑠2 𝑚2 𝑠
𝑘𝑔 𝑘𝑔 𝑘𝑔 𝑚2 𝑠 𝑚
𝐾= ∶ = × =
𝑚 𝑠 2 𝑚2 𝑠 𝑚 𝑠2 𝑘𝑔 𝑠

𝑓𝐿𝜌 𝑣 2
∆𝑝 =
2𝐷

4. If dibromopentane (DBP) has a spesific gravity of 1,57. What is its density in kg/m3
and oBe ?
𝑔
𝜌𝑎𝑖𝑟 = 1
𝑐𝑚3
𝜌𝐷𝐵𝑃 𝑔 𝑔
𝑠. 𝑔 = 𝑚𝑎𝑘𝑎 𝜌𝐷𝐵𝑃 = 𝑠. 𝑔 × 𝜌𝑎𝑖𝑟 = 1,57 × 1 3
= 1,57
𝜌𝑎𝑖𝑟 𝑐𝑚 𝑐𝑚3

145 145
°𝐵𝑒 = 145 − = 145 − = 52,643
𝑠. 𝑔 𝐷𝐵𝑃 1,57
5. Given that a 50 kg test run of gas averages 10 % H2 ; 40 % CH4 ; 30 % CO and the rest
is CO2. What is the avarage molecular weight of the gas ?
Clue : choose the convenient basis that suits with the gas composition

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