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Construction and Building Materials: Yong Zhou, Jie Gao, Zhihui Sun, Wenjun Qu
Construction and Building Materials: Yong Zhou, Jie Gao, Zhihui Sun, Wenjun Qu
Construction and Building Materials: Yong Zhou, Jie Gao, Zhihui Sun, Wenjun Qu
h i g h l i g h t s
a r t i c l e i n f o a b s t r a c t
Article history: This study investigates the influence of volume content of aggregates, maximum size and type of coarse
Received 25 April 2015 aggregates, water-to-cement ratio and curing temperature on mechanical properties, i.e. prismatic
Received in revised form 6 July 2015 compressive strength (fc), static modulus of elasticity (Ec) and dynamic modulus of elasticity (Ed) of
Accepted 12 August 2015
concrete at early age. A new equation is proposed to correlate prismatic compressive strength and elastic
Available online 24 August 2015
moduli of concrete. Based on the experimental data and the analysis results, the Ec–Ed relationship is also
proposed. It is found that the relationship between Ec and Ed is linear, and the coefficients of linear
Keywords:
relationship are analyzed by multiple regression analysis, considering aggregate content, maximum size
Early age
Impact resonance test
of the coarse aggregate, water-to-cement ratio and curing temperature. It is found that the volume
Influential factors content of aggregates is the most significant factor that influences the Ec–Ed relationship.
Multiple regression analysis Ó 2015 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.conbuildmat.2015.08.110
0950-0618/Ó 2015 Elsevier Ltd. All rights reserved.
138 Y. Zhou et al. / Construction and Building Materials 98 (2015) 137–145
Table 1
Properties of aggregates.
River sand
Sieve size (mm) 9.50 4.75 2.36 1.18 0.6 0.3 0.15
*
Note: mass retained should be 90% at the sieve size 9.5 mm according to GB/T14685-2011.
Y. Zhou et al. / Construction and Building Materials 98 (2015) 137–145 139
Table 2
Mixture proportions.
Table 3
Regression coefficients of prismatic compressive strength.
Specimens f0 (MPa) A1 A2 t1 t2
SVCA0 25.702 18.521 12.103 19.416 0.881
SVCA0.4 26.662 21.346 20.703 9.981 0.402
SVCA0.65 26.166 17.855 20.929 6.328 0.583
SVCA0.75 25.625 14.676 22.671 5.712 0.746
SMSCA16 26.166 17.855 20.929 6.328 0.583
SMSCA20 25.053 14.241 19.047 6.069 0.941
SMSCA31.5 23.657 12.948 19.550 7.621 0.836
SCL20 25.053 14.241 19.047 6.069 0.941
SG20 23.307 10.075 17.560 10.681 1.787
SWC0.35 47.502 30.716 65.654 14.694 0.368
SWC0.5 26.166 17.855 20.929 6.328 0.583
SWC0.6 23.529 10.972 16.179 17.947 1.937
SCT12.5 33.132 14.743 23.896 9.985 2.689
SCT21 26.166 17.855 20.929 6.328 0.583
SCT33.5 31.513 11.376 23.512 11.178 1.618
where t represents the hydration age (in days), E0, B1, B2, g1 and g2
strength increases rapidly at the age of 12 h to 7 days, while it
are coefficients.
increases slowly at the age of 7–28 days. And the compressive
strength at the age of 7 days was approximately 80% of that at
28 days. All other specimens used in this study showed the same
characteristics. To further study the development of strength
growth, an exponential equation shown as Eq. (3) was proposed
to simulate the development trend.
where t represents the hydration age (in days), f0, A1, A2, t1 and t2
are coefficients from regression.
It is clearly seen that Eq. (3) can depict the development ten-
dency of prismatic compressive strength, and the fitted result of
Adj.R2 is close to 1. For all the tested concrete, the regression coef-
ficients f0, A1, A2, t1 and t2 are listed in the following Table 3.
From both Eq. (3) and the Table 3, it can be seen that the coef-
ficient f0 represents the ultimate strength of the concrete (when
t ? 1, which has a value pretty close to the 28 days strength. By
comparing specimens SVCA0 through SVCA0.75, it can be seen that
changing the volume content of aggregates does not affect the ulti-
mate strength gains of concrete. The f0 values of SMSCA16 through
SMSCA31.5 indicate a decrease of the strength with an increase of Fig. 5. Development of the static and the dynamic modulus for SMSCA20.
Y. Zhou et al. / Construction and Building Materials 98 (2015) 137–145 141
can depict the development tendency of the modulus of elasticity. Code Estimating equation Units
Similar to the compressive strength, the E0 in the equation indicate pffiffiffiffiffi
ACI 318-08 Ec ¼ 4700 f c fc: MPa, Ec: MPa
the ultimate modulus of concrete (when t ? 1; B1 and B2 are two pffiffiffiffiffi
ACI 363-08 Ec ¼ 3300 f c þ 6900 fc: MPa, Ec: MPa
shape factors that control the converge rate of the curve; and g1 pffiffiffiffiffi
NZS 3101-2006 Ec ¼ 3320 f c þ 6900 fc: MPa, Ec: MPa
and g2 are two decay constants. pffiffiffiffiffi
CSA A23.3-04 Ec ¼ 4500 f c fc: MPa, Ec: MPa
The curve fitting results are listed in Tables 4 and 5 for all the EC-2 Ec = 22(fc/10)0.3 fc : MPa, Ec : GPa
coefficients. From the tables, it can be seen that E0 has a value GB 50010 2
Ec ¼ 2:2þ34:7=f
10 fc: MPa, Ec: MPa
c
pretty close to the 28 days modulus of elasticity. To be different
from the compressive strength, the volume content of aggregates
is the most significant influencing factor on the E0 values. B1 and
B2 are also affected by aggregate volume content the most. g1
and g2 are more sensitive to the water-to-cement ratio and the cur-
ing temperature.
Table 4
Regression coefficients of the static modulus of elasticity.
Specimens E0 (GPa) B1 B2 g1 g2
Fig. 6. Comparison of the calculated values and the experimental data of SWC0.5.
SVCA0 12.35 5.57 14.77 10.17 0.56
SVCA0.4 25.11 15.53 68.66 4.64 0.26
SVCA0.65 35.91 12.69 122.14 6.41 0.27
SVCA0.75 38.80 11.47 110.87 4.14 0.34 All other mix proportions have similar characteristics.
Therefore, Ec would be underestimated by using the abovemen-
SMSCA16 35.91 12.69 122.14 6.41 0.27
SMSCA20 37.89 10.00 48.84 14.43 0.69 tioned codes. Previous research found that during its early age,
SMSCA31.5 35.29 10.60 61.09 4.03 0.49 concrete compressive strength is mainly governed by the strength
SCL20 37.89 10.00 48.84 14.43 0.69 of its paste matrix, the flaw size, and the ITZ properties. However,
SG20 32.43 12.32 70.97 5.38 0.39 the elastic modulus of concrete is more influenced by its aggregate
SWC0.35 40.89 9.60 128.32 7.78 0.32 contents and properties [32]. This hints that using one-fit-all equa-
SWC0.5 35.91 12.69 122.14 6.41 0.27 tions to correlate compressive strength and elastic modulus will
SWC0.6 37.92 14.03 48.29 18.74 0.65 not lead to reliable results. Influencing factors, such as aggregate
SCT12.5 38.78 9.66 45.62 17.63 1.16 volume fraction, maximum aggregates size (dominant influence
SCT21 35.91 12.69 122.14 6.41 0.27 on ITZ), water-to-cement ratio, and hydration age, etc. should be
SCT33.5 37.19 10.40 39.98 5.63 0.51
included.
Different from Venkiteela et al. [32], the relationship between
Ed and fc was studied. The equations in Table 6 can be modified
to accommodate the dynamic modulus of elasticity because of
Table 5
the linear relationship between Ec and Ed (in GPa). The equations
Regression coefficients of the dynamic modulus of elasticity.
can be rewritten as follows:
Specimens E0 (GPa) B1 B2 g1 g2
n
SVCA0 13.53 6.11 15.76 7.74 0.56 Ec or Ed ¼ af c þ b ð5Þ
SVCA0.4 28.55 15.51 64.76 4.71 0.30
SVCA0.65 41.93 13.39 99.86 6.37 0.34 where a, b and n are coefficients.
SVCA0.75 45.01 15.04 177.47 3.29 0.26 Fig. 7 shows the result of Eq. (5) and experimental data of
SMSCA16 41.93 13.39 99.86 6.37 0.34 SWC0.5. The regression data are very close to experimental data,
SMSCA20 40.82 10.80 65.68 6.44 0.51 and both R2 values are so close to 1. Coefficient n is nearly 0.295,
SMSCA31.5 40.80 16.42 82.23 2.91 0.36 and is not subjected to the influential factors. Coefficient a governs
SCL20 40.82 10.80 65.68 6.44 0.51 the shape and converging rate of the relationship. As shown in
SG20 39.09 16.40 81.50 4.37 0.35 Table 7, a is more related to the volume content of aggregate
SWC0.35 46.89 9.86 130.75 7.68 0.33 (Vagg) and maximum coarse aggregate size (Magg). Coefficient b is
SWC0.5 41.93 13.39 99.86 6.37 0.34 influenced by the volume content of aggregate, maximum coarse
SWC0.6 41.01 14.35 66.98 9.62 0.48
aggregate size and water-to-cement ratio (w/c). Both this research
SCT12.5 41.94 6.47 48.79 8.91 1.33 and previous research [32] show that curing temperature does not
SCT21 41.93 13.39 99.86 6.37 0.34
affect fc–Ec (or fc–Ed) relationships. The detailed relationships are
SCT33.5 43.93 8.92 43.02 13.94 0.62
expressed as follows:
142 Y. Zhou et al. / Construction and Building Materials 98 (2015) 137–145
Fig. 7. Relationship between Ec or Ed and fc of SWC0.5. Fig. 8. Relationship between Ec and Ed of SMSCA31.5.
Table 7
Coefficients a and b for each specimen. Table 8
Coefficient c and d for the relationship between Ec and Ed.
Specimens Ec (GPa) and fc (MPa) Ed (GPa) and fc (MPa)
Specimens c d
a b n a b n
SVCA0 0.894 0.023
SVCA0 7.00 5.63 0.302 7.87 6.07 0.301
SVCA0.4 0.885 0.089
SVCA0.4 12.89 9.21 0.301 14.72 9.56 0.299
SVCA0.65 0.887 0.134
SVCA0.65 18.51 12.03 0.292 20.02 11.17 0.300
SVCA0.75 0.951 0.401
SVCA0.75 20.27 13.49 0.294 22.66 11.27 0.282
SMSCA16 0.887 0.260
SMSCA16 18.51 12.03 0.292 20.02 11.17 0.300
SMSCA20 0.917 0.211
SMSCA20 18.62 13.40 0.298 20.32 12.34 0.298
SMSCA31.5 0.921 0.238
SMSCA31.5 19.54 14.03 0.299 21.56 13.00 0.296
SCL20 0.917 0.211
SCL20 18.62 13.40 0.298 20.32 12.34 0.298
SG20 0.882 0.229
SG20 18.07 11.51 0.286 20.19 10.16 0.289
SWC0.35 0.951 0.390
SWC0.35 18.25 12.49 0.293 20.03 9.86 0.285
SWC0.5 0.887 0.134
SWC0.5 18.51 12.03 0.292 20.02 11.17 0.300
SWC0.6 0.901 0.230
SWC0.6 18.42 12.04 0.297 20.41 10.76 0.297
SCT12.5 0.914 0.243
SCT12.5 18.16 12.22 0.292 20.19 11.02 0.280
SCT21 0.887 0.134
SCT21 18.51 12.03 0.292 20.02 11.17 0.300
SCT33.5 0.971 0.353
SCT33.5 18.11 12.39 0.298 20.01 10.65 0.286
because the surface of crushed limestone is rougher than that of temperature (e.g. 12.5 °C) both Ec and Ed would approach their ulti-
gravel, so a better adhesion between crushed limestone and mate values much slower than those cured under higher tempera-
cement paste is ensured. However, the aggregate type does not tures. For the specimens cured in 33.5 °C, higher increase rates of Ec
affect the relationship between Ec and Ed. One can notice that the and Ed can be expected during its early age that leads to a quick
two lines in Fig. 11(b) are almost overlapped. This can also be converge to their final values. SCT21 represents the specimens
reflected by the similar values of c and d (for SLG20 and SG20) in cured in normal temperature (21 °C). One should notice that in
Table 8. Table 8, although the values c and d varied a lot, a direct correlation
Fig. 12 shows the influence of water-to-cement ratio on Ec, Ed, between temperature and c, d values cannot be found. This again
and Ec–Ed relationship. From Fig. 12(a), it can be seen that for a indicates that aggregate is the dominant phase that affect the Ec–
given age, both Ec and Ed decrease with the increase of the Ed relationship, as temperature mainly influence the hydration of
water-to-cement ratio within the studied range. A lower water- the cement paste.
to-cement ratio will lead to a stronger paste matrix, which According to the above analysis, the linear coefficients c and d in
enhances the elastic moduli of concrete. As shown in Fig. 12(b) Eq. (8) are influenced by volume content of aggregate and the max-
and Table 8, the values c and d are not influenced by the water- imum aggregate size. Multiple regression analysis was applied to
to-cement ratio. This hints that the aggregates are the dominant establish the relationship between the linear coefficients c and d
phase that governs the Ec–Ed relationship. and the above influential factors. They are listed as follows:
The temperature influences on Ec, Ed, and Ec–Ed relationship are
given in Fig. 13. In Fig. 13(a), it shows that for a lower curing c ¼ 0:048V agg þ 0:0005Magg þ 0:8755 ð9Þ
144 Y. Zhou et al. / Construction and Building Materials 98 (2015) 137–145
d ¼ 0:855V 3agg 0:023 ð10Þ [4] American Concrete Institute, ACI 318-08 Building Code for Structural Concrete,
Detroit, USA, 2008.
[5] American Concrete Institute, ACI 363R-08 State of the Art Report on High
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[9] Code For Design of Concrete Structures (GB 50010-2010), State Development
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