HAFIZ SHABBIR POST GRADUATE COLLEGE SKG

Paper: Chemistry (7,9,10,11,01) Class: 2nd Year T. Time: 01:30 Mints

Name: ________________ Date: 08-04-2020 T. Marks: 50
Q No.1:- Choose the correct options of the following. 10
1. Select the pair of amphoteric oxides.
(a) MgO, CaO (b) NO, PO3 (c) BeO,ZnO (d) SO3, SiO2
2. Which of the following ion has greater hydration energy.
(a) Ca+2 (b) Mg+2 (c) Al+3 (d) I-
3. Select mercapto group.
(a) SCN- (b) SH- (c) OH- d) NH2-
4. Who many isomers are shown by Butane.
(a) 2 (b) 3 (c) 1 (d) 4
5. In benzene each carbon is hybridized.
(a) sp (b) sp3 (c) sp2 (d) dsp2
6. Which of the following compound oxidation yields benzoic acid.
(a) benzene (b) phenol (c) analine (d) toluene
7. Order of SN2 mechanism is.
(a) 1 (b) 2 (c) 3 (d) 0
8. Tertiary alkyl halides follow.
(a) E1 (b) E2 (c) both (d) none
9. Primary alcohols shows Lucas test.
(a) immediately (b) 5-10 mint (c) on heating (d) none
10. Which compound is more soluble in water.
(a) ethyl alcohol (b) phenol (c) acetone (d)n-Hexanol
Q No.2:- Write the short answers. 13 x 2 = 26
1. How ether are prepared by Williamson synthesis.
2. How Bakelite is prepared.
3. How will you distinguish between methanol and ethanol?
4. Write reaction of Grignard reagent with followings.
a) Acetone b) formaldehyde c) carbon dioxide
5. Discuss Wurtz synthesis.
6. Discuss mechanism of Acylation.
7. What is vapour density method?
8. Write mechanism of nitration of benzene.
9. Write condition for Wurtz-fittig reaction.
10. Define Tautomerism and cis-trans isomerism.
11. Why second electron affinity does is positive.
12. How do you prove that ZnO is amphoteric?
13. Justify that diamond is nonconductor while graphite is conductor.
Long Questions:
1.(a). Discuss in detail classification of organic compounds. (4)
(b). What is Friedel-Crafts Alkylation. Write its mechanism. (3)
2. (a). Discuss in detail SN2 mechanism. (4)
(b). Write mechanisms of nitration, sulphonation and halogenation of phenol. (3)