A simple view on hard and soft

Materials Chemistry

wikipedia.org

acids

bases

61

HSAB in figures
Materials Chemistry

free electron level

LUMO

energy

HOMO

62
E. Riedel, Moderne Anorganische Chemie (de Gruyter).
 Solid Acids and Bases after Lux/Flood
Materials Chemistry

63
J. Huheey, E. Keiter, R. Keiter, Anorganische Chemie, 4. Aufl.

Solid Acids and Bases after Lux/Flood

Materials Chemistry

64
J. Huheey, E. Keiter, R. Keiter, Anorganische Chemie, 3. Aufl.
 Tetracyanoplatinate(II)
Materials Chemistry

D. M. Washecheck et al., 66
Inorg. Chem. 1976, 15, 74.

Tetrahydridoplatinate(II)
Materials Chemistry

J. Huheey, E. Keiter, R. Keiter, 67

Anorganische Chemie 3. Aufl.
 Tetrahydridoplatinate(II)
Materials Chemistry

68
R. Hoffmann, Angew. Chem. 1987, 99, 871-906.

Tetrahydridoplatinate(II)
Materials Chemistry

EF

EF (ox)

69
R. Hoffmann, Angew. Chem. 1987, 99, 871-906.
 Synthetic Approaches
Materials Chemistry

400°C
3 B2O3 + 2 LiBF4 Li2B6O9F2 + 2 BF3

solid state reaction

S. Jantz, H. A. Höppe et al. 70

Chem. Eur. J. 2017, in press.

Synthetic Approaches
Materials Chemistry

LiBF4 ∆T LiF + BF3

9 LiBO2 + 3 BF3 350°C 2 Li2B6O9F2 + 5 LiF

reaction via gas phase

S. Jantz, H. A. Höppe et al. 71

Chem. Eur. J. 2017, in press.
 Synthetic Approaches
Materials Chemistry

75°C, 45 min
GdCl3·6H2O + 6 SOCl2 GdCl3 + 6SO2 + 12HCl
reflux

diffusion controlled reaction in a

liquid phase

P. Gross, A. Kirchhain, H. A. Höppe, 72

Angew. Chem. Int. Ed. 2016, 55, 4353.

Crystal Growth
Materials Chemistry

W. Kleber, H. Bautsch, J. Bohm, D. Klimm, Einführung in die Kristallographie, 73

Oldenbourg, 19. Aufl., 2010.
 Crystal Growth
Materials Chemistry

W. Kleber, H. Bautsch, J. Bohm, D. Klimm, Einführung in die Kristallographie, 74

Oldenbourg, 19. Aufl., 2010.

Crystal Growth I
Materials Chemistry

A. R. West, Solid State Chemistry And Its 75

Applications, John Wiley, 1984 . wikipedia.org
 Synthetic Approaches
Materials Chemistry

250°C, 60h
2 GdCl3 + 2 H[B(HSO4)4] Gd2[B2S6O24] + 2H2SO4 + 6HCl

diffusion controlled reaction in a

liquid phase under solvothermal
conditions

P. Gross, A. Kirchhain, H. A. Höppe, 76

Angew. Chem. Int. Ed. 2016, 55, 4353.

Synthetic Approaches
Materials Chemistry

MnCl2 + 2H3BO3 + 2(NH4)2HPO4 + H3PO4 (85%)

drying oven
(180 °C / 8d)

diffusion controlled reaction in a wash (H2O) & dry

liquid phase under solvothermal
conditions

(NH4)2Mn[B2P3O11(OH)2]Cl

K. Förg, H. A. Höppe, 77
Z. Anorg. Allg. Chem. 2015, 641, 1009.
 Synthetic Approaches
Materials Chemistry

1050°C
Ga(CH3)3 + NH3 GaN + 3 CH4

reaction via gas phase

S. Nakamura, Y. Harada, M. Seno, 78

Appl. Phys. Lett. 1991, 58, 2021.

Materials Chemistry

79
07.11.2017 19:38
Materials Chemistry

81

Acid and Base Strengths

Materials Chemistry

M. Binnewies, M. Jäckel, H. Willner, G. Rayner-Canham, 82

Allgemeine und AnorganischenChemie , 2. Aufl.
 Aqueous Solutions
Materials Chemistry

M. Binnewies, M. Jäckel, H. Willner, G. Rayner-Canham, 83

Allgemeine und AnorganischenChemie , 2. Aufl.

Solubility Products
Materials Chemistry

M. Binnewies, M. Jäckel, H. Willner, G. Rayner-Canham, 84

Allgemeine und AnorganischenChemie , 2. Aufl.
 Crystal Systems
Materials Chemistry

85
U. Müller, Inorganic Structural Chemistry, Wiley, 2nd ed.

Point Group Symmetry

Materials Chemistry

86
U. Müller, Inorganic Structural Chemistry, Wiley, 2nd ed.
 Point Group Symmetry
Materials Chemistry

87
U. Müller, Inorganic Structural Chemistry, Wiley, 2nd ed.

Point Group Symmetry

Materials Chemistry

source: James Madison University 88

http://csma31.csm.jmu.edu
 Crystal Classes
Materials Chemistry

89
B. E. Douglas, S.-M. Ho, Structure and Chemistry of Crystalline Solids, Springer 2006 .