Assignment of Applied Chemistry

Assignment Topic: Chemical Reactions of Polymers with Aromatic and

Pendant Group

Submitted To: Sir.Dr. Riaz Hussain shb

Submitted By: Syeda Tooba Fatima

(MS/M.Phil Chemistry)

Roll No. F20-MS CHEM-1027

Semester 1st Morning

UNIVERSITY OF OKARA, OKARA

Chemical Reactions of Polymers with Aromatic and Pendant
Group:
A group attached to the polymer backbone and present in the repeating unit is called a pendant
group.

Examples of pendant groups are the methyl group in polypropylene and the benzene ring in
polystyrene.

CH3 * H2C C *
* H2C C * H
H

Chemical reactions:

1) Poly(tetrahydrofuran):
After studying fragrant polyamides, completely fragrant polyamides or aramides for the
last 8 years, we explain the latest technology here. These polymers belong to the family
of high performance materials due to their high thermal and mechanical properties.
Commercially, they have turned into fibers and produce highly sophisticated composites,
paper and cut and fire retardant clothing. Much research has been done on the use of
these functions in modern applications related to transport applications, optical dynamics,
electronics, smart materials and even better mechanical and thermal conductive materials.

COOR

O O
NH O C N C OR
n
m
LiMDS

COOR
O
n
 2) Polymers with Pendant Chloromethyl Groups Using 1,8-Diazabicyclo-
[ 5.4.0]-7 –undecene:
The reaction is carried out with PCMS (5mmol) and Benzoc Use DBU (5 mmol) in acid
(5 mmol) solvents at 60 ° C for 1 hour measured 0.5 gdl-1 in DMF for 30 ° C .

H2 H
* C C * H
* H2C C *
DBU
COOH

CH2Cl
CH2OCO

The reaction is in polymers (5 mmol) and benzoquine Use DBU (5mmol) in DMF (1Oml) at 60
° C acid (5 mm) for 24 hours. Analysis of chlorine shows that DMF contains 0.5 GDL1 The
reaction continued at 30 ° C for 1 to 60 C.

H2 H H2 H
* C C * * C C *
O
DBU
COOH O
CH2
in DMF CH2
CH2 CH2OCO
Cl
3) Synthesis of Aromatic Polyesters Bearing Pendant Clickable Maleimide
Group:
Side chain melamine group containing phenol, ie. N-triamido-3,3-bis (4-hydroxyphenyl)
isobenzopyrrolidone (PPH-MA) is synthesized from phenolphthalein. Dirt A pendulum
with a melamine group consists of polyester PPH-MA and aromatic chlorine dioxide (i.e.,
fatluel chloride (IPC)), terphthalolochloride (TPC) and. 50:50 Mole ٪ IPC and TPC low
temperature solution blend Multi-condensation technology. The copolymer is also a
compound High density PPH-MA in different density ratios Phenol A with IPC. Genetic
viscosity and average Fragrance (co) is in the molecular weight of polyester This was
0.52-0.97 dL / g and 20,200-32,800 g / mol, respectively, indicating that a medium to
molecular weight polymer was formed. Spectral analysis of copolymer 13C NMR shows
Random copolymer. (Participants) 10% weight loss temperature. The temperature range
of polyester was found to be 470-448 C, which is a good sign. Thermally stable selected
pendant with polyester perfume. Thellol-melamide group is chemically modified by
melamide. In addition to Michael, it also reacts with two representative tea phenol
compounds. That is, a postmodern polymer was quantified with 4-chlorothyphenol and 1-
adenoma. Besides that, This indicates that the polyester side chain contains melamine
group. It can be used to create invincible crossbows Many ideas are intertwined.
HO
OH

m O n HO OH
N
N

O (m+n)ClOC-Ar-COCl

Et3N/CH2Cl
0-25 c

O O O O
* O
O C C O OCArC *
m n

O
N
N

O
Where ;

Ar= or