SORSOGON STATE COLLEGE

Sorsogon City Campus

Sorsogon City

Name: JHON DAVE SURBANO Year and Section: BSED-SCIENCE 1A

Analytical Chemistry
Lecture Exercise 2
mole-mole
mass-mass

I. Answer the following:

1.Calculate the number of moles of NaOH that are necessary to produce 7.5 moles of Na2SO4 from
the reaction:
2NaOH + H2SO4 Na2SO4 + 2H2O
Given: 7.5 moles of Na2SO4
2𝑚𝑜𝑙 𝑁𝑎𝑂𝐻
Mole ratio: 1𝑚𝑜𝑙 𝑁𝑎2𝑆𝑂4
Required: mole of NaOH
𝟐𝒎𝒐𝒍 𝑵𝒂𝑶𝑯
7.5mol NaSO4 x 𝟏𝒎𝒐𝒍 𝑵𝒂𝟐𝑺𝑶𝟒= 15moles NaOH
𝟏𝒎𝒐𝒍 𝑵𝒂𝟐𝑺𝑶𝟒
15moles NaOH x 𝟐𝒎𝒐𝒍 𝑵𝒂𝑶𝑯
= 7.5 moles

2. Calculate the number of grams of magnesium chloride that could be obtained from 8.50g of
Hydrochloric acid when the latter is reacted with an excess of magnesium oxide.
MgO + 2HCl H2O + MgCl2
Given:
Mass of HCI: 850g
Molar mass of HCI: 36.45x2=72.9 g/mol
Molar mass of MgCI: 95.2g
𝟐𝒎𝒐𝒍 𝐇𝐂𝐈
8.50g HCI x 𝒈 = 0.233 mol HCI
𝟕𝟐.𝟗 𝑯𝑪𝑰
𝒎𝒐𝒍
𝟏𝒎𝒐𝒍 𝐌𝐠𝐂𝐈
0.233 mol HCI x = 0.1165mol MgCI
𝟐𝒎𝒐𝒍 𝑯𝑪𝑰
𝟗𝟓.𝟐 𝒎𝒐𝒍 𝐌𝐠𝐂𝐈
0.1165mol MgCI x 𝟏 𝒎𝒐𝒍 𝑴𝒈𝑪𝑰 = 11.09g MGCI

3. Ammonium nitrate decomposes to dinitrogen monoxide and water according to the following
equation:
NH4NO3 N2O +2H2O
In certain experiment, 45.7g ammonium nitrate is decomposed. Find the mass of each of the product
formed.
Given:
Mole ratio: 1 mole of NH4NO3
1 mole of N2O
2 moles of H2O
Molar mass of N2O: 44.02g
Molar mass of H2O: 18.02g
Molar mass of NH4NO3: 80.06g

Required: mass of N2O and mass of H2O

g NH4NO3 mol NH4NO3 mol N2O g N2O

g NH4NO3 mol NH4NO3 mol H2O g H2O

For mass of N2O

𝟏𝒎𝒐𝒍 𝐍𝐇𝟒𝐍𝐎𝟑
47.7g NH4NO3 x 𝟖𝟎.𝟎𝟔𝒈 𝐍𝐇𝟒𝐍𝐎𝟑= 0.5708 mol
𝟏𝒎𝒐𝒍 𝐍𝟐𝐎
0.5708 mol NH4NO3 x 𝟏𝒎𝒐𝒍 𝐍𝐇𝟒𝐍𝐎𝟑= 0.5708 mol N2O
𝟒𝟒.𝟎𝟐𝒈 𝑵𝟐𝑶
0.5708 mol N2O x 𝟏𝒎𝒐𝒍 𝑵𝟐𝑶
= 25. 12g N2O
For mass of H2O
𝟏𝒎𝒐𝒍 𝐍𝐇𝟒𝐍𝐎𝟑
45.7g NH4NO3 x 𝟖𝟎.𝟎𝟔𝒈 𝑵𝑯𝟒𝑵𝑶𝟑= 0.5708 mol
𝟏𝒎𝒐𝒍 𝐇𝟐𝐎
0.5708 NH4NO3 x 𝟏𝒎𝒐𝒍 𝑵𝑯𝟒𝑵𝑶𝟑= 0.5708 mol H2O

𝟏𝟖.𝟎𝟐𝒎𝒐𝒍 𝐇𝟐𝐎
0.5708 mol H2O x 𝟏𝒎𝒐𝒍 𝑯𝟐𝑶
=10.285816g x 2 = 20.5g H2O

4. Tin metal reacts with hydrogen fluoride to produce tin(II) fluoride and hydrogen gas according to
the following balanced equation:

Sn +2HF SnF2 +H2

How many moles of hydrogen fluoride are required to react completely with 75.0g of tin?
Given: 75.0g Sn
Mole ratio of Sn: 118.6g moles of SO2= 3 moles of O2
Molar mass: 32.00g/mol
Required: mass of oxygen Flouride
𝟏𝒎𝒐𝒍 𝐒𝐧
75.0g Sn x 𝟏𝟏𝟖.𝟔𝟗𝒈 𝑺𝒏= 0.631mol Sn
𝟐𝒎𝒐𝒍 𝑯𝑭
0.631mol Sn x 𝟏𝒎𝒐𝒍 𝑺𝒏 = 1.262 mol HF

5. Hydrogen sulfide gas burns in oxygen to produce sulfur dioxide and water vapor.

2H2S + 3O2 2SO2 +2H2O

What mass of oxygen gas is consumed in a reaction that produces 4.60 mol SO2?
Given: 460 mol SO2
Mole ratio: 2 moles of SO2= 3 moles of O2
Molar mass: 32.00g/mol
Required: mass of oxygen

𝟑𝒎𝒐𝒍 𝐎𝟐 𝟑𝟐.𝟎𝟎𝒈𝒎𝒐𝒍 𝐎𝟐
460mol SO2 x 𝟐𝒎𝒐𝒍 𝐒𝐎𝟐 x 𝟏𝒎𝒐𝒍 𝐎𝟐
= 221g 𝐎𝟐