Clariant SDS Sanodure Fiery Red ML Canada English

SAFETY DATA SHEET
Sanodure Fiery Red ML Page 1
Substance key: KS8715 Revision Date: 02/27/2019

Version : 4 - 1 / CDN Date of printing :11/03/2020
SECTION 1. IDENTIFICATION
Identification of the Colorants Solutions Deutschland GmbH

company: Brüningstraße 50
Frankfurt am Main, 65929
Telephone No.: +49 69 305 18000
Information of the substance/preparation:

Product Stewardship, +1-704-331-7710
e-mail: SDS.NORAM@clariant.com
Emergency tel. number: +1 800-424-9300 CHEMTREC, +1 (703)
527-3887 INTERNATIONAL
Trade name: Sanodure Fiery Red ML

Material number: 102263
Synonyms: Aluminum Fiery Red ML
Chemical family: azo dyestuff/chromium complex
Primary product use: Colouring agents, dyes
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the Hazardous Products Regulations

Combustible dust
GHS label elements

Signal word : Warning
Hazard statements : May form combustible dust concentrations in air.
Precautionary statements :
Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P243 Take precautionary measures against static discharge.
P233 Keep container tightly closed.
Additional Labelling
The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity:
2.7067 %
Other hazards
No hazards to be specially mentioned.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

SAFETY DATA SHEET

Substance / Mixture : Mixture
Components
Chemical name CAS-No. Concentration (% w/w)
Sodium sulphate 7757-82-6 10 - 30
Formic acid 64-18-6 1-5
2-Methylpentane-2,4-diol 107-41-5 1-5
Sodium hydroxide 1310-73-2 1-5
Chromium triacetate 1066-30-4 1-5
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
SECTION 4. FIRST AID MEASURES
General advice : Get medical advice/ attention if you feel unwell.
If inhaled : Move the victim to fresh air.

Give oxygen or artificial respiration if needed.
Get immediate medical advice/ attention.
Never give anything by mouth to an unconscious person.
In case of skin contact : Remove contaminated clothing and wash affected areas with
soap and plenty of water for at least 15 minutes. If redness or
skin irritation occurs, seek medical attention.
In case of eye contact : Hold eyelids apart and flush eyes with plenty of water for at
least 15 minutes. Get medical attention.
If swallowed : If swallowed, DO NOT induce vomiting.

Get immediate medical advice/ attention.
Most important symptoms : The possible symptoms known are those derived from the
and effects, both acute and labelling (see section 2).
delayed No additional symptoms are known.
Notes to physician : Treat symptomatically.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : all
Unsuitable extinguishing : No restrictions

media
Specific hazards during : Carbon oxides

firefighting
Chromium oxides
SAFETY DATA SHEET

Nitrogen oxides (NOx)
Sulphur oxides
Avoid generating dust; fine dust dispersed in air in sufficient

concentrations, and in the presence of an ignition source is a
potential dust explosion hazard.
Routine housekeeping should be instituted to ensure that
dusts do not accumulate on surfaces.
Further information : Cool container and metallic parts with a water spray jet
Special protective equipment : Self-contained breathing apparatus

for firefighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Wear suitable protective equipment.

protective equipment and Wear prescribed protective equipment. Sweep up or shovel
emergency procedures into disposal containers using non-sparking tools. Eliminate
ignition sources. Wet down with non-reactive liquid if required
to limit dusting. If melted, allow to solidify first. Clean up spill
location. Must not be released into sewers, drains or wells.
Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.
Methods and materials for : Take up mechanically

containment and cleaning up Treat recovered material as described in the section "Disposal
considerations".
SECTION 7. HANDLING AND STORAGE
Advice on protection against : Take precautionary measures against static discharges.

fire and explosion Keep away from heat and sources of ignition.
Dust can form an explosive mixture in air.
Advice on safe handling : not required under normal use

Avoid dust formation.
Further information on : Keep containers tightly closed in a cool, well-ventilated place.

storage conditions
Keep containers tightly closed in a cool, well-ventilated place.

Handle and open container with care.
SAFETY DATA SHEET

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
Formic acid 64-18-6 TWA 5 ppm CA AB OEL
9.4 mg/m3
STEL 10 ppm CA AB OEL
19 mg/m3
TWA 5 ppm CA BC OEL
STEL 10 ppm CA BC OEL
STEV 10 ppm CA QC OEL
19 mg/m3
TWAEV 5 ppm CA QC OEL
9.4 mg/m3
TWA 5 ppm ACGIH
STEL 10 ppm ACGIH
2-Methylpentane-2,4-diol 107-41-5 (c) 25 ppm CA AB OEL
121 mg/m3
C 25 ppm CA BC OEL
C 25 ppm CA QC OEL
121 mg/m3
TWA 25 ppm ACGIH
(Vapour)
STEL 50 ppm ACGIH
(Vapour)
STEL 10 mg/m3 ACGIH
(Inhalable
fraction,
Aerosol only)
Sodium hydroxide 1310-73-2 (c) 2 mg/m3 CA AB OEL
C 2 mg/m3 CA BC OEL
C 2 mg/m3 CA QC OEL
C 2 mg/m3 ACGIH
Chromium triacetate 1066-30-4 TWA 0.5 mg/m3 CA AB OEL
(chromium)
TWA (Total) 0.5 mg/m3 CA BC OEL
(chromium)
Engineering measures : Handle only in a place equipped with local exhaust (or other
appropriate exhaust).
Personal protective equipment

Respiratory protection : Respirator with a dust filter
Hand protection
Remarks : Rubber or plastic gloves
Eye protection : Safety glasses with side-shields

SAFETY DATA SHEET

Skin and body protection : Avoid skin contact.

Wear suitable protective clothing.
Protective measures : Wear suitable protective equipment.
Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it
before reuse.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Granules
Colour : red
Odour : not specified
Odour Threshold : not required
pH : approx. 4 (20 °C)

Concentration: 5 g/l
Melting point : Decomposition: no

Not applicable
Boiling point : Decomposition: no

Not applicable
Flash point : Not applicable
Evaporation rate : Not applicable
Flammability (solid, gas) : no reaction up to 360 °C

Method: Sandoz Ignition test of deposited dust.
Remarks: Ignition test of deposited dust
Self-ignition : no data available
Upper explosion limit / upper : not determined

flammability limit
Lower explosion limit / Lower : not determined

flammability limit
Vapour pressure : Not applicable
Relative vapour density : not determined
Relative density : no data available
Density : not determined

SAFETY DATA SHEET

Bulk density : approx. 800 kg/m3
Solubility(ies)
Water solubility : approx. 100 g/l soluble (20 °C)
Partition coefficient: n- : not determined

octanol/water
Auto-ignition temperature : not determined
Decomposition temperature : 200 °C

Heating rate: 0.75 K/min
open cup
190 °C
Heating rate: 0 K/min
open cup
Viscosity
Viscosity, dynamic : Not applicable
Viscosity, kinematic : Not applicable
Oxidizing properties : no data available
Molecular weight : no data available
Minimum ignition energy : > 1 J (1,013 hPa)

Method: modified Hartmann tube
Particle size : not determined
SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable
Possibility of hazardous : When used and handled as intended, none.

reactions
Conditions to avoid : None known.
Incompatible materials : not known
Hazardous decomposition : No decomposition if stored and applied as directed.

products
SAFETY DATA SHEET

SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure

Eye contact
Skin contact
Inhalation
Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat, male): > 5,000 mg/kg
Acute inhalation toxicity : Acute toxicity estimate: > 10 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Acute dermal toxicity : LD50 (Rat, male): > 5,000 mg/kg
Components:
Sodium sulphate:
Acute oral toxicity : LD50 (Rat, female): > 2,000 mg/kg
Method: OECD Test Guideline 423
GLP: yes
Acute inhalation toxicity : LC50 (Rat, male and female): > 2.4 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
GLP: yes
Assessment: The substance/mixture is not toxic on inhalation
as defined by dangerous goods regulations.
Acute dermal toxicity : Remarks: Not applicable
Acute toxicity (other routes of : LD50 (Rat): 3,000 - 4,100 mg/kg

administration) Application Route: Intraperitoneal injection
Method: Other
GLP: no
Formic acid:
Acute oral toxicity : LD50 (Rat, male and female): 730 mg/kg
GLP: No information available.
Acute inhalation toxicity : LC50 (Rat, male and female): 7.85 mg/l
Exposure time: 4 h
GLP: no
Acute dermal toxicity : LD50 (Rat, male and female): > 2,000 mg/kg
SAFETY DATA SHEET


GLP: yes
Remarks: By analogy with a product of similar composition
2-Methylpentane-2,4-diol:
Acute oral toxicity : LD0 (Rat, male and female): >= 2,000 mg/kg
GLP: yes
Acute inhalation toxicity : LC0 (Rat, male): saturated vapor

Exposure time: 8 h
GLP: no
Acute dermal toxicity : LD0 (Rat, male and female): >= 2,000 mg/kg
GLP: yes
Sodium hydroxide:
Acute oral toxicity : Remarks: Not relevant
Acute inhalation toxicity : Remarks: Not relevant
Acute dermal toxicity : Remarks: Not relevant
Skin corrosion/irritation
Product:
Species: Rabbit
Result: No skin irritation
Components:
Sodium sulphate:
Species: Rabbit
Exposure time: 4 h
Result: No skin irritation
GLP: yes
Formic acid:
Remarks: not required
Extremely corrosive and destructive to tissue.
Species: Rabbit
Exposure time: 4 h
Result: Mild skin irritation
SAFETY DATA SHEET

GLP: yes
Sodium hydroxide:
Species: In Vitro Membrane Barrier Test Method for Skin Corrosion - CORROSITEX
Result: Causes severe burns.
GLP: no data available
Serious eye damage/eye irritation

Product:
Species: Rabbit
Result: No eye irritation
Components:
Sodium sulphate:
Species: Rabbit
Result: No eye irritation
Exposure time: 24 h
GLP: yes
Formic acid:
Remarks: not required
Extremely corrosive and destructive to tissue.
Species: rabbit eye
Result: Mild eye irritation
GLP: yes
Sodium hydroxide:
Species: Rabbit
Result: Risk of serious damage to eyes.
GLP: no
Respiratory or skin sensitisation

Product:
Remarks: no data available
Components:
Sodium sulphate:
Test Type: Maximisation Test
SAFETY DATA SHEET

Exposure routes: Dermal

Species: Guinea pig
Result: Not a skin sensitizer.
GLP: yes
Formic acid:
Test Type: Buehler Test
Species: Guinea pig
GLP: yes
Test Type: Guinea pig maximization test
Exposure routes: Skin contact
Species: Guinea pig
Result: Does not cause skin sensitisation.
GLP: yes
Sodium hydroxide:
Test Type: Patch Test 24 Hrs.
Species: Humans
Method: Other
GLP: no
Germ cell mutagenicity

Product:
Genotoxicity in vitro : Remarks: no data available
Germ cell mutagenicity - : No information available.

Assessment
Components:
Sodium sulphate:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Concentration: 312,5 - 5000 µg/plate
Metabolic activation: with and without metabolic activation
Method: Ames test
Result: negative
GLP: yes
Test Type: Mammalian cell gene mutation assay

SAFETY DATA SHEET

Test system: mouse lymphoma cells

Concentration: 44,4 - 1420 µg/ml
Result: negative
GLP: yes
Test Type: Chromosome aberration test in vitro

Test system: V79 cells (embryonic lung fibroblasts) of the
Chinese hamster
Result: negative
GLP: yes
Germ cell mutagenicity - : In vitro tests did not show mutagenic effects
Assessment
Formic acid:
Genotoxicity in vitro : Test Type: sister chromatid exchange assay
Test system: V79 cells (embryonic lung fibroblasts) of the
Chinese hamster
Result: negative
Test Type: In vitro gene mutation study in mammalian cells

Test system: Chinese hamster ovary cells
Concentration: 25 - 500 µl/ml
Result: negative
GLP: yes
Test Type: sister chromatid exchange assay

Test system: Human lymphocytes
Concentration: 29 - 460 µg/ml
Metabolic activation: without
Result: negative
GLP: yes
Test Type: Chromosome aberration test in vitro

Result: negative
SAFETY DATA SHEET

Test Type: Ames test

Concentration: 10 - 3333 µg/plate
Result: negative
Genotoxicity in vivo : Species: Drosophila melanogaster (vinegar fly) (male)

Application Route: oral (feed)
Exposure time: entire larval stage
Dose: 0,1% as formic acid
Result: negative
GLP: no
Germ cell mutagenicity - : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.
Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro
Result: negative
GLP: yes
Test Type: In vitro gene mutation study in mammalian cells

Test system: mouse lymphoma cells
Concentration: 0,16 - 10 mM
Result: negative
GLP: yes
Test Type: Ames test

Concentration: 31,25 - 4000 µg/plate
Result: negative
GLP: yes
Sodium hydroxide:
Genotoxicity in vitro : Remarks: In vitro tests did not show mutagenic effects
Genotoxicity in vivo : Remarks: Not classified due to data which are conclusive
although insufficient for classification.
SAFETY DATA SHEET

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment
Components:
Sodium sulphate:
Carcinogenicity - : No evidence of carcinogenicity in animal studies.
Assessment
Formic acid:
Carcinogenicity - : Animal testing did not show any carcinogenic effects.
Assessment
Carcinogenicity - : Not classifiable as a human carcinogen.
Assessment
Sodium hydroxide:
Carcinogenicity - : Not applicable
Assessment
Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment
Components:
Sodium sulphate:
Effects on fertility : Test Type: Fertility
Species: Rat, male and female
Strain: wistar
Application Route: oral (gavage)
Dose: 100 - 300 - 1000 mg/kg
General Toxicity - Parent: NOEL: 1,000 mg/kg body weight
General Toxicity F1: NOEL: 1,000 mg/kg body weight
GLP: yes
Effects on foetal : Test Type: reproductive and developmental toxicity study

development Species: Mouse, male and female
Strain: Other
SAFETY DATA SHEET


Dose: 2800 mg/kg bw/day
General Toxicity Maternal: NOAEL: 2,800 mg/kg body weight
Developmental Toxicity: NOAEL: 2,800 mg/kg body weight
Method: Other
GLP: no
Reproductive toxicity - : No evidence of adverse effects on sexual function and fertility,

Assessment or on development, based on animal experiments.
Formic acid:
Effects on fertility : Test Type: Two-generation study
Strain: wistar
Dose: 100 - 300 - 1000 mg/kg
General Toxicity - Parent: NOAEL: 1,000 mg/kg body weight
General Toxicity F1: NOAEL: 1,000 mg/kg body weight
GLP: yes
Effects on foetal : Species: Rabbit, female

development Strain: Himalayan
Dose: 100 - 300 - 1000 mg/kg
General Toxicity Maternal: NOAEL: 1,000 mg/kg body weight
Teratogenicity: NOAEL: 1,000 mg/kg body weight
GLP: yes
Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.
Effects on fertility : Species: Rat, male and female
Strain: Sprague-Dawley
Dose: 200 - 500 - 1000 mg/kg
General Toxicity - Parent: NOAEL: >= 1,000 mg/kg body
weight
General Toxicity F1: NOAEL: 500 mg/kg body weight
GLP: yes
Effects on foetal : Species: Rat

development Application Route: oral (gavage)
Dose: 30 - 300 - 1000 mg/kg
General Toxicity Maternal: NOAEL: 300 mg/kg body weight
Teratogenicity: NOAEL: 300 mg/kg body weight
SAFETY DATA SHEET

GLP: yes
Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.
Sodium hydroxide:
Reproductive toxicity - : Not applicable
Assessment
STOT - single exposure

Product:
Components:
Sodium sulphate:
Assessment: The substance or mixture is not classified as specific target organ toxicant, single
exposure.
Formic acid:
exposure.
exposure.
Sodium hydroxide:
exposure.
STOT - repeated exposure

Product:
Components:
Sodium sulphate:
Assessment: The substance or mixture is not classified as specific target organ toxicant,
repeated exposure.
Formic acid:
repeated exposure.
SAFETY DATA SHEET

repeated exposure.
Sodium hydroxide:
repeated exposure.
Repeated dose toxicity

Product:
Remarks: This information is not available.
Components:
Sodium sulphate:
NOEL: 1000 mg/kg
Exposure time: 4 - 7 weeks
Number of exposures: daily
Dose: 100 - 300 - 1000 mg/kg
Group: yes
GLP: yes
Species: Rabbit, male and female

LOAEL: 320 mg/kg
Application Route: Dermal
Exposure time: 91 d
Number of exposures: 65 treatments in 91 days
Dose: 2 ml/kg/day-16 % w/w aq
Group: yes
GLP: no
Formic acid:
NOAEL: 400 mg/kg
LOAEL: 2,000 mg/kg
Exposure time: 52 w
Dose: 50 - 400 - 2000 mg/kg
Group: yes
GLP: yes

NOAEL: 0.122 mg/l
LOAEL: 0.244 mg/l
SAFETY DATA SHEET

Application Route: Inhalation

Exposure time: 13 w
Number of exposures: 6 hours/day; 5 days/week
Dose: 0,015 - 0,244 mg/l
Group: yes
GLP: yes

Remarks: The study is not necessary from a scientific perspective.
NOAEL: 50 mg/kg
Exposure time: 91 d
Dose: 50 - 150 - 450 mg/kg
Group: yes
GLP: yes

Application Route: Skin contact

Sodium hydroxide:
Application Route: Oral
Method: Repeated dose toxicity


Aspiration toxicity
Product:
no data available
Components:
Sodium sulphate:
No aspiration toxicity classification
SAFETY DATA SHEET

Formic acid:
Sodium hydroxide:
Corrosive to the respiratory tract.
Experience with human exposure

Product:
General Information : The possible symptoms known are those derived from the
labelling (see section 2).
Components:
Sodium sulphate:
General Information : Health injuries are not known or expected under normal use.
Sodium hydroxide:
General Information : Respiratory system
Respiratory disorders
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Toxicity to fish : LC0 (Oncorhynchus mykiss (rainbow trout)): 1,000 mg/l
Exposure time: 48 h
Toxicity to daphnia and other :

aquatic invertebrates Remarks: no data available
Toxicity to algae/aquatic :
plants Remarks: no data available
Toxicity to fish (Chronic : Remarks: no data available

toxicity)
Toxicity to microorganisms : IC50 (activated sludge): > 100 mg/l

End point: Bacteria toxicity (respiration inhibition)
Components:
Sodium sulphate:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 7,960 mg/l
SAFETY DATA SHEET

End point: mortality

Exposure time: 96 h
Test Type: static test
Analytical monitoring: yes
Method: EPA
GLP: no
Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 1,766 mg/l
aquatic invertebrates End point: mortality
Exposure time: 48 h
Method: EPA
Toxicity to algae/aquatic : ErC50 (Nitscheria linearis): 1,900 mg/l

plants End point: Growth rate
Exposure time: 5 d
Analytical monitoring: no
Method: Other
GLP: no
Remarks: The details of the toxic effect relate to the nominal
concentration.
Toxicity to fish (Chronic : Remarks: not required

toxicity)
Toxicity to daphnia and other : LOEC (Ceriodaphnia dubia (water flea)): 1,329 mg/l
aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Test Type: semi-static test
Method: Other
EC50 (Ceriodaphnia dubia (water flea)): 1,698 mg/l

End point: Reproduction rate
Test Type: semi-static test
Method: Other
Toxicity to microorganisms : NOEC (activated sludge): 8,000 mg/l

Exposure time: 36 d
Test Type: aquatic
Method: Other
GLP: no
concentration.
Toxicity to soil dwelling : Remarks: Not applicable

organisms
SAFETY DATA SHEET

Plant toxicity : Remarks: The study is not necessary from a scientific

perspective.
Sediment toxicity : LC50 (Hyalella azteca (Scud)): 757 - 4222 mg/l

Solvent: no
Duration: 96 h
Sediment: artificial soil
Basis for effect: mortality
Method: Other
Toxicity to terrestrial : End point: Other

organisms Remarks: Not applicable
Formic acid:
Toxicity to fish : LC50 (Danio rerio (zebra fish)): ca. 95 mg/l
Exposure time: 96 h
Test Type: flow-through test
GLP: yes
The details of the toxic effect relate to the nominal
concentration.
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): ca. 266 mg/l
aquatic invertebrates Exposure time: 48 h
GLP: yes
concentration.
NOEC (Daphnia magna (Water flea)): ca. 131 mg/l

Exposure time: 48 h
GLP: yes
concentration.
Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (green algae)): ca. 905

plants mg/l
End point: Growth rate
SAFETY DATA SHEET

Exposure time: 72 h
GLP: yes
concentration.
NOEC (Pseudokirchneriella subcapitata (green algae)): ca. <

56 mg/l
Exposure time: 72 h
GLP: yes
concentration.

toxicity)
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): >= 100 mg/l
aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 21 d
Test Type: semi-static test
GLP: yes
concentration.
Toxicity to microorganisms : NOEC (activated sludge, domestic): 72 mg/l

End point: Bacteria toxicity (respiration inhibition)
Exposure time: 13 d
Method: Other
GLP: no
concentration.

organisms
Plant toxicity : Remarks: Not applicable
Sediment toxicity : Remarks: Not applicable
Toxicity to terrestrial : Remarks: Not applicable

SAFETY DATA SHEET

organisms
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 8,690 mg/l
Exposure time: 96 h
Test Type: flow-through test
GLP: no
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 5,410 mg/l
aquatic invertebrates Exposure time: 48 h
GLP: no
Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (green algae)): > 429

plants mg/l
Exposure time: 72 h
GLP: yes

toxicity)
Toxicity to daphnia and other : Remarks: not required

aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms : NOEC: ca. 200 mg/l

Exposure time: 10 d
Test Type: aquatic
Method: Other
GLP: no
concentration.

organisms
Plant toxicity : Remarks: Not applicable
Sediment toxicity : Remarks: Not applicable
Toxicity to terrestrial : Remarks: Not applicable

organisms
SAFETY DATA SHEET

Sodium hydroxide:
Toxicity to fish : Remarks: Not classified due to inconclusive data.
Toxicity to daphnia and other : EC50 (Ceriodaphnia spec.): 40,4 mg/l

aquatic invertebrates End point: Immobilization
Exposure time: 48 h
Method: Other
GLP: no
Toxicity to algae/aquatic : Exposure time:

plants Remarks: no data available
Toxicity to fish (Chronic : Remarks: no data available

toxicity)
Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates
(Chronic toxicity)
Persistence and degradability

Product:
Biodegradability : Test Type: aerobic
Concentration: 400 mg TOC/l
Biodegradation: approx. 44 %
Exposure time: 14 d
Components:
Sodium sulphate:
Biodegradability : Remarks: The methods for determining biodegradability are
not applicable to inorganic substances.
Biochemical Oxygen : Remarks: Not applicable

Demand (BOD)
Chemical Oxygen Demand : Remarks: Not applicable

(COD)
BOD/COD : Remarks: Not applicable
Physico-chemical : Remarks: Inorganic product, cannot be eliminated from the

removability water by biological purification processes.
Stability in water : Test Type: abiotic

Method: Other
GLP: no
Remarks: Not applicable
Formic acid:
Biodegradability : aerobic
SAFETY DATA SHEET

Inoculum: Other
Concentration: 100 mg/l
BOD in % of theoretical OD
Result: Readily biodegradable.
Biodegradation: 100 %
Exposure time: 14 d
Method: OECD Test Guideline 301C
GLP: no
Biodegradability : aerobic
Inoculum: activated sludge
Concentration: 2,3 mg ThOD/l
CO2 formation in % of theoretical value
Result: Readily biodegradable.
Biodegradation: 81 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
GLP: yes
Photodegradation : Test Type: air

Rate constant: (1.5+/- 0.4)x10-11cm3mol-1s-1
Method: see user defined free text
GLP: no
Remarks: Decomposes rapidly in contact with light.
Sodium hydroxide:
Biodegradability : Remarks: The methods for determining biodegradability are
not applicable to inorganic substances.
Biochemical Oxygen : Remarks: Not applicable

Demand (BOD)
Bioaccumulative potential
Product:
Bioaccumulation : Remarks: not tested.
Components:
Sodium sulphate:
Bioaccumulation : Species: Other
Partition coefficient: n- : log Pow: -4.38

octanol/water Method: other (calculated)
GLP: no
Formic acid:
Bioaccumulation : Remarks: Not applicable
SAFETY DATA SHEET

Due to the low logPow bioaccumulation is not expected
Bioaccumulation : Remarks: Due to the distribution coefficient n-octanol/water,
accumulation in organisms is not expected.
Mobility in soil
Components:
Sodium sulphate:
Distribution among : adsorption
environmental compartments Medium: water - soil
Formic acid:
Distribution among : adsorption
environmental compartments Medium: water - soil
log Koc: < 1.25
Distribution among : Remarks: Not applicable
environmental compartments
Other adverse effects

Product:
Environmental fate and : Remarks: no data available
pathways
Results of PBT and vPvB : Remarks: no data available

assessment
Additional ecological : no data available

information
Components:
Sodium sulphate:
Environmental fate and : no data available
pathways
Results of PBT and vPvB : Remarks: The substance does not meet the criteria for PBT or
assessment vPvB substance.
Additional ecological : The product, since it is an inorganic, non-reducing type of

information substance, has neither a BOD nor a COD.
Formic acid:
SAFETY DATA SHEET

Environmental fate and : not available

pathways
Results of PBT and vPvB : The substance is not identified as a PBT or as a vPvB
assessment substance.
Additional ecological : Do not allow to enter ground water, waterways or waste water.
information
Environmental fate and : not available
pathways
Results of PBT and vPvB : This substance is not considered to be persistent,

assessment bioaccumulating and toxic (PBT).
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.
Sodium hydroxide:
Results of PBT and vPvB : Remarks: Not applicable
assessment
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
Must be incinerated in a suitable incineration plant holding a

permit delivered by the competent authorities.
Contaminated packaging : This material and its container must be disposed of in a safe
way.
SECTION 14. TRANSPORT INFORMATION
TDG not restricted

IATA not restricted
IMDG not restricted
SECTION 15. REGULATORY INFORMATION
NPRI Components : Formic acid

Chromium triacetate
The components of this product are reported in the following inventories:
DSL : All components of this product are on the Canadian DSL
SAFETY DATA SHEET

SECTION 16. OTHER INFORMATION
Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
CA AB OEL : Canada. Alberta, Occupational Health and Safety Code (table
2: OEL)
CA BC OEL : Canada. British Columbia OEL
CA QC OEL : Québec. Regulation respecting occupational health and
safety, Schedule 1, Part 1: Permissible exposure values for
airborne contaminants
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
ACGIH / C : Ceiling limit
CA AB OEL / TWA : 8-hour Occupational exposure limit
CA AB OEL / STEL : 15-minute occupational exposure limit
CA AB OEL / (c) : ceiling occupational exposure limit
CA BC OEL / TWA : 8-hour time weighted average
CA BC OEL / STEL : short-term exposure limit
CA BC OEL / C : ceiling limit
CA QC OEL / TWAEV : Time-weighted average exposure value
CA QC OEL / STEV : Short-term exposure value
CA QC OEL / C : Ceiling
AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECx - Concentration associated with x% response; ELx - Loading rate associated with x%
response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan);
ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response
Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation
Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International
Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety
and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea
Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 -
Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch -
Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed
(Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican
Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD
- Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety
and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS -
Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of
the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
SAFETY DATA SHEET

Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System
Revision Date : 02/27/2019
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information’s accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application. NO
EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR
SERVICE. Nothing included in this information waives any of Clariant’s General Terms and
Conditions of Sale, which control unless it agrees otherwise in writing. Any existing
intellectual/industrial property rights must be observed. Due to possible changes in our products
and applicable national and international regulations and laws, the status of our products could
change. Material Safety Data Sheets providing safety precautions, that should be observed when
handling or storing Clariant products, are available upon request and are provided in compliance
with applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.
CA / EN

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SAFETY DATA SHEET

Sanodure Fiery Red ML Page 1

Substance key: KS8715 Revision Date: 02/27/2019

Identification of the Colorants Solutions Deutschland GmbH

Information of the substance/preparation:

Trade name: Sanodure Fiery Red ML

Primary product use: Colouring agents, dyes

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the Hazardous Products Regulations

GHS label elements

Hazard statements : May form combustible dust concentrations in air.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Sanodure Fiery Red ML Page 2

Substance key: KS8715 Revision Date: 02/27/2019

Substance / Mixture : Mixture

SECTION 4. FIRST AID MEASURES

General advice : Get medical advice/ attention if you feel unwell.

If inhaled : Move the victim to fresh air.

If swallowed : If swallowed, DO NOT induce vomiting.

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : all

Unsuitable extinguishing : No restrictions

Specific hazards during : Carbon oxides

Sanodure Fiery Red ML Page 3

Substance key: KS8715 Revision Date: 02/27/2019

Nitrogen oxides (NOx)

Avoid generating dust; fine dust dispersed in air in sufficient

Special protective equipment : Self-contained breathing apparatus

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective equipment.

Methods and materials for : Take up mechanically

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Take precautionary measures against static discharges.

Advice on safe handling : not required under normal use

Further information on : Keep containers tightly closed in a cool, well-ventilated place.

Keep containers tightly closed in a cool, well-ventilated place.

Sanodure Fiery Red ML Page 4

Substance key: KS8715 Revision Date: 02/27/2019

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Personal protective equipment

Eye protection : Safety glasses with side-shields

Sanodure Fiery Red ML Page 5

Substance key: KS8715 Revision Date: 02/27/2019

Skin and body protection : Avoid skin contact.

Protective measures : Wear suitable protective equipment.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Odour : not specified

Odour Threshold : not required

pH : approx. 4 (20 °C)

Melting point : Decomposition: no

Boiling point : Decomposition: no

Flash point : Not applicable

Evaporation rate : Not applicable

Flammability (solid, gas) : no reaction up to 360 °C

Self-ignition : no data available