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Construction and Building Materials: Hatice Öznur Öz
Construction and Building Materials: Hatice Öznur Öz
h i g h l i g h t s
a r t i c l e i n f o a b s t r a c t
Article history: Using pervious concrete (PC) as a pavement material in low-volume road applications has gained great
Received 10 October 2017 importance since its positive environmental benefits. The paper presented herein addresses the prospec-
Received in revised form 29 January 2018 tive use of acidic pumice aggregate in pervious concrete. At a constant water/cement ratio of 0.30, two
Accepted 1 February 2018
control concretes were produced with only crushed stone aggregates with cement contents of 300 and
Available online 22 February 2018
420 kg/m3, respectively. Thereafter, the acidic pumice were replaced with the crushed stone at 10%,
20%, 30%, 40% and 50%, respectively by total aggregate volume. A total of 12 pervious concretes (PC) were
Keywords:
produced and tested for the compressive, splitting tensile, and flexural strengths as well as the total void
Acidic pumice
Mechanical properties
ratio and permeability at 28 and 90 days. Additionally, the surface abrasion resistances of PCs incorporat-
Permeability ing pumice were tested at 90-day. Test results have revealed that the PCs incorporating pumice had bet-
Pervious concrete ter water permeability and surface abrasion resistance, irrespective of the replacement level. However,
Total void ratio the compressive, splitting tensile and flexural strengths of PCs decreased with increasing the replacement
level of pumice.
Ó 2018 Elsevier Ltd. All rights reserved.
https://doi.org/10.1016/j.conbuildmat.2018.02.010
0950-0618/Ó 2018 Elsevier Ltd. All rights reserved.
602 H.Öznur Öz / Construction and Building Materials 166 (2018) 601–609
appeared to be much more effective on the permeability as well as ever, there is a shortage in the literatures related to the usage of
the porosity of PC. The aggregate gradation of PC characteristically lightweight aggregate (especially acidic pumice) in the production
consists of single-sized coarse aggregates/binary mixture [14]. In of PC.
some studies summarized in Table 1, aggregate with the grain size This study covers an experimental program in which the effects
in the range of 2.36–9.5 mm have been utilized in order to improve of acidic pumice on the mechanical, durability, and permeability
the strength of PC [18–22]. However, the grain sizes of 9.5–19 mm properties of pervious concretes were investigated. For this, a total
were applied to provide sufficient voids [23]. Additionally, K. Cosic of 12 mixtures in two different groups of PC were designed to have
et al. [2] showed that the connected porosity as a main parameter cement dosages of 300 and 420 kg/m3, respectively. The control
for estimating the efficiency of PC were surprisingly influenced mixtures were made with full crushed stone aggregates while
more by the type of aggregate than its size. Furthermore, the the rest of the mixtures were generated by the crushed stone with
higher amount of small aggregate, the higher density of the con- the acidic pumice at 10%, 20%, 30%, 40% and 50% by total aggregate
crete mixtures which inturn provided the greater flexural strength. volume. The pervious concretes with and without acidic pumice
The study of Y. Zaetang et al. [8] indicated that the recycled con- were tested for the porosity, permeability, compressive, flexural
crete block aggregate and the recycled concrete aggregate and splitting tensile strengths at 28 and 90-day. Additionally, the
increased the compressive strengths of PCs except for the high abrasion resistances of PC incorporating pumice were tested at
replacement level of 100%. However, the addition of recycled con- 90-day.
crete aggregate improved the surface abrasion resistance of PC.
Moreover, M. Gesoglu et al. [11] found that the tire rubber utiliza-
2. Experimental study
tion possessed positive effect on the pervious concrete against the
abrasion so that pervious concrete with rubber had the superior
2.1. Materials
abrasion resistance. The cement content, w/c ratio, type of finish,
and curing method seemed to have marked influence on the sur-
An Ordinary Portland cement (CEM I 42,5R) with Blaine fineness
face abrasion more than on the strength [15,24]. In the literature,
of 326 m2/kg and specific gravity of 3.15 was used. Physical and
however, lightweight aggregates such as pumice and diatomite
chemical properties of the cement used in the production of pervi-
have not taken adequate attention as much as natural, crushed,
ous concrete are listed in Table 2. In this study, 10–12 mm sizes
recycle aggregates and waste rubber to be used in the production
crushed limestone and/or acidic pumice were used as the coarse
of PC.
aggregate (Fig. 1). Specific gravity of the crushed stone and the
Pumice which is used as the aggregate and/or the mineral
acidic pumice were 2.65 and 0.99, respectively. The water absorp-
admixture in the production of concrete is identified as a natural
tion of acidic pumice was measured to be 33.2% according to ASTM
pozzolanic material of volcanic origin [25,26]. It has come out
C127 [30]. Slake durability test was also conducted with respect to
because of the gas release during the solidification of lava
ASTM D4644-16 to determine the stability of pumice against frag-
[26–28]. Due to a sudden release of the gases in the structure of
mentation and weakening [31]. The test identified the slake dura-
pumice during its cool down and formation, the connectivity of
bility of acidic pumice as 98.35%.
the pore structure of pumice may range from completely closed
to completely open [27,29]. There are two types of pumice known
2.2. Concrete mixture proportioning and casting
as acidic and basic. While acidic pumice is a lightweight aggregate,
specific gravity of basic pumice is close to that of natural aggregate.
In this study, it was aimed to determine the maximum and min-
Also, basic pumice has higher rough surface when compared to the
imum cement dosage by considering the limitation for compres-
acidic pumice. Acidic pumice, which possesses a porous structure,
sive strength and water permeability coefficient as well as the
provides superior advantages of low weight, high heat and sound
aggregate/cement ratio for PCs. At first, test batches were gener-
insulation, and easy workability [27]. Total pumice reserve found
ated by using the varying amounts of cement dosage and ratio of
in Turkey forms approximately 40% of total pumice reserve located
aggregate/cement until the limiting value were reached in the
in the world (18 billion m3) [28]. However, Italy, Greece, Saudi Ara-
design of PCs incorporating acidic pumice. Then, it was decided
bia, Chile and the other world countries (i.e., USA, Spain, France,
that two groups of pervious concretes with 300 and 420 kg/m3
Equator, New Zealand, Algeria etc.) have approximately 22%, 9%,
cement dosages were designed which consisted of two control
7%, 6% and 17% of the total pumice reserves, respectively. Y. Zae-
and ten acidic pumice mixtures. In this manner, a total of 12 mix-
tang et al. [26] identified that the PC incorporating pumice and
tures were produced at a constant water/cement ratio of 0.30. The
recycled aggregate showed lower mechanical properties associated
control concretes were made of full crushed stone aggregates while
with higher thermal conductivity and water permeability than
the rest of mixtures for given cement content were generated by
those with diatomite aggregate. It can be concluded that the use
replacing the crushed stone with the acidic pumice at 10 to 50%
of materials with high porosity and low specific gravity such as
pumice in the design of PC is vital to provide sufficient drainage
conforming the purpose of PC. To the knowledge of authors, how- Table 2
Chemical compositions and physical properties of Port-
land cement.
2.3.1. Compressive, splitting tensile and flexural strengths 3. Results and discussion
The compressive strength was performed on three cubes of 150
150 150 mm dimensions according to the ASTM C 39 [33]. 3.1. Compressive, splitting tensile, and flexural strengths
Three cylindrical specimens with dimensions of 100 200 mm
were used to measure the splitting tensile strength according to A noticeable negative effect of acidic pumice on the compres-
the ASTM C496 [34]. Moreover, three prisms of 100x100x400 sive strength of PCs can be seen in Fig. 3, irrespective of the cement
mm dimensions were tested under three-point bending according content. The compressive strength of all concretes increased with
to the ASTM C293/C293M-10 to determine the flexural strength the testing age in the line with the literature. The maximum com-
[35]. Test results were reckoned by averaging the results from pressive strength was measured to be 15.21 MPa for the mix
the three samples at each testing age of 28 and 90 days. ‘‘420PCAP0” whereas the lowest one was 3.85 MPa for the mix
604 H.Öznur Öz / Construction and Building Materials 166 (2018) 601–609
2
Compressive Strength (MPa)
18
15
1.5
12
9 1
3 0.5
0% 10% 20% 30% 40% 50% 0% 10% 20% 30% 40% 50%
Volumetric Acidic Pumice Replacement Volumetric Acidic Pumice Replacement
‘‘300PCAP50”. The decrease in strength for compression seemed to for the mixes 300PCAP50 and 420PCAP50 at 28 days, respectively.
be 50.51% and 41.35% at 28 and 90-day, respectively, in the first Similarly, 90-day test results revealed a strength loss of 40.84% and
group of concretes. However, the second group concretes experi- 38.76% for the former and the latter, respectively. The main reason
enced a strength loss of as high as 48.58% and 44.90% at 28 and of this strength loss was attributed to the very porous structure of
90-day, respectively, compared to the control concrete. In general, the pumice by virtue of which they became quite weak as well as
the compressive strength of pervious concretes is related to the to the connectivity of its pore structure ranging from completely
aggregate strength as well as the total porosity. As a natural light- closed to completely open [26]. In addition, when the halved con-
weight aggregate, the acidic pumice is expected to have much cretes were visually inspected, the splitting appeared to occur
lower density and strength that the crushed stone. Therefore, the along the paste and/or through the aggregates rather than interfa-
compressive strength of PC reduced with the use of the acidic cial transition zone (ITZ) due to the strong bond between the
pumice. The compressive strength of PCs ranges from 5 to 30 cement paste and the aggregate particles [1,39,40]. The porosity
MPa or 3.5 to 28 MPa as stated in the literature [6,2] so that all of PCs led to the initiation and propagation of the tensile cracks
of the concretes in this study conformed the compressive strength offering a lower ultimate tensile strength for the hardened
qualification except for the two mixes, namely 300 PCAP40 and composites [41]. Moreover, PCs having a cement content of 420
300PCAP50 mixture. Therefore, the most of mixtures proposed kg/m3 gave better results than those of PCs a 300 kg/m3 of cement
herein can be utilized in the case of pavements that commonly content. As seen in Fig. 4, however, the reduction in splitting
necessitate a restricted concrete compressive strength. As seen in strength of the PCs was governed by the replacement ratio of
Fig. 3, the compressive strength increased with the cement content pumice. In addition, the ratio of the splitting tensile strength to
at both 28 and 90-days. Similarly, Y. Zaetang et al. [26] showed that the compressive strength ranged from 11.70 to 17.92% with the
the compressive strength of PC incorporating acidic pumice can be average of 14.29%. These results were nearly close to that of the
improved with increasing cement content. PC incorporating natural aggregate as ranging from 9 to 14% [42].
As observed in Fig. 4, there is a reduction in splitting tensile Flexural strengths of PCs at 28 and 90 days are shown graphi-
strength of the both group concretes as the acidic pumice had cally in Fig. 5. It was observed that the behavior of PCs in terms
replaced the crushed stone. Splitting tensile strengths of the of flexural strength was similar to that seen in the splitting tensile
300PCAP0 and 420PCAP0 control mixes were found to be 1.1 and strength such that increasing the replacement level of pumice low-
1.5 MPa, respectively, which inturn reduced to 0.69 and 0.86 MPa ered the flexural strength, irrespective of the testing age as well as
H.Öznur Öz / Construction and Building Materials 166 (2018) 601–609 605
300PCAP-28 Days 300PCAP- 90Days to determine the statistical significance of the cement dosage on
420PCAP- 28Days 420PCAP-90 Days the mechanical properties at 28 days. As seen in Table 4, all of
2.5 the calculated t-value by using data obtained in this study is
Flexural Strength (MPa)
greater than that of the t table value 2.13 at a 0.05 level of signif-
icance. Therefore, using different cement dosage had marked
2
effects on the mechanical properties at 28 days.
Table 4
The t-table test results of mechanical properties at 28 days.
Test type Replacement level of Cement dosage (kg/m3) Mean value n SD DF t-value
pumice (%)
Compressive strength (MPa) 0 300 7.78 3 1.40 4 6.41*
420 13.69 3 0.77
10 300 6.71 3 0.77 4 5.39*
420 11.99 3 1.51
20 300 5.89 3 1.58 4 3.55*
420 10.85 3 1.83
30 300 5.08 3 0.57 4 5.54*
420 8.65 3 0.96
40 300 4.11 3 0.72 4 4.41*
420 7.27 3 1.01
50 300 3.85 3 0.69 4 6.71*
420 7.04 3 0.45
Splitting tensile strength (MPa) 0 300 1.10 3 0.05 4 6.73*
420 1.50 3 0.09
10 300 1.01 3 0.04 4 8.13*
420 1.43 3 0.08
20 300 0.93 3 0.13 4 4.16*
420 1.31 3 0.09
30 300 0.88 3 0.17 4 3.24*
420 1.24 3 0.08
40 300 0.83 3 0.11 4 3.85*
420 1.12 3 0.07
50 300 0.69 3 0.05 4 3.42*
420 0.86 3 0.07
Flexural strength (MPa) 0 300 1.72 3 0.22 4 2.98*
420 2.17 3 0.14
10 300 1.68 3 0.25 4 2.48*
420 2.06 3 0.09
20 300 1.63 3 0.15 4 3.87*
420 2.01 3 0.08
30 300 1.49 3 0.11 4 5.728*
420 1.96 3 0.09
40 300 1.34 3 0.06 4 5.23*
420 1.80 3 0.14
50 300 1.21 3 0.12 4 2.99*
420 1.69 3 0.25
(n: number of observed data, SD: standard deviation, DF: degree of freedom).
606 H.Öznur Öz / Construction and Building Materials 166 (2018) 601–609
300PCAP 420PCAP
1900
Bulk Density ( kg/m3)
1800
1700
1600
1500
1400
1300
1200
0% 10% 20% 30% 40% 50%
Volumetric Acidic Pumice Replacement Fig. 8. Relationship between compressive strength and total void ratio of PCAPs.
structure due to the highly porous structure of acidic pumice. Variation in the permeability coefficient (k) of PCs in cm/s is
Therefore, as the acidic pumice had replaced the crushed stone shown in Fig. 9. The use of acidic pumice resulted an increase in
aggregate up to 50%, the total void ratio of PCs increased, irrespec- the permeability coefficient (k) of PCs. For instance, k value of
tive of the cement content. Moreover, increase in the cement con- 300PCAP0 for at 28-day was 0.93 cm/s which increased to 1.05,
tent provided the thicker paste covering the pumice so as to reduce 1.08, 1.14, 1.26, and 1.37 cm/s at the mixes 300PCAP10,
the total void ratio, which inturn enhanced the mechanical proper- 300PCAP20, 300PCAP30, 300PCAP40 and 300PCAP50, respectively.
ties of PCs [26]. As mentioned before, because the porosity range In addition, k value of 420PCAP0 at 28-day was 0.43 cm/s which
for PC varies between 11% and 35% [2], all of the mixtures can be increased to 0.49, 0.54, 0.63, 0.72 and 0.77 cm/s in the mixes
used assumed pavement material as meeting the limited total void 420PCAP10, 420PCAP20, 420PCAP30, 420PCAP40 and 420PCAP50,
ratio (Fig. 7). respectively. This positive effect of acidic pumice on the permeabil-
The relationship between the compressive strength and total ity is attributed to its porous structure and quite round shape via
void ratio of PCAPs is plotted in Fig. 8. The empirical equation relat- the accelerating water passes [26]. However, the lower density of
ing compressive strength (r) to the total void ratio (Vr) is PCs with lower cement dosage resulted in a greater amount of pore
explained as: space available for water to pass through. This would also have
contributed to the lower compressive strength [48]. In other
words, the water permeability coefficient of PCs with higher
r ¼ 79:96e0:1035Vr ; R2 ¼ 0:92 ð3Þ cement content were clearly lower than those of low cement
dosage due to fact that the connected pores reduced with the
increased cement content [26]. Since the water permeability range
where r is the compressive strength (MPa), Vr is the total void ratio for PCs varies between 0.2 and 1.2 cm/s [2] in the literature, all of
(%) and R2 is the correlation of the results. the mixtures, but 300PCAP40 and 300PCAP50 (28-day), may be
As shown in Fig. 8, the relatively strong relation between the used in paving applications such as walkways, parking areas and
compressive strength and total void ratio of PCAPs were parallel tennis courts. The permeability values of PCs at 90-day for both
to a porous brittle material and normal pervious concrete as groups decreased with respect to the permeability values of PCs
reported by Y. Zaetang et al. [26], P. Chindaprasirt et al. [45,46], at 28-day due to the hydration process of PCs.
and E. Ryshkewitch [47].
30
25
Total Void Ratio (%)
20
15
10
0
0% 10% 20% 30% 40% 50%
1.5
0.9
0.6
0.3
0
0% 10% 20% 30% 40% 50%
Volumetric Acidic Pumice Replacement
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