Professional Documents
Culture Documents
AITS-2021-OPEN TEST-JEEA-PAPER-2-Sol
AITS-2021-OPEN TEST-JEEA-PAPER-2-Sol
AITS-2021-OPEN TEST-JEEA-PAPER-2-Sol
OPEN TEST
JEE (Advanced)-2021
PAPER –2
TEST DATE: 24-01-2021
SECTION – A
1. A, B, C
F dv
Sol. .
A dy
2. B, C
Sol. mg FB 6rv
gr 2
v
9
1
mgH FBH +Wf = mv 2 0
2
3. A, C, D
3v
Sol. f P
4
3v 3 330
4f 4 550 x=0 x=
9
m 45cm
20
The amplitude of pressure variation in the pipe is
a | P0 sinkx |
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 2
3
a P0 sin x
2
at x = /2
3 P0
a P0 sin
4 2
The maximum pressure at the middle of the pipe
P
P0 0
2
The maximum pressure at the closed end of the pipe = P0 P0
4. A, B
dV 2
Sol.
VdT T
dv dT
2
V T
V kT 2
i.e. PV1/ 2 constant
R
C = CV + C CV 2R
1
1
2
5. B, C, D
4m m
Sol. T 2 4
g K
2 A g
g gT 2 4mg
A
2
4 2 K
4mg
Equilibrium compression X0
K
6. B, C, D
hc
Sol. eV0
1240
1.5 eV
400
V0 1.6volt
1240
For B, V0 2 1.1 volt
400
Energy is equally distributed through out spectrum but for B, th 620 nm for photo electric
effect in metal B range of spectrum is 400 nm to 620 nm.
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
3 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
SECTION – B
7. 3
Sol. =i+e–A
30 = 60 + e 30 30
e = 0 ray is perpendicular on the second surface of
prism, so that r=30 60
o
30
sin60
3
sin30
8. 6
Sol. Angular velocity about centre of mass is same.
So that Where rA rB d
v A rA m r m r A A B B
v B rB d
1 rA
mB v B2 7
k e B
2 6d
k e A 1 rB
mA v 2A 7
2
2
6d
2 MS 7
6
12 MS d 2
7
9. 5
2BA
Sol. eav =
t t
eav t
B
2A
20 103 0.2
= 5
2 4 10 4
10. 9
Sol. F - N = ma B
1 N
80 - 6g = ma ma
3 1
Ma =60 C
A 0
mg
F
ma cos mg sin 0
2 2
tan =1 N A
=45
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 4
11. 5
Sol. The equation of process A B is dT
Sign scheme for
2P dV
P 0 V 5P0
V0 +ve ve
2P0 2 5P0 V0 5 2V0
T V V V0
nRV0 nR 4
dT 4P0 5P0
V
dV nRV0 nR
pdV Sign scheme for C
Now, C CV
ndT +ve ve +ve
3R 5P V 2P0 V
C R 0 0 V0 5 2V0
2 5P0 V0 4P0 V V0 25V0
4
R 25V0 16V 16
C
2 5V0 4V
Hence the heat is absorbed by the gas
25
from V0 to V0
16
Hence the process changes from
endothermic to exothermic at the
25V0
volume
16
12. 4
Sol. Q = Q0 cos t
i = Q0 sin t
Q0 Q0 1
= .sin 8L0 r
n 0Lr L.8 0 r L.8 r 4
0
Q0 1
=
L.80r 2
n=4
SECTION – C
13. 00006.25
Sol. Vsep = e Vapp V2
V1 – V2 = e(V1 +V2)
V1
4
V0 1 e V2 1 e V0
5
V0 1 e 5 37
6.25
V2 1 e 4
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
5 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
14. 00014.14
Sol. ax = 0
a = g sin 30
y
v u at
x
v 5iˆ (5ˆj)1
5iˆ 5ˆj m / s
v2 52 52
R 14.14m
an
5/ 2 y 30
15. 00001.73
Sol. induced emf × P
e Bv × × ×
PQ 2 10 5 2 2
10 3 × × × ×
B
e = 1.73 volt × C
V
× ×
× x × ×
× × ×
16. 00003.25
Sol. When it is at 45 from horizontal N
m2 2
mg cos 45 m N
4 12 16
45
12g
7 2
24g
Conservation of energy gives : 2 mg
7 2
N mgsin 45 m 2
4
4mg
mg cos 45 N = m N
4 7 2
By solving 3.25
17. 00002.50
Sol. COM V1
4 2.5 = 4 VC + 4 V1
Vc + V1 = 2.5
COAM VC
1 1 1
4 2.5 = 4 V1 + [2 2 ( )2]
2 2 2
2.5 = V1 +
2
Vsep = e Vapp
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 6
1 1
VC + V1 2.5
2 2
2.5
VC V1
2 2
2.5 2.5
By solving equation, 2.5 rad / s, VC m / s, V1 m/s
2 2
Loss of energy = K e i K e f 3.12 J
18. 00038.46
Sol. V = 2.5 60 = 150 volt
I IR2 IL2 15.25
V 150
Z 38.46
I 15.25
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
7 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
Chemistry PART – II
SECTION – A
19. A, B, C
Sol. (A) K 2 Zn ClBr CNNO2 has four constitutional isomers and each one is chiral.
(B) 2+ has one chiral centre and hence it exists as a pair of enantiomer.
Me
N N
Pt
H
N N
3
(C) Co ox F 2 Cl2 it has three geometrical isomers and one of them is chiral. So, total
stereoisomers are 4.
(D) K 3 FeF6 is a colourless complex
20. B, D
Sol. (A) Increasing order of stability of conformers of cyclohexane is
chair > twist boat > boat > half-chair
(B) Gauche conformer of 2-fluoroethanol is more stable due to intramolecular hydrogen
bonding than its anti conformer.
(C) OH O OH NH2 CH O
NaOBr OH
CH C NH2 CH N C O
Hoffmann Bromamide
Major
(D) During ozonolysis, cross-ozonides are also formed.
21. B, C, D
Sol. (A)
H3C CHO
H3C CH3
CH3 CHO
Major product
(B) O O
O CH3
C CuLi
2
dil. OH
Retro aldol
O H
Major product
(C) O O O
2
CO
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 8
(D) Br
Br Br
C
Br
N N N
H H
Mg / Ether
N
HO O N
MgBr
Conc. H2 SO4
Major product
22. A, B, C, D
Sol. (A) H3PO4 PO34 H2PO4 HPO24
Initial m. mol 10 10 0 0
m.mol. after neutralization 0 0 10 10
So, pH pK a 8 Buffer
2
(B) H3PO4 H PO
2
4 PO 3
4
10 10 10
0 0 30
pK a pK a38
So, pH 1
5.5
2
2 2
(D) pH will remain same as in option (B).
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
9 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
23. A, C, D
Sol. Formula of ideal solid ‘x’ = AB3
Tf i k f m
0.60 1000
0.2976 1.6 1.86
m x 100
mx 60 g / mole
a o
rA 3 rB a 2A
2
60 1
Density (d) 12.5 g / cm3
6 10 8 1024
23
0.60
Total number of unit cells = Total number of molecules of AB3 6 1023 6 1021
60
If there are 12% cation vacancies it means formula of defected solid would be A 0.88B3.00
36
So, %A 4 ions 100 40.9%
88
24. A, C
Sol. Gas is undergoing free expansion, so, process is irreversible adiabatic as well as isothermal.
V
Ssyst nRn 2
V1
2.73Vi
nRn
Vi
= nR
PV
Ssyst i i
Ti
SECTION – B
25. 0
Sol. Species Geometry Hybridization d-orbitals involved
I. VO acac 2 Square pyramidal dsp3 dx2 y 2
II. Fe CO 5 Trigonal bi-pyramidal dsp3 dz2
III. PtCl4 Square planar dx2 y 2
2
dsp2
IV. K 4 Fe CN6 Octahedral d2 sp3 d x 2 y 2 , dz 2
V. IF7 Pentagonal bi- sp3 d3 dx2 y2 , dz2 and dxy
pyramidal
So, x = 3, y = 4 and z = 1
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 10
26. 8
Sol. OAc
H O
OAc OAc
H
OAc O
OAc H
O
H H
OAc H H OAc
H H
H OAc
27. 5
Sol. RH2 Ca2
RCa 2H
3 10 4 M
3
So, Ca 2 10 4 M
2
3
So, mass of CaCO3 present in 1 L hard water 10 4 100 1.5 10 2 g
2
1.5 102
So, degree of hardness of water 106 10 g
1500
So, degree of hardness = 10 ppm.
So, 2x = 10 and x = 5.
28. 5
Sol. Only, reaction II, IV, V, VI, VII will give tert-butyl benzene as the major product.
29. 6
Sol. Only KNO3 , Ag2 O, KClO3 , HgO, NaNO3 and H2O2 will decompose on heating to give O2 as the
only gaseous product.
30. 9
Sol. O
C2H5 CH3
H5C6 S N ; C H NH ; C H CH ; C H CH C C H;
6 5 2 6 5 3 6 5
O C2H5
C 6 H5
; C6H5 NO2 are insoluble in aq. NaOH and rest are soluble.
OH
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
11 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
SECTION – C
31. 00001.48
11a
Sol. The 4th nearest distance in CsCl structure d1
2
5a
and the 5th nearest distance in NaCl structure d2
2
d1 11
2.2 1.48
d2 5
32. 00004.60
Sol.
Mg NH4 PO4 2 3
Mg NH4 PO 4
K sp Mg2 NH24 PO34 … (1)
Now,
H3PO4 H2O
H2PO4 H3 O ;
pK a1 2.2
H2PO4 H2O 2
HPO4 H3 O ; pK a2 7.2
and HPO24 H2O 3
PO4 H3 O ; pK a3 12.4
from the above data, it is very much clear that at pH = 10, the main component is HPO24 .
Let, the solubility of Mg NH4 PO4 be ‘S’ mol dm-3, then
S Mg2 HPO42 … (2)
PO34 H3 O K a3 HPO 24
K a3 3
or PO 4 … (3)
HPO24 H3 O
So, from Eq. (1), (2) and (3), we get
S
K sp NH4 S K a
3 H3 O
1/2
NH4 K a S 2 K sp H3 O
S
K sp 3
H3 O NH4 K a
3
1
So, p S pK sp pH log10 NH4 pK a
2 3
1
p S 12.6 10 1 12.4
2
p(S) = 4.60
33. 00001.33
Sol. In solid truncated cube, each vertex becomes a triangular face and each square face becomes an
octagonal face.
34. 00004.50
Sol. y = 0, x = 9
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 12
35. 00007.00
Sol.
O
||
H3O conc. H SO
CH2 C CH2 CH C CH3
2 4
X
Y
36. 00006.75
Sol. Wt. of pay load 80 103 g
nRT
80 103 0 100 x 1.25 x
P
x 26.8 27
So, minimum number of balloon required is 27.
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
13 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
SECTION – A
37. A, B, C, D
Sol. 1, 2, 3, ..... n are in H.P.
2 1 1
So, for k = 2, 3, ....., n – 1
k k 1 k 1
38. B, C, D
Sol. bn 1 an bn c n
cn 1 bn1
an 1 bn cn
bn1 an1 an
an1 2 an an1
r 2 2r 2 0
2 48
r 1 3
2
n n
an A 1 3 B 1 3 put a1 = 1, a2 = 2
1 1
A and B
2 3 2 3
39. A, C
Sol. (x2 – 3x)2 + x2 – 3x + a = 0
40. A, B, C
n n
Sol. A f i f r f r f j f r
2
ij
2
A ij A2 = (tr(A))A
r 1 r 1
41. A, B
Sol. 12 OI12 R2 2r1R
42. A, B, C, D
7
C1 6! 4 7
Sol. (A) C4 2 7 C7
3! 3! 2!
SECTION – B
43. 5
Sol. The equation of circle will be (x – 1)(x – 8) + y2 + y = 0 will touch y = x
= 17, 1 as ordinate of P is positive so = 1
x2 + y2 – 9x + y + 8 = 0
81 1 50 5
r 8
4 4 2 2
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 14
44. 0
x
t10 1
Sol. Let h x t
0
10 2
t 1
dt x 2 x
x10 1 x2
h x 10 2
2x 1 =
2x 0
x x 1 x x2 1 10
h(x) decreases in (0, ), h(0) = 0 so no positive real root of the equation
45. 2
1 /2
Sol. Put x = sin , then 0
f x dx f sin cos d
0
..... (1)
1 /2
Put x = cos ,
0
f x dx f cos sin d
0
..... (2)
1 /2 1
Adding equation (1) and (2), we get 2 f x dx
0
0
1 dx , f x dx 4
0
46. 3
1 1
Sol.
0
f x dx f 1 f 0 1 = 1 x
0
2 1/ 4 1 x 2 1/ 4 f x dx (C.S. inequality)
1 1
1 2 1 2
1 x 2
1/2
dx
1 x 2 1/2 f x 2 dx
0 0
1
1
1 x
0
2 1/2 f x 2 dx
ln 1 2
47. 0
1
1 1 x
tan1 x tan 3
1
Sol. tan
3
2 3
1
6 6 x 6
tan1 x
6 3
2 3
1
6 x
1 tan1 x2
2 3
32 2 32 2 32 2
1 1
1
x 22
dx
1
f x dx
1
2
x 1
dx
3 2 2
1 x
tan1 f 3 2 3 tan1 3 2 2
2 2 1 4
48. 1
14
r
Sol. sin 15 4 214 sin 4 15
r 0
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
15 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
SECTION – C
49. 00000.25
Sol. N is mid-point of OH
N
H
50. 00125.00
Sol. a3 cos 3B + 3a2b cos(A – 2B) + 3ab2 cos(2A – B) + b3 cos(2A) = Real part of (ae–iB + beiA)3
a b
= ((a cos B + b cos A) + i(a sin B – b sin A))3 = c 3 .
sin A sinB
51. 00007.20
Sol. G(4, 3.2) G(4, 4)
Tangents of A and B will intersect at corresponding directrix. So A
E and F lies on directrix x = 4. ES is perpendicular to AB where E(4, 2)
P
S is focal chord, also FSG is also S
2 F(4, –2)
B
52. 00017.00
Sol. z 2i 4 1 i z2 z1
2k /4
i
z 2i 2 e
1/4 4
2i
Put k = 0, 1, 2, 3
4 1 1 17
2
Minimum value of z zi = 4 2 8 2 8 28 z3 z1
i1
53. 00000.50
2 4 6 8
1 1 1 1 1
Sol. PA 2 4 8 .....
2
2
2
2 2
54. 00005.00
k k2
n 2
3 1
1 5
Sol. lim
n
k 1
n
k k
n
2
=
2
x x 2 dx =
12
1 2 3 1
0
n n
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com