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Transformer Oil - Wikipedia
Transformer Oil - Wikipedia
Polychlorinated biphenyls
(PCBs)
Polychlorinated biphenyls (PCBs) were
formerly used as transformer oil, since
they have high dielectric strength and are
not flammable. Unfortunately, they are
also toxic, bioaccumulative, not at all
biodegradable, and difficult to dispose of
safely. When burned, they form even more
toxic products, such as chlorinated dioxins
and chlorinated dibenzofurans. Beginning
in the 1970s, production and new uses of
PCBs were banned in many countries, due
to concerns about the accumulation of
PCBs and toxicity of their byproducts. For
instance, in the USA, production of PCBs
was banned in 1979 under the Toxic
Substances Control Act.[8] In many
countries significant programs are in place
to reclaim and safely destroy PCB
contaminated equipment. One method
that can be used to reclaim PCB
contaminated transformer oil is the
application of a PCB removal system, also
called a PCB dechlorination system. PCB
removal systems use an alkali dispersion
to strip the chlorine atoms from the other
molecules in a chemical reaction. This
forms PCB-free transformer oil and a PCB-
free sludge. The two can then be
separated via a centrifuge. The sludge can
be disposed as regular non-PCB industrial
waste. The treated transformer oil is fully
restored, meeting the required standards,
without any detectable PCB content. It
can, thus, be used as the insulating fluid in
transformers again.[9]
PCBs and mineral oil are miscible in all
proportions, and sometimes the same
equipment (drums, pumps, hoses, and so
on) was used for either type of liquid, so
PCB contamination of transformer oil
continues to be a concern. For instance,
under present regulations, concentrations
of PCBs exceeding 5 parts per million can
cause an oil to be classified as hazardous
waste in California.[10]
On-site testing
This section does not cite any sources.
Learn more
See also
Heat-transfer oil
References
1. Gill, Paul (2009). Electrical power
equipment maintenance and testing (2nd
ed.). Boca Raton: CRC Press. p. 193.
ISBN 978-1-57444-656-2.
2. Hirschler, Marcelo M. (2000). Electrical
insulating materials : international issues
(Online ed.). West Conshohocken, Pa.:
ASTM. pp. 82–95. ISBN 978-0-8031-2613-8.
3. Kenneth R. Edwards, Transformers,
American Technical Publishers Ltd., 1996
ISBN 0-8269-1603-1 pp.138-14
4. "Fluids Comparison" . Midel.
5. "What's Your Transformer Got In The
Tank?" (PDF). M&I Materials.
6. "Siemens has produced the world's first
large-scale transformer that uses vegetable
oil" .
7. "Coconut Oil As An Alternative To
Transformer Oil" (PDF). ERU Symposium.
November 2001.
8. Blackmore, Carolyn. "Classification and
Handling of PCB Waste" (PDF). Lawrence
Berkeley National Laboratory. Retrieved
20 October 2017.
9. "PCB Dechlorination System" . Hering-
VPT GmbH. Retrieved 20 October 2017.
10. California Code of Regulations, Title 22,
section 66261
11. "Transformer Oil Detoriation - Why is
transformer oil purification essential?" .
Less and nonflammable liquid-insulated
transformers, approval standard class
Number 3990, Factory Mutual Research
Corporation, 1997.
McShane C.P. (2001) Relative properties of
the new combustion-resistant vegetable oil-
based dielectric coolants for distribution and
power transformers. IEEE Trans. on Industry
Applications, Vol.37, No.4, July/August 2001,
pp. 1132–1139, No. 0093-9994/01, 2001
IEEE.
"The Environmental technology verification
program", U.S. Environmental Protection
Agency, Washington, DC, VS-R-02-02, June
2002. [1]
IEEE Guide for loading mineral-oil-immersed
transformers, IEEE Standard C57.91-1995,
1996.
External links
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