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Hydrogen: Experiment No. 1
Hydrogen: Experiment No. 1
1:00-4:00 W
Experiment No. 1
HYDROGEN
S E A
A. DISCOVERY
In the early 1500s the alchemist Paracelsus noted that the bubbles given off when
iron filings were added to sulfuric acid were flammable. In 1671 Robert Boyle made
the same observation. Neither followed up their discovery of hydrogen, and so
Henry Cavendish gets the credit. In 1766 he collected the bubbles and showed
that they were different from other gases. He later showed that when hydrogen
burns it forms water, thereby ending the belief that water was an element. The
gas was given its name hydro-gen, meaning water-former, by Antoine Lavoisier.
However it was only much later that it was recognized as an element by Henry
Cavendish (1731-1810; an English chemist and physicist who also independently
discovered nitrogen) in 1766 when he collected it over mercury and described it as
"inflammable air from metals". Cavendish described accurately hydrogen's
properties but thought erroneously that the gas originated from the metal rather
than from the acid. Hydrogen was named by Lavoisier. Sometime prior to the
autumn of 1803, the Englishman John Dalton was able to explain the results of
some of his studies by assuming that matter is composed of atoms and that all
samples of any given compound consist of the same combination of these atoms.
Dalton also noted that in series of compounds, the ratios of the masses of the
second element that combine with a given weight of the first element can be
reduced to small whole numbers (the law of multiple proportions). This was further
evidence for atoms. Dalton's theory of atoms was published by Thomas Thomson in
the 3rd edition of his System of Chemistry in 1807 and in a paper about strontium
oxalates published in the Philosophical Transactions. Dalton published these ideas
himself in the following year in the New System of Chemical Philosophy. In 1839 a
British scientist Sir William Robert Grove carried out experiments on electrolysis.
He used electricity to split water into hydrogen and oxygen. He then argued one
should be able to reverse the electrolysis and so generate electricity from the
reaction of oxygen with hydrogen. He enclosed platinum strips in separate sealed
bottles, one containing hydrogen and one oxygen. When the containers were
immersed in dilute sulphuric acid a current indeed flowed between the two
electrodes and water was formed in the gas bottles. He linked several of these
devices in series to increase the voltage produced in a gas battery. Later the term
fuel cell was used by the chemists Ludwig Mond and Charles Langer. In 1932 Dr
Francis Thomas Bacon, an engineer at Cambridge University in the UK, worked
further on designs of Mond and Langer. He replaced the platinum electrodes with
less expensive nickel gauze and substituted the sulphuric acid electrolyte for
alkaline potassium hydroxide (less corrosive to the electrodes). This was in essence
the first alkaline fuel cell (AFC) and was called the Bacon Cell. It took Bacon
another 27 years to demonstrate a machine capable of producing 5 kW of power,
enough to power a welding machine. At about the same time the first fuel cell
powered vehicle was demonstrated. Much later fuel cells were by NASA in the
1960s for the Apollo space missions. Fuel cells have been used for more than 100
missions in NASA spacecraft. Fuel cells are also used in submarines. The lifting
agent for the ill fated Hindenberg balloon was hydrogen rather than the safer
helium. The image below is the scene probably in a way you have not seen it before.
This is a "ray-traced" image reproduced with the permission of Johannes Ewers,
the artist, who won first place with this image in the March/April 1999 Internet
Raytracing Competition. For details of ray-tracing you can't beat the POV-Ray site.
B. PROPERTIES
A colourless, odourless gas. It has the lowest density of all gases. On Earth,
hydrogen is found in the greatest quantities as water. It is present as a gas in the
atmosphere only in tiny amounts – less than 1 part per million by volume. Any
hydrogen that does enter the atmosphere quickly escapes the Earth’s gravity into
outer space.
Common oxidation states 1, -1
Natural
Atomic Mode of
Isotopes
Atomic Isotope abundance Half life
mass decay
radius, Covalent radius (%)
1.10 0.32
non-bonded 1 (Å)
H 1.008 99.9885 - -
(Å)
2
H 2.014 0.0115 - -
Electron
3
HElectronegativity
3.016 - 12.31 y β-
affinity 72.769 2.20
(Pauling scale)
(kJ mol−1)
1st
1312.05
2nd
-
3rd
-
4th
Ionization
-
energies
5th
(kJ mol−1)
-
6th
-
7th
-
8th
-
Physical Properties of Hydrogen
Hydrogen is the smallest chemical element because it consists of only one proton in
its nucleus. Its symbol is H, and its atomic number is 1. It has an average atomic
weight of 1.0079 amu, making it the lightest element. Hydrogen is the most
abundant chemical substance in the universe, especially in stars and gas giant
planets. However, monoatomic hydrogen is rare on Earth is rare due to its
propensity to form covalent bonds with most elements. At
standard temperature and pressure, hydrogen is a nontoxic, nonmetallic, odorless,
tasteless, colorless, and highly combustible diatomic gas with the molecular
formula H2. Hydrogen is also prevalent on Earth in the form of chemical compounds
such as hydrocarbons and water.
Hydrogen has one one proton and one electron; the most common isotope, protium
(1H), has no neutrons. Hydrogen has a melting point of -259.14 °C and
a boiling point of -252.87 °C. Hydrogen has a density of 0.08988 g/L, making it less
dense than air. It has two distinct oxidation states, (+1, -1), which make it able to
act as both an oxidizing and a reducing agent. Its covalent radius is 31.5 pm.
Hydrogen exists in two different spin isomers of hydrogen diatomic molecules that
differ by the relative spin of their nuclei. The orthohydrogen form has parallel
spins; the parahydrogen form has antiparallel spins. At standard temperature and
pressure, hydrogen gas consists of 75 percent orthohydrogen and 25 percent
parahydrogen. Hydrogen is available in different forms, such as compressed
gaseous hydrogen, liquid hydrogen, and slush hydrogen (composed of liquid
and solid), as well as solid and metallic forms.
Chemical properties
Hydrogen burns in air or oxygen to produce water:
Stars use hydrogen as a fuel with which to produce energy. Antares—the brightest
star in the constellation Scorpius—is shown here.
Stars use hydrogen as a fuel with which to produce energy. Antares—the brightest
star in the constellation Scorpius—is shown here.
It also combines readily with other non-metals, such as sulfur, phosphorus, and the
halogens. The halogens are the elements that make up Group 17 (VIIA) of the
periodic table. They include fluorine, chlorine, bromine, iodine, and astatine. As an
example:
BIBLIOGRAPHY
OXYGEN
A. DISCOVERY
S E A
Oxygen had been produced by several chemists prior to its discovery in 1774, but
they failed to recognize it as a distinct element. Joseph Priestley and Carl Wilhelm
Scheele both independently discovered oxygen, but Priestly is usually given credit
for the discovery. They were both able to produce oxygen by heating mercuric
oxide (HgO). Priestley called the gas produced in his experiments 'dephlogisticated
air' and Scheele called his 'fire air'. The name oxygen was created by Antoine
Lavoisier who incorrectly believed that oxygen was necessary to form all acids.
Oxygen is the third most abundant element in the universe and makes up nearly
21% of the earth's atmosphere. Oxygen accounts for nearly half of the mass of
the earth's crust, two thirds of the mass of the human body and nine tenths of
the mass of water. Large amounts of oxygen can be extracted from liquefied air
through a process known as fractional distillation. Oxygen can also be produced
through the electrolysis of water or by heating potassium chlorate (KClO 3).
Oxygen is a highly reactive element and is capable of combining with most other
elements. It is required by most living organisms and for most forms of
combustion. Impurities in molten pig iron are burned away with streams of high
pressure oxygen to produce steel. Oxygen can also be combined with acetylene
(C2H2) to produce an extremely hot flame used for welding. Liquid oxygen, when
combined with liquid hydrogen, makes an excellent rocket fuel. Ozone (O 3) forms a
thin, protective layer around the earth that shields the surface from the sun's
ultraviolet radiation. Oxygen is also a component of hundreds of thousands of
organic compounds. Oxygen first appeared in the Earth’s atmosphere around 2
billion years ago, accumulating from the photosynthesis of blue-green algae.
Photosynthesis uses energy from the sun to split water into oxygen and hydrogen.
The oxygen passes into the atmosphere and the hydrogen joins with carbon dioxide
to produce biomass. When living things need energy they take in oxygen for
respiration. The oxygen returns to the atmosphere in the form of carbon dioxide.
Oxygen gas is fairly soluble in water, which makes aerobic life in rivers, lakes and
oceans possible. Oxygen was discovered in 1774 by Joseph Priestley in England and
two years earlier, but unpublished, by Carl W. Scheele in Sweden. Priestley later
noted the new gas’s biological role. He placed a mouse in a jar of oxygen, expecting
it would survive for 15 minutes maximum before it suffocated. Instead, the mouse
survived for a whole hour and was none the worse for it. In 1668 John Mayow
wrote that air contains the gas oxygen [he called it nitroarial spirit], which is
consumed in respiration and burning. Mayow observed that: substances do not burn
in air from which oxygen is absent; animals absorb oxygen into their blood when
they breathe; air breathed out by animals has less oxygen in it than fresh air.
B. PROPERTIES
Gaseous chemical element, symbol: O, atomic number: 8 and atomic weight 15,9994.
It’s of great interest because it’s the essential element in the respiratory
processes of most of the living cells and in combustion processes. It’s the most
abundant element in The Earth’s crust. Nearly one fifth (in volume) of the air is
oxygen. Non-combined gaseous oxygen normally exists in form of diatomic
molecules, O2, but it also exists in triatomic form, O3, named ozone.In normal
conditions oxygen is a colourless, odourless and insipid gas; it condensates in a light
blue liquid. Oxygen is part of a small group of gasses literally paramagnetic, and it’s
the most paramagnetic of all. Liquid oxygen is also slightly paramagnetic. Oxygen is
reactive and will form oxides with all other elements except helium, neon, argon
and krypton. It is moderately soluble in water (30 cm 3 per 1 liter of water dissolve)
at 20 Celsius. Oxygen is a tasteless gas. It has no smell or color. It comprises 22%
of the air. The gas is part of the air people use to breathe. This element is found in
the human body, the Sun, oceans and the atmosphere. Without oxygen, humans will
not be able to survive. It is also part of the stellar life cycle.
Chemical Properties
Oxygen comprises a fifth of air volume, two-thirds of the human body and 87%
water. In its natural form it is all over the atmosphere. Commercial preparation
involves fractional distillation of air and liquefaction and water electrolysis. Of the
group 16 of the periodic table, it is the primary member. Oxygen can be used to
make compounds with all elements minus inert gasses. Oxygen may be dissolved.
This gas supports combustion. However, it does not conduct electricity or heat
well. Oxygen in the air is known as diatomic gas. Ozone O 3 is an allotrope. It is
composed of ultraviolet light or electrical discharge.Oxygen is paramagnetic
whether it is gaseous, liquid or solid. Oxides are generated when oxygen joins with
other elements. It is part of hydroxides and various acids. Oxygen can be cooled
under boiling point. It will turn light blue. This color is retained even when in a solid
state.
Physical Properties
Oxygen exists in all three forms - liquid, solid, and gas. The liquid and solid forms
are a pale blue colour. However, oxygen gas is colourless, odourless, and tasteless.
The elemental structure is a cubic crystal shape. Oxygen changes from a gas to a
liquid at a temperature of 182.96°C, and then can be solidified or frozen at
a temperature of -218.4°C. Oxygen exists in all three allotropic forms. The three
allotropic forms include normal oxygen, diatomic oxygen, or dioxygen; nascent,
atomic, or monatomic oxygen; and ozone or triatomic oxygen. The three allotropes
differ in several ways; such as, atoms and molecules. For example, the oxygen
we're most familiar with in the atmosphere has two atoms in every molecule.
Nascent oxygen only has one atom in every molecule, and the third allotrope
(ozone) has three atoms in every molecule.
Atomic number 8
Atomic mass 15.999 g.mol -1
Electronegativity according to Pauling 3.5
Density 1.429 kg/m3 at 20°C
Melting point -219 °C
Boiling point -183 °C
Vanderwaals radius 0.074 nm
Ionic radius 0.14 nm (-2)
Isotopes 4
Electronic shell [ He ] 2s 2 2p 4
BIBILIOGRAPHY