r FORM TP 2016169 %.

TEST CODE 02212020

MAY/JUNE 2OI6
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CARIBBEAN EXAMINATIONS COUNCIL
CARIBBEAN ADVANCED PROFICIENCY EXAMINATION@

CHEMISTRY

UNIT 2 -Paper 02

2 hours 30 minutes

RBAD THE FOLLOWING INSTRUCTIONS CAREFULLY.

1 This paper consists of SIX questions in TWO sections. Answer ALL questions

2 Write your answers in the spaces provided in this booklet.

J Do NOT write in the margins.

4 Where appropriate, ALL WORKING MUST BE SHOWN in this booklet.

5 A data booklet is provided.

6 You may use a silent, non-programmable calculator to answer questions.

7 If you need to rewrite any answer and there is not enough space to do so on the
original page, you must use the extra lined page(s) provided at the back ofthis booklet.
Remember to draw a line through your original answer.

8. If you extra page(s) you MUST write the question number clearly in the
use the
box provided at the top of the extra page(s) and, where relevant, include the
question part beside the answer.

DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO.

Copyright O 2015 Caribbean Examinations Council

All rights reserved.

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0221202003 I
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MODULE 1 :1I
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THE CHBMISTRY OF CARBON COMPOUNDS .-i
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1. (a) Define the term'structural isomerism'.
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[1 mark] :.-$

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(b) 60 cm3 of oxygen were mixed with l0 cm3 of a gaseous hydrocarbon, X, C*H,. After ,-_t
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exploding and cooling to room temperature, 40 cm3 of gas were left. On shaking with nh
.-.->r
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aqueous sodium hydroxide, l0 cm3 of oxygen remained. (All measurements were made i-5
at the same temperature and pressure.) The combustion of X can be represented by the ;.Ji1
:+
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following equation: :-{i
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'-_r

c,H, * @+ ----------> x cor* ! aro ..-F

+)o, -'--a
.---s
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(i) Calculate the formula of the hydrocarbon, X. lis

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:=
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=
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:-J*
:-lli
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,.:t
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(ii) Hence, write its displayed formula. i-I(
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rA
:-\j
I mark] a
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02212020/CAPE 2016

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0221202004
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There are four alcohols with the molecular formula C4HroO. The formulae
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fortwo ofthem
ate

cH3cHrcH2cH2oH and cH3cHrcHOHCH3

Butan- I -ol Butan-2-ol

(i) Write the name and displayed formula for EACH of the other two alcohols.

Displayed Formula Displayed Formula

Name Name

[2 marks]

(ii) When butan-2-ol is heated with phosphoric acid, a mixture of alkenes is produced.
One of these alkenes exhibits isomerism.

Write the names and displayed formulae of the two isomers of this alkene.

Displayed Formula Displayed Formula

Name: Name

[2 marks]

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02212020/CAPE 2016

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0221202005
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r (d)
-6-

Table 1 shows two pairs of compounds. Complete the table by describing simple laboratory
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tests to distinguish between EACH pair of compounds.

TABLE 1: DISTINGUISHING COMPOUNDS

Compound Test Observation

cH3cH(oH)cH3

cH3cH2cH3oH

[2 marks] [1 markl

cH3cH(oH)cH3

cH3ccH3(oH)cH3

[1 mark] I markl

[5 marks]

Total 15 marks

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02212020/CAPE 2016

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0221202006
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 r MODULE
-7 -

2
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ANALYTICAL METHODS AND SEPARATION TECHNIQUES

,.::
7- 2. (a) Explain the origin of infrared (lR) absorption by compounds.

[3 marks]

(b) State the properties of compounds which absorb IR radiation.

[2 marksl

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022t2020lcAPE 2016

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0221202007
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The IR spectrum of an organic compound, Y, has major absorption peaks in the regions
3350-3500 cm-r and 1680-1 800 cm I respectively. Y has a relative molecular mass of 75
and forms an aqueous solution which is neutral.

(i) Identify the groups responsible for the above absorptions.

[2 marks]

(ii) State the name of Compound Y and draw its displayed formula.

Name
[1 mark]

Displayed Formula

[2 marksl

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022120201cAP8 2016

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(d) Describe the steps taken in the preparation of a solid sample for IR analysis

r+

[4 marksl

(e) State ONE limitation of IR spectroscopy,

[1 markl

Total 15 marks

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022120201CAP8 2016

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0221202009
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r MODULE
-10-

3
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INDUSTRY AND THB ENVIRONMENT

3. (a) Sulfur dioxide and sulfur trioxide are toxic compounds and if allowed to escape during
the Contact Process can cause acid rain. Write an equation to represent the formation of
acid rain by ONE of these compounds.

[2 marksl

(b) Outline TWO ways in which other industrial chemicals lead to water pollution.

[2 marks]

(c) Explain how a named pollutant affects

(i) the quality of water for human consumption

[2 marks]

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022t2020lcAPE 2016

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0221202010
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r (ii) the aquatic environment.
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[2 ma ;k;j

(d) (i) Complete Table 2 by outlining simple laboratory tests that would confirm the
NOr- in a sample of water.
presence of Pb2* and

TABLE 2: CONFIRMATORY TESTS

Ion Test Obseruation

Pb2* a a

(l mark) (1 mark)
Nor- a a

(2 marks) (1 mark)

[5 marks]

(ii) Write the ionic equation to represent the test on Pb2* in Table 2

[2 marks]

Total 15 marks

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022r2020tcAPE 2016

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0221202011 J
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SECTION B

AnswerALL questions.

MODULE 1

THE CHEMISTRY OF CARBON COMPOUNDS

4. The following diagram represents some of the reactions of benzene.

NO, cHs

II
<-III -+

IV Benzene
I
I
cHr

PhenoV OH
Dye

x
Br

(a) State the type of reaction labelled I and IV.

Reaction I

Reaction lV:

[2 marksl

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022120201CAPE 2016

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0221202012
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List the reagents and conditions required for Reactions Il and IV.
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Reaction II

Reagents:

Conditions:

Reaction IV

Reagents: .........

Conditions: ......
[4 marksl
(c) Draw the displayed formula for Compound X

[1 mark]

(d) Outline the mechanism for Reaction I using curved arows to indicate the movement of
electrons, being careful to identify the various steps involved.

[4 marks]
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02212020/CAPE 20t6

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0221202013
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r (e)
-14-

Write the structural formula for the products formed when phenol is treated
with

(i) aqueous bromine

(ii) sodium hydroxide

(iii) ethanoyl chloride.

[3 marksl

(f) Write the equation for the reaction in (e) (iii).

[1 markl

Total 15 marks
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022t2020lcAPE 2016

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0221202014
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r MODULE
- 15 -

2
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ANALYTICAL METHODS AND SEPARATION TECHNIQUES

5. (a) (i) state Raourt's raw for an idear mixture of two liquids

[2 marks]

(ii) List TWO characteristics of an ideal solution.

[2 marks]

(b) A and B are components of a liquid which forms an azeotropic mixture

(i) Define the term 'azeotropic mixture'.

[1 mark]

(ii) State ONE reason why azeotropes are NOT compounds

[1 mark]

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02212020/CAPE 2016

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0221202015
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-16-

The following graph shows the composition of a minimum boiling

point mixture'

B
B.pt
B. pt
,L\=

E
o
a
E!
tr
o
tr

lO0Yo Composition x l00%o

A B

Using the graph, explain clearly the result of distilling a mixture of

Composition X as indicated.

[6 marks]

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022t2020lcAPE 2016

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0221202016
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(c) An aqueous solution contains 2.5 g of a compound in 50 cm3 of solution. The partition
coefficient of the compound between water and an organic solvent is 0.200.

Calculate the mass of the compound extracted by shaking 100 cm3 of aqueous
solution
with 25 cm3 of the solvent.

[3 marksl

Total 15 marks

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022t2020lcAPE 2016

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0221202017
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 -l
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- l8 -

INDUSTRY AND THE ENVIRONMENT

6. (a) (i) Describe the process involved in the production of aluminium from alumina'
(Include appropriate equations.)

[4 marks]

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022t2020lcAPE 2016

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0221202018
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-19-

State the effect of the production of oxygen on the process

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[1 markl
(iii) Write an equation to represent the effect in (a) (ii)

[1 mark]
(b) Suggest THREE factors which would influence the location of a bauxite plant.

[3 marks]

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02212020/CAPE 2016

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0221202019
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(c) (i) Define the term 'recYcling'

[1 mark]

(ii) Describe how aluminum is recycled

[2 marks]

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022t2020lcAPE 2016

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0221202020 I
t- -21 - -l
(d) Suggest THREE ways in which recycled aluminium can be used.

[3 marks]

Total 15 marks

END OF'TEST

IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST.

02212020/CAPE 2016

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0221202021
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r EXTRA SPACE
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If you use this extra page, you MUST write the question number clearly in the box provided.

Question No.

022120201CAP8 2016

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0221202022
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