r FORM TP 2017173

qto TEST CODE 02212032

MAY/JUNE 20I7
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CARIBBEAN EXAMINATIONS COUNCIL
CARIBBEAN ADVANCED PROFICIENCY EXAMINATION@

CHEMISTRY

UNIT2-Paper032
ALTERNATIVE TO SCHOOL.BASED ASSESSMENT

2 hours

READ THE FOLLOWING INSTRUCTIONS CAREFULLY.

I . This paper consists of THREE questions. Answer ALL questions.

2. Write your answers in the spaces provided in this booklet.

3. Do NOT write in the margins.

4. Where appropriate, ALL WORKINC MUST BE SHOWN in this booklet.

5. A data booklet is provided.

6. You may use a silent, non-programmable calculator to answer questions.

7. You are advised to take some time to read through the paper and plan your answers.

8. If you need to rewrite any answer and there is not enough space to do so on the
original page, you must use the extra lined page(s) provided at the back of this
booklet. Remember to draw a line through your original answer.

9. If you write the question number clearly in the

use the extra page(s) you MUST
box provided at the top of the extra page(s) and, where relevant, include the
question part beside the answer.

DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO.

Copyright O 2015 Caribbean Examinations Council

All rights reserved.

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r AnswerALL questions.
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1. (a) You have been provided with samples of three unknown organic compounds labelled A,
B and C.

Carry out the tests indicated in Table l, being careful to add reagents gradually until no
further change is observed and shaking gently after EACH addition.

Your recordings should include details of colour changes and precipitates formed.

TABLE 1: TESTS ON COMPOUNDS A, B AND C

Observation
Test
COMPOUND A COMPOUND B COMPOUND C

Carry out the following tests on

approximately 2 cm3 of EACH
compound.
I :,:iir-i:1j::ij .1. '.
i::;'iir :.'ir ;,-:ii-..1':t:rl ,
:,:;., ..
1.;5U, I,
:ti:::.::.;t:Wr:.,*1 ll
".; ii.r:1,;itillil i

(i) Add KMnOo(aq) followed o a a

by dilute HrSOo(aq) and

warTn.
[1 mark] [1 mark] [1 markl

(ii) Add approximately 2 cm3 of o a a

NaOH(aq) followed by I,
dropwise, until I, is no
longer decolourized. Warm
gently. [1 markl [1 markl [1 markl

(iii) Add a few drops of a o o

2,4-DNPH.

I markl [1 markl I markl

(iv) Add a small quantity of a o

NaHCOT(s).

I markl I markl I markl

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 r (b) (i)
5

Based on your recorded observations in Thble l, draw the strutural formulae

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of
the functional groups present in Compounds A, B and C.

Compound Stuctural Formula of Functional Group

[3 marksl

(ii) State ONE reaction which formed the basis for EACH of your answers in (b) (i).

4..............

[3 marksl

Total 18 marks

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)
-6-

As the first step in the calculation of the concentration of the Mn2* ion in an aqueous solution, a
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student measures the absorbance of a number of solutions of potassium manganate(VII) of varying
concentrations. The results are shown in Table 2.

(a) Complete Table 2 to show the concentration values in mol dm-3

TABLE 2: ABSORBANCE AND CONCENTRATION

OF MAI\IGAI\ATE(VII) SOLUTION

Absorbance Concentration / gdmr Concentration / mol dm{

0.2s 1.58

0.38 2.37

0.48 3.16

0.72 4.74

0.96 6.32

1.08 7.11

1.20 7.90

[4 marks]

(b) On the grid provided on page7, plot a graph of absorbance agai nst concentration of
manganate(VlI) solution in mol dm-3, circling each plotted point 8. [6 marksl

(c) State the name of the type of graph plotted in (b).

[1 markl

(d) Deduce from the graph the

(i) concentration of the solution with absorbance 0.62

I mark]

(ii) absorbance of the solution whose concentration is 0.035 moldm-3.

[1 mark]

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r (e) Calculate the gradient of the graph.
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[2 marksl
(f) State the significance of the value of the gradient.

[1 markl

Total 16 marks

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3.
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It has been suggested that olive oil is a healthier alternative to margarine in the human
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diet because
ofa greater presence ofunsaturated fatty acids.

Plan and design an experiment to test the accuracy of this suggestion.

Your answer should include the following:

(a) Hypothesis

[1 markl
(b) Aim

[1 markl
(c) Apparatus and materials

[3 marksl
(d) Experimental method

[3 marksl

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r (e) Variables
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(i) Manipulated

[1 markl

(ii) Controlled

[1 mark]

(iii) Responding

[1 markl

(0 Expected results

[1 markl

(g) ONE assumption made

[1 markl

(h) ONE safety precaution to be taken

[1 markl

Total 14 marks

END OF TEST

IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON TI{IS TEST.

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