Punjab Group of Colleges

Quarter test # 3 (Ch # 9, 11, 13, 14)

F.Sc Part II
Chemistry
Time:1:45 Hours Subjective Max. Marks: 48
(Section I)

Q # 2 Write short answers to all questions. (16 × 2= 32)

1. How ether can be prepared by Williamsons synthesis?
2. How can we distinguish between methanol and ethanol?
3. Write three reactions of ethanol in which O-H bond is broken.
4. How can we convert methanol into ethanol?
5. Discuss the side chain halogenation of toluene.
6. What is Wurtz-Fittig reaction? What is its importance?
7. Define resonance. Write five resonance structures of benzene.
8. How will you prepare p-chloronitrobenzene from benzene in two steps?
9. Write mechanism of the reaction of acetic acid with thionyl chloride.
10. How ethanoic acid is prepared from.
(a) 2-butene (b) Ethyne
11. What is peptide bond? Write the formula of a dipeptide.
12. Why molecular mass of carboxylic acids become double in non-polar solvents?
13. Write the mechanism of the addition polymerization.
14. Differentiate between glucose and fructose.
15. Explain hardening of oils with chemical reaction.
16. What are steroids? Write the formula of cholesterol.

SECTION II
Note: Attempt all the 2 questions;
Q:3 (A) Explain along the mechanism the alkylation and acylation of benzene. (4)
(B) Using phenol how would you prepare the following compounds? (4)
(a) Bakelite (b) Phenyl acetate
(c) Picric acid (d) Benzene
Q:4 (A) Write a note on thermodynamic stability of benzene. (4)
(B) What is fermentation? Explain preparation of ethanol from molasses and starch. (4)
 Punjab Group of Colleges
Quarter test # 3 (Ch # 9, 11, 13, 14)
F.Sc. Part II
Chemistry
Time: 15 Minutes Objective Max. Marks: 12
Note: You have four choices for each objective type question as A,B,C and D.The choice which you
think is correct, fill that circle in front of that question number. Use marker or pen to fill the circles.
Cutting or filling of two or more circles will result zero in that question.

1. The benzene molecule contains

(a) Three double bonds (b) Two double bonds
(c) One double bond (d) Delocalized π-charge
2. Which of the following acid can be used as a catalyst in Friedel-Crafts reactions?
(a) AlCl3 (b) HNO3 (c) BeCl2 (d) NaCl
3. Among the following, the compound that can be most readily sulphonated is.
(a) toluene (b) benzene (c) nitrobenzene (d) chlorobenzene
4. Which compound will have the maximum repulsion with H2O?
(a) C6H6 (b) C2H5OH (c) CH3CH2CH2OH (d) CH3-O-CH3
5. Methyl alcohol is not used :
(a) as a solvent (b) as an anti-freezing agent
(c) as a substitute for petrol (d) for denaturing of ethyl alcohol
6. Rectified spirit contains alcohol about
(a) 80% (b) 85% (c) 90% (d) 95%
7. Which following derivative cannot be prepared directly from acetic acid?
(a) acetamide (b) acetyl chloride (c) acetic anhydride (d) acetic acid
8. Which reagent is used to reduce a carboxylic group to an alcohol?
(a) H2/Ni (b) H2/Pt (c) NaBH4 (d) LiAlH4
9. The solution of which acid is used for seasoning of food:
(a) Formic acid (b) acetic acid (c) benzoic acid (d) butanoic acid
10. Which of these polymers is a synthetic polymer?
(a) Animal fat (b) starch (c) cellulose (d) polyester
11. The fibre which is made from acrylonitrile as monomer;
(a) PVC (b) rayon fibre (c) acrylic fibre (d) polyester fibre
12. Which one of the following statements about glucose and sucrose is incorrect
(a) Both are soluble in water (b) both are naturally occurring
(c) Both are carbohydrates (d) both are disaccharides