Diagrama de Equilibrio Liquido - Vapor

Usando Ley de Raoult

Sistema Benceno-Tolueno
Sistema Tb (°C) A B C
Benceno 80.1 6.87987 1196.76 219.161
Tolueno 110.6 6.95087 1342.31 219.187

P (atm) 1

T (°C) x1 x2 Ps1(mmHg)Ps2(mmHg)K1 K2 y1 y2 ∑yi

110.61414 0 1 1781.7703 759.99593 2.3444347 0.9999946 0 0.9999946 0.9999946
106.14065 0.1 0.9 1588.3498 668.10552 2.089934 0.8790862 0.2089934 0.7911776 1.000171
102.10701 0.2 0.8 1428.0911 592.98744 1.8790672 0.7802466 0.3758134 0.6241973 1.0000108
98.465511 0.3 0.7 1294.3404 531.07003 1.7030794 0.6987764 0.5109238 0.4891434 1.0000673
95.167026 0.4 0.6 1181.7071 479.52555 1.5548778 0.6309547 0.6219511 0.3785728 1.0005239
92.119689 0.5 0.5 1084.5187 435.52467 1.4269982 0.5730588 0.7134991 0.2865294 1.0000285
89.338047 0.6 0.4 1001.316 398.23308 1.317521 0.5239909 0.7905126 0.2095964 1.000109
86.77393 0.7 0.3 929.08996 366.16418 1.2224868 0.481795 0.8557408 0.1445385 1.0002792
84.402013 0.8 0.2 865.94932 338.37561 1.139407 0.4452311 0.9115256 0.0890462 1.0005718
82.167966 0.9 0.1 809.58745 313.77706 1.0652467 0.4128646 0.958722 0.0412865 1.0000084
80.100185 1 0 760.0138 292.31204 1.0000182 0.3846211 1.0000182 0 1.0000182

Grafico de dispersion
Sistema Benceno/Tolueno
120

100

80
Temperatura

60

40

20

0
0 0.2 0.4 0.6 0.8 1 1.2

Composicion