Professional Documents
Culture Documents
Kiln Burning Systems: Raw Mill From Storage Feed Rate
Kiln Burning Systems: Raw Mill From Storage Feed Rate
1 239
by Con G. Manias*
Once raw materials have been selected and blended, and ground and homogenized into a
fine and uniform kiln feed, they must then be subjected to enough heat to allow the
clinkering reactions to proceed. This is the pyroprocessing stage of cement manufacture,
beginning with the kiln feed material extracted from storage and weighed and transported to
the kiln, and finishing with the clinker from the cooler going to clinker storage. A schematic
diagram on different stages of cement manufacturing is shown in Figure 3.1.1
Feed rate
Control
Pre-heater system
+ Calciner
Fuel
Kiln rotation
Kiln
Fuel
To clinker storage
Cooler
CO
2
byweight
CaCO3
meal
Portions
Raw
Low-quartz High-quartz
Clay minerals
C
Fe2O3 H2O
C2(A,F)
The main problem with long wet kilns is their Dimensionally, long dry kilns are similar to long
poor fuel efficiency, because of the water to be wet kilns. These kilns were developed and
evap-orated from the slurry. This became a severe became popular particularly in North America.
problem only when the cost of fuel escalated Their advantage over wet kilns is potentially
during the 1970s, and only a few wet kilns have improved fuel consumption because the kiln feed
been built since that time. However, there are is dry. However, without any enhanced heat
some rare situations where raw material transfer fittings in the preheating zone, kiln exit
moistures, cheap (waste) fuels, low technology temperatures of 700°C or more meant that water
workforce, or other factors may still favor wet spray cooling was required, and very little
process production. advantage was realized over wet process.
However, kiln internals fitted at a later stage of
Another disadvantage of a wet process kiln is development included kiln chains (similar to wet
that it is limited in production rate because of kilns), kiln metallic crosses, and ceramic heat
mechanical limitations on kiln size. A 1500 tpd exchangers. The crosses and ceramic heat
wet kiln is a large kiln, with 2000 tpd being an exchangers basically split the kiln into 3 or 4
upper economic limit cross-sectional areas over a distance of about 15
without encountering to 20 m, splitting both the feed and gas flow, and
severe maintenance providing improved heat transfer.
prob-lems. Apart from
the sheer weight and With these enhancements, the kiln gas exit
stresses on mechanical temperatures were reduced to 350°C – 400°C,
drives and supports, specific fuel consumption improved some 30% and
shell deflection makes it output increased by 35% to 40% compared to wet
increasingly difficult to kilns.
achieve acceptable
refractory life. Figure Kiln production rates for long dry kilns are
3.1.3 depicts a typical marginally higher than long wet kilns. A
long wet process kiln. typical long dry kiln is shown in Figure
3.1.4.
These kilns have a short rotary kiln section, L/D of 12 to 15, preceded by a travelling grate
covered by a 150 mm to 200 mm layer of nodulized raw meal. The kiln exit gases at
1000°C or so pass through this nodule layer providing preheat of material before it enters
the rotary kiln at about 800°C. The gases exit the grate section at around 100°C, implying
very efficient recovery of heat. For some grate preheater kiln systems, the kiln feed nodules
experience two separate passes of the hot gases, the first for drying and the second for
preheating and partial calcination. Figure 3.1.5 shows a typical Lepol kiln system.
The nodules or pellets formed as kiln feed can either be produced from dry raw meal mixed
with about 13% moisture in a pan granulator, or produced from raw meal slurry after it has
passed through a filter press and been extruded and sliced into cylindrical pellets.
The raw material properties are critical to the performance of the Lepol kiln system. The
nodules or pellets formed have to be strong and plastic enough to withstand the
mechanical handling and thermal shock on the grate without breaking down. Nodule
breakdown causes blinding of the holes on the travelling preheater grate, increasing
pressure drop, and reducing airflow and hence capacity of the kiln system.
The output of a particular kiln can vary by almost double depending on the suitability of
raw feed for this process and nodule formation in particular.
244 Innovations in Portland Cement Manufacturing
Figure 3.1.6. The
most common is the
4-stage suspension
preheater, where
gases typically leave
the preheater system
at around 350°C.
Kiln capacities up to 3500 tpd exist, with specific fuel consumption usually around 750 to
800 kcal/kg (3.2 to 3.5 MJ/kg). The larger capacity kilns are built with two preheater
tower systems to keep cyclone sizes to economic proportions and required efficiency.
The operation of the cyclone preheater kilns can be improved by firing some fuel in the
riser duct to increase the degree of calcination in the preheater. The production rate can
also be increased marginally, depending on the limitation to output for a particular plant.
Preheater kilns can be subjected to flushing of material due to the fluidization of raw meal
that occurs during calcination in the kiln. Increasing the degree of calcination in the riser
(up to 50%) before the material enters the kiln reduces this tendency. Furthermore, burning
some fuel in the riser duct reduces the fuel requirement and thermal loading in the kiln,
thus improving the kiln refractory life.
In this kiln system, the excess air in the burning zone is increased, and the additional oxygen in the
riser duct allows additional fuel to be burnt there. This can be an ideal place to burn some waste fuel
such as waste oils or tires. The limitation as to how much fuel can be burnt in the riser can be limited
by the geometry of the duct, combustion system design, or fuel type. However, even under ideal
conditions, the fuel quantity is limited to about 25% of total fuel because of the limitation to the
amount of excess air that can be passed through the burning zone. Too much excess air will reduce
burning zone temperature to below the levels needed for clinkering. This reduction in burning zone
temperature can be countered by oxygen enrichment, as discussed later in the paper.
Precalciner Kilns
In precalciner kilns, the combustion air for burning fuel in the preheater no longer passes through the
kiln, but is taken from the cooler region by a special tertiary air duct to a specially designed com-
bustion vessel in the preheater tower. Typically, 60% of the total fuel is burnt in the calciner, and the
raw meal is over 90% calcined before it reaches the rotary kiln section. Since the calciner operates at
temperatures around the calcination temperature of raw meal (800°C to 900°C), there may not be a
flame as such. The calciner efficiency is dependent on uniform air flow and uniform dispersion of
fuel and raw meal in the air. Typically, average residence times calculated on gas flow for early units
were about 1 to 2 seconds for coal and oil, and 2 to 3 seconds for natural gas. In recent years, though,
there has been a trend toward larger calciner vessels to reduce some of the combustion problems of
the earlier designs and provide greater flexibility for using lower grade fuels.
Precalciner kilns can have very large outputs in excess of 10,000 tpd, with specific fuel consump-tion
below 3 MJ/kg (700 kcal/kg). There are many different configurations, with one, two, or three
preheater towers operating with one or two calciner vessels in either an in-line configuration or
separate line configuration. Some (mostly recent) designs include a separate precombustion
246 Innovations in Portland Cement Manufacturing
preheater tower.
Other Systems
Figure 3.1.7. In-line calciner system with single
produce clinker in other
The rotary kiln has been the reactors including a flash
standard clinkering unit forcalcining/clinkering and fluid
cement production over the pastbed calcining/clinkering vessels
century. During that time, there
have been various attempts to
Kiln Burning Systems 247
The motivation has been to reduce capital and operating costs or to allow smaller economic
clink-ering plants to be built in remote locations.
The author was involved with one such project during the 1980s, where clinker was produced in a
fluid bed fed with raw meal. Although this did not proceed to commercialization, it was noted that the
clinker produced from this pilot plant was much more reactive than any conventionally produced
clinker, and gave cement strengths 20% higher than those produced from good quality rotary kiln
clinker. This was thought to be due to the absence of overburning in the fluid bed clinker because of
the more uniform temperature that can be achieved. The mineral structure certainly showed much
finer alite and belite crystals in the 10 to 20 µm range. This gives some indication of the potential
quality improvement possible through better control of rotary kiln temperature.
Critical data on the kiln systems discussed above are summarized in Table 3.1.1. The data reflects
mechanical, operational, thermal, fuel, production, and efficiency parameters of each kiln system.
The residence time of material in the kiln is governed by the kiln slope, the speed of rotation,
and any internal restrictions either by design (dam rings) or through kiln ring formation.
Kiln Slope
Kiln Capacity
When designing a kiln for a certain capacity, or
when evaluating an existing kiln for potential
output, there are a number of key parameters that
must be evaluated. These include:
Kiln Burning Systems 249
There are design limits for all of the above that may vary between different processes, but any of
the above could be the limitation to a kiln’s output. These limitations will typically manifest
them-selves as kiln instability and ring or coating buildup, excessive dust loss, poor refractory
life, poor clinker quality, or high fuel consumption. Usually, however, the limitation is found to
be more a question of a fan capacity, a burner capacity, or milling of raw materials or coal.
CLINKER COOLERS
Cooling of clinker takes place at two locations: 1) in the kiln after the material passes the burning
zone region, and 2) in the specially designed clinker coolers after the material falls out of the kiln.
The rate of cooling can be critical to the clinker quality and performance of cement. The rate of
cooling in the kiln is determined by the flame and resulting heat flux, flame temperature, and
speed of material flow through the kiln. As the clinker temperature exiting the kiln is normally
1200°C to 1250°C, the clinker characteristics have been already largely established before the
clinker enters the cooler. A long flame gives slow heat-up and slow cooling of the kiln charge
before it falls from the kiln. This will tend to produce clinker with large alite and belite
crystals, resulting in a coarse-grained clinker matrix with poor reactivity and poor grindability.
Slow cool-ing can also result in reversion of C2S from the α' phase to the less reactive β form,
or in extreme cases even to the unreactive γ form, and can even allow C3S to revert to C2S and
CaO. All of these have a negative impact on cement strength.
A further quality problem can arise if there are high levels of MgO in the clinker, because
slow cooling allows large periclase crystals to form such that when these hydrate slowly in
concrete, the expansion can cause the concrete to rupture.
There are two main types of coolers used in cement clinker production. These are the satellite (or
planetary) type and the oscillating grate type. The 1990s saw tremendous advances in clinker cooler
technology that greatly improved heat efficiency and potential output from a given kiln system.
The fuel introduced by the burner will clearly be influenced by the secondary and tertiary
air flow patterns, given that 85% to 100% of the combustion air comes from this source and
the momen-tum of these large airflows dominates the combustion region. Typical
aerodynamic patterns in two different kiln combustion zones are shown in Figure 3.1.9-a,b.
Hood
Flame
(a)
Flame
(b)
Figure 3.1.9-a,b. Some typical kiln aerodynamic patterns encountered during kiln studies.
In order to ensure that all relevant factors are taken into account in combustion system
design, process parameters and kiln system design must be considered when designing a
burner for a given application.
1• Geometric design of cooler, cooler bull The following section will cover the types
nose, cooler throat, kiln, off-take ducts, burner and operational features of different
posi-tion, burner angle, burner channels (types, burners used in cement manufacturing.
numbers and sizes), calciner size and shape, and
tertiary air inlet
Turbulent Jet Diffusion Burners
2• Process design, such as fuel rate, type, For most kiln burners, fuel/air mixing occurs
properties; primary air mass and velocity; as a result of secondary air entrainment into
secondary air and tertiary air temperature, mass the fuel and primary air jet. Friction between
and velocity; production rates; heat transfer the different jet streams creates local
(convection, conduction, radiation); and heat fluxturbulence at the boundaries with the fuel jet
profiles developed expanding as it entrains surrounding air. The
nature and rate of mixing is determined by the
As no single modeling technique can provide all relative momentum of the various jet streams
the answers, a combination of physical and math- as well as the system aerodynamics.
ematical modeling provides the best information
for arriving at an optimized burner design.
Observation from a fuel/air mixing model using
acid-alkali techniques is shown in Figure 3.1.10.
The overriding consideration when implementing
results of modeling work is understanding the
limitations and the conclusions that can be drawn
from each technique, as well as ensuring that the
techniques used have been adequately validated.
In a rotary kiln, the secondary air to be entrained into the fuel jet is limited to that coming
from the cooler, and the expansion of the fuel jet is constrained by the diameter of the kiln.
If the burner jet momentum (fuel and primary air) is less than that required for complete
entrainment, then fuel/air mixing will be inadequate for good combustion, and a long, lazy
flame with high CO is the likely result.
If the burner momentum is greater than that required for complete secondary air entrainment,
then the excess momentum of the fuel jet is dissipated in pulling back exhaust gases from
further down the kiln into the flame. This so-called “recirculation” has a positive effect in
stabilizing the flame (making it less susceptible to minor process fluctuations) and in protecting
refractory surfaces from burning fuel particles. Note though, that too much recirculation can be
detrimental to fuel efficiency and produce an overly aggressive combustion environment. An
ideal flame from use of secondary air entrainment and recirculation is shown in Figure 3.1.11.
Secondary
air
Secondary
air
Recirculated
combustion gases
Figure 3.1.11. Idealized flame in rotary kiln showing secondary air entrainment and
recircula-tion of combustion gases indicating adequate burner momentum for satisfactory
fuel/air mixing.
Good burner design therefore requires optimizing fuel jet momentum and
primary air mass and velocity to create a recirculatory flame while interacting
with that particular kiln system’s aerodynamics. The secondary air temperature,
mass, velocity, and directional flows must all be considered in the design process
as these affect the burner system design. The variables to
opti-mize include primary air mass and velocity, axial and
radial flow splits, fuel jet momentum, and burner insertion
length and direction. A typical multi-fuel burner
used in a rotary kiln is shown in Figure 3.1.12.
Figure 3.1.12. Typical multi-fuel burner.
254 Innovations in Portland Cement Manufacturing
Flame Stability
Unstable flames adversely affect kiln operation as well as being unsafe to plant and personnel.
An unstable flame is one that has a varying ignition point and a variable stand off distance from
the burner tip as shown in Figure 3.1.14. There is a high risk of flame out, and substantial
amount of unburnt fuel between the burner tip and the ignition point that is a potential
explosion risk. Gas burners are more prone to instability because of the high ignition
temperature, slow flame propa-gation speed, and narrow flammability limits for this fuel.
Flame envelope
Ensuring early ignition of fuel entering the combustion zone enhances flame stability. In
some applications, this can be by a continuous pilot burner, but in rotary kilns this is best
achieved by ensuring recirculation of hot gases as the ignition source for new fuel. Once a
kiln is up to operat-ing temperature, radiation from refractory provides the ignition energy.
Kiln Burning Systems 255
External circulation from properly designed burners brings hot combustion gases back into the com-
bustion region to help stabilize the ignition point. Internal circulation can be even more effective.
Internal circulation can be induced by the use of a bluff body to create a low pressure region
in the center of the burner nozzle that then draws hot combustion gases back into this region.
This can then act as the ignition source for the new fuel. Bluff bodies, though, can suffer
heat damage in this demanding location (see Figure 3.1.15).
Reverse flow
Primary air
Gas
Primary air
Bluff body
Figure 3.1.15. Stabilization of flame with internal recirculation created by bluff body.
A more durable means of creating internal flame re-circulation is the use of swirl in either
the fuel or primary air jet stream as shown in Figure 3.1.16. However, swirl would broaden
the flame that can adversely affect refractory life due to flame impingement (see Figure
3.1.17). In gas firing, the most effective design uses limited swirl for both primary air and
gas fuel. In oil firing, primary air swirl is typically used, while for solid fuel firing swirl is
often unnecessary for producing a stable flame. Each case is designed on the merits of the
fuel and the combustion environment in which it will operate.
Burner
Flame envelope
Figure 3.1.16. Flame stabilized by internal circulation.
256 Innovations in Portland Cement Manufacturing
20,000
14,000
6000
5000
4750Dia.
N C
L
2498 2600
Outlet Dam
cone 2498 ring 4600
Discharge Cam
zone section
The flame itself does not precess. The effect is to produce large-scale mixing, via the
“stirring” action of the jet and a rapidly spreading flame. This is in contrast to the fine scale
mixing of turbu-lent jet diffusion burners. The precessing motion is generated without any
moving parts within the Gyro-Therm nozzle.
Although the flame spreads more than that from a conventional turbulent jet nozzle, the amount of
spread can be controlled. This fact is important in rotary kilns where direct impingement of a flame on
the product could produce instability or reducing conditions which would be detrimental to product
quality or damage the refractory. A simple but extremely effective flame shaping tech-nique is built
into the burner. The technique for flame shape adjustment is based on a high momentum gas jet
injected at a critical point into the precessing jet flow field. This jet (termed the center body jet, CBJ)
is expelled through the center body of the precessing jet nozzle, modifying the pressure fields within
the vicinity of the burner in such a way that the fuel gas is directed more toward the kiln axis. As the
proportion of gas is increased through the center body jet, the flame spread is reduced and the heat
flux profile lengthened. An air channel is provided for burner cool-ing and for flame shaping during
the warm-up phase. A schematic of Gyro-Therm burner with gas channel for flame adjustment and
cooling air is shown in Figure 3.1.19.
PJ Gas
r
efractory profiles to produce much improved
calciner aerodynamics and hence greatly improve
calciner combustion.
OXYGEN INJECTION
The technical benefits available from using oxygen to replace air for combustion in cement
kilns have long been recognized. These benefits arise from increased flame temperature
(leading to improved heat transfer rates), faster reaction rates with some difficult fuels, and
reduced combus-tion gas volume (due to less nitrogen).
In general, this will lead to reduced specific fuel consumption (less waste gas volume and
better heat transfer) and increased production from a particular kiln. The effect on NO x
emissions will be variable, but with small amounts of oxygen substitution NO x will
usually increase as a conse-quence of elevated flame temperature.
However, the cost of oxygen has generally been prohibitive in the past, preventing the
wholesale use of oxygen to enhance cement kiln performance.
The availability of cheaper production methods for oxygen such as the vacuum swing
adsorption process, together with increased demand for cement, have combined in some
regions to make the strategic use of oxygen a viable alternative for increasing production.
This is particularly so where short term peaks in demand are encountered and oxygen
injection can be implemented without significant plant down time for modifications.
Oxygen injection can be carried out either in the kiln or calciner. A process evaluation of the
specific kiln system will reveal the most advantageous point. Generally, this will involve
identifying bottlenecks to increased production and how these can be addressed through the use
of oxygen. A modeling strategy for designing oxygen-injecting system for a calciner is shown in
Figure 3.1.21. Strategic use of oxygen can impart the following processing benefits:
determine the design of
1• Allow more fuel to be burned in either the kiln the oxygen injection
or calciner where fan capacity is limiting output, system into the calciner.
and therefore increase output
However, there are also potential risks of overheating refractories and kiln charge or calciner
feed unless due consideration is given to the design of injection points and oxygen lances.
Typical chemical analysis of raw meal, clinker, and select processing parameters are given
in Table 3.1.2.
Table 3.1.2. Typical Composition of Raw Meal, Clinker, and Relevant Processing
Parameters
Parameters Raw meal Loss free Coal ash Clinker
SiO2 14.4 22.3 54.3 22.6
Al2O3 3.2 5.0 26.2 5.2
Fe2O3 1.8 2.8 16.7 2.9
CaO 42.4 65.7 0.6 65.0
MgO 1.30 2.02 0.8 2.0
SO3 0.37 0.57 0.1 0.6
K2O 0.60 0.93 1.2 0.9
Na2O 0.17 0.26 0.1 0.3
TiO2 0.17 0.26
Mn2O3 0.12 0.19
P2O5 0.11 0.17
Cl 0.03 0.05
LOI 35.5 0 0 0
SR 2.9 2.9 1.3 2.78
AR 1.8 1.8 1.6 1.77
LSF 91.7 91.7 0.3 91.1
C3S 60.6 60.6 -610.1 53.6
C2S 18.3 18.3 616.0 24.4
C3A 8.4 8.4 41.2 8.8
C4AF 8.5 8.5 50.8 8.9
The hypothetical compounds are calculated using the Bogue equations to determine the percent-age
of calcium silicates (C3S and C2S), calcium aluminate (C3A) and calcium alumino ferrite (C4AF)
phases, which would be present in the clinker if all reactions proceeded to completion under
equilibrium conditions. In reality, the calculated or hypothetical composition differs from actual
analysis of clinker by X-ray diffraction or microscopic analysis. This is because chemical
Kiln Burning Systems 261
equilibrium is reached only occasionally, and the degree to which actual analysis differs from the
calculated analysis is influenced by the heat treatment of the material. In addition, small amounts of
trace elements can have a profound effect on the eventual mineralogical composition of clinker.
3• Aluminate and ferrite phases can be either higher or lower, but on average are 2%
lower than calculated
These stages determine the size of alite and belite crystals and their reactivity, the formation of
these crystals (α, β, γ), and the nature of the liquid phase, as well as the position in the structure
where minor elements such as Mg, Na, and K, are found; all are critical to cement quality.
Some aspects of plant operation that help kiln performance are kiln feed size,
homogeneity, kiln time/temperature profile, heat balance, and volatile and dust cycles;
these are discussed in the following sections.
The kiln feed must be ground finely enough, within the context of the raw materials
mineralogy, to allow the particles to react together within the time and temperature
conditions in the kiln. Coarser particles require a higher reaction temperature and are likely
to form relicts of the larger particles they originate from as alite and belite clusters.
Localized chemical variations that occur when kiln feed is not properly homogenized mean there
are different localized requirements for raw meal to form clinker. In a kiln situation, this will
imply that some of the easier-to-burn regions may be overburnt in order to completely burn the
diffi-cult-to-burn regions. The difference between well homogenized and poorly homogenized
kiln feed can be an increase of up to 200°C in the operating temperature of the burning zone, the
associated high fuel consumption, high NOx, poor refractory life, and poor product reactivity.
Localized variations can also be created by deposition of coal ash on the kiln charge or
irregular return of kiln dust back to the kiln.
262 Innovations in Portland Cement Manufacturing
Time/Temperature Profile
The kiln charge must spend sufficient time at a high enough temperature to reach near
complete reaction to form clinker minerals. There must be no material flushing or
underburning, as this produces poor quality clinker. The material bed must tumble
adequately to ensure uniform heat-ing through the mass.
If clinker is underburnt, it will form small crystals of alite surrounded by abundant (solidified)
liquid phase, whereas the belite will exist in discrete clusters. There may also be significant free
lime present together with alite and belite, which has not had the opportunity to completely
react. Overburnt clinker will have large alite and belite crystals, and exhibit poor reactivity.
Add Inefficiencies
kJ/kg kcal/kg
Heat losses related to inefficiencies Dry Wet Dry Wet
during the kiln operation process process process process
Evaporation of water 20 2100 5 502
Heat losses, gas, clinker, dust 840 1250 201 299
Radiation, convection loss 650 360 156 86
Total heat consumption =
(endothermic heat – exothermic heat)
+ heat losses due to inefficiencies 3275 5475 782 1307
Kiln Burning Systems 263
The heat of formation (Q) of the clinker minerals is a function of the chemical composition and the
mineralogical composition. It can be expressed as kcal/kg in a general equation as follows:
Q = 2.22% Al2O3 +5.86% hH +6.48% MgO+7.646% CaO– 5.116% SiO2 – 0.59% Fe2O3 (2)
Where hH = % water of crystallization in the clay, g/100g clinker, and all analyses are on clinker.
The kiln burner is the main source of heat input to the rotary kiln and is primarily
responsible for setting the heat flux profile in the kiln. However, there are other significant
but insidious factors which need to be considered.
Firstly, there are dust cycles in the system which move heat around, such as:
1• Dust cycle between the cooler and kiln, where 5% to 10% of the clinker is recycling
between the two, moving high grade heat from the kiln to the cooler, and returning back to
the kiln at lower temperature.
2• Dust cycle between the burning zone and the back of the kiln, removing heat from the
burn-ing zone to the back of the kiln. This can be about 10% of the kiln throughput.
3• Dust cycle between the kiln and the preheater kiln, taking some 10% of kiln feed and
associ-ated heat back into the preheater.
4• Dust cycles between cyclone stages, where 20% to 30% of material flow is returned
back to higher cyclones.
5• Kiln dust losses, amounting to some 10% of kiln feed, which are lost to the kiln system.
These dust cycles can limit a given kiln’s output, as increasing gas velocities through the system
will eventually render the kiln inoperative. The increasing dust loads will increase kiln back end
temperatures and reduce kiln burning zone temperatures, leading to kiln instability.
Secondly, there are phase changes that move heat within and around the system in the
form of latent heat of the materials. This includes:
1• Volatile materials which vaporize in the burning zone (predominantly alkali sulfates,
and chlorides) and recondense in cooler parts of the system, releasing the latent heat
2• Liquid phase materials which melt in the hotter parts of the kiln and resolidify in the
cooling section of the kiln
3• Some phase changes occurring in the main clinker minerals as they cool
264 Innovations in Portland Cement Manufacturing
These materials are not usually in the pure
form, but form a eutectic mixture with an
Other less insidious factors are the sensible heat overall melt-ing point below that of the pure
of introduced streams, the secondary air heat salts. In practice, these salts generally will
input to the kiln, the calcination reaction, and appear in the melt in the temperature range of
heats of formation of the various components. 600°C to 800°C.
The heat exchange occurring within a kiln is The volatile compounds cannot readily escape from
therefore a multi-dimensional phenomenon. the kiln system because they condense (before they
can be removed in the exit gas stream) and re-enter
KILN RINGS AND BUILDUPS the kiln. Their concentration will therefore continue
to build, sometimes reaching a concentration in the
The formation of kiln rings and subsequent
recycle stream significantly greater than the
buildups result from melt formation followed
concentration in the raw materials. As they pass
by solidification that act as binder for dust
particles to agglomerate. There are also other through a sticky condition during the
factors that lead to different mechanisms and melting/vaporization and recondensing stages, they
types of ring formation as are discussed in the can be catalysts for forming coating buildup in the
following sections. preheater tower and rings in the back end of the
kiln. These can be particularly disruptive to kiln
Kiln Volatiles operation in the cyclone preheater tower, and older
preheater kilns can run into severe opera-tional
The kiln volatiles referred to in cement manufacture
problems because the effect of the volatile cycle
are those compounds that volatilize in the burning
was unrecognized in their design.
zone of a rotary kiln and recondense in the cooler
parts of the kiln or preheater. They are usually
sodium or potassium sulfates and chlorides, but can
also include certain calcium salts. Their melting
points and relative volatilities in the kiln burning
zone are given in Table 3.1.4.
As a guide, the acceptable concentration limits of these materials (as % of clinker) in the kiln riser are:
Na2O and K2O < 3% to 5%
SO3< 3% to 5%
Cl < 1.2% to 1.6%
1• The gas velocity in the burning zone has a strong influence on the volatility of these materials. A
higher gas velocity reduces the vapor pressure of volatiles in the atmosphere, increasing their
volatility. A kiln operating beyond its design limitations could be adversely affected.
2• A higher burning zone temperature as required for harder burning mix will increase volatility.
3• A higher CO2 concentration in the kiln will increase volatility of sodium and potassium.
4• Reducing conditions will increase the volatility of sulfur, while higher oxygen
levels will decrease it. The equilibrium reaction is
A low oxygen level shifts the equilibrium to the right. The volatility of sodium and
potassium is less affected by oxygen levels than that of sulfur.
1• Increased water vapor promotes formation of alkali hydroxides that are more volatile
than the sulfates. Potassium volatility is increased at 1200°C, while sodium volatility is
increased at 1400°C.
2• SO2 (from the fuel) reduces the volatility of potassium, while the sodium
volatility is unaffected.
3• The mineralogical composition of raw materials producing volatiles is a major determinant
of the alkali volatility, depending on the alkali carriers. Mica > illite > feldspar. Also, an easier
burning material means lower burning zone temperature and hence less volatility.
4• The fineness of raw meal has an indirect effect if it produces an easier burning mix.
A further factor is the alkali-to-sulfur ratio. Alkalies will preferentially combine with any
chloride present. The best alkali-to-sulfur ratio is when there is just enough sulfur present
to combine stoi-chiometrically with the remaining alkalies. If there is an excess of sulfur,
then calcium sulfate will form from which the sulfur will volatilize completely.
If there is an excess of alkalies, alkali aluminate can form which will cause stiffening
problems in concrete and mortar. There are also likely to be rings and buildup formed in the
kiln system from a variety of other alkali salts produced.
In some cases, where low alkali cement is the target, and there is an alkali bypass installed. Alkali
volatility is an advantage, and CaCl2 can be added to the mix to promote alkali volatility.
266 Innovations in Portland Cement Manufacturing
The rings form when sticky ash impinges and
deposits onto the refractory surface. As the
Preheater Kiln Middle Rings kiln turns, some of the kiln charge material
adheres onto the sticky ash. The ring
These are dense hard rings that form at 7 to 10
gradually builds as more and more ash and
kiln diameters from the kiln discharge and are
charge material stick on top of each other as
typi-cally 15 to 20 m long. They are clinker-like
the kiln operates.
in appearance and composition.
1• Stable kiln operation, such as uniform feed rate, chemical composition, and fineness
of coal and raw meal, and a well-designed combustion system
2• Lower kiln system velocities and dust loads
3• Lower volatile cycles attained by:
– choice of raw materials
– minimize < 20µ material in raw meal
– discard some kiln dust to control % volatiles in kiln
– eliminate cold air leakage into the P/H to avoid cold spots
4• Avoid sinter rings by controlling liquid phase level and selecting refractories less
prone to clinging by liquid phase
5• Avoid coal ash rings by using lower ash coal or improving burner design
6• Avoid clinker rings by burning closer to the kiln discharge (burner design) and using
blasters for any snowmen in cooler
7• Maintain an oxidizing environment in the burning zone
8• Maintain a short heat flux profile (burner design)
9• Optimize chemistry and mineralogy of raw mix to give an easier burning kiln feed
10• Optimize kiln aerodynamics to avoid high velocity areas and flame impingement
CONCLUSIONS
The heat transfer processes occurring inside a kiln are multi-dimensional and extremely
compli-cated. There is no single factor that can be considered in isolation when seeking to
optimize kiln performance and product quality.
The raw materials and kiln feed preparation will have a major impact on kiln performance
and will set the blueprint for fuel economy, kiln stability, clinker quality, refractory life, kiln
throughput, and environmental impact. The kiln operation and the combustion system will
determine as to what extent the potential inherent in the raw materials will be realized.