First of all you need Cheat Engine.

Go google it. It's a program that alter ram memory of processes such as games or programs.
Download and install it.
Start Dragon Ball Xenoverse and then Cheat Engine.
In the game go to Offline Battles or Parallel Quests.
Once you are at the character select screen in the game don't select a character but do this.

Go to Cheat Engine by press Shift + Tab. 

You need to attach Dragon Ball Xenoverse Process to "Cheat Engine"

Click the little flickering PC icon (might not flicker at all but should)
A list of processes will show...select "DBXV.exe".
Now you have attached the game to the Cheat Engine.

Go to search and highlight value type. Select "String"

Type your profile name EXACTLY as you wrote it when you created it ... in my case it is White Lord.

Picture:

Now press "First Scan" and a small number of results should popup depending on your profile name.
Now only one of the results is THE ONE you need. Don't worry it usually starts with 0D and is always the
fifth result from top-bottom (well at least in my case lol) . 
In case it isn't just make sure to see similar result by clicking "Browse This Memory Region" right clicking
the result with your mouse.

See the next picture....

After clicking "Browse this Memory Region" you will see this....
I highlighted the area where you should by default be.

Now the important part is the next one.

If the result you browse is the right one you will see a number of FFFFFFF filled areas in this region around
your profile name and elsewhere. 
Use Calculator in "Programmer " HEX mode in order to subtract addresses.

This is what you should do. Now below are the character id's 

2C - GREAT APE Vegeta

2D - GREAT APE Bardock
2E - Great Ape Baby
35 - Demigra
36 - Demigra Final 
38 - SHENRON - CRASH WHEN PLAYER CONTROL
39 - SUPREME KAI OF TIME
3E - MIRA
3F - TOWA 
42 - UNKNOWN CHARACTER - SOME POD LIKE
4A - GREAT APE NAPPA!
4B - IMPERFECT CELL
4C - TOKI TOKI LOL
4D - BIG TOKI TOKI

Replace the custom character slot modifier address id with one of the above ids and you will get your
chosen NPC/Boss on the character select screen.
Note that the code is DMA so it won't work anymore after you QUIT the game. You have to repeat the
progress each time or TO FIND A DMA Pointer and save this trouble once and for all. 

Google " how to find DMA pointer with Cheat Engine" for more instructions.
Hope this saves troubles. 

And as a little bonus I will share the Special SKILL's id's for other devs to make skill/move modifiers.

DRAGON BALL XENOVERSE SKILL/MOVES ID'S for modding purposes! Enjoy DB Scene!

SKILL ID's in HEX.

Equip a skill search for it's name in the list and it's id.
Search for it's id in the Cheat Engine using HEX option with EXACT Value to find difference or just swap skills.
It's your choice ...advanced mod devs.

Elite Beam - 029e

Elite Shooting - 029F
Kai Kai - 028C
Strike of Revelation - 028B
Prelude to Destruction - 028A
Eternal Charge - 026E
Diabolic Cyclone - 026D
Diabolic Mine - 026C
Beam Rifle - 0258
Meteor Crash - 0254
Meteor Strike - 0253
Meteor Blow - 0252
Maximum Charge - 0251
Full Power Charge - 0250
Energy Charge - 024F
Energy Shot - 024E
Tricky Strike - 021E
Boiling Ball - 021D
Energy Cannon - 021C
Rage Saucer - 0216
Bloody Saucer - 0215
Darkness Mixer - 0214
Seasoning Arrow - 0213
Time Shackles - 0212
Present for You - 020A
Rolling Hercule Punch - 0209
Dynamite Kick - - 0208
Bluff Kamehameha - 01FF
Big Bang Kamehameha - 01FE
Dragon Thunder - 01F6
Whirlwhind Blade - 01F5
Dragon Flash Bullet - 01F4
Fighting Sun - 01EF
Burst Reflection - 01ED
Burst Attack - 01EB
Ice Field - 01E5
Ice Claw - 01E3
Freezing Beam - 01E1
Boulder Break - 01BA 
Boulder Toss - 01B9
Great Ape Beam - 01B8
Dancing Parapara - 01A6
Prepare to be Punished - 01A5
Feint Shot - 01A4
God of Destruction's Wrath - 019C
God of Destruction's Rampage - 019B
God of Destruction's Anger - 019A
Gigantic Slam - 0192
Gigantic Omega - O191
Blaster Shell - 0190
Split Finger Shot - 0188
Pressure Sign - 0187
Big Bang Attack - 0186
Super Ghost Kamikaze Attack - 017E
Galactic Donuts - 017D
Die Die Missle Barrage - 017C
Pearl Flash - 0175
Quick Sleep - 0174
Vanishing Ball - 0173
Majin Kamehameha - 0172
III Rain - 016A
III Bomber - 0169
III Flash - 0168
Explosive Buu Buu Punch - 0162
ZigZag Express - 0161
Angry Hit - 0160
Innocence Cannon - 015F
Innocence Bullet - 015E
Hawk Charge - 0156
Eagle Kick - 0155
Justice Rush - 0154
Taunt - 014A
Perect Shot - 0138
Gravity Impact - 0137
All Clear - 0136
Deadly Dance - 012E
Endless Shoot - 012D
Power Blitz - 012C
Hyper Drain - 0127
Super Drain - 0126
Drain Charge - 0125
Thunder Eraser - 0124
Drain Field - 0123
Flash Bomber - 0122
Smile Charge - 011A
Freedom Kick - 0119
Side Bridge - 0118
Final Cannon - 0110
Double Buster - 010F
Finsih Buster - 010E
Burning Slash - 0109
Shining Slash - 0108
Change the Future - 0106
God Breaker - 0105
Burning Attack - 0104
Death Slicer - 0F4
Death Crasher - 0F3
Death Slash - 0F2
Death Psyco Bomb - 0F1
Death Beam - 0F0
Emperor's Sign - 0E6
Fighting Pose F - 0DF
Milky Cannon - 0DE
Holstein Shock - 0DD
Fighting Pose A - 0DC
Fighting Pose G - 0D5
Fighting Pose B - 0D4
Sauzer Blade - 0D3
Crusher Ball - 0D2
Fighting Pose K - 0CC
Fighting Pose J - 0CB
Fighting Pose E - 0CA
Recoome Kick - 0C9
Recoome Eraser Gun - 0C8
Mach Kick - 0C1
Mach Punch - 0C0
Fighting Pose I - 0BF
Fighting Pose D - 0BE
Fighting Pose H - 0B8
Fighting Pose C - 0B7
Guldo Fighting Pose - 0B6
Time Control - 0B4
Sledgehammer - 0A4
Shine Shot - 0A3
Finish Breaker - 0A2
Flash Strike - 0A1
Galick Gun - 0A0
Arm Crash - 098
Genocide Shell - 097
Bomber DX - 096
Sailbabeam - 08E
Poison - 08D
Acid - 08C
Shining Friday - 084
Saturday Crash - 083
Double Sunday - 082
Spirit Boost - 07D
Rise to Action - 07C
Solar Flare - 07B
Volleyball Fist - 07A
Tri Beam - 079
Dodon Ray - 078
Fake Death - 074
Afterimage - 073
Ki Blast Thrust - 06F
Wolf Fang Fist - 06E
Cross Arm Drive - 06B
Lullaby Punch - 06A
Turtle Style Last Rescort - 069
X20 Kaioken - 068
X3 Kaioken - 067
Kaioken - 066
Destructo-Disc - 065
Orin Combo - 064
Evil Eyes - 05E
Light Grenade - 05D
Evil Flight Strike - 05C
Wall Defense - 05B
Evil Explosion - 05A
Justice Pose - 052
Ki Blast Cannon - 051
Burst Rush - 050
Evil Whirlwind - 047
Super Dragon Flight - 046
Masenko - 03E
Evil Rise Strike - 03D
Evil Ray Strike - 03C
Kamekameha - 035
Consecutive Energy Blast - 034
Stone Buller - 033
Charge - 032
Power Pole - 02C
Power Pole Combo - 02B
Power Pole - 02A
Scissors Rapper Kick - 029
Kamekameha Boost - 028
x10 Kamekameha - 015
Afterimage Strike - 014
Super Guard - 00E
Tyrant Lancer - 00C
Rebellion Spear - 00B
Riot Javelin - 00A
Spirit Bomb Tower (Time Patroller Specific) - 005
Instant Transmission - 004
Super Dragon Fist - 003
Super God Fist - 002
Kamehameha - 000
If you like my work and the DaTeHaCKs team you can donate to me
at paypal email:

00 - Goku
01 - Bardok
02 - Goku SSJ4
03 - Goku SSJ God
04 - Goku GT //No model
05 - Goten
06 - Gohan Kid
07 - Gohan Teen
08 - Gohan Adult
09 - Piccolo
0A - Krillin
0B - Yamcha
0C - Tien
0D - Raditz
0E - Saibaman et. al.
0F - Nappa
10 - Vegeta
11 - Vegeta SSJ4
12 - Guldo
13 - Burter
14 - Recoome
15 - Jeice
16 - Ginyu
17 - Frieza 1st Form
18 - Frieza Final
19 - Frieza Full Power
1A - Trunks Future
1B - Trunks Kid
1C - Androit 17
1D - Super 17
1E - Androit 18
1F - Cell Perfect
20 - Cell Full Power
21 - Cell Jr.
22 - Videl
23 - Majin Buu
24 - Super Buu
25 - Kid Buu
26 - Gotenks
27 - Vegito
28 - Broly
29 - Beerus
2A - Pan //no model
2B - Giru (GT Robot)
2C - Vegeta Ape
2D - Bardok Ape
2E - Baby Ape
30 - Eis Shenron //no model
31 - Nuova Shenron //no model
32 - Omega Shenron
33 - Gogeta SSJ4
34 - Hercule
35 - Demigra Human
36 - Demigra Final
38 - Shenron
39 - Surpreme Kai of Time
3A - Buu
3B - Nabana
3C - Raspberry
3D - Gohan 4 years old
3E - Mira
3F - Towa
41 - Whis
42 - Shop Robot
43 - Jaco //no model
47 - Landing Pod
48 - Ginyu Frog
49 - Hercule
4A - Nappa Ape
4B - Cell Imperfect
4C - Tokitoki
4D - Tokitoki Big
59 - Unknown Saiyan Male //Trailer
5A - SYM (Saiyan Male)
5B - SYF (Saiyan Female)
5C - NAM (Namekian Male)
5D - MAM (Majin Male)
5E - MAF (Majin Female)
60 - Time Patrol Recruit 1 (Human/Saiyan Male) //Demigra Saga Outro Video
61 - Time Patrol Recruit 2 (Human/Saiyan Female) //Demigra Saga Outro Video
62 - Time Patrol Recruit 3 (Namekian) //Demigra Saga Outro Video
63 - Time Patrol Recruit 4 (Majin Female) //Demigra Saga Outro Video
64 - Human Male
65 - Human Female
66 - Saiyan Male
67 - Saiyan Female
68 - Namekian
69 - Frieza Race
6A - Majin Male
6B - Majin Female