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THE MINISTRY OF AGRICULTURE
OF
THE REPUBLIC OF INDONESIA
DIRECTORATE GENERAL
OF
AGRICULTURAL INFRASTRUCTURE AND FACILITIES
DIRECTORATE OF FERTILIZER AND PESTICIDE
Jl. Harsono RM No. 3, D Building 8-9th Floor, Ragunan Pasar Minggu - Jakarta Selatan
Phone (62.21) 7890043 - 7810044, Fax (62.21) 7890043
No. : 1194/Kompes/2016
In accordance with the Decree of the Minister of Agriculture number

693/Kpts/SR.330/10/2016
We hereby certify that :
Company name : PT BASF Indonesia

Company address : DBS BANK TOWER CIPUTRA WORLD 1 LT 26-
27
JL. PROF. DR. SATRIO KAV 3-5
KARET KUNINGAN - SETIABUDI
JAKARTA SELATAN - DKI JAKARTA 12940
Is recognized as the registration holder of the following product :
Trade name : ABATE 1 GR

Common name and content of a.i. : temephos : 1%
Registration number : RI. 060901197496
The product mentioned above is offically registered.
Expiry: 18 October 2021 Jakarta, 9 November 2016

Director,
Dr. Ir. Muhrizal Sarwani, MSc
This document is official document of Ministry of Agriculture which do not require signature
since being issued electronically from Sistem Informasi Manajemen Pelayanan Perizinan Pertanian (SIM-PPP).
Ministry of Agriculture is responsible for any information in this document.
Safety data sheet
Page: 1/15
BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 22.03.2017 Version: 2.0
Product: Abate® 1 GR
(ID no. 30671913/SDS_CPA_00/EN)
Date of print 17.05.2019
1. Identification
Product identifier
Abate® 1 GR
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: crop protection product, insecticide
Details of the supplier of the safety data sheet
Company:
PT BASF Indonesia
DBS Bank Tower, 27th Floor, Ciputra
World 1 Jakarta, Jl. Prof. Dr. Satrio Kav 3 -
5
Jakarta 12940, INDONESIA
Telephone: +62 21 2988 6000
Emergency telephone number
International emergency number:

Telephone: +49 180 2273-112
2. Hazards Identification
Classification of the substance or mixture
According to UN GHS criteria
STOT RE 2
Aquatic Acute 1
Aquatic Chronic 1
Page: 2/15
(ID no. 30671913/SDS_CPA_00/EN)
For the classifications not written out in full in this section the full text can be found in section 16.
Label elements
Globally Harmonized System (GHS)
Pictogram:
Signal Word:
Warning
Hazard Statement:
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary Statement:
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
Precautionary Statements (Prevention):

P260 Do not breathe dust.
Precautionary Statements (Response):

P314 Get medical advice/attention if you feel unwell.
P391 Collect spillage.
Precautionary Statements (Disposal):

P501 Dispose of contents/container to hazardous or special waste collection
point.
Hazard determining component(s) for labelling: TEMEPHOS
Other hazards
See section 12 - Results of PBT and vPvB assessment.
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.
Page: 3/15
(ID no. 30671913/SDS_CPA_00/EN)
3. Composition/Information on Ingredients
Substances
Not applicable
Mixtures
Chemical nature
crop protection product, insecticide, Granule (GR)
Hazardous ingredients (GHS)

temephos (ISO); Phosphorothioic acid, O,O'-(thiodi-4,1-phenylene) O,O,O',O'-tetramethyl ester

Content (W/W): 1 % Acute Tox. 4 (Inhalation - vapour)
CAS Number: 3383-96-8 Acute Tox. 5 (oral)
EC-Number: 222-191-1 Acute Tox. 5 (dermal)
STOT RE 1
Aquatic Acute 1
Aquatic Chronic 1
H313, H332, H303, H372, H400, H410
methanol
Content (W/W): < 1 % Flam. Liq. 2
CAS Number: 67-56-1 Acute Tox. 3 (Inhalation - vapour)
EC-Number: 200-659-6 Acute Tox. 3 (oral)
INDEX-Number: 603-001-00-X Acute Tox. 3 (dermal)
STOT SE (Central nervous system, Optic nerve)
1
H225, H311, H331, H301, H370
Specific concentration limit:

STOT SE 2: 3 - < 10 %
STOT SE 1: >= 10 %
Calcium dodecylbenzenesulphonate
Content (W/W): < 1 % Skin Corr./Irrit. 2
CAS Number: 26264-06-2 Eye Dam./Irrit. 1
EC-Number: 247-557-8 H318, H315
REACH registration number: 01-
0000015475-68
Quartz (SiO2)
Page: 4/15
(ID no. 30671913/SDS_CPA_00/EN)
Content (W/W): < 100 %
CAS Number: 14808-60-7
EC-Number: 238-878-4
Silicon dioxide
Content (W/W): < 5 %
CAS Number: 61790-53-2
For the classifications not written out in full in this section the full text can be found in section 16.
4. First-Aid Measures
Description of first aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.
Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
water spray, foam, dry powder
Unsuitable extinguishing media for safety reasons:

carbon dioxide
Special hazards arising from the substance or mixture

Page: 5/15
(ID no. 30671913/SDS_CPA_00/EN)
carbon monoxide, Carbon dioxide, sulfur oxides, phosphorus oxides
The substances/groups of substances mentioned can be released in case of fire.
Advice for fire-fighters

Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent
systems. Dispose of fire debris and contaminated extinguishing water in accordance with official
regulations. In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying
with water if exposed to fire.
6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Use personal protective clothing. Avoid contact with the skin, eyes and
clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater. Do not discharge into the subsoil/soil.
Methods and material for containment and cleaning up

For small amounts: Contain with dust binding material and dispose of.
For large amounts: Sweep/shovel up.
Avoid raising dust. Dispose of absorbed material in accordance with regulations. Collect waste in
suitable containers, which can be labeled and sealed. Clean contaminated floors and objects
thoroughly with water and detergents, observing environmental regulations.
Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
7. Handling and Storage

Precautions for safe handling
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of
stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed
before breaks and at the end of the shift.
Protection against fire and explosion:

Avoid dust formation. Dust can form an explosive mixture with air. Prevent electrostatic charge -
sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities

Segregate from foods and animal feeds.
Page: 6/15
(ID no. 30671913/SDS_CPA_00/EN)
Further information on storage conditions: Keep away from heat. Protect against moisture. Protect
from direct sunlight.
Storage stability:
Storage duration: 24 Months
Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
8. Exposure Controls/Personal Protection

Control parameters
Components with occupational exposure limits
67-56-1: methanol
3383-96-8: Temephos
14808-60-7: Quartz (SiO2)
61790-53-2: Silicon dioxide
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection not required.
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
General safety and hygiene measures

The statements on personal protective equipment in the instructions for use apply when handling
crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended.
Store work clothing separately. Keep away from food, drink and animal feeding stuffs.
Page: 7/15
(ID no. 30671913/SDS_CPA_00/EN)
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Form: granules
Colour: brown
Odour: of mercaptans
Odour threshold:
Not determined due to potential
health hazard by inhalation.
pH value:
The product has not been tested.
Melting point:
Boiling point:
The product is a non-volatile solid.
Flash point:
not applicable, the product is a solid
Evaporation rate:
not applicable
Flammability: not flammable
Lower explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Upper explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Vapour pressure:
Relative vapour density (air):
not applicable
Solubility in water: not soluble
Partitioning coefficient n-octanol/water (log Kow):
not applicable
Self ignition: Based on its structural properties the
product is not classified as self-
igniting.
Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.

Viscosity, dynamic:
not applicable, the product is a solid
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating
Page: 8/15
(ID no. 30671913/SDS_CPA_00/EN)
Other information
Self heating ability: It is not a substance capable of

spontaneous heating.
Bulk density: 1.200 - 1.520 kg/m3
10. Stability and Reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.
Conditions to avoid
See MSDS section 7 - Handling and storage.
Incompatible materials
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.
11. Toxicological Information

Information on toxicological effects
Acute toxicity
Assessment of acute toxicity:

Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Virtually
nontoxic by inhalation.
Experimental/calculated data:
LD50 rat (oral): > 2.000 mg/kg (OECD Guideline 401)
No mortality was observed.
Page: 9/15
(ID no. 30671913/SDS_CPA_00/EN)
(by inhalation):The product has not been tested. The statement has been derived from the
properties of the individual components.
LD50 rat (dermal): > 2.000 mg/kg (OECD Guideline 402)

No mortality was observed.
Information on: temephos (ISO); Phosphorothioic acid, O,O'-(thiodi-4,1-phenylene) O,O,O',O'-

tetramethyl ester
LC50 rat (by inhalation): > 4,79 mg/l 4 h (OECD Guideline 403)
An aerosol was tested.
----------------------------------
Irritation
Assessment of irritating effects:

Not irritating to the skin. Not irritating to the eyes.
Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)
Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)
Respiratory/Skin sensitization
Assessment of sensitization:
There is no evidence of a skin-sensitizing potential.
Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406)
Germ cell mutagenicity
Assessment of mutagenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. Mutagenicity tests revealed no genotoxic potential.
Carcinogenicity
Assessment of carcinogenicity:
individual components. The results of various animal studies gave no indication of a carcinogenic
effect.
Reproductive toxicity
Assessment of reproduction toxicity:

individual components. The results of animal studies gave no indication of a fertility impairing effect.
Page: 10/15
(ID no. 30671913/SDS_CPA_00/EN)
Developmental toxicity
Assessment of teratogenicity:
individual components. Animal studies gave no indication of a developmental toxic effect at doses
that were not toxic to the parental animals.
Specific target organ toxicity (single exposure)
Assessment of STOT single:

Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.
Remarks: The product has not been tested. The statement has been derived from the properties of
the individual components.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:

individual components.

tetramethyl ester
Assessment of repeated dose toxicity:
Causes mortality and signs of neurotoxicity through prolonged or repeated exposure.
----------------------------------
Aspiration hazard
No aspiration hazard expected.

Other relevant toxicity information
Misuse can be harmful to health.
12. Ecological Information

Toxicity
Assessment of aquatic toxicity:

Very toxic to aquatic life with long lasting effects.
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.
Toxicity to fish:
LC50 (96 h) 5,4 mg/l, Cyprinodon variegatus (Flow through.)
Page: 11/15
(ID no. 30671913/SDS_CPA_00/EN)
Aquatic invertebrates:
EC50 (96 h) 0,014 mg/l, other (Flow through.)
Aquatic plants:
not determined
Persistence and degradability
Assessment biodegradation and elimination (H2O):


tetramethyl ester
Assessment biodegradation and elimination (H2O):
Not readily biodegradable (by OECD criteria).
----------------------------------
Bioaccumulative potential
Assessment bioaccumulation potential:


tetramethyl ester
Bioaccumulation potential:
Bioconcentration factor: 2.300 (28 d), Lepomis macrochirus (other)
Significant accumulation in organisms is not to be expected.
----------------------------------
Mobility in soil
Assessment transport between environmental compartments:

Adsorption in soil: The product has not been tested. The statement has been derived from the
properties of the individual components.

tetramethyl ester
Assessment transport between environmental compartments:
Adsorption in soil: Following exposure to soil, adsorption to solid soil particles is probable, therefore
contamination of groundwater is not expected.
----------------------------------
Results of PBT and vPvB assessment
The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria
or the vPvB (very persistent/very bioaccumulative) criteria.
Page: 12/15
(ID no. 30671913/SDS_CPA_00/EN)
Other adverse effects
The product does not contain substances that are listed in the Montreal Protocol on substances that
deplete the ozone layer.
Additional information
Other ecotoxicological advice:

Do not discharge product into the environment without control.
13. Disposal Considerations
Waste treatment methods
Must be sent to a suitable incineration plant, observing local regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner
as the substance/product.
14. Transport Information
Land transport
ADR
UN number UN3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains TEMEPHOS)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for Tunnel code: E
user:
RID
UN number UN3077
(contains TEMEPHOS)
Packing group: III
Special precautions for None known
user:
Page: 13/15
(ID no. 30671913/SDS_CPA_00/EN)
Inland waterway transport
ADN
UN number UN3077
(contains TEMEPHOS)
Packing group: III
user:
Transport in inland waterway vessel

Not evaluated
Sea transport
IMDG
UN number: UN 3077
(contains TEMEPHOS)
Packing group: III
Marine pollutant: YES
user:
Air transport
IATA/ICAO
UN number: UN 3077
(contains TEMEPHOS)
Packing group: III
user:
UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.
UN proper shipping name

Page: 14/15
(ID no. 30671913/SDS_CPA_00/EN)
See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.
Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.
Packing group
See corresponding entries for “Packing group” for the respective regulations in the tables above.
Environmental hazards
See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.
Special precautions for user

See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.
Transport in bulk according to Annex II of MARPOL and the IBC Code

Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
15. Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or
mixture
To avoid risks to man and the environment, comply with the instructions for use.
16. Other Information
Full text of classifications, hazard symbols and hazard statements, if mentioned in section 2 or 3:
STOT RE Specific target organ toxicity — repeated exposure
Aquatic Acute Hazardous to the aquatic environment - acute
Aquatic Chronic Hazardous to the aquatic environment - chronic
Acute Tox. Acute toxicity
Flam. Liq. Flammable liquids
STOT SE Specific target organ toxicity — single exposure
Skin Corr./Irrit. Skin corrosion/irritation
Eye Dam./Irrit. Serious eye damage/eye irritation
H313 May be harmful in contact with skin.
H332 Harmful if inhaled.
H303 May be harmful if swallowed.
Page: 15/15
(ID no. 30671913/SDS_CPA_00/EN)
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H225 Highly flammable liquid and vapour.
H311 Toxic in contact with skin.
H331 Toxic if inhaled.
H301 Toxic if swallowed.
H370 Causes damage to organs (Central nervous system, Optic nerve).
H318 Causes serious eye damage.
H315 Causes skin irritation.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.
Lembaran Data Keselamatan Bahan
Halaman: 1/12
PT BASF Indonesia Lembaran Data Keselamatan Bahan
Tanggal / Direvisi: 25.04.2017 Versi: 4.0
Produk: Abate 1 GR
(30671913/SDS_CPA_ID/ID)
Tanggal dicetak 23.01.2018
1. Zat/bahan olahan dan nama perusahaan
Abate 1 GR
Penggunaan: produk untuk melindungi tanaman, insektisida
Perusahaan:
PT BASF Indonesia
DBS Bank Tower, 27th Floor, Ciputra World 1 Jakarta, Jl. Prof. Dr. Satrio Kav 3 - 5
Jakarta 12940, INDONESIA
Telepon: +62 21 2988 6000
Nomer fax: +62 21 2988 5930
Informasi darurat:
+62 21 5437 1979
International emergency number:
Telepon: +49 180 2273-112
2. Identifikasi bahaya
Klasifikasi dari zat tunggal dan campuran:

STOT paparan berulang.: Kat. 2
Berbahaya terhadap lingkungan perairan - akut: Kat. 1
Berbahaya terhadap lingkungan perairan - kronis: Kat. 1
Elemen label dan pernyataan kehati-hatian:
Piktogram:
Kata Sinyal:
Halaman: 2/12
Produk: Abate 1 GR
Peringatan
Pernyataan Bahaya:
Dapat menyebabkan kerusakan organ melalui paparan dalam jangka waktu yang lama atau
berulang. Sangat beracun terhadap biota perairan. Sangat beracun terhadap biota perairan dengan
efek selamanya.
Pernyataan kehati-hatian:
Jika memerlukan bantuan medis, bawa wadah produk atau labelnya. Jauhkan dari jangkauan anak-
anak. Baca label sebelum menggunakan.
Pernyataan Kehati-hatian (Pencegahan):

Jangan hirup debu.
Pernyataan Kehati-hatian (Respon):

Dapatkan saran/petunjuk dokter jika merasa kurang sehat. Kumpulkan tumpahan.
Pernyataan Kehati-hatian (Pembuangan):

Buang isinya/kontainernya ke lokasi pembuangan sampah berbahaya atau yang khusus.
Bahaya lainnya yang tidak mempengaruhi klasifikasi:

Lihat bagian 12 - Hasil dari pengujian PBT dan vPvB.
Jika terdapat informasi yang berkaitan tentang bahaya lain yang tidak memiliki klasifikasi tetapi
dapat memberikan kontribusi pada bahaya keseluruhan dari bahan atau campuran, akan disediakan
dalam bagian ini.
3. Komposisi/informasi ingredien
Sifat kimia
produk untuk melindungi tanaman, insektisida, Butiran (granul)
Ingredien yang berbahaya
Phosphorothioic acid, O,O'-(thiodi-4,1-phenylene) O,O,O',O'-tetramethyl ester

Kadar (berat/berat): 1 % Acute Tox.: Kat. 4 (terhirup - uap)
Nomer CAS: 3383-96-8 Acute Tox.: Kat. 5 (oral)
Acute Tox.: Kat. 5 (dermal)
STOT RE: Kat. 1
Aquatic Acute: Kat. 1
Aquatic Chronic: Kat. 1
methanol
Kadar (berat/berat): < 1 % Flam. Liq.: Kat. 2
Nomer CAS: 67-56-1 Acute Tox.: Kat. 3 (terhirup - uap)
Acute Tox.: Kat. 3 (oral)
Acute Tox.: Kat. 3 (dermal)
STOT SE (Sistem syaraf pusat, syaraf optik):
Kat. 1
Calcium dodecylbenzenesulphonate
Halaman: 3/12
Produk: Abate 1 GR
Kadar (berat/berat): < 1 % Skin Corr./Irrit.: Kat. 2
Nomer CAS: 26264-06-2 Eye Dam./Irrit.: Kat. 1
Quartz (SiO2)
Kadar (berat/berat): < 100 %
Nomer CAS: 14808-60-7
Kieselguhr
Kadar (berat/berat): < 5 %
Nomer CAS: 61790-53-2
4. Tindakan pertolongan pertama
Petunjuk umum:
Lepaskan pakaian yang terkontaminasi.
Jika terhirup:
Jaga korban tetap tenang, pindahkan ke tempat yang berudara segar, cari bantuan medis.
Jika kontak dengan kulit:

Cuci yang bersih dengan sabun dan air.
Jika kontak dengan mata:

Bersihkan mata yang terkena minimal selama 15 menit pada air yang mengalir dengan kelopak mata
terbuka.
Jika tertelan:
Segera berkumur dan kemudian minum air 200 - 300 ml, cari bantuan medis.
Catatan untuk dokter:

Gejala: Gejala dan akibat yang terpenting dijelaskan di label (lihat bagian 2) dan atau bagian 11,
Gejala dan akibat lebih lanjut sejauh ini tidak diketahui
Perawatan: Rawat sesuai dengan gejalanya (dekontaminasi, fungsi vital), antidot yang spesifik tidak
diketahui.
5. Tindakan pemadaman kebakaran
Media pemadam kebakaran yang sesuai:

semprotan air, busa, serbuk kering
Media pemadam kebakaran yang tidak sesuai karena alasan keselamatan:

karbon dioksida
Bahaya yang spesifik:

carbon monoxide, carbon dioxide, oksida-oksida sulfur, oksida-oksida fosfor
Zat/gugus fungsi dari zat tersebut dapat dilepaskan jika terjadi kebakaran.
Peralatan pelindung khusus:

Gunakan alat bantu pernapasan dan pakaian pengaman yang tahan bahan kimia.
Halaman: 4/12
Produk: Abate 1 GR
Informasi lebih lanjut:
Kumpulkan air yang digunakan memadamkan kebakaran yang terkontaminasi secara terpisah,
jangan sampai masuk ke sampah atau saluran limbah. Buang puing-puing kebakaran dan air
pemadam kebakaran yang terkontaminasi sesuai dengan peraturan pemerintah setempat. Jika
terjadi kebakaran dan/atau ledakan jangan menghirup asapnya. Jaga kontainer tetap dingin dengan
disemprot air jika terpapar oleh api.
6. Tindakan penanggulangan kecelakaan
Tindakan pencegahan diri:

Hindari terbentuknya debu. Gunakan alat pelindung diri. Hindari kontak dengan kulit, mata dan
pakaian.
Tindakan pencegahan terhadap lingkungan:

Jangan membuang pada saluran air/air permukaan/air tanah. Jangan membuang ke tanah.
Metoda pembersihan atau pengambilan:

Untuk jumlah yang sedikit: Serap dengan material yang dapat mengikat debu dan kemudian
dibuang.
Untuk jumlah yang banyak: Disapu/disekop.
Hindari terbentuknya debu. Buang material yang terserap sesuai dengan peraturan pemerintah yang
berlaku. Kumpulkan limbah dalam kontainer yang sesuai, yang dapat diberi label dan ditutup.
Bersihkan lantai dan objek yang terkontaminasi dengan air dan deterjen, perhatikan peraturan
mengenai lingkungan.
7. Penanganan dan penyimpanan
Penanganan
Tidak perlu perlakuan khusus jika disimpan dan ditangani dengan benar. Pastikan ventilasi yang
baik pada area penyimpanan dan area kerja. Saat menggunakan produk ini, jangan makan, minum
atau merokok. Tangan dan/atau wajah harus dibersihkan sebelum istirahat dan pada akhir shift.
Perlindungan terhadap kebakaran dan ledakan:

Hindari terbentuknya debu. Debu dapat membentuk campuran yang mudah meledak dengan udara.
Cegah adanya muatan listrik statis - jauhkan dari sumber-sumber nyala - alat pemadam api ringan
harus mudah dijangkau.
Penyimpanan
Pisahkan dari makanan dan pakan ternak.
Informasi lebih lanjut mengenai kondisi penyimpanan: Jauhkan dari panas. Hindari dari kelembaban.
Lindungi dari sinar matahari langsung.
Kestabilan penyimpanan:
Lama waktu penyimpanan: 24 bulan
8. Pengawasan paparan dan perlindungan diri
Komponen dengan batas pajanan kerja

Halaman: 5/12
Produk: Abate 1 GR
methanol, 67-56-1;
Penandaan pada kulit (ACGIH-Nilai Ambang Batas)
Zat ini dapat diadsorb melalui kulit.
Nilai STEL 250 ppm (ACGIH-Nilai Ambang Batas)
Nilai TWA 200 ppm (ACGIH-Nilai Ambang Batas)
Penandaan pada kulit (OEL (ID))
Nilai TWA 200 ppm (OEL (ID))
Nilai STEL 250 ppm (OEL (ID))
temephos, 3383-96-8;
Nilai TWA 1 mg/m3 (ACGIH-Nilai Ambang Batas), Fraksi dan uap yang dapat
terhirup.
Penandaan pada kulit (ACGIH-Nilai Ambang Batas), Fraksi dan uap yang
dapat terhirup.
Nilai TWA 10 mg/m3 (OEL (ID))
Quartz (SiO2), 14808-60-7;

Nilai TWA 0.025 mg/m3 (ACGIH-Nilai Ambang Batas), Fraksi yang dapat
terhirup
Nilai TWA 0.1 mg/m3 (OEL (ID)), Partikel yang dapat terhirup
Kieselguhr, 61790-53-2;
Nilai TWA 10 mg/m3 (OEL (ID)), Partikel yang dapat terhirup
Nilai partikulat yang tidak mengandung asbes dan < 1% silika kristalin.
Nilai TWA 3 mg/m3 (OEL (ID)), Partikel yang dapat terhirup
Nilai partikulat yang tidak mengandung asbes dan < 1% silika kristalin.
Alat pelindung diri

Pelindung pernapasan:
Tidak dibutuhkan pelindung pernapasan
Pelindung tangan:
Sarung tangan yang tahan terhadap bahan kimia (EN 374) untuk kontak yang langsung dan jangka
waktu yang lama (Direkomendasikan: Protective index 6: menunjukkan waktu permeasi berdasarkan
EN 374 >480 menit): misalnya karet nitril (0,4 mm), karet kloroprene (0,5 mm), karet butil (0,7 mm)
dan yang lainnya.
Pelindung mata:
Kacamata pengaman dengan pelindung samping (frame goggle)(EN 166)
Pelindung tubuh:
Pelindung tubuh harus dipilih berdasarkan pada aktivitas dan kemungkinan paparan, misalnya:
apron, sepatu boot pengaman, pakaian pengaman dari bahan kimia (yang berdasarkan pada EN
14605 untuk percikan atau EN ISO 13982 untuk debu).
Tindakan umum untuk keselamatan dan higien:

Pernyataan mengenai alat pelindung diri dalam instruksi penggunaan berlaku saat menangani
bahan pelindung tanaman dalam kemasan untuk pemakai. Direkomendasikan menggunakan
Halaman: 6/12
Produk: Abate 1 GR
pakaian kerja tertutup. Simpan pakaian kerja secara terpisah. Jauhkan dari makanan, minuman dan
bahan-bahan pakan ternak.
9. Sifat fisika dan kimia
Bentuk: granula
Warna: coklat
Bau: dari merkaptan
Batas bau: Tidak ditentukan karena berpotensi membahayakan kesehatan jika
terhirup.
pH:
Produk ini belum pernah diuji.
Titik leleh:
Titik didih:
Produk merupakan padatan yang
tidak mudah menguap.
Titik nyala:
Tidak berlaku, produk adalah
padatan.
Laju penguapan:
Tidak berlaku
Kemudahan terbakar (padat/gas): tidak menyala

Batas bawah ledakan:
Berdasarkan pada pengalaman kami
dengan produk ini dan pada
pengetahuan kami mengenai
komposisinya, produk ini tidak
berbahaya selama digunakan
dengan tepat dan sesuai dengan
tujuan penggunaan produk ini.
Batas atas ledakan:
Berdasarkan pada pengalaman kami
dengan produk ini dan pada
pengetahuan kami mengenai
komposisinya, produk ini tidak
berbahaya selama digunakan
dengan tepat dan sesuai dengan
tujuan penggunaan produk ini.
Dekomposisi thermal: Tidak terjadi dekomposisi jika

disimpan dan ditangani sesuai
dengan anjuran.
Menyala sendiri: Berdasarkan pada sifat strukturnya,
produk ini tidak diklasifikasikan
sebagai produk yang dapat menyala
sendiri.
Halaman: 7/12
Produk: Abate 1 GR
Kemampuan untuk memanaskan sendiri: Zat ini tidak
bisa mengalami pemanasan yang
spontan.
Bahaya ledakan: tidak mudah meledak

Sifat yang dapat membantu kebakaran: tidak menyebabkan
penjalaran api
Tekanan uap:
Massa jenis (bulk): 1,200 - 1,520 kg/m3

Massa jenis uap relatif (udara):
Tidak berlaku
Kelarutan dalam air: tidak dapat larut

Koefisien distribusi n-oktanol/air (log Pow):
Tidak berlaku
Viskositas, dinamis:
Tidak berlaku, produk adalah
padatan.
10. Stabilitas dan reaktivitas

Kondisi yang harus dihindari:
Lihat MSDS bab 7 - Penanganan dan penyimpanan
Dekomposisi thermal: Tidak terjadi dekomposisi jika disimpan dan ditangani sesuai
dengan anjuran.
Zat yang harus dihindari:

asam kuat, basa kuat, oksidator kuat
Reaksi berbahaya:
Tidak terjadi reaksi yang berbahaya jika disimpan dan ditangani sesuai dengan anjuran.
Produk hasil dekomposisi yang berbahaya:

Tidak ada produk hasil dekomposisi yang berbahaya jika disimpan dan ditangani sesuai dengan
yang disarankan.
11. Informasi mengenai toksikologi
Toksisitas akut
Penilaian toksisitas akut:

Sama sekali tidak beracun setelah menelan sekali. Sebenarnya tidak beracun setelah kontak
tunggal dengan kulit. Sama sekali tidak beracun jika terhirup.
Data percobaan/perhitungan:
LD50 tikus (oral): > 2,000 mg/kg (OECD Guideline 401)
Halaman: 8/12
Produk: Abate 1 GR
Tidak ada kematian yang teramati.
(terhirup):Produk belum pernah diuji. Pernyataan ini diturunkan dari sifat-sifat masing-masing
komponennya.
LD50 tikus (kulit): > 2,000 mg/kg (OECD Guideline 402)

Tidak ada kematian yang teramati.
Informasi pada: Phosphorothioic acid, O,O'-(thiodi-4,1-phenylene) O,O,O',O'-tetramethyl ester

LC50 tikus (terhirup): > 4.79 mg/l 4 h (OECD Guideline 403)
Aerosolnya tidak diuji.
----------------------------------
Iritasi
Penilaian mengenai efek iritasi.:

Tidak bersifat iritasi terhadap kulit. Tidak bersifat iritasi terhadap mata.
Korosi/iritasi kulit kelinci: (OECD Guideline 404)
Kerusakan/iritasi mata yang serius kelinci: (OECD Guideline 405)
Sensitisasi pernapasan/kulit
Penilaian mengenai sensitasi:

Tidak ada bukti yang berpotensi menyebabkan sensitisasi kulit.
Guinea pig maximization test marmot: (OECD Guideline 406)
Mutagenisitas Sel Induk
Penilaian mengenai mutagenisitas:

Produk belum pernah diuji. Pernyataan ini diturunkan dari sifat-sifat masing-masing komponennya.
Uji mutagenisitas menunjukkan tidak berpotensi genotoksik.
Karsinogenisitas
Penilaian mengenai karsinogenisitas:

Hasil dari studi dengan berbagai binatang tidak memberikan indikasi adanya efek karsinogenik.
Toksisitas reproduksi
Penilaian terhadap toksisitas reproduksi:

Hasil studi dengan binatang tidak menunjukkan efek merusak kesuburan.
Peningkatan toksisitas
Penilaian terhadap teratogenisitas:

Halaman: 9/12
Produk: Abate 1 GR
Studi dengan binatang tidak menunjukkan efek yang merusak kesuburan pada dosis dimana dosis
tersebut tidak beracun terhadap induk binatang.
Toksisitas organ target yang spesifik (paparan tunggal):
Penilaian mengenai STOT tunggal:

Berdasarkan pada informasi yang ada, diharapkan tidak terjadi toksisitas pada target organ spesifik
setelah paparan tunggal.
Catatan: Produk belum pernah diuji. Pernyataan ini diturunkan dari sifat-sifat masing-masing
komponennya.
Toksisitas dengan dosis berulang dan Toksisitas terhadap Organ Sasaran Spesifik
(paparan berulang)
Penilaian mengenai dosis toksisitas yang diulang:


Penilaian mengenai dosis toksisitas yang diulang:
Menyebabkan kematian dan tanda-tanda keracunan saraf melalui paparan berulang atau yang
berkepanjangan.
----------------------------------
Bahaya jika terhirup
Tidak diharapkan ada bahaya pernapasan.

Informasi toksisitas lainnya yang relevan
Penggunaan yang salah dapat membahayakan kesehatan.
12. Informasi mengenai ekologi
Ekotoksisitas
Penilaian mengenai toksisitas perairan:

Sangat beracun terhadap biota perairan dengan efek selamanya.
Produk ini belum diuji. Pernyataan ini berasal dari senyawa/produk yang memiliki kemiripan struktur
atau komposisi.
Toksisitas terhadap ikan:

LC50 (96 h) 5.4 mg/l, Cyprinodon variegatus (dialirkan.)
Binatang air yang tidak bertulang belakang:

EC50 (96 h) 0.014 mg/l, lainnya (dialirkan.)
Tumbuhan air:
tidak ditentukan
Halaman: 10/12
Produk: Abate 1 GR
Mobilitas
Analisa transport antar kompartemen-kompartemen lingkungan.:


Analisa transport antar kompartemen-kompartemen lingkungan.:
Setelah paparan ke tanah, adsorpsi ke dalam partikel tanah dimungkinkan, oleh karena itu tidak
diharapkan terjadinya kontaminasi terhadap air tanah.
----------------------------------
Ketahanan dan kemampuan terurai
Penilaian biodegradasi dan pemusnahan (H2O):


Penilaian biodegradasi dan pemusnahan (H2O):
Tidak langsung dapat diurai oleh bakteri (kriteria OECD).
----------------------------------
Berpotensi bio-akumulasi
Evaluasi potensi bioakumulasi.:


Berpotensi bio-akumulasi:
Faktor biokonsentrasi: 2,300 (28 hari), Lepomis macrochirus (lainnya)
Akumulasi yang signifikan dalam organisme tidak diharapkan.
----------------------------------
Informasi tambahan
Petunjuk mengenai ekotoksikologi lainnya:

Jangan membuang produk ke lingkungan tanpa kontrol.
13. Pertimbangan pembuangan
Harus dibakar di unit incinerator yang sesuai, perhatikan peraturan pemerintah yang berlaku.
Kemasan yang terkontaminasi:

Kemasan yang terkontaminasi harus sebisa mungkin dikosongkan dan dibuang dengan cara yang
sama dengan zat/produknya.
14. Informasi transportasi

Transportasi domestik:
Kelas bahaya: 9
'Packaging group': III
No. Identifikasi: UN 3077
Halaman: 11/12
Produk: Abate 1 GR
Label bahaya: 9, EHSM
'Proper shipping name': ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(mengandung TEMEPHOS)
Transportasi laut Sea transport

IMDG IMDG
Kelas bahaya: 9 Hazard class: 9
'Packaging group': III Packing group: III
No. Identifikasi: UN 3077 ID number: UN 3077
Label bahaya: 9, EHSM Hazard label: 9, EHSM
Polutan perairan laut: YA Marine pollutant: YES
'Proper shipping name': Proper shipping name:
ENVIRONMENTALLY HAZARDOUS ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S. (mengandung SUBSTANCE, SOLID, N.O.S. (contains
TEMEPHOS) TEMEPHOS)
Transportasi udara Air transport

IATA/ICAO IATA/ICAO
Kelas bahaya: 9 Hazard class: 9
'Packaging group': III Packing group: III
No. Identifikasi: UN 3077 ID number: UN 3077
Label bahaya: 9, EHSM Hazard label: 9, EHSM
'Proper shipping name': Proper shipping name:
ENVIRONMENTALLY HAZARDOUS ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S. (mengandung SUBSTANCE, SOLID, N.O.S. (contains
TEMEPHOS) TEMEPHOS)
15. Informasi peraturan
Komponen penentu bahaya untuk pemberian label: temephos
Regulasi lainnya
Untuk menghindari risiko terhadap orang dan lingkungan, patuhi instruksi penggunaannya.
16. Informasi lainnya
Garis vertikal di margin sebelah kanan menunjukkan perubahan dari versi sebelumnya.
Halaman: 12/12
Produk: Abate 1 GR
Data yang tercantum dalam Lembaran Data Keselamatan Bahan didasarkan pada pengetahuan terkini
kami dan pengalaman dan menggambarkan produk hanya berkaitan dengan persyaratan keselamatan.
Lembaran Data Keselamatan Bahan ini bukan merupakan Certificate of Analysis (CoA) atau Lembaran
Data Teknis dan jangan disalah artikan sebagai perjanjian spesifikasi. Penggunaan yang tercantum
dalam Lembaran Data Keselamatan Bahan ini tidak mewakili kesepakatan pada kualitas bahan /
campuran atau penggunaan yang tercantum sesuai dalam kontrak. Ini adalah tanggung jawab penerima
produk untuk memastikan hak-hak kepemilikan dan mengamati hukum yang ada dan undang-undang
yang berlaku.

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In accordance with the Decree of the Minister of Agriculture number

We hereby certify that :

Company name : PT BASF Indonesia

Is recognized as the registration holder of the following product :

Trade name : ABATE 1 GR

The product mentioned above is offically registered.

Expiry: 18 October 2021 Jakarta, 9 November 2016

Dr. Ir. Muhrizal Sarwani, MSc

Relevant identified uses: crop protection product, insecticide

Details of the supplier of the safety data sheet

Telephone: +62 21 2988 6000

Emergency telephone number

International emergency number:

Classification of the substance or mixture

According to UN GHS criteria

Globally Harmonized System (GHS)

Precautionary Statements (Prevention):

Precautionary Statements (Response):

Precautionary Statements (Disposal):

According to UN GHS criteria

Hazard determining component(s) for labelling: TEMEPHOS

According to UN GHS criteria

See section 12 - Results of PBT and vPvB assessment.

crop protection product, insecticide, Granule (GR)

Hazardous ingredients (GHS)

temephos (ISO); Phosphorothioic acid, O,O'-(thiodi-4,1-phenylene) O,O,O',O'-tetramethyl ester

Specific concentration limit:

On contact with eyes:

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed

Unsuitable extinguishing media for safety reasons:

Special hazards arising from the substance or mixture

Advice for fire-fighters

6. Accidental Release Measures

Methods and material for containment and cleaning up

Reference to other sections

7. Handling and Storage

Protection against fire and explosion:

Conditions for safe storage, including any incompatibilities

Specific end use(s)

8. Exposure Controls/Personal Protection

Components with occupational exposure limits

General safety and hygiene measures

Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.

Self heating ability: It is not a substance capable of

Bulk density: 1.200 - 1.520 kg/m3

10. Stability and Reactivity

Possibility of hazardous reactions

Hazardous decomposition products

Hazardous decomposition products:

11. Toxicological Information

Assessment of acute toxicity:

LD50 rat (dermal): > 2.000 mg/kg (OECD Guideline 402)

Information on: temephos (ISO); Phosphorothioic acid, O,O'-(thiodi-4,1-phenylene) O,O,O',O'-

Assessment of irritating effects:

Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)