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Petrographic and Chemical Characterisation of Fine Ware From Three Archaic and Hellenistic Kilns in Gela, Sicily
Petrographic and Chemical Characterisation of Fine Ware From Three Archaic and Hellenistic Kilns in Gela, Sicily
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Case study
Petrographic and chemical characterisation of fine ware from three Archaic and
Hellenistic kilns in Gela, Sicily
Erica Aquilia a , Germana Barone a , Paolo Mazzoleni a,∗ , Caterina Ingoglia b
a
Dipartimento di Scienze Biologiche, Geologiche ed Ambientali, Università degli Studi di Catania, Corso Italia 57, 95129, Catania, Italy
b
Dipartimento di Scienze dell’Antichità, Università degli Studi di Messina, Messina, Italy
a r t i c l e i n f o a b s t r a c t
Article history: This work is focused on the petro-archeometric characterization of the fine pottery production of the
Received 3 November 2011 archaeological site of Gela (Sicily). Thirty-five samples coming from three Archaic and Hellenistic kilns
Accepted 14 February 2012 and five coming from an Hellenistic house, were investigated by means of optical microscopy, XRD and
Available online 16 March 2012
XRF analysis. With the exception of some ceramics which are undoubtedly imported, all the samples have
similar petrographic features, but on the basis of chemical composition, we can distinguish two different
Keywords: groups. The presence of two local productions is confirmed by the comparison with locally outcropping
Fine pottery
sediments and with archaic and modern bricks of sure Geloan production. This result is particularly
Gela
Petrographic-chemical analysis
significant for the definition of reference groups of this wealthy polis that played an important trading
Reference group role in the Mediterranean area.
Multivariate statistics © 2012 Elsevier Masson SAS. All rights reserved.
1. Research aims and wealthy polis, with prosperous agricultural and commercial
activities thank to the fertile hinterland and the optimal geograph-
This study is aimed to the characterisation of the Geloan fine ical location. From the geological point of view in the area of the
ware production in Archaic and Hellenistic period through petro- ancient polis the terrains are mainly formed by sands and clays
graphic and geochemical analyses. The approach used in order to belonging to the Mt. St. Giorgio marly clays Formation and to
define the local productions is based on the comparison with litera- the Caltagirone Sands Formation, both belonging to Selinuntian
ture data of reference materials such as clayey sediments cropping (Lower Pleistocene) [5]. The archaeological excavations, conducted
out near the ancient city and locally manufactured bricks. The throughout the 20th century [6–8], discovered numerous ceramic
results obtained allow to expand the existing database of ceramic wares that, on the basis of the stylistic and typological examina-
materials for studies of Sicilian ceramics and to contribute to the tion, were ascribed to the local craftsmen and, to a lesser degree,
study of the provenance of findings of uncertain productions as well to importations attesting lively economic and cultural contacts. Up
as the material recovered in the shipwrecks found in the western to now, the previous studies on the Geloan pottery concerning the
and central Mediterranean. definition of the provenance, with rare exceptions concerning the
amphorae productions [1,9–11], have been confined to the descrip-
2. Experimental tion of the artefacts on the basis of the stylistic and autoptic analysis
[6–8,12].
2.1. Introduction
2.2. Materials
This work is part of an archaeometric research on the Sicilian
ceramic productions during the Greek and Roman periods [1–4]. A set of 40 fine ceramics fragments, belonging to different
In particular this paper focuses on the compositional characteri- archaeological typologies were analyzed. These samples were
sation of the fine potteries found during the excavations of three recovered from Gela during the excavations of three kilns located
Archaic and Hellenistic kilns located in Gela. The town of Gela was in Via Bonanno [7], Via Dalmazia [6], and near the Church of S.
founded in 688 B.C. by Rhodian and Cretan colonists on the south- Giacomo [8], hereafter referred to as VB, VD and SG respectively.
ern coast of Sicily and destroyed in 282 B.C. It was an important The ceramist workshops of VB and VD are ascribable to the 7th
to 6th B.C while the kiln in SG is dated late 4th to early 3th B. C.
Furthermore we analysed the Hellenistic pottery (five samples)
∗ Corresponding author. Tel.: +39 09 57 19 57 44; fax: +39 09 57 19 57 60. found in one of via Meli’s dwellings (VM). These archaeological
E-mail address: pmazzol@unict.it (P. Mazzoleni). finds are particularly important since they testify a rich ceramic
1296-2074/$ – see front matter © 2012 Elsevier Masson SAS. All rights reserved.
doi:10.1016/j.culher.2012.02.005
E. Aquilia et al. / Journal of Cultural Heritage 13 (2012) 442–447 443
Table 1
Concentrations of major elements (wt%) and trace elements (ppm) by XRF analysis of studied potteries of which the typology and munsell index are described. The average
data of reference materials are reported (see text for details and references).
Typology Munsell colour SiO2 TiO2 Al2 O3 Fe2 O3 MnO MgO CaO Na2 O K2 O P2 O5 Sr
Via Meli
G36 Black-glazed skyphos 2.5YR6/6 60.68 0.74 13.40 5.77 0.08 2.10 14.02 0.82 2.15 0.23 459.9
G37 Black-glazed skyphos 2.5YR6/6 61.27 0.76 13.97 5.94 0.08 1.87 12.75 0.81 2.21 0.34 499.9
G38 Coarse vase 7.5YR8/3 55.73 0.93 17.00 8.98 0.13 5.81 7.28 0.77 3.23 0.15 249.4
G39 Black-glazed skyphos 2.5YR6/6 57.46 0.96 17.72 8.71 0.12 5.37 5.30 0.75 3.34 0.27 128.3
G40 Black-glazed skyphos 2.5YR6/6 58.12 0.83 17.04 6.97 0.11 7.05 6.12 0.76 2.88 0.12 59.5
Reference material
Clay sediments (Gela) Xmed (12) 60.22 0.69 13.97 4.75 0.07 1.83 15.64 0.58 2.05 0.20 380.11
Modern bricks (Gela) Xmed (6) 60.53 0.65 12.99 5.21 0.07 2.62 14.58 1.14 2.01 0.20 411.67
Archaic mud bricks (Bosco Littorio) Xmed (7) 65.11 1.24 13.16 11.04 0.12 3.29 3.61 0.88 2.28 0.15 293.44
Typology V Cr Co Ni Zn Rb Y Zr Nb Ba La Ce
Table 1 (Continued)
Typology V Cr Co Ni Zn Rb Y Zr Nb Ba La Ce
GE9 Dinos of sub-geometric 70.04 78.85 24.95 45.22 81.92 60.81 14.50 159.36 2.51 298.81 33.72 70.73
style
GE10 Trefoil-mouthed 89.99 92.49 23.54 48.84 72.13 64.12 14.77 151.45 3.95 308.21 41.96 72.55
oinochoe
GE11 Closed vase of 80.21 85.44 23.84 47.10 74.30 70.53 16.31 184.77 4.74 354.29 30.05 78.04
subgeometric style
GE12 Black-glazed kotyle 51.86 79.13 15.13 49.63 61.20 27.51 5.59 61.25 - 277.52 28.75 48.32
GE13 Cup with polished 61.52 388.54 32.76 219.92 211.38 48.82 4.20 29.86 – 509.77 23.60 27.14
surface
GE14 Closed vase of 84.18 90.01 27.61 46.57 93.50 71.49 15.57 157.45 6.03 416.09 41.50 81.23
subgeometric style
GE15 Cup of subgeometric 73.22 77.85 19.58 44.77 129.37 48.24 11.68 134.23 2.03 412.11 25.45 77.70
style
GE16 A filetti kotyle 52.91 137.15 – 138.12 57.81 65.25 4.66 37.41 – 385.64 18.92 29.78
GE34 Kotyle of subgeometric 77.05 82.44 25.20 42.69 73.54 76.66 24.15 207.13 9.50 267.77 32.13 66.64
style
GE35 Closed vase of 77.92 91.33 26.91 44.13 67.29 75.12 22.15 184.50 7.27 308.78 32.50 92.95
subgeometric style
(corinthian imitation)
GE36 Protocorinthian kotyle 22.85 58.06 6.37 76.21 13.22 6.56 1.00 4.47 – 250.80 0.41 1.18
Via Meli
G36 Black-glazed skyphos 52.6 73.8 20.3 35.8 43.4 67.6 27.0 243.1 14.2 344.8 29.9 56.6
G37 Black-glazed skyphos 51.2 72.9 19.9 33.5 42.8 69.0 26.7 232.5 14.9 430.5 30.8 69.1
G38 Coarse vase 64.7 486.1 46.7 336.9 63.1 117.3 25.8 110.4 7.8 426.8 26.8 64.4
G39 Black-glazed skyphos 54.3 373.2 31.9 249.5 50.0 63.1 4.8 64.9 – 420.5 24.1 49.4
G40 Black-glazed skyphos 22.5 186.7 12.5 132.3 19.5 14.6 1.9 17.2 – 184.5 9.3 36.9
Reference material
Clay sediments (Gela) Xmed (12) 58.25 68.14 19.19 29.13 52.23 55.43 18.03 162.99 9.88 258.10 27.01 54.63
Modern bricks (Gela) Xmed (6) 76.59 84.21 25.11 42.42 70.95 70.89 29.75 249.64 12.27 553.27 34.70 72.20
Archaic mud bricks Xmed (7) 24.22 32.06 10.84 19.69 25.01 29.66 17.38 305.70 4.04 569.96 16.66 40.58
(Bosco Littorio)
production in Gela during the investigated period. The mere find- the studied ceramics were compared with literature reference data
ing of ceramics in a kiln dump is generally considered sufficient in from Gela [11] of which the average chemical data are reported in
order to ascribe the pottery to the local production. However, the Table 1:
ceramics from VD kiln are kept in the Gela’s Museum without any
reference to the archaeological layer in which they were found.
The typology and the Munsell colours of the ceramics grouped • mud-bricks of the Archaic Bosco Littorio wall;
according to the founding site are reported in Table 1 . In order • modern bricks actually produced in Gela;
to determine the site of their production, the data obtained on • fourteen clay samples cropping out in the Gela territory.
E. Aquilia et al. / Journal of Cultural Heritage 13 (2012) 442–447 445
Fig. 1. Representative photomicrographs of the studied sherds (crossed nicols): a) sample GE14; b) sample GE8; c) sample GE13; d) sample GE21.
2.4.1. Petrographic and mineralogical analysis • grain size distribution: prevalently unimodal;
All the studied ceramics have fine paste and similar petrographic • inclusions–common: polycrystalline and monocrystalline
characteristics with low amount of inclusions and belong to a quartz; scarce: k-feldspar, plagioclase; rare: fragments of
unique fabric named “dominant quartz and rare feldspars” that, volcanic rocks and volcanic glass (GE25); rare: chert (GE10).
on the basis of the groundmass features may be moreover subdi-
vided (Fig. 1). The petrographic description of the fabric is reported ACF:
below:
Fabric with dominant quartz and rare feldspars: • all thin sections show two ACF types: some of these have irregular
shape, medium size and reddish- blackish colour while the other
• fossiliferous groundmass: GE14 (VB); show smaller size and are characterized to strongly red colour.
• fossiliferous and micaceous groundmass: GE8, 10, 11 (VB), GE25,
Finally, with the aim to give information about the techno-
27 (VD), G34 (SG) and G36 (VM);
• micaceous and rarely fossiliferous groundmass: GE9-13 (VB); logical process and, in particular, on the firing temperatures, the
mineralogical analysis (XRD) were carried out on ten samples con-
GE16, 19, 21, 22 and 29 (VD);
• micaceous groundmass: G38, 39 and G40 (VM). sidered representative of the three studied kilns. The presence of
new formed Ca-silicates-(diopside, gehlenite and anorthite) and
the absence of calcite and clay minerals in all analyzed pottery
Microstructure: indicate high firing temperatures (> 900–950 ◦ C) [14].
• common vughy and vesicles (from 5% to 30%); dimensions range 2.4.2. Chemical analysis
from micro (< 0.05 mm) to meso voids (0.05–0.5 mm); Table 1 shows the chemical composition of the studied ceram-
• spatial distribution: from single space to open; c) preferential ics and the average compositions of reference materials [11]. First
orientation: sometime due to linear vughy. of all, the samples GE13, GE21 and G38 and G39 are considered
446 E. Aquilia et al. / Journal of Cultural Heritage 13 (2012) 442–447
Fig. 3. Biplot of the two first principal components employing major and trace ele-
ments, constructed using the log-ratio (clr) transformed data. Gray area = Archaic
mud bricks Bosco Littorio, light gray area = modern bricks, dark gray = clay sedi-
ments.
clays and the local modern bricks while most of VD products are
plotted near the field of the Archaic mud bricks of Bosco Littorio
wall [11].
3. Conclusions
[8] D. Adamesteanu, Uno scarico di fornace ellenistica a Gela, Archeologia Classica [13] I.K. Whitbread, Greek transport amphorae: a petrological and Archaeological
VI (1956) 129–132. study. Occasional Paper 4, The British School at Athens, Fitch Laboratory, 1995.
[9] S. Giunta, Lo scarico della fornace ellenistica di S. Giacomo a Gela: dati pre- [14] G. Barone, L. Bartoli, C.M. Belfiore, V. Crupi, F. Longo, D. Majolino, P. Mazzoleni,
liminari e prospettive della ricerca, Rivista di Studi Liguri LXXXIV (2008) et al., Comparison between TOF-ND and XRD quantitative phase analysis of
147–175. ancient potteries”, J Anal Atom Spectr 26 (2011) 1060–1067.
[10] G. Olcese, Le anfore greco italiche di Ischia: Archeologia e archeometria. Arti- [15] G. Barone, V. Crupi, F. Longo, D. Majolino, P. Mazzoleni, V. Venuti, et al., Poten-
gianato ed economia nel golfo di Napoli, Edizioni Quasar, Bari, 2010, 480. tiality of non destructive XRF analysis for the determination of Corinthian B
[11] G. Barone, P. Mazzoleni, G. Spagnolo, E. Aquilia, The transport amphorae of Gela: amphorae provenance, X-Ray Spectr 40 (2011) 225.
a multidisciplinary study on provenance and technological aspects, J Archaeol [16] J. Aitchison, The statistical analysis of compositional data, Chapman and Hall,
Sci 39 (2012) 11–22. London, UK, 1986.
[12] D. Adamesteanu, Nuovo Municipio Pozzi e cisterne, in Adamesteanu D. Orlan- [17] Thìo-Henestrosa, J.A. Martín-Fernández, Dealing with compositional data: the
dini P Gela. Nuovi Scavi, Notizie degli Scavi, 1960, 116–18. freeware CoDaPack, Math Geol 37 (7) (2005) 773–793.