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2015 - Piezoresistive In-Situ Strain Sensing of Composite Laminate Structures
2015 - Piezoresistive In-Situ Strain Sensing of Composite Laminate Structures
2015 - Piezoresistive In-Situ Strain Sensing of Composite Laminate Structures
Composites: Part B
journal homepage: www.elsevier.com/locate/compositesb
a r t i c l e i n f o a b s t r a c t
Article history: Various methods have been developed to monitor the health and strain state of carbon fiber reinforced
Received 30 October 2013 polymers, each with a unique set of pros and cons. This research assesses the use of piezoresistive sensors
Received in revised form 23 September for in situ strain measurement of carbon fiber and other composite structures in multidirectional lami-
2014
nates. The piezoresistive sensor material and the embedded circuitry are both evaluated. For the piezo-
Accepted 24 September 2014
Available online 12 October 2014
resistive sensor, a conductive nickel nanocomposite sensor is compared with the piezoresistivity of the
carbon fiber itself. For the circuit, the use of carbon fibers already present in the structure is compared
with the use of nickel coated carbon fiber. Successful localized strain sensing is demonstrated for several
Keywords:
A. Carbon fiber
sensor and circuitry configurations. Numerous engineering applications are possible in the ever-growing
A. Smart materials field of carbon-composites.
A. Nano-structures Ó 2014 Elsevier Ltd. All rights reserved.
B. Electrical properties
1. Introduction bridge decks, composite beams, wind turbine blades, golf clubs,
compliant mechanisms, etc. The reported examples of a tensile
Carbon fiber reinforced polymers (CFRP) possess a unique set of specimen, a beam under bending, and a carbon-fiber pressure ves-
material properties that include high strength-to-weight ratio, low sel, illustrate uses of the methodology that could be adapted for
thermal expansion, and good fatigue characteristics; these benefits various engineering applications.
have led to rapid expansion in numerous areas of engineering
[1–3]. Given the various loading conditions and environments that
this relatively new material has to endure, there is a pressing need 1.1. Current strain sensing methods
for a wide range of structural health and condition monitoring
solutions. A monitoring solution that includes instantaneous strain Various methods exist for measuring strain in carbon fiber
sensing could provide useful feedback for control, actuation and structures. Fiber Bragg gratings, using embedded fiber optics mea-
data logging functions. sure strain [4,5], and other exotic and novel methods (e.g. [6–8])
This paper discusses the development of piezoresistive sensing are making tremendous progress towards providing a suite of solu-
solutions for carbon fiber structures. Of particular interest is the tions that will no longer be confined to expensive laboratory
embedded circuitry that enables the sensing of local strain in a situations.
component via connection to an external resistance meter. The More traditional methods include strain gauges composed of
two in-situ piezoresistive sensors that are evaluated are 1. embed- thin metal films [9]. The advantages of these types of gauges are
ded nickel nanostrand (NiN) nanocomposites and 2. neat prepreg that they are fairly simple to install, low cost, and have proved to
carbon fiber. For the connecting circuitry, nickel coated carbon be successful through years of use in industry. However, metal foils
fibers and carbon fiber prepreg alone are compared as pseudo- also have a very limited strain range, and because these gauges are
wires to the piezoresistive sensor; the probing configuration of adhered to the surface they are susceptible to damage. Further-
the external meter is also considered. Envisaged applications more, wires must be routed across or though the structure to carry
include strain and health monitoring of structural members, as the required signal to the monitoring unit.
well as the sensing of deflection in compliant components such Carbon fiber is itself piezoresistive by nature, and can thus act
as sports equipment and actuation devices. For control and data as a strain gauge [10–12]. However, transverse plies in a multidi-
logging purposes. Actual engineering components might include rectional laminate largely short circuit the piezoresistive response
of the carbon fiber structure [13]. The issue of routing circuitry to
⇑ Corresponding author at: 435 CTB, Brigham Young University, Provo, UT 84602, the point of interest must also be considered for this approach. Car-
USA. Tel.: +1 801 422 6316. bon nanotubes [14,15], carbon black [16], and nickel nanostrands
E-mail address: dfullwood@byu.edu (D.T. Fullwood). [17]. This paper will focus on nickel nanostrand composites due
http://dx.doi.org/10.1016/j.compositesb.2014.09.029
1359-8368/Ó 2014 Elsevier Ltd. All rights reserved.
M.C. Koecher et al. / Composites: Part B 69 (2015) 534–541 535
to their extremely large piezoresistive effect. Johnson et al. discov- the distance between particles (m) [17]. Thus the resistivity of a
ered that directly embedding a nickel nanostrand patch into unidi- nanojunction is a function of the inter-particle distance, s. As a
rectional carbon fiber laminates yielded a significant piezoresistive nanocomposite is strained s will change and a piezoresistive signal
response [18,19]. However, when the same method was applied to is obtained.
multidirectional laminates the signal quickly short-circuited and Another novel material, nickel coated carbon fiber (NCCF), is
no piezoresistive effect was found. To measure piezoresistivity in tested as the basis for the sensor circuitry in this paper. Carbon
multidirectional CFRP layups, a nickel nanostrand nanocomposite fiber receives a uniform coating of nickel through a chemical vapor
was insulated in fiberglass to resolve the short-circuiting issue, deposition process. These coated fibers are much more conductive
and embedded between the layers of carbon fiber. This method than bare carbon fiber and are often used to aid in electrical shield-
not only proved successful for measuring strain but also for detect- ing in carbon fiber structures [25]. Both the nickel nanostrands and
ing damage to the structure. However, due to the large stress con- the nickel coated carbon fiber were produced and provided by Con-
centrations induced by the embedded insulated patch, the strength ductive Composites Company (Heber, Utah). The structure of these
of the composites was severely compromised. materials can be seen in the SEM images depicted in Fig. 1. Along
The current paper will evaluate methods to measure strain in with these novel materials, a traditional unidirectional carbon fiber
multidirectional carbon fiber laminates without significantly alter- prepreg is used as the structural material that is to be monitored:
ing the strength of the carbon fiber structure. Piezoresistive sens- ZR6-P35, provided by Zoltek.
ing material will compose of either the carbon fiber structure Components with various pre-preg layups were created to
itself, or local regions of nano-composite with nickel nanostrands determine the capability and limitations of the embedded conduc-
added to the matrix. The signal path to the monitoring system will tive materials for in situ strain sensing. For initial sensor evalua-
be generated using only the carbon fiber or using embedded nickel tion, laminates were formed in configurations suitable for tensile
coated carbon fibers (NCCF). These coated fibers are at least three testing. Each carbon fiber laminate was composed of layers of pre-
times more conductive than bare carbon fiber [20] thus reducing preg cut to 250 mm 25 mm. Woven fiber glass tabs were
the amount of noise in the piezoresistive signal. The optimized adhered to the ends of the carbon fiber samples to insulate the
configuration of probes for detecting the composite strain will be sample from the metal grips of the tensile tester and ensure that
evaluated, and the resultant methodology will be tested in an these did not interfere with the signal.
engineering situation: a cylindrical carbon fiber pressure vessel. Each sample consisted of a sensor patch location and a sensor
patch material. The patch location refers to the area that strain is
2. Materials and methods to be measured and the patch material was either prepreg embed-
ded with NiNs or simply the carbon fiber prepreg itself. To limit
2.1. Materials variation and guarantee uniformity in the samples with embedded
nanostrands, 0.02 g of nickel nanostrands were filtered through a
Nickel nanostrands (NiNs) display a high strand aspect ratio and 60 mesh screen (250 lm) before being placed in a patch area of
a bifurcated structure that allows conductivity of a nanocomposite 19 mm by 12 mm. For carbon fiber and NiN patches the [0] direc-
to be obtained at small volume fractions of nanostrands [21]. tion (prepreg oriented parallel to the applied strain) and [90] direc-
When combined with a polymer matrix they form a piezo-resistive tion (prepreg oriented transverse to the applied strain) were
material that has been used as the basis for strain sensors [22]. evaluated as the sample was strained in the direction of its length.
The piezoresistivity of such nanocomposites has been most suc- As mentioned previously, the use of NCCF was assessed as a
cessfully modeled using percolation theory and a quantum tunnel- means of forming the sensor circuit. The alternative to NCCF was
ing mechanism [23,24]. With a sufficiently large volume fraction of to allow the signal to carry along the carbon fibers in the prepreg
conductive filler material nanojunctions will form between filler itself. It was hypothesized that the NCCF would better control
particles in which electrons can tunnel through the insulating bar- the signal flow and limit scatter and short-circuiting across the
rier. Once this occurs an electrical network is created through the cross plies of prepreg. Thus nickel coated carbon fiber was embed-
nanocomposite and it becomes conductive. The resistivity of a ded onto the surface of various samples and compared to control
nanojunction can be calculated using Eq. (1): samples with no embedded materials. Fig. 2 is an example of a
sample with embedded nanostrands and nickel coated carbon
2
pffiffiffiffiffiffiffiffiffiffi !
h 4p 2mk fiber. As can be seen in Fig. 2 a small gap was placed between NCCF
q ¼ 2 pffiffiffiffiffiffiffiffiffiffi exp s ð1Þ bundles at the patch location. The gap in the NCCF was required to
e 2mk h
ensure the signal traveled through the carbon fiber or NiN patch at
where h is the Planck constant (J s), e is the electron charge (C), m is the patch location. Table 1 shows the various sample configura-
the electron mass (kg), k is the tunneling barrier height (J), and s is tions tested. Also included in Table 1 are signal-to-noise ratio
Fig. 1. SEM images (from left to right) of nickel nanostrands and nickel coated carbon fiber (NCCF used courtesy of Nathan Hansen, Conductive Composites Company).
536 M.C. Koecher et al. / Composites: Part B 69 (2015) 534–541
Fig. 3. (a) Transverse collinear probe method, (b) box probe method, and (c) longitudinal probe method. In each method the gray lines represent the circuit path using either
the carbon fiber strands from the structure or embedded NCCF. EX+ and EX are the input and output current probes while HI and LO are the voltage reading probes.
M.C. Koecher et al. / Composites: Part B 69 (2015) 534–541 537
sensor. Tensile tests were performed on carbon fiber and NCCF and
compared in Fig. 4. It can be seen that the NCCF is much more con-
ductive than carbon fiber and does not exhibit piezoresistive prop-
erties. This suggested that using NCCF as pseudo-wires to the patch
does not contribute to the piezoresistive signal, and one can be
confident that the strain being measured is precisely located at
the patch location.
Table 2
SNR calculations for various samples with different probing methods.
Test number Orientation NiN patch NCCF Probe method Distance (cm) SNR Standard deviation
1 [0,90,0,90] No No Parallel collinear NA 0.0518 0.043
2 Transverse collinear NA 0.8767 0.099
3 Yes No Box 2.5 3.0018 1.202
4 4 0.1454 0.022
5 Yes 2.5 6.2408 2.448
6 7.5 0.4556 0.049
7 [90,0,0,90] Yes Yes Longitudinal 4 0.5099 0.196
8 14 0.4818 0.068
9 No 14 0.2534 0.032
538 M.C. Koecher et al. / Composites: Part B 69 (2015) 534–541
Table 3
Failure tests results.
3.4. Application
Fig. 11. Longitudinal strain measurement in pressure vessel. The vessel was
pressurized to 552 kPa and then rapidly depressurized starting at approximately
12 s. Fig. 14. Extreme piezoresistive changes when failure occurs (gray region) suggest
that failure can be detected in a carbon fiber structure.
4. Conclusions
Fig. 12. Strain reading on inside surface of pressure vessel. Pressure reached a max
of 827 kPa at approximately 17 s. Embedded nickel nanostrands and nickel coated carbon fiber
were evaluated as tools for in-situ strain sensing in a multidirec-
tional carbon fiber laminate. Tests were conducted via altering of
The results measuring the hoop strain on the interior surface the strain sensor patch and the connecting circuitry. Previous
can be seen in Fig. 12. It was assumed that as the pressure research has used the piezoresistivity of directly embedded nickel
increased there would be a tensile strain in the hoop direction nanostrand nanocomposites to measure strain in unidirectional
and thus a positive piezoresistive signal would be obtained, yet layup. Testing a variety of strain sensor configurations has shown
the results show a negative piezoresistive signal with increasing that directly embedding nickel nanostrands into a multidirectional
stress. These results are being attributed to the compression of laminate is ineffective for strain measurement and does little to
the longitudinal carbon fibers in the radial direction. As the pres- improve upon the piezoresistivity of the carbon fiber.
sure increased the carbon fibers were compressed into intimate Carbon fiber’s piezoresistivity is a good measure of strain, and
contact with one another creating a lower resistance (see thus a valid strain sensor, but if the carbon fiber is also used as
Fig. 13). Unfortunately, the data recording was interrupted before the current carrier to a probe location, the probing location must
complete depressurization and subsequently the vessel was dam- be extremely close to the area where strain is to be measured to
aged so a return of the resistance reading to its unpressurized state allow a discernible electrical signal to be obtained. The more con-
was not seen. Yet, the results still indicate a negative piezoresistive ductive nickel coated carbon fiber does not have the same piezore-
signal in the hoop direction. sistive properties as carbon fiber and hence is a better choice for
From the resistance measurements obtained it is evident that supplying a circuit from the sensor area to the probe location.
using NCCF as pseudo-wires to a patch location can facilitate Using NCCF as the connecting circuitry provides pseudo-wires to
remote strain measurements in a carbon fiber structure. Measuring remotely measure the strain at a desired location without piezore-
sistivity in the circuit affecting the signal. It has been shown that
the best results are obtained when the NCCF circuit is oriented
perpendicular to the carbon fibers that are in the sensor region.
Furthermore the optimal probe geometry involves the four-probe
longitudinal method. Future work will be performed to determine
if embedding the NCCF circuit between layers of a laminate can
accurately determine strain from arbitrary positions within a
sample.
Samples embedded with nickel coated carbon fiber and nickel
nanostrands were loaded to failure in tension to determine the
Fig. 13. Pressure causes the fibers to compress into one another thus lowering the adverse effects these materials have on the strength of the carbon
resistance in the hoop direction. fiber. It has been shown that the embedded materials do not
M.C. Koecher et al. / Composites: Part B 69 (2015) 534–541 541
significantly alter the strength of the structure. Thus, using embed- [8] Caminero MA, Lopez-Pedrosa M, Pinna C, Soutis C. Damage monitoring and
analysis of composite laminates with an open hole and adhesively bonded
ded NCCF is a safe, easy way to remotely measure strain within a
repairs using digital image correlation. Compos B Eng 2013;53:76–91.
carbon fiber structure without compromising structural integrity. [9] Tuttle M, Brinson H. Resistance-foil strain-gage technology as applied to
In addition to tensile and bending tests of laminates, a pressure composite materials. Exp Mech 1984;24(1):54–65.
vessel was built as a proof of concept application of remote strain [10] Wang X, Fu X, Chung DDL. Strain sensing using carbon fiber. J Mater Res
1999;14(3):12.
sensing using embedded nickel coated carbon fiber for the con- [11] Xiaojun W, Chung DDL. Continuous carbon fibre epoxy-matrix composite as a
necting circuit. When pressurized, longitudinal and hoop strain sensor of its own strain. Smart Mater Struct 1996;5(6):796.
were detected. Longitudinal strain yielded positive piezoresistive [12] Wang X, Chung DDL. Self-monitoring of fatigue damage and dynamic strain in
carbon fiber polymer-matrix composite. Compos B Eng 1998;29(1):63–73.
results while hoop strain yielded negative piezoresistive results. [13] Angelidis N, Wei CY, Irving PE. The electrical resistance response of continuous
It was also found that when the pressure vessel began to fail, the carbon fibre composite laminates to mechanical strain. Compos A Appl Sci
failure was detectable through an extreme change in the resistance Manuf 2004;35(10):1135–47.
[14] Park J-M, Kim P-G, Jang J-H, Wang Z, Kim J-W, Lee W-I, et al. Self-sensing and
reading. The tests illustrate the potential for applying such an dispersive evaluation of single carbon fiber/carbon nanotube (CNT)–epoxy
approach in a wide range of engineering applications for health composites using electro-micromechanical technique and nondestructive
monitoring, strain sensing and control of composite components. acoustic emission. Compos B Eng 2008;39(7–8):1170–82.
[15] Pham GT, Park Y-B, Liang Z, Zhang C, Wang B. Processing and modeling of
The distance between the location of measured strain and the conductive thermoplastic/carbon nanotube films for strain sensing. Compos B
probe location is modest in the tests (up to 14 cm); the ability to Eng 2008;39(1):209–16.
place the probes at much greater distances from the location of [16] Stübler N, Fritzsche J, Klüppel M. Mechanical and electrical analysis of carbon
black networking in elastomers under strain. Polym Eng Sci
interest is desirable, and may be increased with further optimiza-
2011;51(6):1206–17.
tion of the method. However, for many applications a surface probe [17] Johnson O, Gardner C, Seegmiller D, Mara N, Dattelbaum A, Rae P, et al.
at similar distances from the strained location may be acceptable. Multiscale model for the extreme piezoresistivity in silicone/nickel nanostrand
nanocomposites. Metall Mater Trans A 2011;42(13):3898–906.
[18] Johnson OK, Gardner CJ, Fullwood DT, Adams BL, Hansen G, Hansen N. The
Acknowledgement colossal piezoresistive effect in nickel nanostrand polymer composites and a
quantum tunneling model. Comput, Mater Continua 2010;15(2):24.
[19] Johnson TM, Fullwood DT, Hansen G. Strain monitoring of carbon fiber
This work was supported, in part, by a National Science Founda- composite via embedded nickel nano-particles. Compos B Eng 2013;43:
tion Grant, Contract Number: CMMI-1235365. 1155–63.
[20] Hansen G. The roles of nanostrands and nickel coated fibers in electrically
conductive composites design. In: Proceedings of 37th ISTC. Seattle, WA,
References Conference October 31–November 3, Conference; 2005.
[21] Hansen N, Adams DO, DeVries KL, Goff A, Hansen G. Investigation of
electrically conductive structural adhesives using nickel nanostrands. J
[1] Gibson RF. Principles of composite materials mechanics. 2 ed. Boca Raton: CRC
Adhes Sci Technol 2011;25(19):2659–70.
Press; 2007.
[22] Hyatt T, Fullwood D, Bradshaw R, Bowden A, Johnson O. In: Proulx T, editor.
[2] Strong AB. Fundamentals of composites manufacturing: materials, methods,
Nano-composite sensors for wide range measurement of ligament strain
and applications. 2 ed. Dearborn: Society of Manufacturing Engineers; 2008.
experimental and applied mechanics, vol. 6. New York: Springer; 2011. p.
[3] Roberts T. The Carbon Fibre Industry Worldwide 2008–2014. MTP; 2009.
359–64.
[4] Kim H-S, Yoo S-H, Chang S-H. In situ monitoring of the strain evolution and
[23] Zhou JF, Song YH, Zheng Q, Wu Q, Zhang MQ. Percolation transition and
curing reaction of composite laminates to reduce the thermal residual stress
hydrostatic piezoresistance for carbon black filled poly(methylvinylsilioxane)
using FBG sensor and dielectrometry. Compos B Eng 2013;44(1):446–52.
vulcanizates. Carbon 2008;46(4):679–91.
[5] Ling H-Y, Lau K-T, Su Z, Wong ET-T. Monitoring mode II fracture behaviour of
[24] Meilikhov EZ. Giant piezoresistivity of nanocomposites with the tunnel
composite laminates using embedded fiber-optic sensors. Compos B Eng
conductivity. Sens Actuators, A 2009;153(2):187–90.
2007;38(4):488–97.
[25] Composites C. Nickel Chemical Vapor Deposition (CVD) Coated Fibers; 2011.
[6] Fu T, Liu Y, Lau K-T, Leng J. Impact source identification in a carbon fiber
[26] Yoshimoto S, Murata Y, Kubo K, Tomita K, Motoyoshi K, Kimura T, et al. Four-
reinforced polymer plate by using embedded fiber optic acoustic emission
point probe resistance measurements using PtIr-coated carbon nanotube tips.
sensors. Compos B Eng 2014;66:420–9.
Nano Lett 2007;7(4):956–9.
[7] Habib F, Martinez M, Artemev A, Brothers M. Structural health monitoring of
[27] Johnson TM, Fullwood DT, Hansen G. Strain monitoring of carbon fiber
bonded composite repairs – a critical comparison between ultrasonic Lamb
composite via embedded nickel nano-particles. Compos: Part B
wave approach and surface mounted crack sensor approach. Compos B Eng
2012;43:1155–63.
2013;47:26–34.