Mol HCO 3 Vol. Aliquat

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M HCl = 0,1M

VP = 40 mL = 0,04L

* mol HCO3- = Va x MOH – VP x MHCL

= 0,05 x 0,1 – 0,04 x 0,1

= 0,005 – 0,004

= 0,001 mol
¿
[HCO3-] = mol HCO 3− vol. aliquat ¿

0,001 0,001
= 25 = 0,025 L = 0,04M

* MHCl = 0,1M

Vb = 36ml = 0,036 L

Vb x MHCl = mol HCO3- = 2. Mol Co32-

0,036 x 0,1 = 0,001 + 2 (mol Co32-)

36 x 10-3 = 0,001 + 2 (mol Co32-)

(36 x 10-3) – (0,001) = 2 (mol Co32-)

26 x 10-3 = 2 (mol Co32-)

2,6 x 10−3
= (mol Co32-)
2

1,3 x 10-3 = mol Co32-

1,3 x 10−3
* [Co32-] =
0,025 L

= 0,052 M
* Alkalinity = 2 [Co32-] + [HCO3-]

= 2 [0,052] + [0,04]

= 0,104 + 0,04

= 0,0144M

* mol Co32- dan HCO3- = M . U

= 0.144 – 50 ml

= 0,144 – 0,05 L

= 7,2 x 10-3

* gr Co32- = mol x Mr

= (7,2 x 10-3) x 105,99

= 0,76 gr

gr HCO3- = mol x Mr

= (7,2 x 10-3) x 84,04

0,61 gr

* Wt % Co32- dan HCO3


g found x 100
= g sampel

( 0,76+0,61 ) x 100
=
3,5 g

1,37 g x 100
= 3,5 g

Wt % = 39,14 %

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