IIFS-:!

006 I of H

PAPER · I
SECTION A

om
l. Answer 3ny four of Ihe ｦｯｬｊｷｩｮｾＺ＠
(a) Wh•l is crysllll1 ｗｲｩｬｾ＠ ou1J11.1nding cltaractenslic• of crystall ine $Olid. Deline unit ｣ｾ ｬ Ｎ＠ Give
thnmc.tcristlC pnrnmcle_r.j of unit cell.
( 1(\)
(h) Discu..s energetics of fonn.uion of sodium ｾ ｨｬｯｲｩ､｣Ｎ＠ Deline bond length. \\'hoi IS covalent

.c
mdiu.lf'?
( 1(\)
(c) Nnme ｾ＠ particle hnvins holh wave nnd pat1ick pmpertics. ｓｴｾＢ＠ tmCI:t1ainty principle. O rn

ce
uoe<•rltlinly principle be upplii:rllo tlying Jcl plane? \\1ty?
( 1(\)
(d) Write n short note on liqucl'nclitm <>I' g:ls"'!. l)iscuss (i) Jon-Dipole nod (ii) London dispersion
Jorccs. ra (I())
(c) Explain :
( J(}J
m
(i) Pseudo uoimolecular reaction
(ii) Pirsl-{)rder reotction
(iii) A"tiv3ted complm theory reoction rntl':!l
xa

(iv) Activotion energy

(n) Wba l are chcmicu l cells? Compore chomicol coils ond ｣ｯｮ＼Ｎｾ ｴ ｬｲｮｴｩｯ＠ cells. Woitc • hor1 note on
primary. fiecondo.r y ond fuel c.ells,
(20)
.e

(b) Who I is Amperomeuy? DiscuS5 t.·dutiquc of J\ntpcmmetrio titr31ions. Write shorl nolo on
lon Selective Electrodes.
(20)
w

3. (o) \Vritc f.1ctors influencing rnle of J reaction. Give charn.ctcrislic,s of a zcro-ordet· reaction.
Show th3t for ｾｲｯﾷ ｲ ､･ｲ＠ re.1c1ion l112 a: a.
w

(20)
(b) Stntc phase rulc. Discuss opplicotion of phose ruJe to two·oomponcml system. \Vhot U.
fractional di.•tillation'/ B.wlain 111 brief solubility of portia lly mt•c ible liquid pain; wilh
w

refen..>nce to \\ ater aniline S}'1tem.

(20)
4, (11) Write limitntions ot' fU'Sl law of thermodynamic•. E:(plain (I) Entropy and (ii) Free energy.
State second lo\1 of thermodynamics in diJferent forms. For a o'e3etion at 25" l'. 1:0lhalpy
｣ｬｴｯｮｧｾ＠ ( ｾｩ Ｉ＠ :md entropy ｣ｨ｡ｵｧｾ＠ {liS ) arc> -11.7 Ｑ Ｐｾ＠ J ouolo1'1 ond -105 Jmol'1 K'1
respectively. Find wholhcr this reaction is sponl3neous or noL (20)
(b) What ill callllysU.'I Give ehnractcristi"' of" e313lyst. Enumcrutc difl'=n:nl typcs of C31.'1lysis.
\Vhol are odsorplion isotherms'/ Write mechanism ofre:tction on halerogenel)us ""I.'! lysis.
(20)
 SECTION 8

5. Auswco· any four oftloc Jollowing:

(a ) Discu•s in brief steo'<IOisomerisru ｡ｭｯｮｾ＠ woo'tliuotioo compounds us ing s uitable illustrations.
( 10)
(h ) ｗ are actiuons? llo"' enrichment of uranium is corned out fi>r nuclear fuerl Write in hrief
ｨｾｴ＠
how ur>niuuo <:.'Ill be '"covered fi·oru fission products.
( 10)

om
(c) ｏｩｾ｣ｵｳ＠ ''arious rout<s of dccny of c)(citcd stntc.' attllin.ed through absorption ofl i!)ht.
(10)
(d) Write in brief • note <)n nitrogen foxation on naJure and prod\oction of ;nllmonia for
｣Ａｬｮｾｵｭｰｴｩ＠ b)' ccll growUo .
!10)

.c
(e) Explain :
(10)

ce
li) Acid-bas" reaction•
(ii) Leveling ef!ect wilb ref<m.'1lco to ｡ｮｨ ｹ､ｲｯ ｕ＾ｾ＠ ｾｵ ｬ ｰｨｵｲｩ ｣＠ ocid os a solvenl
6. D iscu$s role of {i) Chromium, Iii) Iron. (iii) Nickcl•ml (iv) Copper in biological &yst>."tns.
ra (20)
(b) \VItal ＾ｲｾ＠ fo:n·odoxiu.•? Uow ｌｨｾ ｹ＠ lllke part in living procc:s•es? Discuss metuJ ious as charge

(20)
m
7. (a ) Dtidly rueuliuu ｅｦｾ｣ ｬｩ｜Ｇ｣＠ AtoutiQ Numbct· tulc iu u•ausition. melnl complcxe&with s uiwble
ex.•mples. \\'rite Jimitltinn.< of valeuee bond tlteory. Give MO co01·gy level dia!lrotu ｦｯｲ ＩＮｾ＠
type oetnhedr•l conlpl<lll involving ct-bond only.
xa

(lO)
(h) Explain (i ) • plitliug ot d-orbitol• in ｶ｣ｬ｡ｾ､ｲｯ＠ oud tetrahodt·ol complt:.<e>;. (ii) ｣ｲｹｾ ｢ｬ＠ lldd
, Mbiliz.i•tioo c"rrcrgy and show hnw cry•tnl field theory con be 3J>J>Iied to <l)(pllin $pc>ctra l and
magnetic properties nfCO()fdinnlion <:<>mpvunds.
.e

('20)
8. Answer ony Jour of the following
(n) Write an account on ocrie> of complc.< n:octions in the chloropln•ts. Describe in brief
w

Photosystem- 1 ond l'hoto;;ystem- 11.

( I())
(b) D.-cuss bonding in metnl carbonyls.
w

( J(})
(c) Defino and discuss applicntion.'l of cnnunical portilion fwction.
w

(10)
(d) Dis\:USS r.u·e enrUt elemdnls IRBE) witJt reference to -
(i) IotTes tria I ｾ｢ｵｮ､＠ of occorreoce
(ii) isola!ioo
(iii) uses
(vi') electronic configuratinn
1I 0)
(c ) ｄ ｯｳ｣ Ｑｩ｢ ｾ＠ u.<c of Bom-Habc-r cycle lu detunnme tloe lattice energy uf ionic .,o]itls.
(10)
 IFS-2006 J ot'8

CHEMISTRY

PAPER · II
SECTION A

om
I. Answer any four of dte ｦｯ ｬ ｯ Ｂ ｾ ｮｧ＠ (in about 150 words each) :
( l0 > 4- 40)
(a) (i) Commem upon me stabillly of A. B, C and D. ｾ＼ ｰ ｬ ｡ｩ ｮ＠ d1e bas1s of your prediction m
mi11imum possible words·
OH
u:; 00

.c
ｾ＠ (r,
A 8 c D

x· &··<( ce
(i•) SlfUctures of' four hydrocarbons A-D are

!)
ｴ ｣ｵ Ｎｾ ｮ Ｎ＠
ra
L(
A ' 8 C D
m
One of these 1s much more ac1dic than the o01ers. Preediot wh•ch one •s
J!IVe11 here.
that and e-xplain why it ｩｾ＠ unusually ncid1c
(b) Account for !he follow10g observatiOns made for me reacnon giVen below:
1 \ ｾ＠ on-Q
_
xa

F\
ｾ ｴｯ ＮｦｬＴｾ ｾ ｸ＠
p

(t)
.
This condensation is t'atalyscd by only ('H" fon and not by ions like OH or 0 /i t.
•.
.e

(ia) Eloctron anracting subshtutems u1lubat dus reaction.

(iii) Electron dona1ing substituents 100 retard this reaction
(c) Provided mechanism to ralaooaliu the fonnation of the follo\vtng products:
w

l
"
( t,
Cf ｾ Ｍ ｃ ｬ Ｑ＠
0
w

Ｈｩ ｩＩ ｵ ｴ ｾ＠
w
 o·
4 of8

McO-o-- .

oM·-
OR

OR
"·-Q·-
···--0-- OR
0-·
o- OR k (R = ···· (; 11 ,-l: II.)

om
(e) (i) Predic-t which rotatory process (conrotatory or disrotatory) is involved in the
following transformations·

o-o CF()

.c
｡
ｾ ｾｒ＠
H
Al e

ce
(li) Predict mechanism of formation of following products

c(Y"
' u en,
,+ &1
, H, H.
ｾｶ＠
H'" ,..-qu +
0 C"
n.

ｾ
ｵ Ｌ＠

& H•CU .• +-
(:H,
ra ｾ tlｾ＠
'
+

(a) Show how ｾｴ･＠ following products could be formed.

m
(t) Ｐ＼ｾ Ｎ＠ ｾ｡Ｚ＠ + ONR
xa

major III IIUir

(it) o-N, ｐｨｎｾｈ＠ I .. ｏ ｎｾ

li
ｐ ｢＠
.e

4+
II
w

r t:-11·
w

8
ｾＮＭ ＧＡ｜Ｎｾ＠
II
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(b) Explain the following observations;

(2 x4 = 8)
(i) Among ｾｴ･＠ nor-bomatte derivsti ves lhe acetolysis of anli -tosylate C is 10 11 times
faster than A. while ｾ ｴ･＠ acetolysis ()fthc syn· isomcr B is only 104 times faster than t\..
 5 ｬＩ ｦｾ＠
(1i) · trans'- I·Hromo-4-t-butyl ｣ｹ ｬ ｯ ｨｾｸ｡ｮ･＠ tmdergoes E2 ｲ ｾ｣ｴｩｯｮ＠ m ｰｲｾｮ｣･＠ of
0Et
ion much mom slowly than the corresponding 'cis· isomer.
3. (a) Pred•ct U1e preducts of rhe follow•ng reacilous and provtde evidence to show that il1ese
reactions lake place witl1 the retenuon of couJigurallon m the m•grallilg groups m appropnate
compounds;

om
.c
(hl Provide mechanism for the following transformations .
(6 • 2= 121

ce
ｾｆＢｦＮ［＠
Ｈ ｩＩ ｾ＠ ra
m

(c) (i I The reaction gtven below lakes place wid1 a strong nuclcophilc (OH ) under second
order ｣ｾｊ､ ｩ ｴｩｯｮ ｳ Ｎ＠ The rate of reaction is found to be several thousand hmes faster than
xa

the rate of normal substitutlon of hydroxide ion on 2·chiorobutane under similar

conditions, Propose a mech<mism t(l explain d1o enhanced 111ie and the rearrangem<nt
observed m this rcact1on.

ｅ ｴＬｎｾ＠
0
.e

Bu 1o

OH
w

Quinoline ts fot·med from the reacuon of ani line and aci'Olctn (genera!ed in Sttu from
ｾ ｉ ｴ Ｉ＠
glycerol) 10 the Skraup reaction when mtiline, glycerol and a mild oxtdizmg agent are
heated together m H2SO•. ｂｴｾ＠ wben the smne reaction 1s earned out, Ｈｷｲ ｾＱ＠ no glycerol
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use<t "' tl1e <>!action) by the addition or aci'Olem frotn outStde in the reaetion ｭ ｩ ｾ ｴｵ ｲ･ Ｌ＠
qulnolinc is fonncd in lnw yield. Explain.
(h2 = 10)
w

!a) Show how the followmg ｌｲ ｡ｵｳｦｯｲｴｮ＼ｾ ｩ ｯ ｮｳ＠ could take J)lacc
(5x3=15)
 ' (i) (""<-QQM·
I ｖＧ ｴｾ ｯＮｷ ｾ＠
,• • ,.,.. . ex
•(li) u· ｲＬ ｵ Ｌ ｲＢ ﾷ Ｇ ｾ＠ , uc·"·
...cu ｩ Ｇｾｬ ｬ＠
) It

I1/(1) Qfi ｾ＠ 11 ->•t H·!II .........,.

UJO_

" {H,

QQｾ＠
CH,

om
(b) Identify ｴｨｾ＠ prt>ducts inthi! following sequence of ｛＼Ｚ｡｣ｴｩｯｮｾ ［＠ (9-d = 18)

(Y
(
i)
u til LiAtH,
(ill H.O' t
A (i) CS·"
liiJCU 11
KOfl IJo B

Hc:at
c
a<C'L

.c
CR 1 LI ,O " Beat
(ii) A B
N•O H

ce
tiBS
c
(c) Explain the following ｯ｢ｳ･ｭｾｴｩｮ Ｚ＠ (4 + 3 = 7)
Ci ) Cyclohexanone does not gtve the reaction With the yhde of C6H5COGI1Br + PhJP.
However, when phosphonate ester is used al d1e plac.e of tripbeoyl pbosplwte. the
ra
react1on 11\kes place.
(ii) The Otermal f4 I 2] cycloadd•tion of I. 3-buladtene •s ･｡ｾ ｹ＠ but [2 I 2J addition is
diJ'ftcuiL
m
SECTION ·B
5 Answer illlY f9ur of the followmg (in about l 50 words each) ( JQ X 4 = 40)
xa

(a ) Perdict mechamsm ofthefollowmg reactions:

(il C:t' ,, ,....-'\. ｾ＠

cn ,ou., l.r"-OCH,
.e

(ii) 0. N,CH-C-OC,H, ｾ＠
ｾ＠ I
QJ-oc,u,
w

(b) ldentiJ)t Ote produc1s in the following sequence of reactJons and indicate how these could be
fomted;
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(t) 6 mCPB A A LIAIH,

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(ii) ｾ ｐ ｉ Ｎｐｃｈ Ｌ＠ A 0>0. Ｘ ｾ＠ ｾ ｈｏ＠

(cl Pred1ct the products expected lobe fom1ed in the following rencnons and gtve mechamsni of
thetr formation:
 7 of 8
f1• B,R,, THF
(I) INI II 0,. ｾｴ ｏ ｬ＠
H,

(h) c:t:ro ｴﾣＱＧＹｾ Ｎ＠

Account for the formntior1of li•llowing products in the rc110tion given l>elo11

o· ｾＭ Ｂｲﾷｍ o'·.u. a··.｡ﾷ oo

(ct)

ﾷ ﾷ＠ ﾷ ｾ＠ +

om
A 3 C [) U f

ｬｾＩ＠ Ilow will )'\'>U distinguish bctWet'll the tilllolling on the llasis ol' 111 NMR spectroscopy:
(l) Equatorial and Jlxiul protons ol'the cyclohexan.: rtng.
til) Inter and intermolecular hydrogen bonding
6 tu) Indicate the mechanism of(omtation of the following products. (5 ｾ＠ 2 = 10)

.c
(i) -o J4-v.-o .-t:J
ｾ＠ ＮＡｾ＠ ｾＮ｣
..ｾ＠ Ｐｾ＠
ｮ＠

ce
til) c}.{H, ｾ＠
(b\ Predict the products fonncd tn the following sequence of ren(;tions : ra ｃＷｸＲ ］ Ｑｾ Ｑ＠

{I) ｾ＠ {ll"tkll.J t A ftr:-0/HP B HIJU.. C

S (11) C01
t (m)H.O'

A Ｎ｡＾ｾＡＬ｜＠ c
m
Ill) (J)BJ\ • A 9 I.Wll,
ctJ (II) X.,OD;

(0) til When cyclopcntcnc is treated with osmium ｴ｣ｲｯ Ｎ ｾｩ､｣＠ nod the osmatr ester hydrolysed
"itlt aqut'<lus sodium sulphite. the product is n cis I, .2-diol. H<mever, when it is
xa

treated first with peracid und U1e11 h)drolysed with acid, a lrans-1. 2-<liol is formed
E.\pluin.
(ii) Lithium <tluminium hydride cOn\'erts acid chlondes dire<:ll) ttl alcohols. bul when
litltium-tbutoxy aluminium hydride fs used at Uti! place of W\11. aldehydes ure fomted
.e

ｾ ｾ＠ the main products of the reduel ion. Explnin.

14 X 2 8)
(d ) (I) Compound A shows 1111 ･ｳｾＭｰｴｩｯｮｵｬｹ＠ low cnrhonyl ｳｴｲｾ｣ｨｩｮｧ＠ fl'l:quency in IR
w

spccuum ｴｾｬ＠ V.,.., = 16JO cm' 1) thitu fl (V..., = 16$0 cm·1) ｦＮｰｬｾｩｮ＠

CJ-. ｾ ﾷ＠
w

• n
Iii) The ru:tss speer rum of un nldcbyde(.moloculnr funnula Ct,HnOILM• " 100. S%[. exhibits iQIIS
ul m/z. 71115%): 8 (95%) and 43 ( J0<!%1. Propose u structure to tins uldeh)'de.
w

7 (u) Point out the dill'creucc betwc:eu the structures of RNA and DNA.
(b) Ii) Draw 'lntcttlrcs of the rcpc'Utlug ttnils of the l(tllowiug polymcrtc murerials:
CAl Tenon
tD) Terylcnc
!C) Nylon
(D) Natural ruhber
 Mｯｦｾ＠
Oi) Which process. cahonicor ruuomc polymeriattion is suitable for the preparation
of poly (metha acrylme)? Explain.
(iii) The polymers poly (viny l chloride) and poly Ｈｶｩｮ ｾ ｬｴ ､･ｮ＠ chloride) both are prepared
｢ｾ＠ frro radical processes. but the former is amorphous and !he latter Is highl)
crystalline. EKplain
(i•l ｐｯ ｬ ｹ･ｾＱ ｹ ｬｯ ｮ ･＠ cmmot be prepared by callonic poly meri zation whereas polystyrene can.
ll'plsin (4 •·-l·q 14=16)
(C) (i) Predict the frequency shell of carbony I absorplion m ｾ Ｑ･＠ IR spectrum of compounds
(A - F) gi \'en below·

om
d 0 dd· OHd
i\ B C 0 & F

(II} Predict the approXImate \'alue on.,.,, for the K- " • mtd 11-.1 • (ransitioos of each
compound A - 0 given belo1v: ('l+S= 17)

.c
co 0) co;? aCCr

ce
A B C 0
(a) Deduce Ihe structure of a compo1111d on the h3SiS oft he data gi ven below
(i) M olecular fonnula ; C 11 H,,O,
(if) TR (em') ; 1720
(iii) 'H NMR (o-,) ; 1.0 (6H , d)
2.l(J A. m)
4.1 (2H. tl)
ra
7.8 (SH, •n)
m
lbl ｔｾＺｃ｡ｴｭ･ｮ＠ of acetone 1\oth an h) drous amn10n1a lin presence of anhydrous calcium chloride: a
common drying agent) forms a CJYS1alhne product A Spectrnl data of' A is given below
Deduce ｾＱ･＠ structure of A on the basis of ｾｬ ｩ ｳ＠ data. t 12)
xa

CompowJdAICoHn NOJ
(i) MS tmlz) • 155 (M ), ｊｾ ｕ＠
1
(i i) IR(cni ) · 3350 (sharp), 2850 - 291ill. 17115 (s)
!iii) tHNMR(o,..., ) : 1.2{12 H, disappears in Ｐ ｾ ＰＩ＠ 2.3 (4H, s)
.e

Ｈ ｾ Ｉ＠ Establish the structure of a compound on the basis of !he spectrul ､｡ ｴ ｵｾ［ＬＧｩ ｶ ･ｮ＠ below,
(20)
(i) Molecular fornlUla ｣ｾ Ｎ ｯ＠
w

(h) MS, m/1. ( Relauve abundMct>) 132 (l\11 - ｾＰ Ｅ Ｉ＠ 131(1()()";'<,), 1()4 (50%).
1()3 (50%). 78 (30%), 77 (40%)
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(iii) l fll ;._ 241! nm, ( t5.()1)1.))

f..;._., I
(il•) IR (em· •) 31\611 (m), 31120 (m), ＲｾＰ＠ (n\), 275\1 (m).
w

l li751,·s). lfi25 (m). 1450 (s). 750 (vs),

680 (s)
(II) 'HNMR 6 70 (21-L tid)
ｾ ＬＮ ｬ｟＠ JJ = 7.5 H1
J2 = 15.5 Hz
7 -15 (S H, m)
'1.70(1 H. d)
J 1 = 7.5 Hz